JP2018108947A - Skin Cosmetic - Google Patents
Skin Cosmetic Download PDFInfo
- Publication number
- JP2018108947A JP2018108947A JP2016256600A JP2016256600A JP2018108947A JP 2018108947 A JP2018108947 A JP 2018108947A JP 2016256600 A JP2016256600 A JP 2016256600A JP 2016256600 A JP2016256600 A JP 2016256600A JP 2018108947 A JP2018108947 A JP 2018108947A
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- JP
- Japan
- Prior art keywords
- less
- skin
- component
- mass
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Abstract
Description
本発明は、皮膚化粧料に関する。 The present invention relates to a skin cosmetic.
皮膚の正常な代謝において垢となって落屑されるはずの角質層が、紫外線や乾燥などの要因で滞ると角質層全体が固く肥厚し、なめらかさや明るさの低下した外観へと変化することが知られている。このような背景から、本来落屑すべき角質層の除去を促す角質層除去用の化粧料(例えば、特許文献1)が知られている。また、皮膚表面の汚垢を除去後、肌につるつる感及びしっとり感を与えるパック化粧料が提案されている(特許文献2)。 If the stratum corneum, which is supposed to become desquamated in normal metabolism of the skin, is stagnant due to factors such as ultraviolet rays and dryness, the entire stratum corneum becomes hard and thick, and it changes to an appearance with reduced smoothness and brightness. Are known. From such a background, a stratum corneum removal cosmetic (for example, Patent Document 1) that promotes the removal of the stratum corneum that should be desquamated is known. Further, a pack cosmetic that gives a smooth and moist feeling to the skin after removing dirt on the skin surface has been proposed (Patent Document 2).
しかしながら、特許文献1に記載のふきとり用化粧水は、角質層が除去され、肌表面がつるつるになった実感は得られるものの、角質層除去により肌が明るくなったと感じられにくく、また角質層除去された後の肌にスキンケア化粧料を適用した際にその化粧料の浸透が促進されているという感覚が得られるものではなかった。また、特許文献2に記載のパック化粧料では、その後に適用する化粧料の浸透促進感は得られるものの、使用後の肌の明るさ感及び角質層の除去感(つるつる感)に劣るものであった。 However, the skin lotion for wiping described in Patent Document 1 has a feeling that the stratum corneum has been removed and the skin surface has become smooth, but it is difficult to feel that the skin has become brighter due to the removal of the stratum corneum. When the skin care cosmetic was applied to the skin after being applied, the sense that the penetration of the cosmetic was promoted was not obtained. In addition, in the pack cosmetic described in Patent Document 2, although a feeling of promoting penetration of the cosmetic applied thereafter is obtained, it is inferior to the brightness of the skin after use and the feeling of removing the stratum corneum (smooth feeling). there were.
したがって本発明は、使用後の角質層の除去感(つるつる感)と肌の明るさ感に優れ、かつ、その後に適用する化粧料の浸透促進感にも優れる皮膚化粧料に関する。 Therefore, the present invention relates to a skin cosmetic that is excellent in the feeling of removing the stratum corneum after use (smooth feeling) and the brightness of the skin, and also excellent in the penetration permeation of the cosmetic applied thereafter.
本発明者は、上記課題に鑑みて鋭意検討した結果、低級アルコール及び特定の高重合シリコーン油とともに、特定の形状及び大きさの無機粉末と特定のHLBを有するポリエーテル変性シリコーンを併用することにより、上記課題が達成されることを見いだし、本発明を完成するに至った。 As a result of intensive studies in view of the above problems, the present inventor, together with a lower alcohol and a specific highly polymerized silicone oil, together with an inorganic powder having a specific shape and size and a polyether-modified silicone having a specific HLB The inventors have found that the above-mentioned problems can be achieved and have completed the present invention.
すなわち、本発明は次の成分(A)〜(D)を含有し、成分(D)に対する成分(A)の質量比[(A)/(D)]が0.5以上20以下である皮膚化粧料を提供するものである。
(A) 平均粒子径が20μm未満である板状無機体質粉末
(B) 低級アルコール
(C) 動粘度が6,000mm2/s以上100,000mm2/s以下である高重合直鎖状シリコーン油
(D) HLBが12以上のポリエーテル変性シリコーン
That is, the present invention contains the following components (A) to (D), and a skin cosmetic wherein the mass ratio [(A) / (D)] of the component (A) to the component (D) is 0.5 or more and 20 or less. Is to provide.
(A) Plate-like inorganic extender powder having an average particle size of less than 20 μm
(B) Lower alcohol
(C) a high polymerization linear silicone oils kinematic viscosity is less than 6,000 mm 2 / s or more 100,000 mm 2 / s
(D) Polyether-modified silicone with HLB of 12 or more
本発明の皮膚化粧料は、使用後の角質層の除去感(つるつる感)と肌の明るさ感に優れ、かつ、本発明の皮膚化粧料の後に適用する化粧料の浸透促進感にも優れる。 The skin cosmetic of the present invention is excellent in the feeling of removing the stratum corneum after use (smooth feeling) and the brightness of the skin, and is also excellent in the penetration promotion feeling of the cosmetic applied after the skin cosmetic of the present invention. .
〔成分(A):平均粒子径が20μm未満の板状無機体質粉末〕
成分(A)は、平均粒子径が20μm未満の板状無機体質粉末である。ここでいう「体質粉末」とは、化粧料は化粧料に基本的な形や使用感などの特性をもたせるために使用される粉体であり、酸化鉄等の色材、雲母チタン等のパール顔料とは区別されるものである。また、「板状」とは、平均アスペクト比が3〜600であることをいう。
[Component (A): Plate-like inorganic material powder having an average particle size of less than 20 μm]
Component (A) is a plate-like inorganic powder having an average particle size of less than 20 μm. The term “external powder” as used herein is a powder used to give cosmetics basic properties such as shape and feeling of use. Color materials such as iron oxide and pearls such as titanium mica. A distinction is made from pigments. “Plate” means that the average aspect ratio is 3 to 600.
成分(A)の平均粒子径は、使用後の肌の明るさを実感できる観点から、20μm未満であって、好ましくは18μm以下、より好ましくは15μm以下であり、また、好ましくは0.1μm以上、より好ましくは1μm以上、更に好ましくは5μm以上である。成分(A)の平均粒子径は、例えば、レーザー回折/散乱式粒度分布計LMS-350(セイシン企業社製)を用いて測定することができ、「平均粒子径」は、得られる累積粒度分布曲線におけるD50(累積体積頻度が粒径の小さい方から計算して50%になる粒径)の点、すなわち体積中位径を意味する。 The average particle diameter of the component (A) is less than 20 μm, preferably 18 μm or less, more preferably 15 μm or less, and preferably 0.1 μm or more, from the viewpoint of realizing the brightness of the skin after use. More preferably, it is 1 micrometer or more, More preferably, it is 5 micrometers or more. The average particle size of component (A) can be measured using, for example, a laser diffraction / scattering particle size distribution analyzer LMS-350 (manufactured by Seishin Enterprise Co., Ltd.), and the “average particle size” is the cumulative particle size distribution obtained. It means the point of D50 in the curve (the particle diameter at which the cumulative volume frequency is 50% calculated from the smaller particle diameter), that is, the volume median diameter.
成分(A)の平均アスペクト比としては、肌の明るさ、ふき取り後の肌のつるつる感を向上させる観点から、5以上が好ましく、10以上がより好ましく、20以上が更に好ましく、また、400以下が好ましく、200以下がより好ましく、100以下が更に好ましい。 The average aspect ratio of the component (A) is preferably 5 or more, more preferably 10 or more, still more preferably 20 or more, and more preferably 400 or less from the viewpoint of improving the brightness of the skin and the smoothness of the skin after wiping. Is preferably 200 or less, more preferably 100 or less.
ここで、平均アスペクト比は、(平均粒子径)/(平均粒子厚さ)により求め、小数点以下を四捨五入した値とした。平均粒子厚さは、透過型電子顕微鏡写真の同視野中の厚さを読み取り、読み取れるすべての粒子の厚さの算術平均より求めた。 Here, the average aspect ratio was determined by (average particle diameter) / (average particle thickness), and was rounded off to the nearest decimal point. The average particle thickness was determined by reading the thickness in the same field of the transmission electron micrograph and calculating the arithmetic average of the thicknesses of all the particles that could be read.
成分(A)の屈折率としては、肌の自然なつや感が得られ、肌の明るさを向上させる観点から、2.5以下が好ましく、2.2以下がより好ましく、2以下が更に好ましく、1.8以下が更に好ましく、1.6以下が更に好ましく、また、1.4以上が好ましく、1.5以上がより好ましい。 The refractive index of the component (A) is preferably 2.5 or less, more preferably 2.2 or less, further preferably 2 or less, and more preferably 1.8 or less, from the viewpoint of obtaining a natural gloss feeling of the skin and improving skin brightness. More preferably, 1.6 or less is more preferable, 1.4 or more is preferable, and 1.5 or more is more preferable.
成分(A)としては、具体的にはマイカ(屈折率:1.53〜1.59)、無水ケイ酸(屈折率:1.45)、セリサイト(屈折率:1.55〜1.58)、カオリン(屈折率:1.56)、合成金雲母(屈折率:1.55〜1.59)、タルク(屈折率:1.53〜1.59)、ベントナイト(屈折率:1.47〜1.58)、ケイ酸アルミニウムマグネシウム(屈折率:1.52)、窒化ホウ素(屈折率:2.17)、硫酸バリウム(屈折率:1.64)等が挙げられる。これらの中でも、安定に配合できる観点から、マイカ、無水ケイ酸、カオリン、タルクから選ばれる1種以上を含むことが好ましく、マイカ、無水ケイ酸がより好ましい。 Specific examples of the component (A) include mica (refractive index: 1.53 to 1.59), silicic anhydride (refractive index: 1.45), sericite (refractive index: 1.55 to 1.58), kaolin (refractive index: 1.56), Synthetic phlogopite (refractive index: 1.55-1.59), talc (refractive index: 1.53-1.59), bentonite (refractive index: 1.47-1.58), aluminum magnesium silicate (refractive index: 1.52), boron nitride (refractive index: 2.17) ), Barium sulfate (refractive index: 1.64), and the like. Among these, from the viewpoint of stable blending, it is preferable to include one or more selected from mica, silicic anhydride, kaolin, and talc, and mica and silicic anhydride are more preferable.
本発明の皮膚化粧料中における成分(A)の含有量は、使用直後の肌の明るさ感を向上させる観点から、好ましくは0.1質量%以上、より好ましくは0.2質量%以上であり、また、好ましくは1.0質量%以下、より好ましくは0.8質量%以下、更に好ましくは0.5質量%以下である。 The content of the component (A) in the skin cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, from the viewpoint of improving the feeling of skin brightness immediately after use, Preferably it is 1.0 mass% or less, More preferably, it is 0.8 mass% or less, More preferably, it is 0.5 mass% or less.
<成分(B):低級アルコール>
成分(B)は、低級アルコールである。成分(B)としては、炭素数1〜4の飽和一価アルコールから選ばれる1種以上を含むことが好ましく、エタノール、ブタノール、イソプロパノール、プロパノールがより好ましく、エタノールが更に好ましい。
<Component (B): Lower alcohol>
Component (B) is a lower alcohol. The component (B) preferably contains one or more selected from saturated monohydric alcohols having 1 to 4 carbon atoms, more preferably ethanol, butanol, isopropanol, and propanol, and still more preferably ethanol.
本発明の皮膚化粧料中における成分(B)の含有量は、角質層の除去感(つるつる感)を向上させる観点から、好ましくは1質量%以上、より好ましくは3質量%以上、更に好ましくは6質量%以上であり、また、好ましくは25質量%以下、より好ましくは20質量%以下、更に好ましくは15質量%以下である。 The content of the component (B) in the skin cosmetic of the present invention is preferably 1% by mass or more, more preferably 3% by mass or more, and still more preferably from the viewpoint of improving the feeling of removing the stratum corneum (smooth feeling). It is 6% by mass or more, preferably 25% by mass or less, more preferably 20% by mass or less, and further preferably 15% by mass or less.
<成分(C):動粘度が6,000mm2/s以上100,000mm2/s以下である高重合直鎖状シリコーン油>
成分(C)の動粘度が6,000mm2/s以上100,000mm2/s以下である高重合直鎖状シリコーン油としては、メチルシリコーン鎖を直鎖状に重合させた化合物が好ましく、なかでもジメチルポリシロキサンが好ましい。
<Component (C): a high polymerization linear silicone oils kinematic viscosity is less than 6,000 mm 2 / s or more 100,000 mm 2 / s>
The high polymer linear silicone oils kinematic viscosity of component (C) is less than 6,000 mm 2 / s or more 100,000 mm 2 / s, a compound obtained by polymerizing methyl silicone chain linear are preferred, dimethyl Polysiloxane is preferred.
成分(C)は、角質層の除去感(つるつる感)を向上させる観点から、ウベローデ粘度計を用いて測定した1気圧下、25℃での動粘度が、6,000mm2/s以上であって、好ましくは8,000mm2/s以上、より好ましくは10,000mm2/s以上であり、また、100,000mm2/s以下であって、好ましくは70,000mm2/s以下、より好ましくは50,000mm2/s以下である。 Component (C) has a kinematic viscosity of 6,000 mm 2 / s or more at 25 ° C. under 1 atm measured using an Ubbelohde viscometer from the viewpoint of improving the removal feeling (smooth feeling) of the stratum corneum. , preferably 8,000 mm 2 / s or more, more preferably 10,000 mm 2 / s or more, equal to or less than 100,000 mm 2 / s, preferably 70,000mm 2 / s or less, more preferably 50,000 mm 2 / s or less.
本発明の皮膚化粧料中における成分(C)の含有量は、角質層の除去感(つるつる感)を向上させる観点から、好ましくは0.01質量%以上、より好ましくは0.02質量%以上、更に好ましくは0.03質量%以上であり、また、好ましくは0.5質量%以下、より好ましくは0.3質量%以下、更に好ましくは0.1質量%以下である。 The content of the component (C) in the skin cosmetic of the present invention is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, and still more preferably from the viewpoint of improving the feeling of removing the stratum corneum (smooth feeling). It is 0.03% by mass or more, preferably 0.5% by mass or less, more preferably 0.3% by mass or less, and still more preferably 0.1% by mass or less.
〔成分(D):HLBが12以上のポリエーテル変性シリコーン〕
成分(D)のポリエーテル変性シリコーンは、メチルシリコーン鎖を主鎖とし、ポリオキシエチレン基からなる側鎖をもつ化合物であり、具体的には、下記一般式(1)で表されるものから選ばれる1種以上を含むことが好ましい。
[Component (D): polyether-modified silicone with HLB of 12 or more]
The polyether-modified silicone of component (D) is a compound having a methyl silicone chain as the main chain and a side chain composed of a polyoxyethylene group, specifically, from the compound represented by the following general formula (1) It is preferable to include one or more selected.
〔式中、Rは炭素数1〜4のアルキル基を示し、mは5〜50の整数、nは2〜10の整数、pは10〜50の整数をそれぞれ示す。〕 [Wherein, R represents an alkyl group having 1 to 4 carbon atoms, m represents an integer of 5 to 50, n represents an integer of 2 to 10, and p represents an integer of 10 to 50, respectively. ]
成分(D)のHLBは、浸透促進感の向上の観点から、12以上であって、好ましくは13以上であり、また、好ましくは20以下、より好ましくは19以下である。 The HLB of component (D) is 12 or more, preferably 13 or more, and preferably 20 or less, more preferably 19 or less, from the viewpoint of improving the penetration promotion feeling.
またHLBが異なる2種以上のポリエーテル変性シリコーンを使用する場合は、それらの加重平均で求めたHLBが上記範囲になればよい。なお、HLBとは、親水性と親油性のバランスを表す指標であり、本発明においては、以下のグリフィン(Griffin)の式(2)により求められるものを指す。
HLB=20×親水基部の分子量の総和/分子量 (2)
Further, when two or more kinds of polyether-modified silicones having different HLBs are used, the HLB obtained by weighted average thereof may be in the above range. HLB is an index representing the balance between hydrophilicity and lipophilicity, and in the present invention, it is obtained by the following Griffin equation (2).
HLB = 20 x total molecular weight of hydrophilic base / molecular weight (2)
本発明の皮膚化粧料中における成分(D)の含有量は、本化粧料の後に適用する化粧料の浸透促進感を向上させる観点から、好ましくは0.01質量%以上、より好ましくは0.05質量%以上、更に好ましくは0.08質量%以上であり、また、好ましくは2質量%以下、より好ましくは1質量%以下、更に好ましくは0.5質量%以下、更に好ましくは0.25質量%以下である。 The content of the component (D) in the skin cosmetic of the present invention is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, from the viewpoint of improving the penetration promotion feeling of the cosmetic applied after the cosmetic. Further, it is 0.08% by mass or more, preferably 2% by mass or less, more preferably 1% by mass or less, still more preferably 0.5% by mass or less, and further preferably 0.25% by mass or less.
本発明の皮膚化粧料における成分(D)に対する成分(A)の質量比[(A)/(D)]は、経日安定性及び後に使用する化粧料の浸透促進感を向上させる観点から、0.5以上であって、好ましくは0.75以上、より好ましくは1以上であり、また、20以下であって、好ましくは10以下、より好ましくは7.5以下である。 The mass ratio [(A) / (D)] of the component (A) to the component (D) in the skin cosmetic of the present invention is from the viewpoint of improving the stability over time and the permeation promotion feeling of the cosmetic used later. 0.5 or more, preferably 0.75 or more, more preferably 1 or more, and 20 or less, preferably 10 or less, more preferably 7.5 or less.
〔成分(E):多価アルコール〕
本発明の皮膚化粧料には、分散安定性の向上のため、更に成分(E)として多価アルコールを含有させることが好ましい。
[Component (E): Polyhydric alcohol]
In order to improve dispersion stability, the skin cosmetic of the present invention preferably further contains a polyhydric alcohol as component (E).
成分(E)としては、例えば、ジプロピレングリコール、プロピレングリコール、ブチレングリコール、グリセリン、ジグリセリン、エチレングリコール、ポリエチレングリコールから選ばれる1種以上を含むことが好ましく、これらのうちジプロピレングリコールを含むことがより好ましい。 As the component (E), for example, it is preferable to include one or more selected from dipropylene glycol, propylene glycol, butylene glycol, glycerin, diglycerin, ethylene glycol, and polyethylene glycol, and of these, dipropylene glycol is included. Is more preferable.
本発明の皮膚化粧料中における多価アルコールの含有量は、分散安定性と保湿効果を向上させる観点から、好ましくは0.1質量%以上、より好ましくは0.5質量%以上、更に好ましくは1.0質量%以上であり、また、好ましくは10質量%以下、より好ましくは5質量%以下、更に好ましくは2質量%以下である。 The content of the polyhydric alcohol in the skin cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and still more preferably 1.0% by mass or more, from the viewpoint of improving dispersion stability and moisturizing effect. Moreover, it is preferably 10% by mass or less, more preferably 5% by mass or less, and still more preferably 2% by mass or less.
〔成分(F):水溶性高分子〕
本発明の皮膚化粧料には、分散安定性及び経日安定性の向上のため、更に成分(F)として水溶性高分子を含有させることが好ましい。
[Component (F): Water-soluble polymer]
The skin cosmetic of the present invention preferably further contains a water-soluble polymer as component (F) in order to improve dispersion stability and aging stability.
成分(F)としては、カルボキシビニルポリマー、アルキル変性カルボキシビニルポリマー、キサンタンガム、ローカストビーンガム、プルラン、アラビアゴム、タマリンドガム、カラギーナン、ヒアルロン酸、アルギン酸、寒天、デンプンから選ばれる1種以上を含むことが好ましく、カルボキシビニルポリマーを含むことがより好ましい。 Component (F) includes at least one selected from carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, xanthan gum, locust bean gum, pullulan, gum arabic, tamarind gum, carrageenan, hyaluronic acid, alginic acid, agar, and starch. It is more preferable that it contains a carboxyvinyl polymer.
本発明の皮膚化粧料中における水溶性高分子の含有量は、分散安定性及び経日安定性を向上させる観点から、好ましくは0.01質量%以上、より好ましくは0.05質量%以上、更に好ましくは0.1質量%以上であり、また、好ましくは3質量%以下より好ましくは1.5質量%以下、更に好ましくは0.7質量%以下である。 The content of the water-soluble polymer in the skin cosmetic of the present invention is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and still more preferably 0.1% from the viewpoint of improving dispersion stability and aging stability. The content is not less than 3% by mass, preferably not more than 3% by mass, more preferably not more than 1.5% by mass, and still more preferably not more than 0.7% by mass.
〔色材、パール顔料〕
本発明の皮膚化粧料には、肌色を調整する目的で色材やパール顔料を含有させることができる。色材としては、カーボンブラック、酸化鉄、ベンガラ、グンジョウ、コンジョウ、酸化クロム、水酸化クロム、チタン酸リチウムコバルト等が挙げられる。パール顔料としては、雲母チタン、塩基性炭酸鉛、オキシ塩化ビスマス等が挙げられる。
[Color material, pearl pigment]
The skin cosmetic of the present invention can contain a color material and a pearl pigment for the purpose of adjusting the skin color. Examples of the color material include carbon black, iron oxide, bengara, gunjo, koji, chromium oxide, chromium hydroxide, and lithium cobalt titanate. Examples of the pearl pigment include mica titanium, basic lead carbonate, and bismuth oxychloride.
本発明の皮膚化粧料中における色材及びパール顔料の含流量は、肌の自然なツヤ感、明るさを得る観点から、0.1質量%以下であることが好ましく、0.05質量%以下であることがより好ましく、0.01質量%以下であることが更に好ましく、実質的に含有していないことが更に好ましい。 The flow rate of the coloring material and the pearl pigment in the skin cosmetic of the present invention is preferably 0.1% by mass or less, and preferably 0.05% by mass or less from the viewpoint of obtaining a natural glossy feeling and brightness of the skin. More preferably, it is more preferably 0.01% by mass or less, and still more preferably substantially not contained.
〔その他の任意成分〕
本発明の皮膚化粧料には、以上の成分のほかに、目的に応じて本発明の効果を損なわない範囲内で、成分(C)を除く油剤、界面活性剤、植物エキス、ビタミン類、酸化防止剤、防菌防腐剤、消炎剤、血行促進剤、昆虫忌避剤、塩類、キレート剤、中和剤、pH調整剤、香料等を含有することができる。なお、これら各剤は、各剤としての用途に限られず、目的に応じて他の用途にも用いられる。
[Other optional ingredients]
The skin cosmetic of the present invention includes, in addition to the above components, oils, surfactants, plant extracts, vitamins, oxidants, excluding component (C), as long as the effects of the present invention are not impaired depending on the purpose. Inhibitors, antibacterial and antiseptics, anti-inflammatory agents, blood circulation promoters, insect repellents, salts, chelating agents, neutralizing agents, pH adjusters, fragrances and the like can be contained. In addition, these each agent is not restricted to the use as each agent, It is used also for another use according to the objective.
〔用途、使用方法、形態〕
本発明の皮膚化粧料は、角質層を除去する観点から、ふき取り用の化粧料として用いることが好ましい。使用方法としては、本発明の皮膚化粧料を、化粧用コットン等に適量含ませるか又は適量手に取り、肌に塗布した後、ふき取ることが好ましい。より好ましくは、コットンに定量含ませ、肌に塗布後、ふき取る使用方法が好ましい。
[Use, usage, form]
The skin cosmetic of the present invention is preferably used as a cosmetic for wiping from the viewpoint of removing the stratum corneum. As a method of use, it is preferable that the skin cosmetic composition of the present invention is contained in an appropriate amount in a cosmetic cotton or the like, or taken in an appropriate amount and applied to the skin, and then wiped off. More preferably, a method of using a fixed amount in cotton and wiping after application to the skin is preferred.
本発明の皮膚化粧料の形態は、液状、ゲル状、ペースト状、クリーム状など適宜選択できるが、成分(A)の分散安定性、及びふき取り用途での使用形態から、ゲル状が好ましく、ローション、乳液、保湿液、美容液等に応用することができる。 The form of the skin cosmetic of the present invention can be appropriately selected from a liquid form, a gel form, a paste form, a cream form, etc., but from the dispersion stability of the component (A) and a use form for wiping, a gel form is preferred, and a lotion It can be applied to milky lotion, moisturizing liquid, cosmetic liquid and the like.
〔粘度〕
本発明の皮膚化粧料の25℃における粘度は、成分(A)の分散安定性を向上する観点、及びふき取り使用に好適なものとする観点から、好ましくは1,000mPa・s以上、より好ましくは3,000mPa・s以上、更に好ましくは5,000mPa・s以上であり、また、好ましくは20,000mPa・s以下、より好ましくは17,000mPa・s以下、更に好ましくは15,000mPa・s以下である。ここで、25℃における粘度は、B型粘度計を用いて、ローターNo.4、回転数12rpmで30秒測定した時の粘度を指す。
〔viscosity〕
The viscosity at 25 ° C. of the skin cosmetic of the present invention is preferably 1,000 mPa · s or more, more preferably 3,000, from the viewpoint of improving the dispersion stability of the component (A) and making it suitable for use in wiping. mPa · s or more, more preferably 5,000 mPa · s or more, preferably 20,000 mPa · s or less, more preferably 17,000 mPa · s or less, and further preferably 15,000 mPa · s or less. Here, the viscosity at 25 ° C. refers to the viscosity when measured for 30 seconds using a B-type viscometer at rotor No. 4 and 12 rpm.
〔製造方法〕
本発明の皮膚化粧料は、所定の成分を適宜混合することによって製造することができ、混合する順序によらず、全成分を均一に混合・分散することにより製造することができる。具体的には、本発明の皮膚化粧料は、成分(A)〜(D)、及びその他の任意成分を混合攪拌する工程を含む方法により製造することができる。また、混合攪拌する工程においては、必要に応じて加熱する工程を含んでいてもよい。当該加熱温度は、各成分を十分に溶解させる観点から、好ましくは50℃以上、より好ましくは55℃以上であり、また、好ましくは90℃以下、より好ましくは85℃以下である
〔Production method〕
The skin cosmetic of the present invention can be produced by appropriately mixing predetermined components, and can be produced by uniformly mixing and dispersing all the components regardless of the mixing order. Specifically, the skin cosmetic of the present invention can be produced by a method including a step of mixing and stirring the components (A) to (D) and other optional components. Moreover, the step of mixing and stirring may include a step of heating as necessary. The heating temperature is preferably 50 ° C or higher, more preferably 55 ° C or higher, and preferably 90 ° C or lower, more preferably 85 ° C or lower, from the viewpoint of sufficiently dissolving each component.
実施例1〜6及び比較例1〜8
表1に示す組成のふき取り用化粧料を下記製造方法にて製造し、経日安定性、及び以下の使用感について評価した。
Examples 1-6 and Comparative Examples 1-8
A wiping cosmetic material having the composition shown in Table 1 was produced by the following production method and evaluated for stability over time and the following feeling of use.
(製法)
成分2〜6及び10〜12を60℃で均一に溶解させ、成分7及び8を加え60℃で混合し、成分9を加えて中和する。成分1を前記混合物に添加後、ホモミキサーを用いて撹拌し、混合物を30℃まで冷却してふきとり用化粧料を得る。
(Manufacturing method)
Ingredients 2-6 and 10-12 are uniformly dissolved at 60 ° C, ingredients 7 and 8 are added and mixed at 60 ° C, and ingredient 9 is added to neutralize. After component 1 is added to the mixture, the mixture is stirred using a homomixer, and the mixture is cooled to 30 ° C. to obtain a wiping cosmetic.
(1)経日安定性
表1の各化粧料をガラス容器(容量50mL)に50gずつ充填し、密閉して45℃の環境下に3か月間静置した。3か月後に、目視により沈殿や分離の有無、試料の粘度変化及び外観の変化(変色)を観察し、以下の基準に従って評価した。
○:試料の粘度変化、外観変化(変色)及び沈殿や分離は生じていない
△:沈殿や分離は生じていないが、試料の粘度変化又は外観の変化が生じている
×:沈殿や分離が生じている
(1) Daily stability 50 g of each cosmetic material in Table 1 was filled in a glass container (capacity 50 mL), sealed, and allowed to stand in a 45 ° C. environment for 3 months. After 3 months, the presence or absence of precipitation or separation, the change in viscosity of the sample, and the change in appearance (discoloration) were visually observed and evaluated according to the following criteria.
○: Viscosity change, appearance change (discoloration) of the sample and precipitation or separation did not occur. Δ: No precipitation or separation occurred, but viscosity change or appearance change of the sample occurred. X: Precipitation or separation occurred. ing
(2)使用感
「肌の明るさ感」、「ふき取った後のつるつる感」
表1のふき取り用化粧料(2mL)を化粧用コットン(カネボウ とりさるコットン)に含ませ肌に塗布後、同コットンでふき取った後のつるつる感・肌の明るさ感に関する使用試験を行った。
ふき取った後のつるつる感は、つるつる感を感じた場合を5点、つるつる感を感じない場合を1点として1点刻みで評価(5段階評価)し、10人の女性評価パネラーによる評価の平均点を求めた。
ふき取った後の肌の明るさは、ふき取った直後から3分の間に肌が明るくなったと感じた場合を3点、3分の間に肌が明るくなったと感じなかった場合を1点として1点刻みで評価(5段階評価)し、10人の女性評価パネラーによる評価の平均点を求めた。
(2) Feeling of use “Skin brightness”, “Smooth after wiping”
The cosmetics for wiping (2 mL) shown in Table 1 were included in cosmetic cotton (Kanebo-removable cotton) and applied to the skin.
The smoothness after wiping is evaluated in 5 points when the feeling of smoothness is felt and when the feeling of smoothness is not felt as one point (five-step evaluation), and the average of the evaluations by 10 female evaluation panelists I asked for a point.
The brightness of the skin after wiping is 1 for 3 points when the skin feels brightened in 3 minutes immediately after wiping, and 1 for the case when the skin is not brightened in 3 minutes Evaluation was made in point increments (5-level evaluation), and the average score of evaluation by 10 female evaluation panelists was obtained.
「浸透促進感」
更に、表1のふき取り用化粧料でふき取った約5分後、化粧水(3mL)を使用した際の化粧水の皮膚への浸透促進感に関する使用試験を行った。
ふき取り化粧料使用後の化粧水が皮膚に浸透していると感じた場合を5点、浸透していると感じなかった場合を1点として1点刻みで評価(5段階評価)し、10人の女性評価パネラーによる評価の平均点を求めた。
"Permeation promotion"
Further, about 5 minutes after wiping with the wiping cosmetic of Table 1, a use test was conducted on the feeling of promoting penetration of the skin into the skin when using skin lotion (3 mL).
5 points when the skin lotion feels that it has penetrated the skin after use of the wiping cosmetic, and 1 point when the skin lotion does not feel penetrated. The average score of evaluation by female evaluation panelists was obtained.
*1:セリサイトFSE(三信鉱工社製)
*2:1886L タルク(Brenntag Specialties, Inc社製)
*3:雲母粉 SA-310(ヤマグチマイカ社製)
*4:TIMIRON SUPERSHEEN MP-1001(メルク社製)
*5:シリコーン KF-96H-3万CS(信越化学工業社製)
*6:シリコーン KF-96A-6CS(信越化学工業株社製)
*7:シリコーン KF-6011(信越化学工業株社製)
*8:シリコーン KF-6013(信越化学工業株社製)
*9:シンタレン K(和光純薬工業社製)
*10:ニッコール HCO-60(医薬用)(日本サーファクタント工業社製)
*11:レオドール TW-L120(花王社製)
* 1: Sericite FSE (Sanshin Mining Co., Ltd.)
* 2: 1886L talc (manufactured by Brenntag Specialties, Inc)
* 3: Mica powder SA-310 (manufactured by Yamaguchi Mica)
* 4: TIMIRON SUPERSHEEN MP-1001 (Merck)
* 5: Silicone KF-96H-30,000CS (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 6: Silicone KF-96A-6CS (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 7: Silicone KF-6011 (Shin-Etsu Chemical Co., Ltd.)
* 8: Silicone KF-6013 (Shin-Etsu Chemical Co., Ltd.)
* 9: Shintalen K (manufactured by Wako Pure Chemical Industries, Ltd.)
* 10: Nikkor HCO-60 (for pharmaceutical use) (manufactured by Nippon Surfactant Co., Ltd.)
* 11: Leodoll TW-L120 (Kao Corporation)
表1より、本発明の実施例は経日安定性に優れ、肌の明るさ、ふき取り後のつるつる感、及び浸透促進効果のいずれも優れるものであった。 From Table 1, the examples of the present invention were excellent in day-to-day stability, and all of the brightness of the skin, the smooth feeling after wiping off, and the penetration promoting effect were excellent.
以下、本発明の処方例を記す。いずれも実施例と同等の効果を奏するものである。 Hereinafter, prescription examples of the present invention will be described. Both have the same effects as the embodiment.
処方例1(ふき取り化粧水)
(成分) (質量%)
マイカ(*1) 0.3
ジメチルポリシロキサン(30,000mm2/s)(*5) 0.05
ポリオキシエチレン・メチルポリシロキサン共重合体(HLB14.5)(*7) 0.1
エタノール 10.0
ポリオキシエチレン硬化ヒマシ油(60E.O.)(*10) 1.0
モノラウリン酸ポリオキシエチレンソルビタン(20E.O.) 0.5
1,3-ブチレングリコール 4.0
ジプロピレングリコール 5.0
ポリオキシエチレンメチルグルコシド(20E.O.)(*12) 2.0
フェノキシエタノ−ル 0.3
キサンタンガム(*13) 0.2
メチルセリン(*14) 0.1
N−アセチルグルコサミン(*15) 0.1
海藻エキス(1)(*16) 0.01
ヒアルロン酸ナトリウム(*17) 0.01
チョウジエキス(*18) 0.01
アンズ果汁・濃グリセリン混合液(*19) 0.1
ゲットウ葉エキス(*20) 0.01
香料 0.01
精製水 残量
Formulation example 1 (wipe lotion)
(Ingredient) (mass%)
Mica (* 1) 0.3
Dimethylpolysiloxane (30,000mm 2 / s) (* 5) 0.05
Polyoxyethylene / methylpolysiloxane copolymer (HLB14.5) (* 7) 0.1
Ethanol 10.0
Polyoxyethylene hydrogenated castor oil (60E.O.) (* 10) 1.0
Polyoxyethylene sorbitan monolaurate (20E.O.) 0.5
1,3-butylene glycol 4.0
Dipropylene glycol 5.0
Polyoxyethylene methyl glucoside (20E.O.) (* 12) 2.0
Phenoxyethanol 0.3
Xanthan gum (* 13) 0.2
Methylserine (* 14) 0.1
N-acetylglucosamine (* 15) 0.1
Seaweed extract (1) (* 16) 0.01
Sodium hyaluronate (* 17) 0.01
Clove extract (* 18) 0.01
Apricot juice / concentrated glycerin mixture (* 19) 0.1
Ghetto leaf extract (* 20) 0.01
Fragrance 0.01
Purified water remaining
*12:グルカムE-20(アマコール社製)
*13:サンエースC(三栄源エフ・エフ・アイ社製)
*14:N-メチル-L-セリンT(高砂ケミカル社製)
*15:マリンスウィートF(焼津水産社製)
*16:ALARIANE(BiotechMarine社製)
*17:ヒアルロン酸FCH-SU(紀文フードケミファ社製)
*18:チョウジ抽出液(丸善製薬社製)
*19:アプリコットエキスKS(香栄興業社製)
*20:月桃葉抽出液BG(丸善製薬社製)
* 12: Gurucam E-20 (Amacor)
* 13: San Ace C (manufactured by San-Ei Gen FFI)
* 14: N-methyl-L-serine T (manufactured by Takasago Chemical)
* 15: Marine Sweet F (made by Yaizu Suisan)
* 16: ALARIANE (BiotechMarine)
* 17: Hyaluronic acid FCH-SU (manufactured by Kibun Food Chemifa)
* 18: Clove extract (Maruzen Pharmaceutical Co., Ltd.)
* 19: Apricot extract KS (manufactured by Koei Kogyo Co., Ltd.)
* 20: Moon peach leaf extract BG (Maruzen Pharmaceutical Co., Ltd.)
処方例2(ふき取り用乳液)
(成分) (質量%)
無水ケイ酸(*21) 0.3
ジメチルポリシロキサン(30,000mm2/s)(*5) 0.05
ポリオキシエチレン・メチルポリシロキサン共重合体(HLB14.5)(*7) 0.1
エタノール 10.0
水素添加大豆リン脂質(*22) 0.2
コレステロール 0.1
シクロペンタポリシロキサン 3.0
ミリスチン酸オクチルドデシル 2.0
1,3-ブチレングリコール 8.0
ジプロピレングリコール 5.0
濃グリセリン 2.0
アクリル酸・メタクリル酸アルキル共重合体(*23) 0.1
カルボキシビニルポリマー(*24) 0.02
キサンタンガム 0.1
水酸化カリウム 0.05
エデト酸二ナトリウム 0.02
フェノキシエタノール 0.1
ハイビスカス花エキス(*25) 0.1
乳酸桿菌/セイヨウナシ果汁発酵液(*26) 0.1
豆乳発酵液(*27) 0.1
ヒアルロン酸ジメチルシラノール(*28) 0.1
オランダカラシエキス(*29) 0.1
ノイバラ果実エキス(*30) 0.1
精製水 残量
Formulation Example 2 (Emulsion for wiping off)
(Ingredient) (mass%)
Silicic anhydride (* 21) 0.3
Dimethylpolysiloxane (30,000mm 2 / s) (* 5) 0.05
Polyoxyethylene / methylpolysiloxane copolymer (HLB14.5) (* 7) 0.1
Ethanol 10.0
Hydrogenated soybean phospholipid (* 22) 0.2
Cholesterol 0.1
Cyclopentapolysiloxane 3.0
Octyldodecyl myristate 2.0
1,3-butylene glycol 8.0
Dipropylene glycol 5.0
Concentrated glycerin 2.0
Acrylic acid / alkyl methacrylate copolymer (* 23) 0.1
Carboxyvinyl polymer (* 24) 0.02
Xanthan gum 0.1
Potassium hydroxide 0.05
Edetate disodium 0.02
Phenoxyethanol 0.1
Hibiscus flower extract (* 25) 0.1
Lactobacillus / Pear juice fermented liquid (* 26) 0.1
Soymilk fermentation broth (* 27) 0.1
Dimethylsilanol hyaluronate (* 28) 0.1
Dutch mustard extract (* 29) 0.1
Neubara Fruit Extract (* 30) 0.1
Purified water remaining
*21:アエロジル300(日本アエロジル社製)
*22:コートソームNC-21(日本油脂社製)
*23:PEMULENE TR-1(G.F.Goodroch社製)
*24:シンタレンL(3V SIGMA社製)
*25:ハイビスカスエキス(A)(GREENTECH S.A.社製)
*26:ファーメンテージ セイヨウナシB(一丸ファルコス社製)
*27:豆乳発酵液(三省製薬社製)
*28:D.S.H. C N 6(EXSYMOL s.a.m社製)
*29:ウォータークレスKB(Silab社製)
*30:エイジツ抽出液BG-R(丸善製薬社製)
* 21: Aerosil 300 (Nippon Aerosil)
* 22: Cotesome NC-21 (Nippon Yushi Co., Ltd.)
* 23: PEMULENE TR-1 (manufactured by GFGoodroch)
* 24: Shintalen L (manufactured by 3V SIGMA)
* 25: Hibiscus extract (A) (GREENTECH SA)
* 26: Fermentage pear B (made by Ichimaru Falcos)
* 27: Fermented soymilk (Sansho Pharmaceutical Co., Ltd.)
* 28: DSH CN 6 (manufactured by EXSYMOL sam)
* 29: Watercress KB (Silab)
* 30: Agetsu Extract BG-R (Maruzen Pharmaceutical Co., Ltd.)
処方例3(ふき取り用O/W型マッサージクリーム)
(成分) (質量%)
マイカ(*1) 0.3
ジメチルポリシロキサン(30,000mm2/s)(*5) 0.05
ポリオキシエチレン・メチルポリシロキサン共重合体(HLB14.5)(*7) 0.1
エタノール 6.0
ラウロイル-L-グルタミン酸ナトリウム 0.5
モノオレイン酸ポリオキシエチレンソルビタン(20E.O.) 1.0
トリステアリン酸ポリオキシエチレンソルビタン(20E.O.) 1.5
ポリオキシエチレンソルビットミツロウ(6E.O.) 1.0
ベヘニルアルコール 3.0
親油型モノステアリン酸グリセリン 1.0
ステアリン酸 2.0
ワセリン 3.0
サラシミツロウ 1.0
パルミチン酸セチル 0.5
スクワラン 7.0
トリ2-エチルヘキサン酸グリセリル 3.0
ジメチルポリシロキサン 3.0
マルチトール液(70%水溶液) 3.0
1,3-ブチレングリコール 5.0
ジプロピレングリコール 5.0
キサンタンガム 0.2
フェノキシエタノール 0.5
エデト酸二ナトリウム 0.02
グリチルリチン酸ジカリウム(*31) 0.05
ニコチン酸アミド(*32) 0.2
カンゾウ葉エキス(*33) 0.01
ビターオレンジ果皮エキス(*34) 0.01
スイカズラ花エキス(*35) 0.01
テンチャエキス(*36) 0.1
精製水 残量
Formulation Example 3 (O / W massage cream for wiping)
(Ingredient) (mass%)
Mica (* 1) 0.3
Dimethylpolysiloxane (30,000mm 2 / s) (* 5) 0.05
Polyoxyethylene / methylpolysiloxane copolymer (HLB14.5) (* 7) 0.1
Ethanol 6.0
Lauroyl-L-sodium glutamate 0.5
Polyoxyethylene sorbitan monooleate (20E.O.) 1.0
Polyoxyethylene sorbitan tristearate (20E.O.) 1.5
Polyoxyethylene Sorbit Beeswax (6E.O.) 1.0
Behenyl alcohol 3.0
Lipophilic glyceryl monostearate 1.0
Stearic acid 2.0
Vaseline 3.0
Sarah Beeswax 1.0
Cetyl palmitate 0.5
Squalane 7.0
Glyceryl tri-2-ethylhexanoate3.0
Dimethylpolysiloxane 3.0
Maltitol solution (70% aqueous solution) 3.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Xanthan gum 0.2
Phenoxyethanol 0.5
Edetate disodium 0.02
Dipotassium glycyrrhizinate (* 31) 0.05
Nicotinamide (* 32) 0.2
Daylily extract (* 33) 0.01
Bitter orange peel extract (* 34) 0.01
Honeysuckle Flower Extract (* 35) 0.01
Tencha extract (* 36) 0.1
Purified water remaining
*31:グリチルリチン酸ジカリウム(丸善製薬社製)
*32:ナイアシンアミドUSP PC(DSM Nutritional Products社製)
*33:甘草葉抽出液BG(丸善製薬社製)
*34:トウヒリキッドB(一丸ファルコス社製)
*35:ファルコレックス スイカズラFB(一丸ファルコス社製)
*36:甜茶抽出液BGW(丸善製薬社製)
* 31: Dipotassium glycyrrhizinate (Maruzen Pharmaceutical Co., Ltd.)
* 32: Niacinamide USP PC (DSM Nutritional Products)
* 33: Licorice leaf extract BG (Maruzen Pharmaceutical Co., Ltd.)
* 34: Spruce Liquid B (Ichimaru Falcos)
* 35: Falco Rex Honeysuckle FB (Ichimaru Falcos)
* 36: Green tea extract BGW (Maruzen Pharmaceutical Co., Ltd.)
なお、前記処方例1で用いた香料は、以下のフローラル系調合香料処方である。なお、成分名中に記載される1%DPG、5%DPG、10%DPGとは、香料の有効成分含量がそれぞれ1質量%、5質量%、10質量%のジプロピレングリコール溶液であることを示す。 In addition, the fragrance | flavor used in the said prescription example 1 is the following floral system mixing | blending fragrance | flavor prescription. In addition, 1% DPG, 5% DPG, and 10% DPG described in the component name means that the active ingredient content of the fragrance is 1% by mass, 5% by mass, and 10% by mass, respectively. Show.
フローラル系調合香料処方
(成分) 含有量(質量%)
ベルガモットオイル(天然香料) 2.0
リナリールアセテート 1.5
メチルアンスラニレート 0.2
ペチグレインオイル(天然香料) 0.5
オーランチオール 10%DPG(ヒドロキシシトロネラールとメチルアンスラニレートとのシッフ塩基) 1.0
アミルアリルグリコレート 1%DPG 0.5
ガルバナムオイル 1%DPG(天然香料) 0.1
ブラックカラントバズアブソリュート 10%DPG(天然香料) 1.5
タジェットオイル 10%DPG(天然香料) 0.8
イランイランオイルエキストラ(天然香料) 2.0
ベンジールアセテート 5.0
メチルジヒドロジャスモネート 13.0
シスジャスモン 10%DPG 1.0
ジャスミンアブソリュート(天然香料) 0.5
インドール 5%DPG 0.5
アルファヘキシルシンナミックアルデヒド 1.5
L-シトロネロール 0.5
ローズオイル(天然香料) 0.5
ローズアブソリュート(天然香料) 0.5
ダマセノン 1%DPG 0.5
L-ローズオキサイド 1%DPG 0.5
ジメチルベンジルカーボニルアセテート 1.0
ヒドロキシシトロネラール 3.0
リラール(化合物名:4-(4-ヒドロキシ-4-メチルペンチル)-3-シクロヘキセン-1-カーボキシアルデヒド) 3.5
シクラメンアルデヒド(化合物名:2-メチル-3-(4-イソプロピルフェニル)-プロパノール) 0.5
アルファイソメチルヨノン(化合物名:5-(2,2,6-トリメチル-2-シクロヘキセニル)-3-メチル-3-ブテン-2-オン) 4.0
オリスコンクリート 10%DPG(天然香料) 0.8
メチルオイゲノール 0.5
イソEスーパー(化合物名:7-アセチル-1,2,3,4,5,6,7,8-オクタハイドロ-1,1,6,7-テトラメチルナフタレン) 2.5
ベルトフィックスクール(化合物名:4-アセチル-トリメチル-6,8α-エタノ-1,2,3,5,6,7,8,8α-オクタヒドロナフタレノン) 4.0
ベチバーアセテート 2.0
サンダルウッドオイル(天然香料) 1.5
バグダノール 10%DPG(化合物名:2-エチル-4-(2,2,3-トリメチル-3-シクロペンテン-1-イル)-2-ブテン-1-オール) 1.0
パチュリーオイル 10%DPG(天然香料) 0.2
エベルニール 10%DPG(化合物名:メチル-2,4-ジヒドロキシ-3,6-ジメチルベンゾエート) 1.5
ガラクソリッド 50%ベンジールベンゾエート(化合物名:4,6,6,7,8,8-ヘキサメチル-1,3,4,6,7,8-ヘキサヒロドシクロペンタベンゾピラン) 10.0
シクロペンタデカノリッド 4.0
ヘリオトロピン 0.5
クマリン 0.5
バニリン 10%DPG 0.5
エチルバニリン 10%DPG 2.5
ラズベリーケトン 10%DPG(化合物名:4-(4-ヒドロフェニル)-2-ブタノン) 0.5
ガンマウンデカラクトン 10%DPG 1.5
ガンマデカラクトン 10%DPG 1.5
ラブダナム アブソリュート 10%DPG(天然香料) 0.5
ジプロピレングリコール 残量
Floral-based blended fragrance formulation (component) Content (mass%)
Bergamot oil (natural fragrance) 2.0
Linarel acetate 1.5
Methyl anthranilate 0.2
Pettigrain oil (natural flavor) 0.5
Auranthiol 10% DPG (Schiff base of hydroxycitronellal and methylanthranilate) 1.0
Amyl allyl glycolate 1% DPG 0.5
Galvanum oil 1% DPG (natural fragrance) 0.1
Blackcurrant Buzz Absolute 10% DPG (natural fragrance) 1.5
Tadget oil 10% DPG (natural fragrance) 0.8
Ylang Ylang Oil Extra (natural fragrance) 2.0
Benzyl acetate 5.0
Methyl dihydrojasmonate 13.0
Sis Jasmon 10% DPG 1.0
Jasmine absolute (natural fragrance) 0.5
Indole 5% DPG 0.5
Alphahexyl cinnamic aldehyde 1.5
L-citronellol 0.5
Rose oil (natural fragrance) 0.5
Rose Absolute (natural fragrance) 0.5
Damasenone 1% DPG 0.5
L-Rose oxide 1% DPG 0.5
Dimethylbenzyl carbonyl acetate 1.0
Hydroxycitronellal 3.0
Liral (compound name: 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde) 3.5
Cyclamenaldehyde (Compound name: 2-Methyl-3- (4-isopropylphenyl) -propanol) 0.5
Alpha isomethyl ionone (compound name: 5- (2,2,6-trimethyl-2-cyclohexenyl) -3-methyl-3-buten-2-one) 4.0
Oris Concrete 10% DPG (natural fragrance) 0.8
Methyl eugenol 0.5
Iso-E super (compound name: 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene) 2.5
Belt Fix Cool (compound name: 4-acetyl-trimethyl-6,8α-ethano-1,2,3,5,6,7,8,8α-octahydronaphthalenone) 4.0
Vetiver acetate 2.0
Sandalwood oil (natural fragrance) 1.5
Bagdanol 10% DPG (Compound name: 2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol) 1.0
Patchouli oil 10% DPG (natural fragrance) 0.2
Evernil 10% DPG (Compound name: Methyl-2,4-dihydroxy-3,6-dimethylbenzoate) 1.5
Galac Solid 50% Benzyl Benzoate (Compound name: 4,6,6,7,8,8-Hexamethyl-1,3,4,6,7,8-Hexahydrocyclopentabenzopyran) 10.0
Cyclopentadecanolide 4.0
Heliotropin 0.5
Coumarin 0.5
Vanillin 10% DPG 0.5
Ethyl vanillin 10% DPG 2.5
Raspberry ketone 10% DPG (compound name: 4- (4-hydrophenyl) -2-butanone) 0.5
Gamma undecalactone 10% DPG 1.5
Gamma decalactone 10% DPG 1.5
Love Danum Absolute 10% DPG (natural fragrance) 0.5
Dipropylene glycol
Claims (6)
(A) 平均粒子径が20μm未満である板状無機体質粉末
(B) 低級アルコール
(C) 動粘度が6,000mm2/s以上100,000mm2/s以下である高重合直鎖状シリコーン油
(D) HLBが12以上のポリエーテル変性シリコーン A skin cosmetic comprising the following components (A) to (D), wherein the mass ratio [(A) / (D)] of the component (A) to the component (D) is 0.5 or more and 20 or less.
(A) Plate-like inorganic extender powder having an average particle size of less than 20 μm
(B) Lower alcohol
(C) a high polymerization linear silicone oils kinematic viscosity is less than 6,000 mm 2 / s or more 100,000 mm 2 / s
(D) Polyether-modified silicone with HLB of 12 or more
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JP6804974B2 JP6804974B2 (en) | 2020-12-23 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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US11786445B2 (en) | 2016-10-31 | 2023-10-17 | L'oreal | Composition for natural skin brightening effect |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07330536A (en) * | 1994-06-02 | 1995-12-19 | Shiseido Co Ltd | Cosmetic |
JPH08268831A (en) * | 1995-03-31 | 1996-10-15 | Shiseido Co Ltd | Emulsified cosmetic |
JP2000256129A (en) * | 1999-03-12 | 2000-09-19 | Kose Corp | Pack cosmetic material |
JP2004107221A (en) * | 2002-09-13 | 2004-04-08 | Shiseido Co Ltd | Cosmetic for improving makeup adhesion |
JP2015105259A (en) * | 2013-12-02 | 2015-06-08 | 日本メナード化粧品株式会社 | Pigment dispersion cosmetic |
-
2016
- 2016-12-28 JP JP2016256600A patent/JP6804974B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07330536A (en) * | 1994-06-02 | 1995-12-19 | Shiseido Co Ltd | Cosmetic |
JPH08268831A (en) * | 1995-03-31 | 1996-10-15 | Shiseido Co Ltd | Emulsified cosmetic |
JP2000256129A (en) * | 1999-03-12 | 2000-09-19 | Kose Corp | Pack cosmetic material |
JP2004107221A (en) * | 2002-09-13 | 2004-04-08 | Shiseido Co Ltd | Cosmetic for improving makeup adhesion |
JP2015105259A (en) * | 2013-12-02 | 2015-06-08 | 日本メナード化粧品株式会社 | Pigment dispersion cosmetic |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11786445B2 (en) | 2016-10-31 | 2023-10-17 | L'oreal | Composition for natural skin brightening effect |
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