JP2018521036A - 防汚オリゴマー化触媒系 - Google Patents
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Abstract
Description
背景
Claims (48)
- ポリマー汚損を低減する触媒系であって、
少なくとも1つのチタネート化合物と、
少なくとも1つのアルミニウム化合物と、
ホスホニウムまたはホスホニウム塩、スルホネートまたはスルホン酸塩、スルホニウムまたはスルホニウム塩、環状部分を含むエステル、無水物、ポリエーテル、及び長鎖アミン末端処理化合物のうちの1つ以上から選択される、防汚剤と、を含む、触媒系。 - 前記防汚剤が、ホスホニウムまたはホスホニウム塩を含む、請求項1に記載の触媒系。
- 前記防汚剤が、テトラアルキルホスホニウムハライド、ホスホニウムマロネート、トリヘキシルテトラデシルホスホニウムハライド、テトラブチルホスホニウムハライド、テトラブチルホスホニウムテトラハロボレート、テトラブチルホスホニウムハライド、テトラブチルホスホニウムヘキサハロホスフェート、及びテトラブチルホスホニウムテトラハロボレートのうちの1つ以上を含む、請求項2に記載の触媒系。
- 前記防汚剤が、スルホネートまたはスルホン酸塩を含む、請求項1に記載の触媒系。
- 前記防汚剤が、ドデシルベンゼンスルホン酸ナトリウム、ジオクチルスルホコハク酸ナトリウム、テトラブチルホスホニウムメタンスルホネート、テトラブチルホスホニウムp−トルエンスルホネート、ヘキサデシルトリメチルアンモニウムp−トルエンスルホネート、3−(ジメチル(オクタデシル)アンモニオ)プロパン−1−スルホネート、3,3’−(1,4−ジドデシルピペラジン−1,4−ジイウム−1,4−ジイル)ビス(プロパン−1−スルホネート)、及び3−(4−(tert−ブチル)ピリジニオ)−1−プロパンスルホネートのうちの1つ以上を含む、請求項4に記載の触媒系。
- 前記防汚剤が、スルホニウムまたはスルホニウム塩を含む、請求項1に記載の触媒系。
- 前記防汚剤が、環状部分を含むエステルを含む、請求項1に記載の触媒系。
- 前記防汚剤が、ε−カプロラクトン及び2−フェニルエチルアセテートのうちの1つ以上を含む、請求項7に記載の触媒系。
- 前記防汚剤が、無水物を含む、請求項1に記載の触媒系。
- 前記無水物が、150g/mol〜200,000g/molの数平均分子量(Mn)を有する無水物末端処理ポリマーである、請求項9に記載の触媒系。
- 前記防汚剤が、150g/mol〜200,000g/molの数平均分子量(Mn)を有するポリエーテルを含む、請求項1に記載の触媒系。
- 前記防汚剤が、長鎖アミン末端処理化合物を含む、請求項1に記載の触媒系。
- 前記防汚剤が、ポリイソブテン−モノ−スクシンイミド及びポリイソブテン−ビス−スクシンイミドのうちの1つ以上を含む、請求項12に記載の触媒系。
- 前記長鎖アミン末端処理化合物が、150g/mol〜200,000g/molの数平均分子量(Mn)を有する、請求項12に記載の触媒系。
- 非ポリマーエーテル化合物をさらに含む、請求項1に記載の触媒系。
- 前記非ポリマーエーテル化合物が、テトラヒドロフラン、ジオキサン、またはテトラヒドロピランである、請求項15に記載の触媒系。
- 前記チタネート化合物のうちの少なくとも1つが、アルキルチタネートである、請求項1に記載の触媒系。
- 前記アルキルチタネートが、構造Ti(OR)4を有し、式中、Rは2〜8個の炭素原子を含む分岐または直鎖アルキル基である、請求項17に記載の触媒系。
- 前記アルキルチタネートが、テトラエチルチタネート、テトライソプロピルチタネート、テトラ−n−ブチルチタネート、または2−テトラエチルヘキシルチタネートから選択される、請求項17に記載の触媒系。
- 前記アルミニウム化合物のうちの少なくとも1つが、構造AlR’3またはAlR’2Hを有し、式中、R’は、2〜8個の炭素原子を含む分岐または直鎖アルキル基である、請求項1に記載の触媒系。
- 前記アルミニウム化合物のうちの少なくとも1つが、トリエチルアルミニウム、トリプロピルアルミニウム、トリ−イソ−ブチルアルミニウム、トリヘキシルアルミニウム、またはアルミノキサンから選択される、請求項1に記載の触媒系。
- 全チタネート化合物対全アルミニウム化合物のモル比が、1:10〜1:1である、請求項1に記載の触媒系。
- 全チタネート化合物対全防汚剤のモル比が、1:10〜1:0.01である、請求項1に記載の触媒系。
- 全チタネート化合物対全非ポリマーエーテル化合物のモル比が、1:10〜1:0である、請求項1に記載の触媒系。
- 1−ブテンを選択的に製造する方法であって、
エチレンを触媒系に接触させて、前記エチレンをオリゴマー化して、1ブテンを選択的に形成させることを含み、前記触媒系が、
少なくとも1つのチタネート化合物と、
少なくとも1つのアルミニウム化合物と、
ホスホニウムまたはホスホニウム塩、スルホネートまたはスルホン酸塩、スルホニウムまたはスルホニウム塩、環状部分を含むエステル、無水物、ポリエーテル、及び長鎖アミン末端処理化合物のうちの1つ以上から選択される、防汚剤と、を含む、方法。 - 前記防汚剤が、ホスホニウムまたはホスホニウム塩を含む、請求項25に記載の触媒系。
- 前記防汚剤が、テトラアルキルホスホニウムハライド、ホスホニウムマロネート、トリヘキシルテトラデシルホスホニウムハライド、テトラブチルホスホニウムハライド、テトラブチルホスホニウムテトラハロボレート、テトラブチルホスホニウムハライド、テトラブチルホスホニウムヘキサハロホスフェート、及びテトラブチルホスホニウムテトラハロボレートのうちの1つ以上を含む、請求項26に記載の触媒系。
- 前記防汚剤が、スルホネートまたはスルホン酸塩を含む、請求項25に記載の触媒系。
- 前記防汚剤が、ドデシルベンゼンスルホン酸ナトリウム、ジオクチルスルホコハク酸ナトリウム、テトラブチルホスホニウムメタンスルホネート、テトラブチルホスホニウムp−トルエンスルホネート、ヘキサデシルトリメチルアンモニウムp−トルエンスルホネート、3−(ジメチル(オクタデシル)アンモニオ)プロパン−1−スルホネート、3,3’−(1,4−ジドデシルピペラジン−1,4−ジイウム−1,4−ジイル)ビス(プロパン−1−スルホネート)、及び3−(4−(tert−ブチル)ピリジニオ)−1−プロパンスルホネートのうちの1つ以上を含む、請求項28に記載の触媒系。
- 前記防汚剤が、スルホニウムまたはスルホニウム塩を含む、請求項25に記載の触媒系。
- 前記防汚剤が、環状部分を含むエステルを含む、請求項25に記載の触媒系。
- 前記防汚剤が、ε−カプロラクトン及び2−フェニルエチルアセテートのうちの1つ以上を含む、請求項31に記載の触媒系。
- 前記防汚剤が、無水物を含む、請求項25に記載の触媒系。
- 前記無水物が、150g/mol〜200,000g/molの数平均分子量(Mn)を有する無水物末端処理ポリマーである、請求項33に記載の触媒系。
- 前記防汚剤が、150g/mol〜200,000g/molの数平均分子量(Mn)を有するポリエーテルを含む、請求項25に記載の触媒系。
- 前記防汚剤が、長鎖アミン末端処理化合物を含む、請求項25に記載の触媒系。
- 前記防汚剤が、ポリイソブテン−モノ−スクシンイミド及びポリイソブテン−ビス−スクシンイミドのうちの1つ以上を含む、請求項36に記載の触媒系。
- 前記長鎖アミン末端処理化合物が、150g/mol〜200,000g/molの数平均分子量(Mn)を有する、請求項25に記載の触媒系。
- 非ポリマーエーテル化合物をさらに含む、請求項25に記載の方法。
- 前記非ポリマーエーテル化合物が、テトラヒドロフラン、ジオキサンまたはテトラヒドロピランである、請求項39に記載の方法。
- 前記チタネート化合物のうちの少なくとも1つが、アルキルチタネートである、請求項25に記載の方法。
- 前記アルキルチタネートが、構造Ti(OR)4を有し、式中、Rは2〜8個の炭素原子を含む分岐または直鎖アルキル基である、請求項41に記載の方法。
- 前記アルキルチタネートが、テトラエチルチタネート、テトライソプロピルチタネート、テトラ−n−ブチルチタネート、または2−テトラエチルヘキシルチタネートから選択される、請求項41に記載の方法。
- 前記アルミニウム化合物のうちの少なくとも1つが、構造AlR’3またはAlR’2Hを有し、式中、R’は、2〜8個の炭素原子を含む分岐または直鎖アルキル基である、請求項25に記載の方法。
- 前記アルミニウム化合物のうちの少なくとも1つが、トリエチルアルミニウム、トリプロピルアルミニウム、トリ−イソ−ブチルアルミニウム、トリヘキシルアルミニウム、またはアルミノキサンから選択される、請求項25に記載の方法。
- 全チタネート化合物対全アルミニウム化合物のモル比が、1:10〜1:1である、請求項25に記載の方法。
- 全チタネート化合物対全防汚剤のモル比が、1:10〜1:0.01である、請求項25に記載の方法。
- 全チタネート化合物対全非ポリマーエーテル化合物のモル比が、1:10〜1:0である、請求項25に記載の方法。
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