JP2019001847A - 洗浄剤組成物。 - Google Patents
洗浄剤組成物。 Download PDFInfo
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- JP2019001847A JP2019001847A JP2017115301A JP2017115301A JP2019001847A JP 2019001847 A JP2019001847 A JP 2019001847A JP 2017115301 A JP2017115301 A JP 2017115301A JP 2017115301 A JP2017115301 A JP 2017115301A JP 2019001847 A JP2019001847 A JP 2019001847A
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- fatty acid
- detergent composition
- acid
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- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000003599 detergent Substances 0.000 title claims abstract description 18
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 24
- 229930195729 fatty acid Natural products 0.000 claims abstract description 24
- 239000000194 fatty acid Substances 0.000 claims abstract description 24
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 21
- 235000021314 Palmitic acid Nutrition 0.000 claims abstract description 13
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 5
- 238000004140 cleaning Methods 0.000 claims description 18
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical group CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 8
- -1 fatty acid salt Chemical class 0.000 claims description 8
- 238000013329 compounding Methods 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 7
- 238000002425 crystallisation Methods 0.000 abstract description 4
- 230000008025 crystallization Effects 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000001629 suppression Effects 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940007062 eucalyptus extract Drugs 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012676 herbal extract Substances 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Abstract
Description
成分A:パルミチン酸
成分B:分岐脂肪酸
成分C:炭素数が5〜8のジオール化合物
成分D:両性界面活性剤
を含有し、成分Aの配合量が5質量%〜30質量%である洗浄剤組成物である。
<評価方法>
実施例および比較例のクリーム型洗顔料をチューブ容器(口径直径4mm)に充填し、5℃1ヶ月および10℃1ヶ月静置した後に粘度を測定し、経時安定性について下記に示す判断基準により評価を行った。また粘度に関しては、Rion粘度計(リオン(株))により30℃、ローターNo.2、10秒後の条件下で測定した。
<評価基準>
◎:問題なくチューブから出せる(粘度:8〜20 Pa・s未満)
○:やや負荷がかかるものの問題なくチューブから出せる(粘度:20Pa・s以上、30 Pa・s未満)
△:通常使用時以上の力を加えればチューブから出せる(粘度:30Pa・s以上、45 Pa・s未満)
×:チューブから出ない (粘度:45Pa・s以上)
製剤1gを手にとり、水9gを3回に分けて加えながら2分間泡立てた後、その泡を全量プラスチックボードの上にサンプリングした。泡の縦(cm)、横(cm)、高さ(cm)を測定しその積を算出した。この値を起泡力の指標とした。
判定は◎:120(cm3)以上、○:90(cm3)以上120(cm3)未満、△:60(cm3)以上90(cm3)未満、×60(cm3)未満である。
例えば脂肪酸と水酸化カリウムで鹸化した場合、脂肪酸と水酸化カリウムはそれぞれ等モル数にて反応し、脂肪酸カリウムと水になる。表1に記載してある脂肪酸質量比は、鹸化後の残存脂肪酸と脂肪酸カリウムとの質量比の理論値である。脂肪酸質量比の数値は、小数点第2位を四捨五入した概数を記載している。
配合成分 配合量(%)
ラウリン酸 7
ミリスチン酸 15
パルミチン酸 18
ステアリン酸 10
イソステアリン酸 0.5
1,2−ペンタンジオール 0.5
ジプロピレングリコール 1
グリセリン 20
ラウリルヒドロキシスルホベタイン液 10
ノバラエキス 0.1
ユーカリエキス 0.1
ヒアルロン酸ナトリウム 0.01
水酸化カリウム 10.5
キレート剤 適量
保存料 適量
水 残余
合計 100
Claims (5)
- 次の成分A〜D
成分A:パルミチン酸
成分B:分岐脂肪酸
成分C:炭素数が5〜8のアルカンジオール
成分D:両性界面活性剤
を含有し、成分Aの配合量が配合成分全体に対し5質量%〜30質量%である洗浄剤組成物。 - 成分Bが、イソステアリン酸である請求項1に記載の洗浄剤組成物。
- 成分Bの配合量が0.01質量%〜10質量%である請求項1〜2に記載の洗浄剤組成物。
- 成分Dを1質量%以上含む請求項1〜3に記載の洗浄剤組成物。
- 鹸化後の脂肪酸:脂肪酸塩の質量比が10:90〜30:70である請求項1〜4に記載の洗浄剤組成物。
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JP2019001847A true JP2019001847A (ja) | 2019-01-10 |
Family
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023085182A1 (ja) * | 2021-11-12 | 2023-05-19 | 花王株式会社 | 発泡洗浄剤組成物 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06192685A (ja) * | 1992-03-25 | 1994-07-12 | Lion Corp | 透明ジェル状組成物 |
JPH08133962A (ja) * | 1994-11-11 | 1996-05-28 | Kao Corp | 液体身体洗浄剤組成物 |
JPH0940526A (ja) * | 1995-07-28 | 1997-02-10 | Noevir Co Ltd | 無水透明液状洗浄料 |
JPH09157154A (ja) * | 1995-12-04 | 1997-06-17 | Kao Corp | 液体身体洗浄剤組成物 |
JP2000297007A (ja) * | 1999-04-12 | 2000-10-24 | Pola Chem Ind Inc | 発泡性化粧料 |
JP2000297008A (ja) * | 1999-04-12 | 2000-10-24 | Pola Chem Ind Inc | 発泡性化粧料 |
JP2003160470A (ja) * | 2001-11-26 | 2003-06-03 | Kao Corp | 液体身体洗浄剤組成物 |
JP2012149198A (ja) * | 2011-01-21 | 2012-08-09 | Kracie Home Products Ltd | 皮膚洗浄剤組成物 |
-
2017
- 2017-06-12 JP JP2017115301A patent/JP6320602B1/ja active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06192685A (ja) * | 1992-03-25 | 1994-07-12 | Lion Corp | 透明ジェル状組成物 |
JPH08133962A (ja) * | 1994-11-11 | 1996-05-28 | Kao Corp | 液体身体洗浄剤組成物 |
JPH0940526A (ja) * | 1995-07-28 | 1997-02-10 | Noevir Co Ltd | 無水透明液状洗浄料 |
JPH09157154A (ja) * | 1995-12-04 | 1997-06-17 | Kao Corp | 液体身体洗浄剤組成物 |
JP2000297007A (ja) * | 1999-04-12 | 2000-10-24 | Pola Chem Ind Inc | 発泡性化粧料 |
JP2000297008A (ja) * | 1999-04-12 | 2000-10-24 | Pola Chem Ind Inc | 発泡性化粧料 |
JP2003160470A (ja) * | 2001-11-26 | 2003-06-03 | Kao Corp | 液体身体洗浄剤組成物 |
JP2012149198A (ja) * | 2011-01-21 | 2012-08-09 | Kracie Home Products Ltd | 皮膚洗浄剤組成物 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023085182A1 (ja) * | 2021-11-12 | 2023-05-19 | 花王株式会社 | 発泡洗浄剤組成物 |
JP7382476B2 (ja) | 2021-11-12 | 2023-11-16 | 花王株式会社 | 発泡洗浄剤組成物 |
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