JP2017535657A - 熱可塑性樹脂組成物およびこれを含む成形品 - Google Patents
熱可塑性樹脂組成物およびこれを含む成形品 Download PDFInfo
- Publication number
- JP2017535657A JP2017535657A JP2017527336A JP2017527336A JP2017535657A JP 2017535657 A JP2017535657 A JP 2017535657A JP 2017527336 A JP2017527336 A JP 2017527336A JP 2017527336 A JP2017527336 A JP 2017527336A JP 2017535657 A JP2017535657 A JP 2017535657A
- Authority
- JP
- Japan
- Prior art keywords
- thermoplastic resin
- resin composition
- weight
- meth
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 71
- 239000011342 resin composition Substances 0.000 title claims abstract description 51
- -1 siloxane compound Chemical class 0.000 claims abstract description 72
- 229920005989 resin Polymers 0.000 claims abstract description 70
- 239000011347 resin Substances 0.000 claims abstract description 70
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 33
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 16
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 25
- 229920006164 aromatic vinyl copolymer Polymers 0.000 claims description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 9
- 229920006026 co-polymeric resin Polymers 0.000 claims description 9
- 125000001545 dialkoxyaryl group Chemical group 0.000 claims description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000003700 epoxy group Chemical group 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 125000001165 hydrophobic group Chemical group 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000000178 monomer Substances 0.000 description 29
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 18
- 229920000578 graft copolymer Polymers 0.000 description 16
- 230000000704 physical effect Effects 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 15
- 229920001971 elastomer Polymers 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 9
- 229910052697 platinum Inorganic materials 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- UHUUYVZLXJHWDV-UHFFFAOYSA-N trimethyl(methylsilyloxy)silane Chemical compound C[SiH2]O[Si](C)(C)C UHUUYVZLXJHWDV-UHFFFAOYSA-N 0.000 description 8
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 7
- 239000000376 reactant Substances 0.000 description 7
- NJXYTXADXSRFTJ-UHFFFAOYSA-N 1,2-Dimethoxy-4-vinylbenzene Chemical compound COC1=CC=C(C=C)C=C1OC NJXYTXADXSRFTJ-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000002952 polymeric resin Substances 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920000638 styrene acrylonitrile Polymers 0.000 description 5
- 238000010557 suspension polymerization reaction Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920003244 diene elastomer Polymers 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CXYAFFSHJZNAKZ-UHFFFAOYSA-N C[Si]1(O[Si](O[Si](O[Si](O1)(C)C)(C)C)(C)C)C.C[Si]1(O[Si](O[Si](O[Si](O1)(C)C)(C)C)(C)C)C Chemical compound C[Si]1(O[Si](O[Si](O[Si](O1)(C)C)(C)C)(C)C)C.C[Si]1(O[Si](O[Si](O[Si](O1)(C)C)(C)C)(C)C)C CXYAFFSHJZNAKZ-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- DEAKWVKQKRNPHF-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;prop-2-enenitrile;styrene Chemical compound C=CC#N.COC(=O)C(C)=C.C=CC1=CC=CC=C1 DEAKWVKQKRNPHF-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920001470 polyketone Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- YYDWZJCCIAMZIH-UHFFFAOYSA-N 1-ethenyl-3,5-dimethoxybenzene Chemical compound COC1=CC(OC)=CC(C=C)=C1 YYDWZJCCIAMZIH-UHFFFAOYSA-N 0.000 description 1
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- CYLVUSZHVURAOY-UHFFFAOYSA-N 2,2-dibromoethenylbenzene Chemical compound BrC(Br)=CC1=CC=CC=C1 CYLVUSZHVURAOY-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- TVONJMOVBKMLOM-UHFFFAOYSA-N 2-methylidenebutanenitrile Chemical compound CCC(=C)C#N TVONJMOVBKMLOM-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- QROGIFZRVHSFLM-QHHAFSJGSA-N [(e)-prop-1-enyl]benzene Chemical compound C\C=C\C1=CC=CC=C1 QROGIFZRVHSFLM-QHHAFSJGSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000746 allylic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Abstract
Description
以下、実施例および比較例で用いられた各成分の仕様は次の通りである。
(A1)(メタ)アクリル系樹脂:ポリメチルメタアクリレート(PMMA、製造社:サムスンSDI、製品名:PM−7200、重量平均分子量:115,000g/mol)を用いた。
(B1)フラスコに、テトラメチルジシロキサン(tetramethyldisiloxane:HMM)とオクタメチルシクロテトラシロキサン(octamethylcyclotetrasiloxane)を1:4のモル比で入れ、0℃でトリフルオロメタンスルホン酸(trifluoromethanesulfonic acid)を添加した後、20℃ないし30℃で24時間反応させて下記式2のシロキサン化合物(R1=メチル基、nの平均値=20)を製造し、製造した式2のシロキサン化合物とアリルグリシジルエーテル(allyl glycidyl ether)を1:2.5のモル比でトルエン(式2のシロキサン化合物とアリルグリシジルエーテル(反応物)100重量部に対して、100重量部)に入れて、白金触媒50ppm(反応物重量基準)を添加した後、90℃で7時間反応させて製造した下記式1aで表されるシロキサン化合物(nの平均値=20)を用いた。製造された式1aで表されるシロキサン化合物および式2で表されるシロキサン化合物の1H−NMRスペクトルを図1および図2に表した。
前記各構成成分を下記表1、表2および表3に記載されている通りの含量で添加した後、200℃ないし280℃で押出してペレットを製造した。このとき、押出は、L/D=36、直径45mmの二軸押出機を用いており、製造されたペレットは、80℃ないし100℃で4時間以上乾燥した後、射出機(成形温度290℃、金型温度:90℃)で射出して試片を製造した。製造された試片に対して下記の方法で物性を評価し、その結果を下記表1、表2および表3に表した。
(1)耐衝撃性評価:ASTM D256に規定されている評価方法によって厚さ1/8”のアイゾット試片にノッチ(Notch)を作り、アイゾット(Izod)衝撃強度(単位:kgf・cm/cm)を測定した。
Claims (13)
- (メタ)アクリル系樹脂および芳香族ビニル系樹脂を含む熱可塑性樹脂;および下記式1で表されるシロキサン化合物を含むことを特徴とする熱可塑性樹脂組成物:
- 前記(メタ)アクリル系樹脂は、メチル(メタ)アクリレートのホモポリマー、メチルアクリレートとメチルメタクリレートとの共重合体、またはメチル(メタ)アクリレートと、エチル(メタ)アクリレート、プロピル(メタ)アクリレート、ブチル(メタ)アクリレート、フェニル(メタ)アクリレートおよびスチレンのうち1種以上を含むコモノマーとの共重合体を含むことを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記芳香族ビニル系樹脂は、アクリロニトリル−ブタジエン−スチレン共重合体樹脂(ABS樹脂)、アクリロニトリル−エチレンプロピレンゴム−スチレン共重合体樹脂(AES樹脂)、またはアクリロニトリル−アクリルゴム−スチレン共重合体樹脂(AAS樹脂)のうち少なくとも1種を含むゴム変性芳香族ビニル系共重合体樹脂を含むことを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂は、前記(メタ)アクリル系樹脂約10重量%ないし約90重量%および前記芳香族ビニル系樹脂約10重量%ないし約90重量%を含むことを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記シロキサン化合物の含量は、前記熱可塑性樹脂約100重量部に対して、約0.1重量部ないし約10重量部であることを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記式1で表されるシロキサン化合物は、A1およびA2がジアルコキシアリール基で、nの平均値は約30ないし約40であることを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記シロキサン化合物は、下記式1aで表される化合物、下記式1bで表される化合物、下記式1cで表される化合物および下記式1dで表される化合物のうち1種以上を含むことを特徴とする、請求項1に記載の熱可塑性樹脂組成物:
- 前記熱可塑性樹脂組成物は、疎水性に表面改質されたシリカをさらに含むことを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記疎水性に表面改質されたシリカは、シリカ表面のヒドロキシ基が炭素数1ないし8のアルキル基、またはシラン化合物のうち少なくとも1種を含む疎水性基で置換されたことを特徴とする、請求項8に記載の熱可塑性樹脂組成物。
- 前記疎水性に表面改質されたシリカの含量は、前記熱可塑性樹脂約100重量部に対して、約0.1重量部ないし約5重量部であることを特徴とする、請求項8に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂組成物は、ASTM D523によって摩擦堅ろう度試験機(crockmeter)で測定した約10cm×約15cmサイズの試片の白綿布約10回摩擦前後の約60°鏡面光沢度差(ΔGloss(60°))が、約16以下であることを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂組成物は、ASTM D256によって測定した約1/8”厚さ試片のアイゾット衝撃強度が約3kgf・cm/cmないし約15kgf・cm/cmで、ASTM D1238によって約300℃、約1.2kgf荷重条件で測定した流動指数(melt flow index:MI)が約10g/10分ないし約30g/10分で、ASTM D1525によって約5kgf荷重で測定したビカット軟化温度(Vicat Softening Temperature:VST)が約90℃ないし約110℃で、ボールタイプスクラッチプロファイルテスト(Ball Type Scratch Profile Test)によるスクラッチ幅(width)が約180μmないし約250μmであることを特徴とする、請求項1に記載の熱可塑性樹脂組成物。
- 請求項1ないし請求項12のいずれか1項に記載の熱可塑性樹脂組成物から形成されることを特徴とする成形品。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2014-0163814 | 2014-11-21 | ||
KR20140163814 | 2014-11-21 | ||
KR10-2015-0150394 | 2015-10-28 | ||
KR1020150150394A KR101886482B1 (ko) | 2014-11-21 | 2015-10-28 | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
PCT/KR2015/011694 WO2016080675A1 (ko) | 2014-11-21 | 2015-11-03 | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017535657A true JP2017535657A (ja) | 2017-11-30 |
JP6841755B2 JP6841755B2 (ja) | 2021-03-10 |
Family
ID=56138355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017527336A Active JP6841755B2 (ja) | 2014-11-21 | 2015-11-03 | 熱可塑性樹脂組成物およびこれを含む成形品 |
Country Status (5)
Country | Link |
---|---|
US (1) | US10196519B2 (ja) |
EP (1) | EP3222670B1 (ja) |
JP (1) | JP6841755B2 (ja) |
KR (1) | KR101886482B1 (ja) |
WO (1) | WO2016080675A1 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101886482B1 (ko) | 2014-11-21 | 2018-09-07 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
WO2018110938A1 (ko) * | 2016-12-14 | 2018-06-21 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
KR101980018B1 (ko) * | 2016-12-14 | 2019-05-17 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
US11655359B2 (en) * | 2017-02-10 | 2023-05-23 | Ineos Styrolution Group Gmbh | Acrylonitrile-butadiene-styrene copolymer composition with high surface energy |
WO2019020686A1 (en) * | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | STRIPPED STYRENE COPOLYMER COMPOSITION CONTAINING MODIFIED ORGANOPOLYSILOXANE COMPOUNDS |
KR102165697B1 (ko) * | 2017-10-27 | 2020-10-14 | 주식회사 엘지화학 | 그라프트 공중합체, 이를 포함하는 열가소성 수지 조성물 및 이의 제조방법 |
KR102183999B1 (ko) | 2018-03-20 | 2020-11-30 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
WO2019182334A1 (ko) * | 2018-03-20 | 2019-09-26 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
KR102186650B1 (ko) * | 2018-03-30 | 2020-12-04 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
CN108822481A (zh) * | 2018-06-22 | 2018-11-16 | 苏州彤帆智能科技有限公司 | Mabs合金光学材料及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH111600A (ja) * | 1997-06-11 | 1999-01-06 | Ube Cycon Ltd | 耐傷つき性を有する熱可塑性樹脂組成物 |
JPH11124519A (ja) * | 1997-08-21 | 1999-05-11 | Mitsui Chem Inc | 熱硬化性粉体塗料組成物 |
JP2009203397A (ja) * | 2008-02-29 | 2009-09-10 | Kaneka Corp | 粉末成形用樹脂組成物及び成形品 |
JP2010514892A (ja) * | 2006-12-29 | 2010-05-06 | チェイル インダストリーズ インコーポレイテッド | 低温衝撃強度及び機械的強度に優れたポリカーボネート−ポリシロキサン共重合体樹脂組成物ならびにその製造方法 |
JP2011202155A (ja) * | 2010-03-03 | 2011-10-13 | Nippon A&L Inc | 熱可塑性樹脂組成物 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4499149A (en) * | 1980-12-15 | 1985-02-12 | M&T Chemicals Inc. | Siloxane-containing polymers |
US5354796A (en) * | 1992-10-01 | 1994-10-11 | General Electric Company | Low gloss thermoplastic molding compositions |
EP1085052B1 (en) * | 1999-04-19 | 2005-04-13 | General Electric Company | Thermoplastic molding composition |
US6153680A (en) | 1999-06-30 | 2000-11-28 | Delphi Technologies, Inc. | Thermoplastic polymer alloy compositions and in-line compounding process for direct sheet extrusion of sheets prepared from the thermoplastic polymer alloy compositions |
ES2280190T3 (es) * | 1999-10-26 | 2007-09-16 | Ciba Specialty Chemicals Holding Inc. | Mezcla de aditivos para mejorar las propiedades mecanicas de los polimeros. |
JP4064181B2 (ja) * | 2001-08-28 | 2008-03-19 | 東レ・ダウコーニング株式会社 | 難燃性有機樹脂組成物 |
KR100788736B1 (ko) | 2006-12-18 | 2008-01-02 | 엘지엠엠에이 주식회사 | 무도장 외장재용 아크릴계 수지 조성물 |
US20090043038A1 (en) | 2007-08-10 | 2009-02-12 | Bayer Materialscience Llc | Thermoplastic composition having low gloss |
EP2123706A1 (en) | 2008-05-19 | 2009-11-25 | Evonik Degussa GmbH | Thermoplastic elastomers |
EP2294114B1 (en) | 2008-06-05 | 2012-08-15 | Advanced Polymerik Pty Ltd | Photochromic polymer and composition comprising photochromic polymer |
US8951933B2 (en) * | 2009-11-25 | 2015-02-10 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Polysiloxane-modified polyhydroxy polyurethane resin, method for producing same, heat-sensitive recording material using the resin, imitation leather, thermoplastic polyolefin resin skin material, material for weather strip, and weather strip |
EP2610276B1 (en) * | 2010-08-26 | 2017-11-01 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Self-crosslinking polysiloxane-modified polyhydroxy polyurethane resin, resin material containing same, method for producing same, artificial leather comprising same, and thermoplastic polyolefin skin material comprising same |
KR101616168B1 (ko) * | 2013-11-27 | 2016-04-27 | 제일모직주식회사 | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
KR101886482B1 (ko) | 2014-11-21 | 2018-09-07 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
-
2015
- 2015-10-28 KR KR1020150150394A patent/KR101886482B1/ko active IP Right Grant
- 2015-11-03 JP JP2017527336A patent/JP6841755B2/ja active Active
- 2015-11-03 EP EP15861890.0A patent/EP3222670B1/en active Active
- 2015-11-03 US US15/528,177 patent/US10196519B2/en active Active
- 2015-11-03 WO PCT/KR2015/011694 patent/WO2016080675A1/ko active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH111600A (ja) * | 1997-06-11 | 1999-01-06 | Ube Cycon Ltd | 耐傷つき性を有する熱可塑性樹脂組成物 |
JPH11124519A (ja) * | 1997-08-21 | 1999-05-11 | Mitsui Chem Inc | 熱硬化性粉体塗料組成物 |
JP2010514892A (ja) * | 2006-12-29 | 2010-05-06 | チェイル インダストリーズ インコーポレイテッド | 低温衝撃強度及び機械的強度に優れたポリカーボネート−ポリシロキサン共重合体樹脂組成物ならびにその製造方法 |
JP2009203397A (ja) * | 2008-02-29 | 2009-09-10 | Kaneka Corp | 粉末成形用樹脂組成物及び成形品 |
JP2011202155A (ja) * | 2010-03-03 | 2011-10-13 | Nippon A&L Inc | 熱可塑性樹脂組成物 |
Also Published As
Publication number | Publication date |
---|---|
EP3222670B1 (en) | 2019-08-07 |
US10196519B2 (en) | 2019-02-05 |
EP3222670A4 (en) | 2018-07-04 |
JP6841755B2 (ja) | 2021-03-10 |
EP3222670A1 (en) | 2017-09-27 |
WO2016080675A1 (ko) | 2016-05-26 |
KR101886482B1 (ko) | 2018-09-07 |
US20170327688A1 (en) | 2017-11-16 |
KR20160061877A (ko) | 2016-06-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6841755B2 (ja) | 熱可塑性樹脂組成物およびこれを含む成形品 | |
JP6284249B2 (ja) | ポリメチルメタクリレートアクリル系共重合体アロイ高光沢組成物及び成形品 | |
JP5330410B2 (ja) | 柔らかな表面質感を有する低光沢熱可塑性樹脂組成物及びその成形品 | |
US9353253B2 (en) | Low gloss thermoplastic resin composition having improved scratch resistance | |
JP5930964B2 (ja) | 耐スクラッチ性が向上した耐衝撃性メチルメタクリレート樹脂組成物 | |
US10941289B2 (en) | Graft copolymer, thermoplastic resin composition including graft copolymer, and method of preparing thermoplastic resin composition | |
US20130165577A1 (en) | Thermoplastic Resin Composition with Flowability, Transparency, and Impact Strength | |
US9382369B2 (en) | Rubber-modified vinyl-based graft copolymer, and thermoplastic resin composition including the same | |
JP6622704B2 (ja) | 高分子樹脂組成物およびその成形品 | |
JP7121134B2 (ja) | コア-シェル共重合体、その製造方法、およびそれを含む熱可塑性樹脂組成物 | |
JPWO2006004058A1 (ja) | ゴム強化樹脂及びその製造方法並びにゴム強化樹脂組成物 | |
KR101810294B1 (ko) | 종이 질감을 갖는 열가소성 수지 조성물 및 이로부터 형성된 성형품 | |
KR101726480B1 (ko) | 방향족 비닐계 공중합체 및 이를 포함하는 열가소성 수지 조성물 | |
EP2837656B1 (en) | Lubricating thermoplastic resin composition, and molded product thereof | |
KR101717820B1 (ko) | 방향족 비닐계 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 | |
KR19990007156A (ko) | 스티렌계 수지 조성물 및 그의 성형체 | |
JP3173024B2 (ja) | 熱可塑性樹脂組成物 | |
EP3650477A1 (en) | Polymer, graft polymer, and thermoplastic resin composition | |
TWI847407B (zh) | 接枝共聚物、熱可塑性樹脂組成物及成形體 | |
CN114829494A (zh) | 热塑性树脂组合物和使用其制造的成型品 | |
KR20220040650A (ko) | Abs계 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품 | |
KR20190076821A (ko) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 | |
KR20100075078A (ko) | 열가소성 수지 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20181012 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190718 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190730 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20191025 |
|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A712 Effective date: 20200312 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200519 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200811 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210126 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20210218 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6841755 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |