JP2020079405A - 汚れリリースポリマーの使用方法 - Google Patents
汚れリリースポリマーの使用方法 Download PDFInfo
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- JP2020079405A JP2020079405A JP2020013832A JP2020013832A JP2020079405A JP 2020079405 A JP2020079405 A JP 2020079405A JP 2020013832 A JP2020013832 A JP 2020013832A JP 2020013832 A JP2020013832 A JP 2020013832A JP 2020079405 A JP2020079405 A JP 2020079405A
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- JP
- Japan
- Prior art keywords
- article
- alkyl
- cleaning
- surfactants
- alkaline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 title claims abstract description 112
- 239000002689 soil Substances 0.000 title claims abstract description 61
- 229920000642 polymer Polymers 0.000 title claims abstract description 45
- 238000004140 cleaning Methods 0.000 claims abstract description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims description 118
- 239000004094 surface-active agent Substances 0.000 claims description 69
- 238000005406 washing Methods 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000003513 alkali Substances 0.000 claims description 26
- 239000003599 detergent Substances 0.000 claims description 25
- 102000004190 Enzymes Human genes 0.000 claims description 23
- 108090000790 Enzymes Proteins 0.000 claims description 23
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
- 239000004382 Amylase Substances 0.000 claims description 7
- 102000013142 Amylases Human genes 0.000 claims description 7
- 108010065511 Amylases Proteins 0.000 claims description 7
- 235000019418 amylase Nutrition 0.000 claims description 7
- 150000004760 silicates Chemical class 0.000 claims description 7
- 108091005804 Peptidases Proteins 0.000 claims description 6
- 239000004365 Protease Substances 0.000 claims description 6
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 150000004679 hydroxides Chemical class 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 abstract description 18
- -1 etc.) Chemical group 0.000 description 78
- 125000000217 alkyl group Chemical group 0.000 description 51
- 125000004432 carbon atom Chemical group C* 0.000 description 42
- 150000001875 compounds Chemical class 0.000 description 30
- 230000002209 hydrophobic effect Effects 0.000 description 29
- 239000002253 acid Chemical group 0.000 description 27
- 239000000126 substance Substances 0.000 description 25
- 239000002738 chelating agent Substances 0.000 description 22
- 150000003839 salts Chemical class 0.000 description 20
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 19
- 239000002736 nonionic surfactant Substances 0.000 description 19
- 239000000463 material Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000004744 fabric Substances 0.000 description 16
- 150000001412 amines Chemical group 0.000 description 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 14
- 239000002280 amphoteric surfactant Substances 0.000 description 14
- 239000000835 fiber Substances 0.000 description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- 239000007844 bleaching agent Substances 0.000 description 13
- 239000003093 cationic surfactant Substances 0.000 description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 12
- 229920001296 polysiloxane Polymers 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 150000007513 acids Chemical group 0.000 description 11
- 150000007942 carboxylates Chemical class 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 9
- 239000003752 hydrotrope Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 9
- 239000002888 zwitterionic surfactant Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 8
- 150000001298 alcohols Chemical group 0.000 description 8
- 125000000623 heterocyclic group Chemical group 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 244000060011 Cocos nucifera Species 0.000 description 7
- 235000013162 Cocos nucifera Nutrition 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 150000001720 carbohydrates Chemical class 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- 239000003518 caustics Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 125000001165 hydrophobic group Chemical group 0.000 description 6
- 125000006353 oxyethylene group Chemical group 0.000 description 6
- 150000004965 peroxy acids Chemical class 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 229920005646 polycarboxylate Polymers 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 150000003863 ammonium salts Chemical class 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 235000013772 propylene glycol Nutrition 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- 150000003512 tertiary amines Chemical class 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 150000002148 esters Chemical group 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 239000010705 motor oil Substances 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 4
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical class OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000002015 acyclic group Chemical group 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 238000005804 alkylation reaction Methods 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 159000000001 potassium salts Chemical class 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 230000003381 solubilizing effect Effects 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 125000000547 substituted alkyl group Chemical group 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 2
- GTXVUMKMNLRHKO-UHFFFAOYSA-N 2-[carboxymethyl(2-sulfoethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCS(O)(=O)=O GTXVUMKMNLRHKO-UHFFFAOYSA-N 0.000 description 2
- XWSGEVNYFYKXCP-UHFFFAOYSA-N 2-[carboxymethyl(methyl)amino]acetic acid Chemical compound OC(=O)CN(C)CC(O)=O XWSGEVNYFYKXCP-UHFFFAOYSA-N 0.000 description 2
- CZUSWJYAWTXIIZ-UHFFFAOYSA-N 2-carboxyoxybenzenesulfonic acid Chemical compound OC(=O)OC1=CC=CC=C1S(O)(=O)=O CZUSWJYAWTXIIZ-UHFFFAOYSA-N 0.000 description 2
- REICWNSBQADONN-UHFFFAOYSA-N 2-hydroxy-n,n-dimethyldodecan-1-amine oxide Chemical compound CCCCCCCCCCC(O)C[N+](C)(C)[O-] REICWNSBQADONN-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- UXJZLKNQKNMGDH-UHFFFAOYSA-N 3-dodecoxy-1-hydroxy-n,n-bis(2-hydroxyethyl)propan-1-amine oxide Chemical compound CCCCCCCCCCCCOCCC(O)[N+]([O-])(CCO)CCO UXJZLKNQKNMGDH-UHFFFAOYSA-N 0.000 description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Natural products CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical class OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical class OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 2
- 125000004442 acylamino group Chemical group 0.000 description 2
- 239000012615 aggregate Substances 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical group OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 2
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
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- QPCDCPDFJACHGM-UHFFFAOYSA-K pentetate(3-) Chemical compound OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O QPCDCPDFJACHGM-UHFFFAOYSA-K 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- LUSSRKMAXZEBEC-UHFFFAOYSA-N phenyl 4-nitrobenzoate Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(=O)OC1=CC=CC=C1 LUSSRKMAXZEBEC-UHFFFAOYSA-N 0.000 description 1
- YNFAEFZZHQSSDP-UHFFFAOYSA-N phenyl acetate;sodium Chemical compound [Na].CC(=O)OC1=CC=CC=C1 YNFAEFZZHQSSDP-UHFFFAOYSA-N 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- YSWYYGKGAYSAOJ-UHFFFAOYSA-N phosphane Chemical compound P.P YSWYYGKGAYSAOJ-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 235000019338 polyoxypropylene-polyoxyethylene polymer Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- UTKKIJMYLPPCSV-UHFFFAOYSA-M potassium;2-benzoyloxybenzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 UTKKIJMYLPPCSV-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000003642 reactive oxygen metabolite Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229920006261 self reinforced polyphenylene Polymers 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 150000004666 short chain fatty acids Chemical class 0.000 description 1
- 235000021391 short chain fatty acids Nutrition 0.000 description 1
- FXRCBEABKXBWGV-UHFFFAOYSA-M sodium 2-sulfonylethyl carbonate Chemical compound C(OCC=S(=O)=O)([O-])=O.[Na+] FXRCBEABKXBWGV-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- MIKSWWHQLZYKGU-UHFFFAOYSA-M sodium;2-benzoyloxybenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 MIKSWWHQLZYKGU-UHFFFAOYSA-M 0.000 description 1
- OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 229940006295 sulfonated oleic acid Drugs 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000004354 sulfur functional group Chemical group 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000011975 tartaric acid Chemical class 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- XSROQCDVUIHRSI-UHFFFAOYSA-N thietane Chemical compound C1CSC1 XSROQCDVUIHRSI-UHFFFAOYSA-N 0.000 description 1
- VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 1
- 150000003553 thiiranes Chemical class 0.000 description 1
- ZKWDCFPLNQTHSH-UHFFFAOYSA-N tribromoisocyanuric acid Chemical compound BrN1C(=O)N(Br)C(=O)N(Br)C1=O ZKWDCFPLNQTHSH-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- OZHBUVQCJMARBN-UHFFFAOYSA-N undecylamine-n,n-dimethyl-n-oxide Chemical compound CCCCCCCCCCC[N+](C)(C)[O-] OZHBUVQCJMARBN-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
Description
本出願は、2015年10月28日に出願された米国特許出願第14/925,195号に対する優先権を主張する。本特許出願の内容全体は、明細書、特許請求の範囲、及び要約、並びにこれらのあらゆる図、表、又は図面を含むが、これらに限定されることなく、ここに明示的に本明細書に参照により組み込まれる。
本発明の洗濯方法は、SRPの使用を含む。本発明の一態様では、SRPは、油性及びグリース性の汚れの除去を向上させることができる。これは、工業的洗濯環境において、特に有益である。SRPは、水酸化物系アルカリ分を実質的に含まない予備洗浄ステップに含まれる。好ましい実施形態では、水酸化物系アルカリ分を実質的に含まない予備洗浄ステップは、ケイ酸塩系アルカリ性源の使用を用いる。別の好ましい実施形態では、水酸化物系アルカリ分を実質的に含まない予備洗浄ステップは、中性予備洗浄ステップであり、後に水酸化物系アルカリ分を含む主洗浄ステップが続き得る。
汚れリリースポリマーは、本発明の方法に含まれ得る。ポリマーは、疎水性モノマー及び親水性モノマーの両方を有することにより作用し、それによりSRPがポリエステル及びポリエステルブレンドの生地表面に付着することが可能になり、表面がより親水性になる。表面をより親水性にすることにより、汚いモーター油等の油性汚れとポリエステル及びポリエステルブレンド生地との親和性が低下し、汚れが簡単に除去できるようになる。ポリマーが生地上にビルドアップすると知られているため、SRPが複数の洗浄サイクルにわたって使用される場合、この効果はより大きい。
本発明の方法では、予備洗浄ステップは、あらゆるアルカリ性源なしで、中性で、又は水酸化物系アルカリ分を実質的に含まずに用いられ得る。更に、本発明の実施形態では、主洗浄ステップは、アルカリ性源を含有し、それは水酸化物系アルカリ分源を含み得る。したがって、本発明中における使用に好適なアルカリ性源としては、アルカノールアミン、炭酸塩、水酸化物、及びケイ酸塩を挙げることができる。本発明の好ましい態様では、アルカリ性源は、ケイ酸塩系である。
本発明のステップは、典型的には、担体を用いて行われる。一実施形態では、担体は水であるが、特定の実施形態では、異なる溶媒が使用され得る。
いくつかの実施形態において、本発明の組成物は、界面活性剤を含む。本発明の組成物と一緒に使用するのに好適な界面活性剤としては、非イオン界面活性剤、陰イオン界面活性剤、陽イオン界面活性剤、両性界面活性剤、及び双性イオン界面活性剤が挙げられるが、これらに限定されない。いくつかの実施形態において、本発明の組成物は、約5重量%〜約50重量%の界面活性剤を含む。他の実施形態において、本発明の組成物は、約10重量%〜約40重量%の界面活性剤を含む。更に他の実施形態において、本発明の組成物は、約15重量%〜約35重量%の界面活性剤を含む。本組成物及び方法で使用するために選択された界面活性剤のクラス、一体性、及び数は、本組成物及び方法中の他の構成成分に基づいて、及び除去の対象となる汚れのタイプに基づいて変更され選択されてよい。
有用な非イオン界面活性剤は、一般的に、有機疎水性基及び有機親水性基の存在を特徴とし、典型的には、有機脂肪族、アルキル芳香族、又はポリオキシアルキレン疎水性化合物と、一般的には、エチレンオキシド又はその多水和生成物(polyhydration product)、ポリエチレングリコールである親水性アルカリ性オキシド部分との縮合によって生成される。具体的には、反応性水素原子を有するヒドロキシル、カルボキシル、アミノ、又はアミド基を有する任意の疎水性化合物を、エチレンオキシド、若しくはその多水和付加物、又はプロピレンオキシド等のアルコキシレンとのその混合物と縮合させて、非イオン表面活性剤を形成することができる。任意の特定の疎水性化合物と縮合する親水性ポリオキシアルキレン部分の長さは、親水性特性と疎水性特性との間の所望の程度のバランスを有する水分散性又は水溶性化合物を生成するように、容易に調節され得る。有用な非イオン性界面活性剤は、以下を含む。
5.エチレンオキシドをエチレングリコールに付加して指定の分子量の親水性物質を提供し;次いでプロピレンオキシドを付加して分子の外側(端部)に疎水性ブロックを得ることにより改質され、本質的に反転された(1)からの化合物。分子の疎水性部分は、約1,000から約3,100の分子量を有し、中心の親水性物質は、最終的な分子の10重量%から約80重量%を含む。これらの反転Pluronics(商標)は、BASF CorporationによりPluronic(商標)R界面活性剤の商標で製造されている。同様に、Tetronic(商標)R界面活性剤は、BASF Corporationにより、エチレンオキシド及びプロピレンオキシドのエチレンジアミンへの逐次的付加によって製造されている。分子の疎水性部分は、約2,100から約6,700の分子量を有し、中心の親水性物質は、最終的な分子の10重量%から約80重量%を含む。
7.次式
半極性型の非イオン性表面活性剤は、本発明の組成物において有用な別のクラスの非イオン性界面活性剤である。一般に、半極性非イオン性物質は、高発泡物質及び泡安定剤であり、これはCIPシステムにおけるそれらの適用を制限し得る。しかしながら、高発泡浄化方法用に設計された本発明の組成上の実施形態において、半極性非イオン性物質は、即時的な実用性を有する。半極性非イオン性界面活性剤は、アミンオキシド、ホスフィンオキシド、スルホキシド及びそれらのアルコキシル化誘導体を含む。
疎水性物質の電荷が負であるためアニオンとして分類される界面活性物質、又はもしpHが中性若しくはそれ以上に上昇しなければ分子の疎水性部分が電荷を持たない界面活性剤(例えば、カルボン酸)もまた、本発明で有用である。カルボキシレート、スルホネート、スルフェート、及びホスフェートは、アニオン性界面活性剤中に見られる極性(親水性)可溶性基である。これらの極性基を伴うカチオン(対イオン)のうち、ナトリウム、リチウム、及びカリウムは、水溶性を付与し、アンモニウム及び置換アンモニウムイオンは、水溶性及び油溶性の両方を提供し、カルシウム、バリウム、及びマグネシウムは、油溶性を促進する。当業者には理解される通り、アニオンは、優れた洗浄性界面活性剤であるため、重質洗剤組成物への好ましい添加物である。
R−O−(CH2CH2O)n(CH2)m−CO2X (3)
式中、Rは、C8〜C22アルキル基又は
表面活性物質は、分子のヒドロトロープ部分上の電荷が正である場合、陽イオンと分類される。ヒドロトロープが、pHが中性近く、又はそれ以下まで下げられない限り電荷を帯びないが、その後陽イオン(例えばアルキルアミン)である界面活性剤も、この群に含まれる。理論的には、陽イオン界面活性剤は、「オニウム」構造RnX+Y−−を含む元素のいずれの組み合わせからも合成され得、リン(ホスホニウム)及び硫黄(スルホニウム)等の窒素(アンモニウム)以外の化合物を含み得る。実際には、陽イオン界面活性剤の分野は、恐らく、窒素の陽イオン界面活性剤への合成経路が単純かつ容易であり、高収率の生成物を生じ、これが、窒素の陽イオン界面活性剤をより安価にするために、窒素含有化合物によって支配されている。
両性(Amphoteric)又は両性(ampholytic)界面活性剤は、塩基性親水性基及び酸性親水性基の両方、並びに有機疎水性基を含有する。これらのイオンの実体は、他の種類の界面活性剤に関して本明細書に記載される陰イオン基又は陽イオン基のうちのいずれかでもよい。塩基性窒素及び酸性カルボキシレート基は、塩基性親水性基及び酸性親水性基として使用される典型的な官能基である。少数の界面活性剤において、スルホネート、スルフェート、ホスホネート、又はホスフェートは、負電荷をもたらす。
双性イオン界面活性剤は、両性界面活性剤のサブセットと捉えられ得、陰イオン電荷を含み得る。双性イオン性界面活性剤は、第二級及び第三級アミンの誘導体、複素環式の第二級及び第三級アミンの誘導体、又は第四級アンモニウム、第四級ホスホニウム、若しくは第三級スルホニウム化合物の誘導体と、広く説明され得る。典型的には、双性イオン性界面活性剤は、正電荷を持つ第四級アンモニウム、又は場合によりスルホニウム若しくはホスホニウムイオンと、負電荷を持つカルボキシル基と、アルキル基とを含む。双性イオンは、一般に、分子の等電領域でほぼ等しい度合いまでイオン化し、正電荷−負電荷中心の間に強い「分子内塩」引力を発生し得る陽イオン及び陰イオン基を含有する。そのような双性イオン性の合成界面活性剤の例としては、脂肪族ラジカルが直鎖であっても分岐鎖であってもよく、脂肪族置換基のうちの1つが8〜18個の炭素原子を含有し、1つが陰イオン性水溶化基、例えば、カルボキシ、スルホネート、スルフェート、ホスフェート、又はホスホネートを含有する、脂肪族第四級アンモニウム、ホスホニウム、及びスルホニウム化合物の誘導体が挙げられる。
本方法にて用いられる構成成分は、洗濯用途での使用に好適な様々な機能性構成成分と更に組み合わせることができる。これらの構成成分の選択は、除去される汚れのタイプに影響を受ける場合があり、本組成物及び方法に用いられる他の構成成分に基づき得る。これらの追加的な機能性構成成分を、予備洗浄ステップ、主洗浄ステップ、ブースターステップ、及び/又は酸味ステップに加えることができる。
本発明の方法は、主洗浄後に任意の酸味ステップを含み得る。酸性源ステップを使用して、あらゆるアルカリ性残留物を中和し、染み及び/又は汚れの除去を手助けすることができる。特定の汚れの除去、並びに特定の染みの除去及び/又は防止に、特に有用であり得る。任意の好適な酸味組成物を用いることができる。本発明の実施形態では、水酸化物系アルカリ分を含む主洗浄ステップを有する酸味ステップが好ましい場合がある。
本発明の方法における使用に好適な漂白剤は、ハロゲン系漂白剤又は酸素系漂白剤であり得る。しかしながら、酸素系漂白剤が好ましい。
本明細書において、キレート化とは、二座又は多座リガンドの結合又は錯体形成を意味する。これらのリガンドは、多くの場合有機化合物であり、キレート剤、キレータ、キレート剤、及び/又は水処理剤と呼ばれる。キレート剤は、単一の金属イオンと複数の結合を形成する。キレート剤は、特定の金属イオンと溶解性の錯体分子を形成する化学物質であり、イオンを不活性化し、その結果、それらは他の元素又はイオンと正常に反応して沈殿物又はスケールを生成することができない。リガンドは、基質とキレート錯体を形成する。この用語は、金属イオンがキレート剤の2つ以上の原子に結合された錯体に関するものである。本発明で使用するためのキレート剤は、結晶成長阻害特性を有するようなもの、すなわち、小さい炭酸カルシウム粒子及び炭酸マグネシウム粒子と相互作用し、それらが硬質スケール堆積物に凝集することを防止するようなものである。粒子は、互いに反発し、水中で浮遊したままか、又は沈降し得る緩いアグリゲートを形成する。これらの緩いアグリゲートは、簡単にすすぎ落とされ、堆積物を形成しない。
湿潤剤及び脱泡剤もまた、本発明の組成物中で有用である。湿潤剤は、本発明の抗菌組成物の表面接触又は浸透活性を高めるように機能する。本発明の組成物中で使用できる湿潤剤は、本発明の組成物の表面活性を高めるために、当技術分野において既知の成分のいずれかを含む。
様々な染料、香料を含む臭気剤、及び他の美的促進剤も、本発明の方法で利用する組成物中に含まれてもよい。染料、例えば、ダイレクトブルー86(Miles)、ファスツゾールブルー(Mobay Chemical Corp.)、アシッドオレンジ7(American Cyanamid)、ベーシックバイオレット10(Sandoz)、アシッドイエロー23(GAF)、アシッドイエロー17(Sigma Chemical)、サップグリーン(Keystone Analine and Chemical)、メタニルイエロー(Keystone Analine and Chemical)、アシッドブルー9(Hilton Davis)、サンドランブルー/アシッドブルー182(Sandoz)、ヒゾルファストレッド(Capitol Color and Chemical)、フルオレセイン(Capitol Color and Chemical)、及びアシッドグリーン25(Ciba−Geigy)等は、本組成物の外観を変化させるために含まれてもよい。本組成物に含まれてもよい芳香剤又は香料としては、例えば、シトロネロール等のテルペノイド、アミルシンナムアルデヒド等のアルデヒド、CIS−ジャスミン mjアスマール(mj asmal)等のジャスミン、バニリン等が挙げられる。
本発明の実施形態は、1つ以上の酵素の使用を含むことができる。1つ以上の酵素は、プロテアーゼを含むことができる。1つ以上の酵素は、アミラーゼを含むことができる。特定の実施形態では、この方法は、プロテアーゼ及びアミラーゼを用いる。酵素は、この方法の任意のステップにて、浄化組成物中に含まれ得る。いくつかの好ましい実施形態では、酵素は、予備洗浄ステップ中又はそれ独自のステップで使用されるブースター組成物である。
ヒドロトロープ成分を使用して、界面活性剤成分の安定化を手助けすることができる。ヒドロトロープ成分は、任意であり、界面活性剤成分の安定化に必要ない場合、省略することができることが理解されるべきである。多くの場合、ヒドロトロープ成分は、界面活性剤成分の安定化を手助けするために存在することが期待されている。
本組成物は、任意選択的に、いずれかのステップ中に溶媒を含むことができる。溶媒は、水への所望の溶解度及び他の構成成分との適合性に基づいて、選択することができる。特定の実施形態では、好ましい溶媒としては、アルコール又はポリオールを挙げることができる。メタノール、エタノール、プロパノール、及びイソプロパノールにより例示された低分子量一級又は二級アルコールが、好適である。一価アルコールは、界面活性剤を可溶化するために好ましいが、約2個〜約6個の炭素原子、及び約2個〜約6個のヒドロキシ基を含有しているもののようなポリオール(例えば、プロピレングリコール、エチレングリコール、グリセリン、及び1,2−プロパンジオール)も更に使用することができる。
上述のように、SRPの使用は、特定の汚れタイプ、特に工業的洗濯環境に見られる油性汚れの除去に望ましい。SRPは、織物上の汚れのその直接処理において有用であり得、更に、残留効果を有し得、それにより後に汚れが付着することを防止する。したがって、特定の状況では、洗濯が完了する際、織物上に残ることがSRPにとって有益であってよい。しかしながら、典型的な工業的洗濯方法と組み合わせた場合、SRPは、アルカリ分がSRPを加水分解するため、その効果的な特性を保持しないということが見出された。したがって、従来の工業的洗濯方法下では、SRPは、多くの場合加水分解され、洗濯方法中に汚れを除去するのに効果的ではなく、及び/又は生地への油の付着を防止できる残留効果のために生地上に残らない。
0.05%のスーダンレッドを有する0.25gのオリーブオイル染料でスワッチを汚したことを除いて、実施例1に記述されている手順に従って、表5の工業的洗浄プロセスを試験した。
表7及び表8に示す2つの工業的洗浄主洗浄プロセスを、2タイプのアルカリ及び各個々のアルカリの投与量を比較して、評価した。洗浄プロセスを、28lbの65/35ポリ/コットン充填及び5グレーンの水を有する35lb洗濯機中で、各サイクルの間に乾燥を伴う5回連続サイクルで使用した。表7及び表8に記載の両方の洗剤試験にて、アルカリ以外の全ての化学物質を等しく投与した。表9及び表10は、例となるアルカリ組成物を示す。使用された洗剤は、Solvay製の5% Repel−O−Tex Crystalを含んでいた。
[態様1]
物品の浄化方法であって、
(a)浄化される物品を提供するステップと、
(b)予備洗浄ステップにて前記物品と予備洗浄組成物及び水とを接触させるステップであって、前記予備洗浄ステップは、約6.5〜約10.5のpHにて行われ、前記予備洗浄組成物は、汚れリリースポリマーを含み、前記予備洗浄組成物の水酸化物系アルカリ分が0.5重量%未満である、接触させるステップと、
(c)主洗浄ステップにて前記物品とアルカリ性洗剤を接触させるステップと、
(d)前記物品をすすぎ洗いするステップと、を含む方法。
[態様2]
前記予備洗浄ステップが、約6.5〜約7.5のpHにて行われる、態様1に記載の方法。
[態様3]
前記予備洗浄ステップが、約7.5〜約10.5のpHにて行われ、アルカリ性源を更に含む、態様1に記載の方法。
[態様4]
前記アルカリ性源が、アルカノールアミン、炭酸塩、ケイ酸塩、及びそれらの組み合わせからなる群から選択される、態様3に記載の方法。
[態様5]
前記アルカリ性源が、ケイ酸塩である、態様3又は4のいずれかに記載の方法。
[態様6]
前記予備洗浄組成物が、1つ以上の界面活性剤を更に含む、態様1〜5のいずれかに記載の方法。
[態様7]
前記予備洗浄組成物が、酵素を更に含む、態様1〜6のいずれかに記載の方法。
[態様8]
前記酵素が、プロテアーゼ、アミラーゼ、又はプロテアーゼとアミラーゼの組み合わせである、態様7に記載の方法。
[態様9]
(e)酸味(sour)ステップを更に含む、態様1〜8のいずれかに記載の方法。
[態様10]
前記アルカリ性洗剤が、水酸化物系アルカリ分源を含む、態様1〜9のいずれかに記載の方法。
[態様11]
物品の浄化方法であって、
(a)浄化される物品を提供するステップと、
(b)予備洗浄ステップにて前記物品と予備洗浄組成物及び水とを接触させるステップであって、前記予備洗浄ステップは、約6.5〜約10.5のpHにて行われ、前記予備洗浄組成物は、汚れリリースポリマーを含み、前記予備洗浄組成物の水酸化物系アルカリ分が0.5重量%未満である、接触させるステップと、
(c)主洗浄ステップにて前記物品とアルカリ性洗剤を接触させるステップであって、前記アルカリ性洗剤の水酸化物系アルカリ分が0.5重量%未満である、接触させるステップと、
(d)前記物品をすすぎ洗いするステップと、を含む方法。
[態様12]
前記予備洗浄ステップが、約6.5〜約7.5のpHにて行われる、態様11に記載の方法。
[態様13]
前記予備洗浄ステップが、約7.5〜約10.5のpHにて行われ、アルカノールアミン、炭酸塩、水酸化物、ケイ酸塩、及びそれらの組み合わせからなる群から選択されるアルカリ性源を更に含む、態様1に記載の方法。
[態様14]
前記アルカリ性源が、水酸化物である、態様13に記載の方法。
[態様15]
前記予備洗浄組成物が、酵素、酵素安定剤、脱泡剤、界面活性剤、又はそれらの組み合わせを更に含む、態様1〜14のいずれかに記載の方法。
[態様16]
(e)酸味ステップを更に含む、態様11〜15のいずれかに記載の方法。
[態様17]
(a)浄化される物品を提供するステップと、
(b)前記物品と浄化組成物及び水とを接触させるステップであって、前記浄化組成物は、汚れリリースポリマーを含み、前記浄化組成物の水酸化物系アルカリ分が0.5重量%未満であり、前記接触ステップは、約6.5〜約11の間のpHにて行われるステップと、
(c)前記物品をすすぎ洗いするステップと、を含む物品の浄化方法。
[態様18]
ステップ(b)の前又はステップ(b)の後に、前記物品とアルカリ性源との接触ステップを更に含む、態様17に記載の方法。
[態様19]
前記アルカリ性源が、水酸化物を含む、態様18に記載の方法。
[態様20]
(d)酸味ステップを更に含む、態様17〜19のいずれかに記載の方法。
Claims (20)
- 物品の浄化方法であって、
(a)浄化される物品を提供するステップと、
(b)予備洗浄ステップにて前記物品と予備洗浄組成物及び水とを接触させるステップであって、前記予備洗浄ステップは、約6.5〜約10.5のpHにて行われ、前記予備洗浄組成物は、汚れリリースポリマーを含み、前記予備洗浄組成物の水酸化物系アルカリ分が0.5重量%未満である、接触させるステップと、
(c)主洗浄ステップにて前記物品とアルカリ性洗剤を接触させるステップと、
(d)前記物品をすすぎ洗いするステップと、を含む方法。 - 前記予備洗浄ステップが、約6.5〜約7.5のpHにて行われる、請求項1に記載の方法。
- 前記予備洗浄ステップが、約7.5〜約10.5のpHにて行われ、アルカリ性源を更に含む、請求項1に記載の方法。
- 前記アルカリ性源が、アルカノールアミン、炭酸塩、ケイ酸塩、及びそれらの組み合わせからなる群から選択される、請求項3に記載の方法。
- 前記アルカリ性源が、ケイ酸塩である、請求項3又は4のいずれか一項に記載の方法。
- 前記予備洗浄組成物が、1つ以上の界面活性剤を更に含む、請求項1〜5のいずれか一項に記載の方法。
- 前記予備洗浄組成物が、酵素を更に含む、請求項1〜6のいずれか一項に記載の方法。
- 前記酵素が、プロテアーゼ、アミラーゼ、又はプロテアーゼとアミラーゼの組み合わせである、請求項7に記載の方法。
- (e)酸味(sour)ステップを更に含む、請求項1〜8のいずれか一項に記載の方法。
- 前記アルカリ性洗剤が、水酸化物系アルカリ分源を含む、請求項1〜9のいずれか一項に記載の方法。
- 物品の浄化方法であって、
(a)浄化される物品を提供するステップと、
(b)予備洗浄ステップにて前記物品と予備洗浄組成物及び水とを接触させるステップであって、前記予備洗浄ステップは、約6.5〜約10.5のpHにて行われ、前記予備洗浄組成物は、汚れリリースポリマーを含み、前記予備洗浄組成物の水酸化物系アルカリ分が0.5重量%未満である、接触させるステップと、
(c)主洗浄ステップにて前記物品とアルカリ性洗剤を接触させるステップであって、前記アルカリ性洗剤、接触させるステップと、
(d)前記物品をすすぎ洗いするステップと、を含む方法。 - 前記予備洗浄ステップが、約6.5〜約7.5のpHにて行われる、請求項11に記載の方法。
- 前記予備洗浄ステップが、約7.5〜約10.5のpHにて行われ、アルカノールアミン、炭酸塩、水酸化物、ケイ酸塩、及びそれらの組み合わせからなる群から選択されるアルカリ性源を更に含む、請求項1に記載の方法。
- 前記アルカリ性源が、水酸化物である、請求項13に記載の方法。
- 前記予備洗浄組成物が、酵素、酵素安定剤、脱泡剤、界面活性剤、又はそれらの組み合わせを更に含む、請求項1〜14のいずれか一項に記載の方法。
- (e)酸味ステップを更に含む、請求項11〜15のいずれか一項に記載の方法。
- (a)浄化される物品を提供するステップと、
(b)前記物品と浄化組成物及び水とを接触させるステップであって、前記浄化組成物は、汚れリリースポリマーを含み、前記浄化組成物の水酸化物系アルカリ分が0.5重量%未満であり、前記接触ステップは、約6.5〜約11の間のpHにて行われるステップと、
(c)前記物品をすすぎ洗いするステップと、を含む物品の浄化方法。 - ステップ(b)の前又はステップ(b)の後に、前記物品とアルカリ性源との接触ステップを更に含む、請求項17に記載の方法。
- 前記アルカリ性源が、水酸化物を含む、請求項18に記載の方法。
- (d)酸味ステップを更に含む、請求項17〜19のいずれか一項に記載の方法。
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US11884899B2 (en) | 2018-06-01 | 2024-01-30 | Amtex Innovations Llc | Methods of laundering stitchbonded nonwoven towels using a soil release polymer |
US10822578B2 (en) | 2018-06-01 | 2020-11-03 | Amtex Innovations Llc | Methods of washing stitchbonded nonwoven towels using a soil release polymer |
IT201800007438A1 (it) * | 2018-07-23 | 2020-01-23 | Additivo schiumogeno a basso impatto ecotossicologico per il condizionamento del terreno in presenza di scavo meccanizzato | |
JP7232562B2 (ja) * | 2018-12-13 | 2023-03-03 | ザ プロクター アンド ギャンブル カンパニー | 洗浄及びすすぎサイクル中に可変phプロファイルで布地を処理する方法 |
CN113502639A (zh) * | 2021-06-21 | 2021-10-15 | 荣昌耀华网络技术(北京)有限公司 | 一种羽绒服高效科学的免刷洗工艺 |
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EP3368646A1 (en) | 2018-09-05 |
BR112018008231B1 (pt) | 2023-03-07 |
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AU2016343677A1 (en) | 2018-04-19 |
JP2019500071A (ja) | 2019-01-10 |
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US9890350B2 (en) | 2018-02-13 |
AU2016343677B2 (en) | 2018-11-22 |
EP3368646B1 (en) | 2023-03-08 |
CN108138087A (zh) | 2018-06-08 |
AU2019200900B2 (en) | 2020-04-09 |
WO2017075384A1 (en) | 2017-05-04 |
JP7057383B2 (ja) | 2022-04-19 |
CN108138087B (zh) | 2021-01-01 |
CA3003660C (en) | 2020-08-18 |
US20180127691A1 (en) | 2018-05-10 |
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