JP2017512630A5 - - Google Patents
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- Publication number
- JP2017512630A5 JP2017512630A5 JP2016554465A JP2016554465A JP2017512630A5 JP 2017512630 A5 JP2017512630 A5 JP 2017512630A5 JP 2016554465 A JP2016554465 A JP 2016554465A JP 2016554465 A JP2016554465 A JP 2016554465A JP 2017512630 A5 JP2017512630 A5 JP 2017512630A5
- Authority
- JP
- Japan
- Prior art keywords
- iron
- organic compound
- zeolite
- mixture
- sapo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 30
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 15
- 229910052742 iron Inorganic materials 0.000 claims 14
- 238000000034 method Methods 0.000 claims 12
- 150000002894 organic compounds Chemical class 0.000 claims 12
- 229910021536 Zeolite Inorganic materials 0.000 claims 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 10
- 239000010457 zeolite Substances 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 7
- 239000002808 molecular sieve Substances 0.000 claims 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 6
- 239000007789 gas Substances 0.000 claims 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 238000010531 catalytic reduction reaction Methods 0.000 claims 4
- 238000005470 impregnation Methods 0.000 claims 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 3
- 230000032683 aging Effects 0.000 claims 3
- 239000004202 carbamide Substances 0.000 claims 3
- 229910001657 ferrierite group Inorganic materials 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 2
- 239000002211 L-ascorbic acid Substances 0.000 claims 2
- 235000000069 L-ascorbic acid Nutrition 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 2
- 229930006000 Sucrose Natural products 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 2
- 229960005070 ascorbic acid Drugs 0.000 claims 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 2
- 235000015165 citric acid Nutrition 0.000 claims 2
- 239000008103 glucose Substances 0.000 claims 2
- 238000005342 ion exchange Methods 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 2
- 235000006408 oxalic acid Nutrition 0.000 claims 2
- 238000006722 reduction reaction Methods 0.000 claims 2
- 239000007790 solid phase Substances 0.000 claims 2
- 238000001694 spray drying Methods 0.000 claims 2
- 239000005720 sucrose Substances 0.000 claims 2
- 150000005621 tetraalkylammonium salts Chemical class 0.000 claims 2
- 125000005270 trialkylamine group Chemical group 0.000 claims 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 claims 1
- CGVPYAREDIUBOY-UHFFFAOYSA-K 2-hydroxypropane-1,2,3-tricarboxylate;iron(2+) Chemical compound [Fe+2].[Fe+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O CGVPYAREDIUBOY-UHFFFAOYSA-K 0.000 claims 1
- 238000001669 Mossbauer spectrum Methods 0.000 claims 1
- JGIBNXVWKYGFLY-UHFFFAOYSA-M [NH4+].C(C(=O)[O-])(=O)[O-].[Fe+] Chemical compound [NH4+].C(C(=O)[O-])(=O)[O-].[Fe+] JGIBNXVWKYGFLY-UHFFFAOYSA-M 0.000 claims 1
- WLZUXSFXGDGPPF-UHFFFAOYSA-L [O-]S([O-])(=O)=O.N.[Fe+2].[Fe+2] Chemical compound [O-]S([O-])(=O)=O.N.[Fe+2].[Fe+2] WLZUXSFXGDGPPF-UHFFFAOYSA-L 0.000 claims 1
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical group C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims 1
- 229910001573 adamantine Inorganic materials 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 150000002505 iron Chemical class 0.000 claims 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims 1
- 229910000358 iron sulfate Inorganic materials 0.000 claims 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims 1
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- -1 nitrogen-containing compound Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 claims 1
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 claims 1
- SEACXNRNJAXIBM-UHFFFAOYSA-N triethyl(methyl)azanium Chemical class CC[N+](C)(CC)CC SEACXNRNJAXIBM-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461946075P | 2014-02-28 | 2014-02-28 | |
| US61/946,075 | 2014-02-28 | ||
| PCT/GB2015/050579 WO2015128668A1 (en) | 2014-02-28 | 2015-02-27 | Scr catalysts having improved low temperature performance, and methods of making and using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2017512630A JP2017512630A (ja) | 2017-05-25 |
| JP2017512630A5 true JP2017512630A5 (enExample) | 2018-04-12 |
Family
ID=52627529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016554465A Pending JP2017512630A (ja) | 2014-02-28 | 2015-02-27 | 低温性能が改善されたｓｃｒ触媒及びその製造ならびに使用方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20150246345A1 (enExample) |
| EP (1) | EP3110548A1 (enExample) |
| JP (1) | JP2017512630A (enExample) |
| KR (1) | KR20160127108A (enExample) |
| CN (1) | CN106029227A (enExample) |
| DE (1) | DE112015001008T5 (enExample) |
| GB (1) | GB2543166A (enExample) |
| RU (1) | RU2016138282A (enExample) |
| WO (1) | WO2015128668A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9868116B2 (en) | 2015-01-29 | 2018-01-16 | Johnson Matthey Public Limited Company | Direct incorporation of iron complexes into SAPO-34 (CHA) type materials |
| EP3336060B1 (en) * | 2015-08-13 | 2020-01-29 | Tosoh Corporation | Method for producing aei zeolite |
| CN108698841B (zh) | 2015-12-22 | 2023-01-17 | 巴斯夫公司 | 制备铁(iii)交换的沸石组合物的方法 |
| GB2551871A (en) | 2016-04-22 | 2018-01-03 | Johnson Matthey Plc | STA-18, A new member of the SFW family of molecular sieve zeotypes, methods of preparation and use |
| CN109071243A (zh) * | 2016-04-28 | 2018-12-21 | 庄信万丰股份有限公司 | Sta-20，一种新分子筛骨架类型，制备方法和用途 |
| JP7155108B2 (ja) * | 2016-08-05 | 2022-10-18 | ビーエーエスエフ コーポレーション | 選択的触媒還元物品およびシステム |
| TWI619539B (zh) | 2016-10-14 | 2018-04-01 | 財團法人工業技術研究院 | 淨化含氮氧化物氣體的組成物及裝置 |
| KR101879695B1 (ko) * | 2016-12-02 | 2018-07-18 | 희성촉매 주식회사 | 2가 구리 이온들을 특정비율로 담지한 제올라이트, 이의 제조방법 및 이를 포함하는 촉매조성물 |
| US20200047168A1 (en) * | 2017-03-13 | 2020-02-13 | Mitsubishi Chemical Corporation | Transition metal-carrying zeolite and production method therefor, and nitrogen oxide purification catalyst and method for using same |
| CN107262145B (zh) * | 2017-07-24 | 2020-11-27 | 安徽纳蓝环保科技有限公司 | 一种沸石碳氢吸附重整催化剂的制备方法 |
| CN108212208B (zh) * | 2018-04-03 | 2020-08-25 | 兰州理工大学 | 一种atn型铁基磷酸铝分子筛催化剂的制备方法 |
| FR3081340B1 (fr) * | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur comprenant un melange d'une zeolithe de type structural afx et d'une zeolithe de type structural bea et au moins un metal de transition pour la reduction selective de nox |
| WO2020150087A1 (en) * | 2019-01-18 | 2020-07-23 | Cummins Emission Solutions Inc. | Treated scr catalysts with enhanced sulfur resistance |
| CN109999895B (zh) * | 2019-04-16 | 2021-06-29 | 上海交通大学 | 一种低温催化去除氮氧化物的催化剂及其制备方法 |
| CN110833831B (zh) * | 2019-11-07 | 2022-11-01 | 上海纳米技术及应用国家工程研究中心有限公司 | 铬钴基一氧化氮常温常压催化剂的制备方法及其产品和应用 |
| KR102528565B1 (ko) | 2020-02-27 | 2023-05-04 | 한국화학연구원 | 잔류염소 제거방법 및 그 방법에 의한 질소산화물 저감용 촉매 |
| EP3919165B1 (en) * | 2020-06-03 | 2025-08-13 | Johnson Matthey Public Limited Company | Method for forming a catalyst article |
| CN114345402B (zh) * | 2021-08-30 | 2024-09-17 | 武汉科技大学 | 一种铁基分子筛催化剂的制备方法 |
| JP7677496B2 (ja) * | 2023-05-12 | 2025-05-15 | 東ソー株式会社 | 鉄含有ｆｅｒ型ゼオライト及びその製造方法 |
| CN121358539A (zh) | 2023-06-06 | 2026-01-16 | 巴斯夫公司 | 用于处理废气的包含含Fe沸石材料的催化材料 |
| CN116786135B (zh) * | 2023-08-18 | 2024-01-02 | 四川大学 | 氧化锰矿烟气脱硫尾渣资源化制备低温脱硝催化剂的方法 |
| CN120004287A (zh) * | 2025-04-18 | 2025-05-16 | 长春理工大学 | 一种Cu-SSZ-13分子筛制备方法和分子筛的应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4255349A (en) * | 1978-12-18 | 1981-03-10 | Mobil Oil Corporation | Conversion of synthesis gas with iron-containing catalyst |
| EP0756891A1 (en) * | 1995-07-26 | 1997-02-05 | Corning Incorporated | Iron zeolite for conversion of NOx |
| US6033641A (en) * | 1996-04-18 | 2000-03-07 | University Of Pittsburgh Of The Comonwealth System Of Higher Education | Catalyst for purifying the exhaust gas from the combustion in an engine or gas turbines and method of making and using the same |
| FR2789911B1 (fr) | 1999-02-18 | 2001-05-04 | Grande Paroisse Sa | Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent |
| EP3278863B1 (en) * | 2007-04-26 | 2019-11-27 | Johnson Matthey Public Limited Company | Transition metal/aei-zeolite scr catalyst |
| US20080287283A1 (en) * | 2007-05-15 | 2008-11-20 | Patrick David Tepesch | Catalyst body and methods |
| CN101827654B (zh) * | 2007-08-13 | 2013-11-06 | Pq公司 | 含铁铝硅酸盐沸石及其制备和使用方法 |
| EP2918330B1 (de) * | 2008-05-07 | 2017-03-15 | Umicore Ag & Co. Kg | Verfahren zur verminderung von stickoxiden in kohlenwasserstoff-haltigen abgasen unter verwendung eines scr-katalysators auf basis eines molekularsiebes |
| WO2010110435A1 (ja) * | 2009-03-27 | 2010-09-30 | 国立大学法人岡山大学 | 有機・無機複合材料及びその製造方法 |
| JP5573453B2 (ja) * | 2010-07-21 | 2014-08-20 | 三菱樹脂株式会社 | 窒素酸化物浄化用触媒及びその製造方法 |
| US20120134916A1 (en) * | 2011-02-28 | 2012-05-31 | Fedeyko Joseph M | High-temperature scr catalyst |
| EP2694208A1 (en) * | 2011-04-04 | 2014-02-12 | PQ Corporation | Fe-sapo-34 catalyst and methods of making and using the same |
-
2015
- 2015-02-27 WO PCT/GB2015/050579 patent/WO2015128668A1/en not_active Ceased
- 2015-02-27 CN CN201580010629.7A patent/CN106029227A/zh active Pending
- 2015-02-27 KR KR1020167026799A patent/KR20160127108A/ko not_active Withdrawn
- 2015-02-27 DE DE112015001008.4T patent/DE112015001008T5/de not_active Withdrawn
- 2015-02-27 US US14/633,658 patent/US20150246345A1/en not_active Abandoned
- 2015-02-27 GB GB1616359.4A patent/GB2543166A/en not_active Withdrawn
- 2015-02-27 EP EP15708040.9A patent/EP3110548A1/en not_active Withdrawn
- 2015-02-27 RU RU2016138282A patent/RU2016138282A/ru not_active Application Discontinuation
- 2015-02-27 JP JP2016554465A patent/JP2017512630A/ja active Pending
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