JP2018500431A5 - - Google Patents
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- JP2018500431A5 JP2018500431A5 JP2017533760A JP2017533760A JP2018500431A5 JP 2018500431 A5 JP2018500431 A5 JP 2018500431A5 JP 2017533760 A JP2017533760 A JP 2017533760A JP 2017533760 A JP2017533760 A JP 2017533760A JP 2018500431 A5 JP2018500431 A5 JP 2018500431A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- hydrocarbyl
- zinc
- aluminum
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 25
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- -1 3-butene-1- Yl Chemical class 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- 150000001336 alkenes Chemical class 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229920000098 polyolefin Polymers 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 239000012986 chain transfer agent Substances 0.000 claims description 7
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 5
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 4
- VQOXUMQBYILCKR-UHFFFAOYSA-N 1-Tridecene Chemical compound CCCCCCCCCCCC=C VQOXUMQBYILCKR-UHFFFAOYSA-N 0.000 claims description 4
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 4
- ADOBXTDBFNCOBN-UHFFFAOYSA-N 1-heptadecene Chemical compound CCCCCCCCCCCCCCCC=C ADOBXTDBFNCOBN-UHFFFAOYSA-N 0.000 claims description 4
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 claims description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- PJLHTVIBELQURV-UHFFFAOYSA-N 1-pentadecene Chemical compound CCCCCCCCCCCCCC=C PJLHTVIBELQURV-UHFFFAOYSA-N 0.000 claims description 4
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 claims description 4
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 4
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 238000010791 quenching Methods 0.000 claims description 4
- 230000000171 quenching effect Effects 0.000 claims description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007983 Tris buffer Substances 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims description 2
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 claims description 2
- KLAWFKRMCIXRFS-UHFFFAOYSA-N 5-ethenylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C=C)CC1C=C2 KLAWFKRMCIXRFS-UHFFFAOYSA-N 0.000 claims description 2
- IQEPEDROVHGOAR-UHFFFAOYSA-N C(C(C)C)[Al](CCC=C)CC(C)C Chemical compound C(C(C)C)[Al](CCC=C)CC(C)C IQEPEDROVHGOAR-UHFFFAOYSA-N 0.000 claims description 2
- HXHXUOYNZWHFLT-UHFFFAOYSA-N C(CCCC=C)[Al](CCCCC=C)CCCCC=C Chemical compound C(CCCC=C)[Al](CCCCC=C)CCCCC=C HXHXUOYNZWHFLT-UHFFFAOYSA-N 0.000 claims description 2
- HEMYFEFGZYYQSU-UHFFFAOYSA-N C=CCCCCCC[Zn]CCCCCCC=C Chemical compound C=CCCCCCC[Zn]CCCCCCC=C HEMYFEFGZYYQSU-UHFFFAOYSA-N 0.000 claims description 2
- ZXDAZVCFYFCCLZ-UHFFFAOYSA-N C=CCCCC[Zn]CCCCC=C Chemical compound C=CCCCC[Zn]CCCCC=C ZXDAZVCFYFCCLZ-UHFFFAOYSA-N 0.000 claims description 2
- PHUYKZNPNVDCIC-UHFFFAOYSA-N CC[Zn]CCCCC=C Chemical compound CC[Zn]CCCCC=C PHUYKZNPNVDCIC-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- GMDSGSPTIDDIAZ-UHFFFAOYSA-N bis(2-methylpropyl)-oct-7-enylalumane Chemical compound CC(C)C[Al](CC(C)C)CCCCCCC=C GMDSGSPTIDDIAZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000085 borane Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910010277 boron hydride Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 239000012018 catalyst precursor Substances 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229940069096 dodecene Drugs 0.000 claims description 2
- DYSCYJQZDQCNEG-UHFFFAOYSA-N hex-5-enyl-bis(2-methylpropyl)alumane Chemical compound C(C(C)C)[Al](CCCCC=C)CC(C)C DYSCYJQZDQCNEG-UHFFFAOYSA-N 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910012375 magnesium hydride Inorganic materials 0.000 claims description 2
- 239000012685 metal catalyst precursor Substances 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- KYOZLPKCURERER-UHFFFAOYSA-N tris(but-3-enyl)alumane Chemical compound C=CCC[Al](CCC=C)CCC=C KYOZLPKCURERER-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910000051 zinc hydride Inorganic materials 0.000 claims description 2
- ZULTYUIALNTCSA-UHFFFAOYSA-N zinc hydride Chemical compound [ZnH2] ZULTYUIALNTCSA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- ZMVFRPYKRCLPGS-UHFFFAOYSA-N C(C)[Zn]CCCCCCC=C Chemical compound C(C)[Zn]CCCCCCC=C ZMVFRPYKRCLPGS-UHFFFAOYSA-N 0.000 claims 1
- RRWJQXJVEHEZJR-UHFFFAOYSA-N tris(oct-7-enyl)alumane Chemical compound C=CCCCCCC[Al](CCCCCCC=C)CCCCCCC=C RRWJQXJVEHEZJR-UHFFFAOYSA-N 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910007926 ZrCl Inorganic materials 0.000 description 2
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical group CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- ZMZGFLUUZLELNE-UHFFFAOYSA-N 2,3,5-triiodobenzoic acid Chemical compound OC(=O)C1=CC(I)=CC(I)=C1I ZMZGFLUUZLELNE-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- VHNNPTGLWYHNHE-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 VHNNPTGLWYHNHE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- FJMJPZLXUXRLLD-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 FJMJPZLXUXRLLD-UHFFFAOYSA-L 0.000 description 1
- NDJMNNSJDIFFTH-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NDJMNNSJDIFFTH-UHFFFAOYSA-L 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- ZMMRKRFMSDTOLV-UHFFFAOYSA-N cyclopenta-1,3-diene zirconium Chemical compound [Zr].C1C=CC=C1.C1C=CC=C1 ZMMRKRFMSDTOLV-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14200125.4A EP3037438A1 (en) | 2014-12-23 | 2014-12-23 | Process for the preparation of a branched polyolefin |
| EP14200125.4 | 2014-12-23 | ||
| PCT/EP2015/081203 WO2016102690A1 (en) | 2014-12-23 | 2015-12-23 | Process for the preparation of a branched polyolefin |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018500431A JP2018500431A (ja) | 2018-01-11 |
| JP2018500431A5 true JP2018500431A5 (cg-RX-API-DMAC7.html) | 2018-11-22 |
| JP6770960B2 JP6770960B2 (ja) | 2020-10-21 |
Family
ID=52130160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017533760A Active JP6770960B2 (ja) | 2014-12-23 | 2015-12-23 | 分岐ポリオレフィンの調製方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10450388B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP3037438A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6770960B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR102510436B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN107207660B (cg-RX-API-DMAC7.html) |
| SA (1) | SA517381805B1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2016102690A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180251585A1 (en) * | 2015-07-23 | 2018-09-06 | Sabic Global Technologies B.V. | Process for the preparation of a polyolefin having one or multiple pending functionalities |
| KR102081523B1 (ko) | 2015-08-31 | 2020-02-25 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비닐 이동제의 사용을 통해 제조된 중합체 |
| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| US9982067B2 (en) | 2015-09-24 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports |
| US10717826B2 (en) | 2015-12-09 | 2020-07-21 | Sabic Global Technologies B.V. | Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains |
| US10927196B2 (en) | 2016-06-30 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Long chain branched polypropylene via polymerization with aluminum vinyl transfer agent |
| US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2018160277A1 (en) * | 2017-02-28 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2018160276A1 (en) * | 2017-02-28 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| WO2018160278A1 (en) | 2017-03-01 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
| US11472900B2 (en) | 2017-12-22 | 2022-10-18 | Sabic Global Technologies B.V. | Process for preparation of ethylene and propylene ionomer |
| WO2019122455A1 (en) | 2017-12-22 | 2019-06-27 | Sabic Global Technologies B.V. | Process for preparation of amorphous functionalized olefin copolymer |
| KR102320012B1 (ko) | 2018-01-12 | 2021-11-02 | 주식회사 엘지화학 | 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
| JP2022516120A (ja) * | 2018-12-28 | 2022-02-24 | ダウ グローバル テクノロジーズ エルエルシー | 有機金属連鎖移動剤 |
| CN111116811B (zh) * | 2020-01-03 | 2022-07-05 | 天津大学 | 一种1-丁烯/降冰片烯共聚物及其制备方法 |
| WO2022029213A1 (en) * | 2020-08-06 | 2022-02-10 | Total Research & Technology Feluy | Process for preparing ethylene polymers having long chain branches |
| JP7697239B2 (ja) * | 2021-03-22 | 2025-06-24 | 日本ポリエチレン株式会社 | エチレン重合用触媒の製造方法および前記エチレン重合用触媒を含むエチレン重合体またはエチレンとα－オレフィンとの共重合体の製造方法。 |
| EP4482680A1 (en) * | 2022-02-23 | 2025-01-01 | Sealed Air Corporation (US) | Bulk cheese barrier bag |
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| AU2005224257B2 (en) * | 2004-03-17 | 2010-08-19 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| JP4615248B2 (ja) * | 2004-05-07 | 2011-01-19 | 毅 塩野 | 極性基含有環状オレフィン系共重合体の製造方法 |
| JP4982365B2 (ja) | 2004-07-30 | 2012-07-25 | サウディ ベーシック インダストリーズ コーポレイション | 高透明性のプロピレンコポリマー組成物 |
| KR20080055837A (ko) * | 2005-09-15 | 2008-06-19 | 다우 글로벌 테크놀로지스 인크. | 중합가능한 셔틀링제를 통한 촉매성 올레핀 블럭 공중합체 |
| EP2027164B1 (en) | 2006-05-24 | 2012-08-15 | Saudi Basic Industries Corporation | Process for preparing a catalyst component for propylene polymerization |
| CN102471393B (zh) | 2009-07-29 | 2013-12-04 | 陶氏环球技术有限责任公司 | 多功能链穿梭剂 |
| US8570160B2 (en) | 2010-04-09 | 2013-10-29 | William Howard Speegle | Methods and systems for controlling devices via power lines |
| EA029440B1 (ru) | 2011-12-12 | 2018-03-30 | Сауди Бейсик Индастриз Корпорейшн | Способ получения бимодального полиэтилена в присутствии данной системы катализатора |
| US8957172B2 (en) | 2012-08-03 | 2015-02-17 | Exxonmobil Chemical Patents Inc. | Nonsymmetric catalysts comprising salan ligands |
| EP2880097B1 (en) | 2012-08-03 | 2023-10-18 | ExxonMobil Chemical Patents Inc. | Process to prepare a vinyl terminated polyethylene with long chain branching |
| BR112014031937A8 (pt) | 2012-08-03 | 2021-04-06 | Exxonmobil Chemical Patents Inc | catalisadores compreendendo ligantes salen, sistema de catalisador, poliolefina e processo para polimerizar olefinas |
-
2014
- 2014-12-23 EP EP14200125.4A patent/EP3037438A1/en not_active Withdrawn
-
2015
- 2015-12-23 WO PCT/EP2015/081203 patent/WO2016102690A1/en not_active Ceased
- 2015-12-23 CN CN201580075828.6A patent/CN107207660B/zh active Active
- 2015-12-23 US US15/537,926 patent/US10450388B2/en active Active
- 2015-12-23 JP JP2017533760A patent/JP6770960B2/ja active Active
- 2015-12-23 EP EP15816486.3A patent/EP3237460A1/en active Pending
- 2015-12-23 KR KR1020177020264A patent/KR102510436B1/ko active Active
-
2017
- 2017-06-22 SA SA517381805A patent/SA517381805B1/ar unknown
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