JP2019513859A - 薄膜及びフィルム形成物を得るための方法 - Google Patents
薄膜及びフィルム形成物を得るための方法 Download PDFInfo
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- JP2019513859A JP2019513859A JP2018552183A JP2018552183A JP2019513859A JP 2019513859 A JP2019513859 A JP 2019513859A JP 2018552183 A JP2018552183 A JP 2018552183A JP 2018552183 A JP2018552183 A JP 2018552183A JP 2019513859 A JP2019513859 A JP 2019513859A
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- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910052598 goethite Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- STCNNBXPNILVDE-UHFFFAOYSA-N methyl 3-aminothieno[2,3-b]pyridine-2-carboxylate Chemical compound C1=CC=C2C(N)=C(C(=O)OC)SC2=N1 STCNNBXPNILVDE-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003880 polar aprotic solvent Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000583 toxicological profile Toxicity 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
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Abstract
Description
・フィルムの使用に関する品質上の課題を発生させる、DMSOを使用した場合に得られる配合物及び/又は薄膜の着色、
・フィルムの調製に関する経済的な課題を発生させる可能性がある、他の溶媒に比べた特定のDMSO系溶液の粘度の上昇、
・経済的な課題を発生させる、DMSO及び任意選択的に水の蒸発中における冶金学的腐食、
・環境的な課題を発生させる、廃水浄化ステーションに送達される水性排出物の悪臭
等の特定の課題を生じさせ得る。
a)スルホキシド官能基を有する少なくとも1つの分子を含み、重量基準で厳密に1000ppm未満の含水量を有し、6以上のpHを有する、溶媒系を用意することと、
b)前記溶媒系中にポリマーを溶解させること又は前記溶媒系中でポリマーを合成することによってポリマー溶液を調製することと、
c)溶媒系を除去して、フィルム又はフィルム形成物を得ることと
を含む、フィルム又はフィルム形成物を得るための方法に関する。
・同一であっても又は異なっていてもよいX及びYが互いに独立に、酸素、硫黄、SO、SO2、NH及びNR”から選択され、
・同一であっても又は異なっていてもよいa及びbが互いに独立に、0又は1を表し、nが、1又は2に等しく、
・同一であっても又は異なっていてもよいR、R’及びR”が互いに独立に、1〜12個の炭素原子を含有する直鎖状又は分岐状アルキル基、2〜12個の炭素原子を含有する直鎖状又は分岐状アルケニル基及び6〜10個の炭素原子を含有するアリール基から選択され、R、R’及びR”が、アルキル、アルケニル、アリール及びハロゲンから選択される基によって置換されてもよく、O、S、N、P及びSiから選択される1個以上のヘテロ原子を含有することができ、R及びR’が、R及びR’を有する原子と一緒になって、O、S及びNから選択される1個以上のヘテロ原子を任意選択的に含有する炭化水素系環状構造をさらに形成することができ、該環状構造が、合計で5個、6個、7個、8個又は9個の環員を含む。)
に対応する。
同一であっても又は異なっていてもよいR及びR’が、1〜4個の炭素原子を含有する直鎖状又は分岐状アルキル基、1〜4個の炭素原子を含有する直鎖状又は分岐状アルケニル基及びフェニル基から選択され、
nが、1又は2に等しく、好ましくは2に等しい。)
に対応する。
a)少なくとも1つのスルホキシド官能基を有する少なくとも1つの分子を含み、重量基準で1000ppm以下の含水量を有し、6以上のpHを有する、溶媒系を用意することと、
b)前記溶媒系中でポリマーを合成すること又は前記溶媒系中にポリマーを溶解させることによって、ポリマー溶液を調製することと、
c)溶媒系を除去して、フィルム又はフィルム形成物を得ることと
を含む、フィルム又はフィルム形成物を得るための方法を提案する。
・同一であっても又は異なっていてもよいX及びYが互いに独立に、酸素、硫黄、SO、SO2、NH及びNR”から選択され、
・同一であっても又は異なっていてもよいa及びbが互いに独立に、0又は1を表し、nが、1又は2に等しく、
・同一であっても又は異なっていてもよいR、R’及びR”が互いに独立に、1〜12個の炭素原子を含有する直鎖状又は分岐状アルキル基、2〜12個の炭素原子を含有する直鎖状又は分岐状アルケニル基及び6〜10個の炭素原子を含有するアリール基から選択され、R、R’及びR”が、アルキル、アルケニル、アリール及びハロゲンから選択される基によって置換されてもよく、O、S、N、P及びSiから選択される1個以上のヘテロ原子を含有することができ、R及びR’が、R及びR’を有する原子と一緒になって、O、S及びNから選択される1個以上のヘテロ原子を任意選択的に含有する炭化水素系環状構造をさらに形成することができ、該環状構造が、合計で5個、6個、7個、8個又は9個の環員を含む。)
によって表される有機スルフィド酸化物である。
Rが、1〜4個の炭素原子を含有する直鎖状又は分岐状アルキル基、2〜4個の炭素原子を含有する直鎖状又は分岐状アルケニル基及びアリール基、好ましくはフェニル基から選択され、
nが、1又は2に等しく、
xが、0又は1を表し、
R’が、1〜4個の炭素原子を含有する直鎖状又は分岐状アルキル基、2〜4個の炭素原子を含有する直鎖状又は分岐状アルケニレン基及びアリール基、好ましくはフェニル基から選択される。)
に対応する。
同一であっても又は異なっていてもよいR及びR’が、1〜4個の炭素原子を含有する直鎖状又は分岐状アルキル基、1〜4個の炭素原子を含有する直鎖状又は分岐状アルケニル基及びフェニル基から選択され、
nが、1又は2に等しく、好ましくはn=2である。)
に対応する。
・アセトン、メチルエチルケトン(MEK)、メチルイソブチルケトン、ヘキサノン、シクロヘキサノン、エチルアミンケトン、イソホロン、トリメチルシクロヘキサノン、γ−ブチロラクトン又はジアセトンアルコール等のケトン、
・モノエタノールアミン(MEoA)、ジエタノールアミン(DEoA)、プロパノールアミン(PoA)、ブチルイソプロパノールアミン(BiPoA)、イソプロパノールアミン(iPoA)、2−[2−(3−アミノプロポキシ)エトキシ]エタノール、N−(2−ヒドロキシエチル)ジエチレントリアミン、(3−メトキシ)プロピルアミン(MoPA)、3−イソプロポキシプロピルアミン(IPOPA)、モノエチルアミン、ジエチルアミン、ジエチルアミノプロピルアミン(DEAPA)、トリエチルアミン(TEA)又はアセトニトリル等のアミン、
・エタノール、メタノール、プロパノール、イソプロパノール、グリセロール、ジアセトンアルコール、ブタノール、メチルイソブチルカルビノール、ヘキシレングリコール又はベンジルアルコール等のアルコール、
・テトラヒドロフラン(THF)、メチルフラン、メチルテトラヒドロフラン、テトラヒドロピラン又はグリコールジアルキルエーテル等のエーテル、
・二塩基性エステル、ジメチルグルタレート、ジメチルスクシネート、ジメチルアジペート、ブチルアセテート、エチルアセテート、ジエチルカルボネート、ジメチルカルボネート、プロピレンカルボネート、エチルメチルカルボネート、グリセロールカルボネート、ジメチル2−メチルグルタレート、ジメチル2−メチルアジペート、ジメチル2−メチルスクシネート、n−ブチルプロピオネート、ベンジルアセテート又はエチルエトキシプロピオネート等のエステル、
・ジメチルスルホン又はスルホラン等のスルホン、
・トルエン又はキシレン等の芳香族化合物、
・メチラール、エチラール、ブチラール、ジオキソラン又はTOU(テトラオキサウンデカン)等のアセタール、
・ジプロピレングリコールジメチルエーテル(DPGDME)又はジプロピレングリコールメチルエーテル等のE型又はP型のグリコールエーテル。
・染料、
・ポリエチレングリコール(PEG)又はポリビニルピロリドン(PVP)等の細孔形成剤
・保存料、
・抗酸化剤
を挙げることができる。
・変形形態c1):前記ポリマーに対する非溶媒であるが溶媒系に対する溶媒である媒体中におけるポリマーの凝析(湿式工程)、
・変形形態c2:溶媒の蒸発(乾式工程)による。
Claims (17)
- フィルム又はフィルム形成物を得るための方法であって、
a)スルホキシド官能基を有する少なくとも1つの分子を含み、重量基準で厳密に1000ppm未満の含水量を有し、6以上のpHを有する、溶媒系を用意することと、
b)前記溶媒系中にポリマーを溶解させること又は前記溶媒系中でポリマーを合成することによってポリマー溶液を調製することと、
c)前記溶媒系を除去して、フィルム又はフィルム形成物を得ることと
を含む、方法。 - 前記溶媒系の含水量が、重量基準で900ppm以下、好ましくは重量基準で500ppm以下、より好ましくは重量基準で300ppm、さらにより好適には重量基準で100ppm以下又は重量基準で50ppm以下である、請求項1に記載の方法。
- 前記溶媒系が、6〜14の範囲、好ましくは6〜10の範囲、及びより好ましくは6.5〜8の範囲のpHを有する、請求項1又は2に記載の方法。
- 前記溶媒系が、前記溶媒系の総重量に対して、5重量%〜100重量%、好ましくは25重量%〜100重量%、より好ましくは50重量%〜100重量%、より好適には65%〜100重量%、さらにより好適には75重量%〜100重量%の少なくとも1つのスルホキシド官能基を有する分子を含む、請求項1から3のいずれか一項に記載の方法。
- 少なくとも1つのスルホキシド官能基を有する前記分子が、式(1):
・同一であっても又は異なっていてもよいX及びYが互いに独立に、酸素、硫黄、SO、SO2、NH及びNR”から選択され、
・同一であっても又は異なっていてもよいa及びbが互いに独立に、0又は1を表し、nが、1又は2に等しく、
・同一であっても又は異なっていてもよいR、R’及びR”が互いに独立に、1〜12個の炭素原子を含有する直鎖状又は分岐状アルキル基、2〜12個の炭素原子を含有する直鎖状又は分岐状アルケニル基、及び6〜10個の炭素原子を含有するアリール基から選択され、R、R’及びR”が、アルキル、アルケニル、アリール及びハロゲンから選択される基によって置換されてもよく、O、S、N、P及びSiから選択される1個以上のヘテロ原子を含有することができ、R及びR’が、R及びR’を有する原子と一緒になって、O、S及びNから選択される1個以上のヘテロ原子を任意選択的に含有する炭化水素系環状構造をさらに形成することができ、該環状構造が、合計で5個、6個、7個、8個又は9個の環員を含む。)
に対応する、請求項1から4のいずれか一項に記載の方法。 - 少なくとも1つのスルホキシド官能基を有する前記分子が、ジメチルスルホキシド分子である、請求項1から6のいずれか一項に記載の方法。
- 前記ポリマー溶液が、前記ポリマー溶液の総重量に対して、1重量%〜90重量%、好ましくは2重量%〜60重量%、及びより好ましくは5重量%〜30重量%のポリマーを含む、請求項1から7のいずれか一項に記載の方法。
- 前記ポリマーが、ポリウレタン、ポリスルホン、ポリビニリデンフルオライド、ポリエーテルスルホン、ポリフェニルスルホン、セルロースアセテート、ポリアミド、ポリアクリル酸、ポリエポキシド、ポリメタクリレート、ポリカルボネート、シリコーン、ビニルポリマー、ポリアミド−イミド及びポリイミドから選択される、請求項1から8のいずれか一項に記載の方法。
- 前記ポリマー溶液が、10℃〜120℃の範囲、好ましくは20℃〜100℃の範囲、より好ましくは50℃〜70℃の範囲の温度で前記溶媒系中に前記ポリマーを溶解させることによって得られる、請求項1から9のいずれか一項に記載の方法。
- 前記溶媒系の除去が、前記ポリマーに対する非溶媒であり、前記溶媒系に対する溶媒である媒体中で前記ポリマーを凝析させることによって実施される、請求項1から10のいずれか一項に記載の方法。
- 前記ポリマーに対する非溶媒であり、前記溶媒系に対する溶媒である前記媒体が、前記ポリマーに対する非溶媒であり、前記溶媒系に対する溶媒である前記媒体の総重量に対して、少なくとも20重量%の水、好ましくは少なくとも40重量%の水、より好ましくは少なくとも60重量%の水、さらにより好適には少なくとも65重量%の水、及び理想的には少なくとも75重量%の水を含む、請求項11に記載の方法。
- ステップc)が完了したときに得られた溶媒排出物を処理するステップd)をさらに含む、請求項1から12のいずれか一項に記載の方法。
- 前記処理ステップd)が、一方のジメチルスルホキシド等の少なくとも1つのスルホキシド官能基を有する分子及び他方の水性排出物を回収するための分離、好ましくは蒸留、再結晶、膜処理による分離の予備ステップd1)を含む、請求項13に記載の方法。
- 前記処理ステップd)が、ステップc)で得られる前記溶媒排出物に直接、又は予備ステップd1)で得られる前記水性排出物に実施される化学的、生物学的及び/又は熱的酸化を含む、請求項13又は14に記載の方法。
- 前記処理ステップd)が、請求項1から12のいずれか一項に記載の方法のステップa)からc)の実施の現場で実施される、請求項13から15の一項に記載の方法。
- 前記処理ステップd)が、請求項1から12のいずれか一項に記載の方法のステップa)からc)の実施の現場と異なる現場で実施される、請求項13から15の一項に記載の方法。
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FR3049605A1 (fr) | 2017-10-06 |
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CA3017550C (fr) | 2021-05-25 |
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CN108884248A (zh) | 2018-11-23 |
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