JP5836608B2 - Cleansing cosmetics - Google Patents
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Description
本発明は、クレンジング化粧料に関する。さらに詳しくは、クレンジング効果、使用感、使用後のさっぱり感に優れ、且つ保存安定性も良好なクレンジング化粧料に関する。 The present invention relates to a cleansing cosmetic. More specifically, the present invention relates to a cleansing cosmetic that is excellent in a cleansing effect, a feeling of use, and a refreshing feeling after use, and also has good storage stability.
従来、皮膚上の皮脂汚れやメイクアップ化粧料を除去するためのクレンジング化粧料としては、液状油等を主成分とする油性クレンジング化粧料、油性成分を界面活性剤により乳化してクリーム状や乳液状にした乳化タイプのクレンジング化粧料、さらに水性成分や水溶性高分子を主成分とする水性クレンジング化粧料等が用いられてきた。 Conventionally, cleansing cosmetics for removing sebum stains and makeup cosmetics on the skin include oily cleansing cosmetics mainly composed of liquid oils, creams and emulsions obtained by emulsifying oily components with a surfactant. Emulsified cleansing cosmetics in the form of an aqueous cleansing cosmetic composition mainly composed of an aqueous component or a water-soluble polymer have been used.
これらのクレンジング化粧料には、環状シリコーン等の揮発性シリコーン油が多用されてきた(特許文献1〜5参照)。環状シリコーン油は、高いクレンジング効果を発揮し、なおかつすっきりと洗い流せる効果が高いなどの優れた特徴を有するが、クレンジング後のさっぱり感については、必ずしも満足できるものではなかった。 For these cleansing cosmetics, volatile silicone oils such as cyclic silicones have been frequently used (see Patent Documents 1 to 5). Cyclic silicone oil has excellent characteristics such as a high cleansing effect and a high cleansing effect, but the refreshing feeling after cleansing is not always satisfactory.
また、使用感を向上させるために高分子増粘剤を配合したクレンジング化粧料では、クレンジング後のさっぱり感を上げるためにイソドデカン、イソヘキサデカン等の揮発性炭化水素油の配合が検討されてきたが、これら揮発性炭化水素油の配合量を上げると分離してしまう場合があり、他の油剤と組合わせる必要があるなど、その使用に制限があった(特許文献6参照)。 In addition, in cleansing cosmetics formulated with a polymer thickener to improve the feeling of use, the blending of volatile hydrocarbon oils such as isododecane and isohexadecane has been studied to increase the refreshing feeling after cleansing. However, when the blending amount of these volatile hydrocarbon oils is increased, they may be separated, and there is a limit to their use, such as the need to combine with other oil agents (see Patent Document 6).
トリス(トリメチルメトキシ)メチルシランは、高い揮発性を有するためメイクアップ化粧料への配合、また減粘剤として乳化化粧料への配合、さらには水溶性抗炎症剤の効果を高めるために皮膚外用剤への配合が検討されている(特許文献7〜9参照)。 Tris (trimethylmethoxy) methylsilane has a high volatility, so it is formulated into makeup cosmetics, formulated into emulsified cosmetics as a thinning agent, and further used as a topical skin preparation to enhance the effectiveness of water-soluble anti-inflammatory agents. The blending of these is being studied (see Patent Documents 7 to 9).
本発明の課題は、クレンジング効果、使用感、使用後のさっぱり感に優れ、且つ保存安定性も良好なクレンジング化粧料を提供することにある。 The subject of this invention is providing the cleansing cosmetics which are excellent in the cleansing effect, the usability | use_condition, the refreshing feeling after use, and are also excellent in storage stability.
本発明者等は、前記課題を解決するために鋭意研究した結果、分岐状の揮発性シリコーンであるトリス(トリメチルシロキシ)メチルシラン、高分子増粘剤及びHLB9以上の非イオン性界面活性剤を組み合わせて配合すると、クレンジング効果が高く、使用時には重さがなく、なめらかで皮膚上での伸びが良く、すすぎ性に優れると共に、使用後におけるさっぱりとした感触にも優れ、さらに保存安定性も良好なクレンジング化粧料が得られることを見出し、本発明を完成させた。 As a result of intensive studies to solve the above problems, the present inventors have combined tris (trimethylsiloxy) methylsilane, which is a branched volatile silicone, a polymer thickener, and a nonionic surfactant of HLB9 or higher. When used, the cleansing effect is high, there is no weight during use, it is smooth and stretches well on the skin, it has excellent rinsing properties, and it has a refreshing feel after use, and also has good storage stability. The present inventors have found that a cleansing cosmetic can be obtained and completed the present invention.
すなわち、本発明は、(A)トリス(トリメチルシロキシ)メチルシランと、(B)高分子増粘剤と、(C)HLB9以上の非イオン性界面活性剤とを含有するクレンジング化粧料を提供するものである。 That is, the present invention provides a cleansing cosmetic containing (A) tris (trimethylsiloxy) methylsilane, (B) a polymer thickener, and (C) a nonionic surfactant of HLB9 or higher. It is.
本発明によれば、クレンジング効果、使用感、使用後のさっぱり感に優れ、さらに保存安定性も良好なクレンジング化粧料を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the cleansing cosmetics which are excellent in the cleansing effect, a feeling of use, and the refreshing feeling after use, and also have favorable storage stability can be provided.
以下、本発明の実施の形態を説明する。 Embodiments of the present invention will be described below.
本発明の成分(A)であるトリス(トリメチルシロキシ)メチルシランは、化学式((CH3)3SiO)3SiCH3で表される分岐状のシリコーン化合物である。トリス(トリメチルシロキシ)メチルシランは市販されているものを用いることができ、例えば、TMF−1.5(信越化学工業株式会社製)が挙げられる。 Tris (trimethylsiloxy) methylsilane which is the component (A) of the present invention is a branched silicone compound represented by the chemical formula ((CH 3 ) 3 SiO) 3 SiCH 3 . What is marketed can be used for tris (trimethylsiloxy) methylsilane, for example, TMF-1.5 (made by Shin-Etsu Chemical Co., Ltd.) is mentioned.
本発明における成分(A)の含有量は、クレンジング化粧料の総量を基準として、好ましくは0.5質量%以上(以下、単に%と略す。)、より好ましくは1%以上、更に好ましくは3%以上、そして、好ましくは40%以下、より好ましくは30%以下、更に好ましくは20%以下である。 The content of the component (A) in the present invention is preferably 0.5% by mass or more (hereinafter simply abbreviated as%), more preferably 1% or more, and further preferably 3 based on the total amount of the cleansing cosmetic. % Or more, preferably 40% or less, more preferably 30% or less, still more preferably 20% or less.
これらの範囲内であれば、より高いクレンジング効果が発揮され、使用後のさっぱり感がより優れたものとなる。 If it is in these ranges, a higher cleansing effect will be exhibited and a refreshing feeling after use will be more excellent.
本発明の成分(B)である高分子増粘剤としては、カルボキシビニルポリマー、アルキル変性カルボキシビニルポリマー、ポリアクリルアミド、(アクリル酸ナトリウム/アクリロイルジメチルタウリン)コポリマー等の合成高分子や、キサンタンガム、カラギニン、セルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、スターチ等の天然高分子又は半合成高分子が挙げられる。 Examples of the polymer thickener as the component (B) of the present invention include synthetic polymers such as carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, polyacrylamide, (sodium acrylate / acryloyldimethyltaurine) copolymer, xanthan gum, carrageenan Natural polymers such as cellulose, hydroxyethyl cellulose, carboxymethyl cellulose and starch, or semi-synthetic polymers.
これらの中でも、アルキル変性カルボキシビニルポリマーは、使用時のなめらかさ、皮膚上での伸びの良さ、クレンジング化粧料の安定性の面で特に優れる。アルキル変性カルボキシビニルポリマーは、アクリル酸とメタクリル酸アルキルの共重合体であり、例えば、PEMULEN TR−1(B.F.Goodrich社製)、PEMULEN TR−2(B.F.Goodrich社製)、Carbopol 1382(B.F.Goodrich社製)等が挙げられる。 Among these, the alkyl-modified carboxyvinyl polymer is particularly excellent in terms of smoothness during use, good elongation on the skin, and stability of cleansing cosmetics. The alkyl-modified carboxyvinyl polymer is a copolymer of acrylic acid and alkyl methacrylate. For example, PEMULEN TR-1 (manufactured by BF Goodrich), PEMULEN TR-2 (manufactured by BF Goodrich), Carbopol 1382 (manufactured by BF Goodrich) and the like.
本発明における成分(B)の含有量は、クレンジング化粧料の総量を基準として、好ましくは0.01%以上、より好ましくは0.05%以上、更に好ましくは0.1%以上、そして、好ましくは10%以下、より好ましくは5.0%以下、更に好ましくは3.0%以下である。 The content of the component (B) in the present invention is preferably 0.01% or more, more preferably 0.05% or more, still more preferably 0.1% or more, and preferably based on the total amount of the cleansing cosmetic. Is 10% or less, more preferably 5.0% or less, and still more preferably 3.0% or less.
これらの範囲内であれば、使用時の感触と製剤の安定性がより優れたものとなる。 Within these ranges, the feel during use and the stability of the preparation will be more excellent.
本発明における成分(C)の非イオン性界面活性剤は、HLB9以上のものである。 The nonionic surfactant of component (C) in the present invention is HLB9 or higher.
ここで、HLB(親水性・親油性バランス)は、グリフィン(Griffin)の式(J,Soc,Cosmet,Chem.,1,311(1949);5,249(1953))により計算されるものである。 Here, HLB (hydrophilic / lipophilic balance) is calculated by the Griffin equation (J, Soc, Cosmet, Chem., 1, 311 (1949); 5,249 (1953)).
本発明で用いる成分(C)の非イオン性界面活性剤は、そのHLBが9以上の非イオン性界面活性剤であれば特に限定されないが、例えば、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレングリセリル脂肪酸エステル、ポリグリセリル脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビトール脂肪酸エステル、ポリオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンアルキルエーテル等が挙げられ、これらは必要に応じて、単独又は2種以上適宜選択して組み合わせて用いることができる。これらの中でも、ポリオキシエチレングリセリル脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油が好ましく用いられる。 The nonionic surfactant of component (C) used in the present invention is not particularly limited as long as its HLB is 9 or more. For example, polyethylene glycol fatty acid ester, polyoxyethylene glyceryl fatty acid ester , Polyglyceryl fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene alkyl ether, and the like. Alternatively, two or more types can be appropriately selected and used in combination. Among these, polyoxyethylene glyceryl fatty acid ester and polyoxyethylene hydrogenated castor oil are preferably used.
本発明において、2種以上の非イオン性界面活性剤を組合わせる場合は、個々のHLBにそれぞれの割合を乗じたものを合計して得られる混合HLBが9以上であればよい。HLBの上限は特に設けないが、好ましくは20以下である。本発明では、HLBが9以上17以下の非イオン性界面活性剤を用いるのが好ましく、特に好ましくはHLBが9以上15以下のものを用いる。これらの範囲であれば、高いクレンジング効果と素早いすすぎ性を両立させることができる。 In the present invention, when two or more kinds of nonionic surfactants are combined, the mixed HLB obtained by summing the individual HLBs multiplied by the respective ratios may be 9 or more. The upper limit of HLB is not particularly provided, but is preferably 20 or less. In the present invention, it is preferable to use a nonionic surfactant having an HLB of 9 to 17, particularly preferably an HLB of 9 to 15. If it is these ranges, a high cleansing effect and quick rinse can be made compatible.
本発明における成分(C)の含有量は、クレンジング化粧料の総量を基準として、好ましくは0.01%以上、より好ましくは0.05%以上、更に好ましくは0.1%以上、そして、好ましくは20%以下、より好ましくは10%以下、更に好ましくは5.0%以下である。 The content of component (C) in the present invention is preferably 0.01% or more, more preferably 0.05% or more, still more preferably 0.1% or more, and preferably, based on the total amount of cleansing cosmetics. Is 20% or less, more preferably 10% or less, and still more preferably 5.0% or less.
これらの範囲内であれば、クレンジング効果、及び使用後の使用感の面でより優れたクレンジング化粧料が得られる。 If it is in these ranges, the cleansing cosmetics more excellent in terms of a cleansing effect and a feeling of use after use can be obtained.
本発明のクレンジング化粧料には、上記必須成分の他に、通常用いられる他の成分を適宜加えることができる。例えば、水、エデト酸塩等のキレート剤、保湿剤、油性成分、美白剤、血行促進剤、抗炎症剤、殺菌剤、紫外線吸収剤、感触向上剤、着色剤、防腐剤、酸化防止剤、香料、動植物抽出物等を挙げることができ、これらを本発明の効果を損なわない範囲で配合することができる。 In addition to the above essential components, other commonly used components can be appropriately added to the cleansing cosmetic of the present invention. For example, chelating agents such as water and edetate, humectants, oily ingredients, whitening agents, blood circulation promoters, anti-inflammatory agents, bactericides, UV absorbers, touch improvers, coloring agents, preservatives, antioxidants, A fragrance | flavor, animal and plant extracts etc. can be mentioned, These can be mix | blended in the range which does not impair the effect of this invention.
油性成分は、主に感触調整を目的として配合され、例えばエステル油、炭化水素油、植物油、シリコーン油、高級脂肪酸、エーテル油、高級アルコール等が挙げられるが、特にエステル油やシリコーン油は、本発明の効果であるすすぎ後のさっぱり感に及ぼす影響が小さいので好ましく用いられる。 The oil component is blended mainly for the purpose of feeling adjustment, and examples thereof include ester oils, hydrocarbon oils, vegetable oils, silicone oils, higher fatty acids, ether oils, higher alcohols, etc. Since the influence on the refreshing feeling after rinsing which is an effect of the invention is small, it is preferably used.
本発明における油性成分の含有量は、クレンジング化粧料の総量を基準として、好ましくは0.1%以上、より好ましくは0.5%以上、更に好ましくは1%以上、そして、好ましくは60%以下、より好ましくは40%以下、更に好ましくは30%以下である。 The content of the oil component in the present invention is preferably 0.1% or more, more preferably 0.5% or more, still more preferably 1% or more, and preferably 60% or less, based on the total amount of the cleansing cosmetic. More preferably, it is 40% or less, and further preferably 30% or less.
本発明のクレンジング化粧料は常法に従って、所定の成分を適宜混合することによって得られ、混合する順序によらず、全成分を均一に混合・分散することにより製造することができる。 The cleansing cosmetic composition of the present invention is obtained by appropriately mixing predetermined components according to a conventional method, and can be produced by uniformly mixing and dispersing all components regardless of the mixing order.
また、使用方法としては、拭き取り使用、洗い流し使用のいずれであっても好適である。 Moreover, as a method of use, it is preferable to use either wiping or washing.
本発明のクレンジング化粧料は、特に、ファンデーション、マスカラ、アイライナー、サンスクリーン等を除去するために好適に使用することができる。 The cleansing cosmetic composition of the present invention can be suitably used for removing foundations, mascaras, eyeliners, sunscreens and the like.
本発明のクレンジング化粧料は、液状、乳液状、ペースト状、ゲル状等の剤型にして使用することができる。 The cleansing cosmetic composition of the present invention can be used in the form of a liquid, emulsion, paste, gel or the like.
以下に、本発明に関して、実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。
なお、実施例13は参考例であって、特許請求の範囲に包含されるものではない。
Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.
Note that Example 13 is a reference example and is not included in the scope of the claims.
表1に記載の配合組成よりなるクレンジング化粧料を常法により調製し、使用試験及び保存安定性試験を、下記の方法にて実施した。
<使用試験>
Cleansing cosmetics having the composition shown in Table 1 were prepared by a conventional method, and a use test and a storage stability test were conducted by the following methods.
<Use test>
女性専門パネラー20名の顔面に市販の油性ファンデーションを塗布し、その30分後、実施例又は比較例のクレンジング化粧料約2gを用い、1分間一定の力及び速さで顔面を手でマッサージし、その後水で洗い流した。 Apply a commercially available oily foundation to the faces of 20 female panelists, and after 30 minutes, massage the face with a constant force and speed for 1 minute using about 2 g of the cleansing cosmetic of Example or Comparative Example. And then rinsed with water.
そして(1)使用感(塗付時の伸び)、(2)クレンジング効果、(3)すすぎ後の感触(さっぱり感)の各項目について評価し、下記基準により5段階評価した。結果を平均値で、表1に併せて示した。
5;非常に良い
4;良い
3;普通
2;やや悪い
1;悪い
<保存安定性試験>
And (1) Usability (elongation at the time of application), (2) Cleansing effect, (3) Feeling after rinsing (feeling refreshed) was evaluated, and five levels were evaluated according to the following criteria. The results are average values and are shown in Table 1.
5; very good 4; good 3; normal 2; somewhat bad 1; bad <storage stability test>
試料を50mLの透明ガラス製容器に入れて密封し、45℃の恒温槽に3ヶ月保存し、目視判定により下記の基準で評価した。その結果を表1に併せて示した。
◎;外観の変化が全くなく、油浮きや分離などが観察されない。
○;ごく僅かに油浮きや分離が認められる。
△;油浮きや分離が認められる。
×;明らかに油浮きや分離が認められる。
The sample was put in a 50 mL transparent glass container, sealed, stored in a 45 ° C. constant temperature bath for 3 months, and evaluated by the following criteria by visual judgment. The results are also shown in Table 1.
A: No change in appearance, no oil floating or separation observed.
○: Oil floatation and separation are observed slightly.
Δ: Oil floating or separation is observed.
X: Oil floating and separation are clearly observed.
表1より明らかなように、本発明の成分を用いた実施例1〜13のクレンジング化粧料は、使用感(塗布時の伸び)、クレンジング効果、すすぎ後の感触(さっぱり感)及び保存安定性の全ての項目において優れた性能を示していた。 As is apparent from Table 1, the cleansing cosmetics of Examples 1 to 13 using the components of the present invention have a feeling of use (elongation at the time of application), a cleansing effect, a feeling after rinsing (a refreshing feeling), and a storage stability. In all the items, excellent performance was shown.
一方、本発明のいずれかの構成を欠く比較例1〜6、比較例8では、使用試験のいずれかの項目又は保存安定性において低い評価を示しており、本発明の目的を達成できなかった。 On the other hand, Comparative Examples 1 to 6 and Comparative Example 8 lacking any configuration of the present invention showed low evaluation in any item of use test or storage stability, and the object of the present invention could not be achieved. .
尚、比較例7のクレンジング化粧料は、調製後すぐに分離してしまうため、使用試験は行わなかった。 In addition, since the cleansing cosmetic of Comparative Example 7 was separated immediately after preparation, no use test was performed.
以下、本発明のクレンジング化粧料のその他の処方例を実施例として挙げる。尚、これらの実施例のクレンジング化粧料についても、使用感(塗布時の伸び)、クレンジング効果、すすぎ後の感触(さっぱり感)及び保存安定性において、優れた特性を有するものであった。 Hereinafter, other prescription examples of the cleansing cosmetic of the present invention will be given as examples. In addition, the cleansing cosmetics of these examples also had excellent characteristics in feeling of use (elongation at the time of application), cleansing effect, feel after rinsing (freshness) and storage stability.
<実施例14(クレンジングミルク)>
(配合成分) (質量%)
・トリス(トリメチルメトキシ)メチルシラン 3.0
(商品名:TMF−1.5;信越化学工業株式会社製)
・イソノナン酸イソノニル 5.0
・オリーブ油 3.0
・α−オレフィンオリゴマー 6.0
・ジメチコン(100cst(0.0001m2/s)) 3.0
・ポリオキシエチレン硬化ヒマシ油(HLB=12.5) 2.0
・トリイソステアリン酸ポリオキシエチレングリセリル 3.0
(HLB=10.9)
・エタノール 3.0
・ジプロピレングリコール 10.0
・グリセリン 10.0
・アクリル・メタクリル酸アルキル共重合体 0.2
(商品名:PEMULEN TR−1;B.F.Goodrich社製)
・キサンタンガム 0.04
・エデト酸二ナトリウム 0.03
・ビフィズス菌エキス 0.1
(商品名:カルチャーB.B.;クルトリヒター社製)
・ホエイエキス 0.1
(商品名:ホエイCPA;一丸ファルコス社製)
・ハチミツ 0.1
(商品名:精製蜂蜜;アピ社製)
・レモンエキス 0.1
(商品名:レモンエキストラリキッド;一丸ファルコス社製)
・カロット液汁 0.1
(商品名:ホモ フルーツ キャロット/N;エスペリス社製)
・シイクワシャー果皮エキス 0.1
(商品名:シークワーサーエキスBG;日油社製)
・水酸化カリウム 0.1
・フェノキシエタノール 0.1
・精製水 残 部
<Example 14 (cleansing milk)>
(Compounding ingredients) (mass%)
・ Tris (trimethylmethoxy) methylsilane 3.0
(Product name: TMF-1.5; manufactured by Shin-Etsu Chemical Co., Ltd.)
-Isononyl isononanoate 5.0
・ Olive oil 3.0
・ Α-olefin oligomer 6.0
・ Dimethicone (100cst (0.0001m 2 / s)) 3.0
・ Polyoxyethylene hydrogenated castor oil (HLB = 12.5) 2.0
・ Polyoxyethylene glyceryl triisostearate 3.0
(HLB = 10.9)
・ Ethanol 3.0
・ Dipropylene glycol 10.0
・ Glycerin 10.0
・ Acrylic / alkyl methacrylate copolymer 0.2
(Brand name: PEMULEN TR-1; manufactured by BF Goodrich)
・ Xanthan gum 0.04
・ Edetic acid disodium 0.03
・ Bifidobacterium extract 0.1
(Brand name: Culture BB; made by Kurtrichter)
・ Whey extract 0.1
(Product name: Whey CPA; manufactured by Ichimaru Falcos)
・ Honey 0.1
(Product name: Refined honey; manufactured by API)
・ Lemon extract 0.1
(Product name: Lemon Extra Liquid; manufactured by Ichimaru Falcos)
・ Carrot juice 0.1
(Product name: Homo Fruit Carrot / N; manufactured by Esperis)
・ Shiiquasha peel extract 0.1
(Product name: Sequwercer Extract BG; manufactured by NOF Corporation)
・ Potassium hydroxide 0.1
・ Phenoxyethanol 0.1
・ Purified water balance
<実施例15(クレンジングミルク)>
(配合成分) (質量%)
・トリス(トリメチルメトキシ)メチルシラン 20.0
(商品名:TMF−1.5;信越化学工業株式会社製)
・ジメチコン(6cst(0.000006m2/s)) 20.0
・ポリオキシエチレン硬化ヒマシ油(HLB=12.5) 4.0
・トリステアリン酸ポリオキシエチレンソルビタン 1.0
(20E.O.、HLB=10.5)
・グリセリン 10.0
・アクリル・メタクリル酸アルキル共重合体 0.1
(商品名:PEMULEN TR−1;B.F.Goodrich社製)
・ヒドロキシプロピルデンプンリン酸 1.0
(商品名:STRUCTURE XL;アクゾノーベル社製)
・キサンタンガム 0.05
・エデト酸二ナトリウム 0.05
・メチルパラベン 0.25
・水酸化カリウム 0.05
・シルク抽出液 0.1
(商品名:シルクプロテインエキス;一丸ファルコス社製)
・L−アスコルビン酸硫酸エステル二ナトリウム 0.01
・カンゾウ抽出末 0.1
(商品名:カンゾウ抽出液;丸善製薬社製)
・ラミナリアオクロロイカエキス 0.1
(商品名:LAMINAINE−BG;
Biotech Marine社製)
・水溶性コラーゲン 0.1
(商品名:Solu−Mar Native;Arch社製)
・フェノキシエタノール 0.3
・精製水 残 部
<Example 15 (cleansing milk)>
(Compounding ingredients) (mass%)
・ Tris (trimethylmethoxy) methylsilane 20.0
(Product name: TMF-1.5; manufactured by Shin-Etsu Chemical Co., Ltd.)
・ Dimethicone (6cst (0.000006m 2 / s)) 20.0
・ Polyoxyethylene hydrogenated castor oil (HLB = 12.5) 4.0
・ Polyoxyethylene sorbitan tristearate1.0
(20E.O., HLB = 10.5)
・ Glycerin 10.0
・ Acrylic / alkyl methacrylate copolymer 0.1
(Brand name: PEMULEN TR-1; manufactured by BF Goodrich)
・ Hydroxypropyl starch phosphate 1.0
(Product name: STRUCTURE XL; manufactured by Akzo Nobel)
・ Xanthan gum 0.05
・ Edetic acid disodium 0.05
・ Methylparaben 0.25
・ Potassium hydroxide 0.05
・ Silk extract 0.1
(Product name: Silk Protein Extract; manufactured by Ichimaru Falcos)
・ L-ascorbic acid sulfate disodium 0.01
・ Liquorice extract powder 0.1
(Product name: Licorice extract; manufactured by Maruzen Pharmaceutical Co., Ltd.)
・ Laminaria blue squid extract 0.1
(Product name: LAMINAINE-BG;
(Biotech Marine)
・ Water-soluble collagen 0.1
(Product name: Solu-Mar Native; made by Arch)
・ Phenoxyethanol 0.3
・ Purified water balance
<実施例16(クレンジングクリーム)>
(配合成分) (質量%)
・トリス(トリメチルメトキシ)メチルシラン 0.5
(商品名:TMF−1.5;信越化学工業株式会社製)
・流動パラフィン 54.4
・トリベヘン酸グリセリル 2.5
・ステアリン酸 1.4
・モノステアリン酸グリセリル(HLB=4.0) 1.4
・パルミチン酸セチル 1.5
・モノステアリン酸ポリオキシエチレンソルビタン 2.25
(20E.O.、HLB=14.9)
・モノステアリン酸ポリオキシエチレンソルビタン 3.4
(6E.O.、HLB=9.5)
・ジメチコン(100cst(0.0001m2/s)) 0.5
・イソノナン酸イソノニル 0.5
・N−ステアロイル−L−グルタミン酸ナトリウム 1.1
(商品名:アミソフトHS−11P;味の素社製)
・ジプロピレングリコール 3.5
・カルボキシビニルポリマー 0.02
(商品名:シンタレンK;和光純薬社製)
・エデト酸二ナトリウム 0.02
・カンゾウ葉エキス 0.1
(商品名:甘草葉抽出液;丸善製薬社製)
・センキュウエキス 0.1
(商品名:センキュウ抽出液BG;丸善製薬社製)
・タイソウエキス 0.1
(商品名:タイソウ抽出液BG−J;丸善製薬社製)
・チンピエキス 0.1
(商品名:チンピ抽出液BG40;丸善製薬社製)
・トウニンエキス 0.1
(商品名:ファルコレックス トウニン B;
一丸ファルコス社製)
・ヨクイニンエキス 0.1
(商品名:ヨクイニン抽出液BG−S;丸善製薬社製)
・ニコチン酸アミド 0.01
・フェノキシエタノール 0.2
・精製水 残 部
<Example 16 (cleansing cream)>
(Compounding ingredients) (mass%)
・ Tris (trimethylmethoxy) methylsilane 0.5
(Product name: TMF-1.5; manufactured by Shin-Etsu Chemical Co., Ltd.)
-Liquid paraffin 54.4
・ Glyceryl tribehenate 2.5
・ Stearic acid 1.4
・ Glyceryl monostearate (HLB = 4.0) 1.4
・ Cetyl palmitate 1.5
-Polyoxyethylene sorbitan monostearate 2.25
(20E.O., HLB = 14.9)
・ Polyoxyethylene sorbitan monostearate3.4
(6E.O., HLB = 9.5)
・ Dimethicone (100cst (0.0001m 2 / s)) 0.5
・ Isononyl isononanoate 0.5
-Sodium N-stearoyl-L-glutamate 1.1
(Product name: Amisoft HS-11P; manufactured by Ajinomoto Co., Inc.)
Dipropylene glycol 3.5
・ Carboxyvinyl polymer 0.02
(Product name: Shintalen K; manufactured by Wako Pure Chemical Industries, Ltd.)
・ Edetic acid disodium 0.02
・ Liquorice leaf extract 0.1
(Product name: Licorice leaf extract; manufactured by Maruzen Pharmaceutical Co., Ltd.)
-Senkyu extract 0.1
(Product name: Senkyu Extract BG; manufactured by Maruzen Pharmaceutical Co., Ltd.)
・ Thizo extract 0.1
(Brand name: Isolate extract BG-J; manufactured by Maruzen Pharmaceutical Co., Ltd.)
・ Chimpi extract 0.1
(Product name: Chinpi extract BG40; manufactured by Maruzen Pharmaceutical Co., Ltd.)
・ Tonin extract 0.1
(Product name: Falco Rex Tonin B;
Ichimaru Falcos)
・ Yokuinin extract 0.1
(Product name: Yokuinin extract BG-S; manufactured by Maruzen Pharmaceutical Co., Ltd.)
・ Nicotinamide 0.01
・ Phenoxyethanol 0.2
・ Purified water balance
本発明によって使用感(塗布時の伸び)、クレンジング効果、使用後のさっぱり感に優れ、且つ保存安定性が良好なクレンジング化粧料を提供することが可能となる。 According to the present invention, it is possible to provide a cleansing cosmetic that is excellent in use feeling (elongation at the time of application), cleansing effect, and refreshing feeling after use, and has good storage stability.
Claims (3)
(B)高分子増粘剤 0.01〜10質量%、並びに
(C)ポリオキシエチレングリセリル脂肪酸エステル及びポリオキシエチレン硬化ヒマシ油の組合せからなるHLB9〜17の非イオン性界面活性剤 0.01〜20質量%
を含有するクレンジング化粧料。 (A) Tris (trimethylsiloxy) methylsilane 0.5-40% by mass,
(B) Polymer thickener 0.01 to 10% by mass, and (C) HLB 9 to 17 nonionic surfactant comprising a combination of polyoxyethylene glyceryl fatty acid ester and polyoxyethylene hydrogenated castor oil 0.01 ~ 20% by mass
Cleansing cosmetics containing a.
Priority Applications (1)
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JP2011044090A JP5836608B2 (en) | 2011-03-01 | 2011-03-01 | Cleansing cosmetics |
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JP2011044090A JP5836608B2 (en) | 2011-03-01 | 2011-03-01 | Cleansing cosmetics |
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JP2012180305A JP2012180305A (en) | 2012-09-20 |
JP5836608B2 true JP5836608B2 (en) | 2015-12-24 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2014122193A (en) * | 2012-12-21 | 2014-07-03 | L'oreal Sa | Cosmetic composition comprising oil, nonionic surfactant and vitamin b3 |
JP6411717B2 (en) * | 2013-07-31 | 2018-10-24 | 株式会社コーセー | Cosmetics and external preparation for skin |
KR102034537B1 (en) * | 2016-09-27 | 2019-10-21 | (주)아모레퍼시픽 | Composition for forming film for coating skin or hair |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0892032A (en) * | 1994-09-19 | 1996-04-09 | Shiseido Co Ltd | Skin detergent |
JP3636865B2 (en) * | 1997-07-28 | 2005-04-06 | 株式会社カネボウ化粧品 | Emulsified composition |
AU6734700A (en) * | 1999-08-30 | 2001-03-26 | Kanebo Limited | Cosmetics |
JP2002255787A (en) * | 2001-02-27 | 2002-09-11 | Shiseido Co Ltd | Skin detergent |
JP4610115B2 (en) * | 2001-03-28 | 2011-01-12 | 株式会社コーセー | Cleansing cosmetics |
WO2004082644A1 (en) * | 2003-03-19 | 2004-09-30 | Kanebo Cosmetics Inc. | Cosmetic preparation |
JP2006022061A (en) * | 2004-07-09 | 2006-01-26 | Kanebo Ltd | Transparent cleansing cosmetic |
JP2006265125A (en) * | 2005-03-22 | 2006-10-05 | Kose Corp | Makeup-removing agent |
JP2009242340A (en) * | 2008-03-31 | 2009-10-22 | Shiseido Co Ltd | Cleansing cosmetic |
JP5604058B2 (en) * | 2009-06-03 | 2014-10-08 | 花王株式会社 | Skin cleanser |
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