JP2020203860A - 水中油型乳化組成物 - Google Patents
水中油型乳化組成物 Download PDFInfo
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- JP2020203860A JP2020203860A JP2019112582A JP2019112582A JP2020203860A JP 2020203860 A JP2020203860 A JP 2020203860A JP 2019112582 A JP2019112582 A JP 2019112582A JP 2019112582 A JP2019112582 A JP 2019112582A JP 2020203860 A JP2020203860 A JP 2020203860A
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229940098695 palmitic acid Drugs 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
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- 230000002087 whitening effect Effects 0.000 description 1
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- 230000037303 wrinkles Effects 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Abstract
Description
(a)トコフェリルリン酸エステルおよび/またはその塩
(b)デキストリン脂肪酸エステル
(c)25℃で液状の油性成分
(d)25℃で固形状および/または半固形状の油性成分((b)を除く)
を含有することを特徴とする水中油型乳化組成物を提供するものである。
得られた水中油型乳化組成物を、20℃の恒温槽にて24時間保管した後、ガラス電極式水素イオン濃度計(堀場製作所製、F−51)を用いて常法により行った。
得られた水中油型乳化組成物を、70mlガラス瓶に充填し、40℃の恒温槽にて6ヶ月保管し、3ヶ月後および6ヶ月後の外観変化を目視にて、また乳化粒子の変化を顕微鏡にて評価し以下の基準により判定した。
◎:6ヶ月間変化なく良好である
○:6ヶ月後で乳化粒子の凝集がわずかに認められる
△:6ヶ月後で乳化粒子の凝集および/または分離が認められる
×:3ヶ月後で乳化粒子の凝集および/または分離が認められる
女性専門パネル(20名)による使用試験を実施した。得られた水中油型乳化組成物を就寝前に使用し、塗布直後および翌朝の「べたつきの無さ」、「しっとり感」、「ハリ感」について下記の基準に従って評価した。
(1)べたつきの無さ
◎:18名以上が、べたつきを感じないと判定した。
○:14〜17名が、べたつきを感じないと判定した。
△:9〜13名が、べたつきを感じないと判定した。
×:べたつきを感じないと判定した人が8名以下。
(2)しっとり感
◎:18名以上が、しっとり感を感じると判定した。
○:14〜17名が、しっとり感を感じると判定した。
△:9〜13名が、しっとり感を感じると判定した。
×:しっとり感を感じると判定した人が8名以下。
(3)ハリ感
◎:18名以上が、ハリ感を感じると判定した。
○:14〜17名が、ハリ感を感じると判定した。
△:9〜13名が、ハリ感を感じると判定した。
×:ハリ感を感じると判定した人が8名以下。
A部を均一に混合した中に、均一に加熱混合したB部を少しずつ添加しながら撹拌し80℃に加温する。均一に混合したC部を80℃に加温した後、A+B部に添加し、乳化する。その後、撹拌しながら30℃まで冷却して水中油型乳化組成物を得た。
(成分) (重量%)
1.トコフェリルリン酸ナトリウム 2.0
2.グリセリン 6.0
3.パルミチン酸デキストリン 0.5
4.メドウフォーム油※11 4.0
5.ミリスチン酸オクチルドデシル※12 3.0
6.ジフェニルシロキシフェニルトリメチコン※13 2.0
7.ワセリン 5.0
8.130°パラフィン※14 1.0
9.水添ホホバ油 3.0
10.精製水 残 余
11.カルボマー 0.2
12.キサンタンガム 0.2
13.2−アミノ−2−メチル−1,3−プロパンジオール 1.0
14.1,3−ブチレングリコール 7.0
15.ジグリセリン 5.0
16.香料 0.1
17.サクシノイルアテロコラーゲン液※15 5.0
18.水溶性コラーゲン液※16 5.0
成分1、2を均一に混合させた中に、均一に加熱混合させた成分3〜9を少しずつ添加しながら混合し80℃に加温する。均一に混合した成分10〜15を80℃に加温した後、成分1〜9に添加し、乳化する。その後、撹拌しながら冷却し、70℃で成分16を添加、50℃で成分17,18を添加、30℃で冷却を停止させ乳化組成物を得た。
(成分) (重量%)
1.トコフェリルリン酸ナトリウム 2.0
2.グリセリン 6.0
3.パルミチン酸デキストリン 1.0
4.スクワラン 3.0
5.イソノナン酸イソトリデシル※17 2.0
6.トリイソステアリン酸トリメチロールプロパン※18 2.0
7.ラウロイルグルタミン酸ジ(オクチルドデシル/フィトステリル/ベヘニル)
※19 2.0
8.ベヘニルアルコール※20 1.0
9.水添ホホバ油 3.0
10.マイクロクリスタリンワックス※21 1.0
11.マカデミアナッツ脂肪酸フィトステリル 2.0
12.精製水 残 余
13.カルボマー 0.1
14.キサンタンガム 0.2
15.ヒアルロン酸Na 0.1
16.2−アミノ−2−メチル−1,3−プロパンジオール 1.0
17.1,3−ブチレングリコール 10.0
18.グリセリン 8.0
19.香料 0.1
成分1、2を均一に混合させた中に、均一に加熱混合させた成分3〜11を少しずつ添加しながら混合し80℃に加温する。均一に混合した成分12〜18を80℃に加温した後、成分1〜11に添加し、乳化する。その後、撹拌しながら冷却し、70℃で成分19を添加、30℃で冷却を停止させ乳化組成物を得た。
※2:レオパールKL2:千葉製粉社製
※3:クロピュア マカダミア−LQ−(JP):クローダジャパン社製
※4:SQUALANE:岸本特殊社製
※5:Floraesters 30:Floratech社製
※6:クロラータム V−SO−(JP):クローダジャパン社製
※7:Plandool−MAS:日本精化社製
※8:AMPD Ultra PC:ANGUS CHEMICAL COMPANY社製
※9:レオパールMKL2:千葉製粉社製
※10:水酸化カリウム:東京応化工業社製
※11:クロピュア メドフォーム−LQ−(JP):クローダジャパン社製
※12:ODM:高級アルコール工業社製
※13:シリコーン KF−56A:信越化学社製
※14:Paraffin Wax 130:日本精蝋社製
※15:シージェムコラーゲンAS:片倉チッカリン社製
※16:アルフォマリン−CL:テクノーブル社製
※17:KAK 139:高級アルコール工業社製
※18:KAK TTI:高級アルコール工業社製
※19:コスモール 168ARV:日清オイリオグループ社製
※20:BEHENYL ALCOHOL:高級アルコール工業社製
※21:MULTIWAX W 445:SONNEBORN社製
Claims (5)
- 次の成分(a)〜(d)
(a)トコフェリルリン酸エステルおよび/またはその塩
(b)デキストリン脂肪酸エステル
(c)25℃で液状の油性成分
(d)25℃で固形状および/または半固形状の油性成分(成分(b)を除く)
を含有することを特徴とする水中油型乳化組成物。 - pHが8.5〜10.5であることを特徴とする請求項1記載の水中油型乳化組成物。
- 成分(a)トコフェリルリン酸エステルおよび/またはその塩の含有量が0.5〜5重量%、成分(b)デキストリン脂肪酸エステルが0.1〜3重量%、成分(c)25℃で液状の油性成分および成分(d)25℃で固形状および/または半固形状の油性成分の合計含有量が5〜40重量%であることを特徴とする請求項1または2記載の水中油型乳化組成物。
- 成分(d)/(成分(c)+成分(d))の重量比が0.3〜0.8であることを特徴とする請求項1〜3いずれか1項記載の水中油型乳化組成物。
- 界面活性剤を含有しないことを特徴とする請求項1〜4いずれか1項記載の水中油型乳化組成物。
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