JP2018016892A5 - Thin film forming apparatus and optical film manufacturing method - Google Patents

Thin film forming apparatus and optical film manufacturing method Download PDF

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JP2018016892A5
JP2018016892A5 JP2017211234A JP2017211234A JP2018016892A5 JP 2018016892 A5 JP2018016892 A5 JP 2018016892A5 JP 2017211234 A JP2017211234 A JP 2017211234A JP 2017211234 A JP2017211234 A JP 2017211234A JP 2018016892 A5 JP2018016892 A5 JP 2018016892A5
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thin film
gas
unit
film forming
base film
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本発明は、スパッタリングにより薄膜を形成する薄膜形成装置、及び光学膜の製造方法に関する。 The present invention relates to a thin film forming apparatus for forming a thin film by sputtering, a method of manufacturing a beauty optical film.

本発明は、このような従来の実情に鑑みて提案されたものであり、幅方向に均一な厚みの薄膜を形成することができる薄膜形成装置、及び光学膜の製造方法を提供する。 The present invention has such a proposed in view of the conventional situation, the thin film forming apparatus capable of forming a thin film of uniform thickness in the width direction, to provide a method of manufacturing beauty optical film.

Claims (11)

基材フィルムを長手方向に巻き出す巻出部と、
成膜部が前記基材フィルムの長手方向に複数配列された成膜室ユニットと、
前記成膜室ユニットにて薄膜が形成された基材フィルムを巻き取る巻取部と、
少なくとも何れか1つの前記成膜室ユニットの後に設けられ、前記基材フィルムが長手方向に連続的に供給され、該基材フィルム上に形成された前記薄膜の幅方向の光学特性のうち反射特性を測定する測定部と、
前記基材フィルムの幅方向に複数のガスノズルが設けられ、ターゲット近傍に反応性ガスを供給する供給部と、
前記測定部における幅方向の前記反射特性に基づいて、前記複数のガスノズルから噴出する前記反応性ガスの流量を制御する制御部と、を備え、
前記測定部には、前記基材フィルム上の前記薄膜に対して光を照射する投光部と、前記基材フィルム上の前記薄膜からの反射光を受光する受光部を有する光学ヘッドと、前記基材フィルムを透過する前記投光部からの光を吸収する光吸収面を有する測定ロールが設けられる薄膜形成装置。
An unwinding section for unwinding the base film in the longitudinal direction;
A film forming chamber unit in which a plurality of film forming portions are arranged in the longitudinal direction of the base film;
A winding unit for winding the base film on which a thin film is formed in the film forming chamber unit;
Reflective characteristics among optical characteristics in the width direction of the thin film provided after at least one of the film forming chamber units, the base film being continuously supplied in the longitudinal direction, and formed on the base film A measurement unit for measuring
A plurality of gas nozzles are provided in the width direction of the base film, and a supply unit that supplies a reactive gas in the vicinity of the target;
A control unit for controlling the flow rate of the reactive gas ejected from the plurality of gas nozzles based on the reflection characteristics in the width direction in the measurement unit;
The measuring unit includes a light projecting unit that irradiates light to the thin film on the base film, an optical head having a light receiving unit that receives reflected light from the thin film on the base film, and A thin film forming apparatus provided with a measurement roll having a light absorption surface that absorbs light from the light projecting portion that passes through the base film.
前記測定ロールは、ブラックロールである請求項1に記載の薄膜形成装置。   The thin film forming apparatus according to claim 1, wherein the measurement roll is a black roll. 前記成膜部は、前記ターゲットに電圧を印加するスパッタ電極と、成膜中における前記基材フィルムの幅方向のプラズマの発光スペクトルを測定するプラズマ測定部とを備え、
前記制御部は、前記測定部における幅方向の光学特性及び前記プラズマ測定部における前記発光スペクトルに基づいて、前記複数のガスノズルから噴出する前記反応性ガスの流量及び前記ターゲットに印加する電圧を制御する請求項1又は2に記載の薄膜形成装置。
The film forming unit includes a sputtering electrode that applies a voltage to the target, and a plasma measuring unit that measures an emission spectrum of plasma in the width direction of the base film during film formation,
The control unit controls the flow rate of the reactive gas ejected from the plurality of gas nozzles and the voltage applied to the target based on the optical characteristics in the width direction of the measurement unit and the emission spectrum of the plasma measurement unit. The thin film forming apparatus according to claim 1 or 2.
前記投光部と前記受光部とが同軸上に配置される請求項1乃至3の何れか1項に記載の薄膜形成装置。   The thin film forming apparatus according to claim 1, wherein the light projecting unit and the light receiving unit are arranged coaxially. 前記投光部は、前記基材フィルム上の薄膜に対して斜め方向から光を照射し、
前記受光部は、前記斜め方向から照射された光の反射光を受光する請求項1乃至4の何れか1項に記載の薄膜形成装置。
The light projecting unit irradiates light from an oblique direction to the thin film on the base film,
The thin film forming apparatus according to claim 1, wherein the light receiving unit receives reflected light of light irradiated from the oblique direction.
前記光学ヘッドは、前記投光部から照射される光を偏光する偏光板を有する請求項1乃至5の何れか1項に記載の薄膜形成装置。   The thin film forming apparatus according to claim 1, wherein the optical head includes a polarizing plate that polarizes light emitted from the light projecting unit. 前記ガスノズルは、前記反応性ガスとキャリアガスとを混合して噴出する請求項1に記載の薄膜形成装置。   The thin film forming apparatus according to claim 1, wherein the gas nozzle mixes and ejects the reactive gas and the carrier gas. 前記ガスノズルは、複数の開口と、内部に反応性ガス用のガス管とキャリアガス用のガス管と混合室とを備え、混合室で前記反応性ガスと前記キャリアガスとを混合し、前記複数の開口から混合ガスを噴出する請求項7に記載の薄膜形成装置。   The gas nozzle includes a plurality of openings, a gas pipe for a reactive gas, a gas pipe for a carrier gas, and a mixing chamber. The gas nozzle mixes the reactive gas and the carrier gas in the mixing chamber. The thin film forming apparatus according to claim 7, wherein a mixed gas is ejected from the opening. 前記反応性ガス用のガス管は、ガスを導入する連結部と、前記連結部から管の開口が等間隔となるようにトーナメント状に分岐された配管とを備え、
前記制御部は、前記連結部にマスフローコントローラを介してガスを導入し、前記複数のガスノズルから噴出するガスの流量を制御する請求項8に記載の薄膜形成装置。
The gas pipe for the reactive gas includes a connecting part for introducing gas, and a pipe branched in a tournament shape so that the opening of the pipe is equidistant from the connecting part,
The thin film forming apparatus according to claim 8, wherein the control unit introduces a gas into the connecting unit via a mass flow controller and controls a flow rate of the gas ejected from the plurality of gas nozzles.
前記請求項1〜9の何れか1項に記載の薄膜形成装置を用いて、多層の光学膜を製造する光学膜の製造方法において、
基材フィルムを長手方向に第1の速度で連続的に供給し、各層について単層の薄膜を形成し、前記基材フィルムの幅方向の光学厚み分布を所定範囲に調整する調整工程と、
前記基材フィルムを長手方向に第1の速度よりも速い第2の速度で連続的に供給し、多層の薄膜を形成する光学膜形成工程と、を有する光学膜の製造方法。
In the manufacturing method of an optical film which manufactures a multilayer optical film using the thin film forming device according to any one of claims 1 to 9,
An adjustment step of continuously supplying the base film at a first speed in the longitudinal direction, forming a single-layer thin film for each layer, and adjusting the optical thickness distribution in the width direction of the base film to a predetermined range;
An optical film forming step of continuously supplying the base film in the longitudinal direction at a second speed higher than the first speed to form a multilayer thin film.
前記調整工程では、各層について単層の幅方向の反射スペクトルのピーク波長又はボトム波長が±15nm以内となるように調整することにより、前記基材フィルムの幅方向の光学厚み分布を所定範囲に調整する請求項10に記載の光学膜の製造方法。 In the adjustment step, the optical thickness distribution in the width direction of the base film is adjusted to a predetermined range by adjusting each layer so that the peak wavelength or bottom wavelength of the reflection spectrum in the width direction of the single layer is within ± 15 nm. The method for producing an optical film according to claim 10 .
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