KR20160127108A - 개선된 저온 성능을 가진 scr 촉매, 및 그것의 제조 및 사용 방법 - Google Patents
개선된 저온 성능을 가진 scr 촉매, 및 그것의 제조 및 사용 방법 Download PDFInfo
- Publication number
- KR20160127108A KR20160127108A KR1020167026799A KR20167026799A KR20160127108A KR 20160127108 A KR20160127108 A KR 20160127108A KR 1020167026799 A KR1020167026799 A KR 1020167026799A KR 20167026799 A KR20167026799 A KR 20167026799A KR 20160127108 A KR20160127108 A KR 20160127108A
- Authority
- KR
- South Korea
- Prior art keywords
- iron
- organic compound
- catalyst
- mixture
- zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 title claims abstract description 207
- 238000000034 method Methods 0.000 title claims abstract description 53
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 290
- 229910052742 iron Inorganic materials 0.000 claims abstract description 125
- 239000010457 zeolite Substances 0.000 claims abstract description 107
- 238000006243 chemical reaction Methods 0.000 claims abstract description 104
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 89
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 81
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 79
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract description 78
- 239000002808 molecular sieve Substances 0.000 claims abstract description 77
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 77
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 229910001657 ferrierite group Inorganic materials 0.000 claims abstract description 39
- 239000007789 gas Substances 0.000 claims abstract description 37
- 238000010531 catalytic reduction reaction Methods 0.000 claims abstract description 32
- 238000001354 calcination Methods 0.000 claims abstract description 24
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004202 carbamide Substances 0.000 claims abstract description 23
- 230000032683 aging Effects 0.000 claims abstract description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 138
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 131
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 69
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 42
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 27
- 235000006408 oxalic acid Nutrition 0.000 claims description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- 229960005070 ascorbic acid Drugs 0.000 claims description 21
- 239000002211 L-ascorbic acid Substances 0.000 claims description 19
- 235000000069 L-ascorbic acid Nutrition 0.000 claims description 19
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 16
- 150000002505 iron Chemical class 0.000 claims description 16
- 230000000052 comparative effect Effects 0.000 claims description 15
- 238000005470 impregnation Methods 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 12
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 9
- 239000003638 chemical reducing agent Substances 0.000 claims description 9
- -1 ZSM-5 Inorganic materials 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 7
- 238000006722 reduction reaction Methods 0.000 claims description 7
- 238000005342 ion exchange Methods 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 235000015165 citric acid Nutrition 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 238000001694 spray drying Methods 0.000 claims description 5
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims description 5
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 claims description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- JGIBNXVWKYGFLY-UHFFFAOYSA-M [NH4+].C(C(=O)[O-])(=O)[O-].[Fe+] Chemical compound [NH4+].C(C(=O)[O-])(=O)[O-].[Fe+] JGIBNXVWKYGFLY-UHFFFAOYSA-M 0.000 claims description 4
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical compound [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 claims description 4
- GLMQHZPGHAPYIO-UHFFFAOYSA-L azanium;2-hydroxypropane-1,2,3-tricarboxylate;iron(2+) Chemical compound [NH4+].[Fe+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O GLMQHZPGHAPYIO-UHFFFAOYSA-L 0.000 claims description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- 239000008103 glucose Substances 0.000 claims description 4
- 239000004313 iron ammonium citrate Substances 0.000 claims description 4
- 235000000011 iron ammonium citrate Nutrition 0.000 claims description 4
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 4
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 4
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 150000005621 tetraalkylammonium salts Chemical class 0.000 claims description 4
- 125000005270 trialkylamine group Chemical group 0.000 claims description 4
- 238000001669 Mossbauer spectrum Methods 0.000 claims description 3
- 238000003776 cleavage reaction Methods 0.000 claims description 3
- 230000007017 scission Effects 0.000 claims description 3
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 3
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 3
- SEACXNRNJAXIBM-UHFFFAOYSA-N triethyl(methyl)azanium Chemical class CC[N+](C)(CC)CC SEACXNRNJAXIBM-UHFFFAOYSA-N 0.000 claims description 3
- YDCPQRQGABOSRY-UHFFFAOYSA-N iron;urea Chemical compound [Fe].NC(N)=O YDCPQRQGABOSRY-UHFFFAOYSA-N 0.000 claims 1
- 239000006185 dispersion Substances 0.000 abstract description 7
- 230000007704 transition Effects 0.000 abstract description 2
- 150000007524 organic acids Chemical class 0.000 description 58
- 239000001384 succinic acid Substances 0.000 description 52
- 229940093915 gynecological organic acid Drugs 0.000 description 36
- 235000005985 organic acids Nutrition 0.000 description 36
- 241000894007 species Species 0.000 description 25
- 230000000694 effects Effects 0.000 description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 18
- 229910002651 NO3 Inorganic materials 0.000 description 18
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 16
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 16
- 150000007530 organic bases Chemical class 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 238000007792 addition Methods 0.000 description 12
- 238000002156 mixing Methods 0.000 description 12
- 239000006259 organic additive Substances 0.000 description 12
- 229910021653 sulphate ion Inorganic materials 0.000 description 12
- 239000000843 powder Substances 0.000 description 9
- 159000000014 iron salts Chemical class 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 3
- 241000269350 Anura Species 0.000 description 3
- 238000004813 Moessbauer spectroscopy Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 3
- 150000002506 iron compounds Chemical class 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical group [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000740 diffuse reflectance ultraviolet--visible spectrum Methods 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- LNOZJRCUHSPCDZ-UHFFFAOYSA-L iron(ii) acetate Chemical compound [Fe+2].CC([O-])=O.CC([O-])=O LNOZJRCUHSPCDZ-UHFFFAOYSA-L 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 238000010850 salt effect Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- FEBUJFMRSBAMES-UHFFFAOYSA-N 2-[(2-{[3,5-dihydroxy-2-(hydroxymethyl)-6-phosphanyloxan-4-yl]oxy}-3,5-dihydroxy-6-({[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}methyl)oxan-4-yl)oxy]-3,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl phosphinite Chemical compound OC1C(O)C(O)C(CO)OC1OCC1C(O)C(OC2C(C(OP)C(O)C(CO)O2)O)C(O)C(OC2C(C(CO)OC(P)C2O)O)O1 FEBUJFMRSBAMES-UHFFFAOYSA-N 0.000 description 1
- 238000004584 57Fe Moessbauer spectroscopy Methods 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical group [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical group OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002305 Schizophyllan Polymers 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OWIUPIRUAQMTTK-UHFFFAOYSA-M n-aminocarbamate Chemical compound NNC([O-])=O OWIUPIRUAQMTTK-UHFFFAOYSA-M 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
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- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Exhaust Gas After Treatment (AREA)
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| PCT/GB2015/050579 WO2015128668A1 (en) | 2014-02-28 | 2015-02-27 | Scr catalysts having improved low temperature performance, and methods of making and using the same |
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| KR20210109196A (ko) | 2020-02-27 | 2021-09-06 | 한국화학연구원 | 잔류염소 제거방법 및 그 방법에 의한 질소산화물 저감용 촉매 |
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| GB2537206A (en) * | 2015-01-29 | 2016-10-12 | Johnson Matthey Plc | Direct incorporation of iron complexes into SAPO-34 (CHA) type materials |
| EP3336060B1 (en) * | 2015-08-13 | 2020-01-29 | Tosoh Corporation | Method for producing aei zeolite |
| JP7016801B2 (ja) | 2015-12-22 | 2022-02-07 | ビーエーエスエフ コーポレーション | 鉄(iii)交換ゼオライト組成物の製造方法 |
| GB2551871A (en) | 2016-04-22 | 2018-01-03 | Johnson Matthey Plc | STA-18, A new member of the SFW family of molecular sieve zeotypes, methods of preparation and use |
| KR20190003615A (ko) | 2016-04-28 | 2019-01-09 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | 신규 분자체 프레임워크 유형인 sta-20, 제조 방법 및 용도 |
| JP7155108B2 (ja) * | 2016-08-05 | 2022-10-18 | ビーエーエスエフ コーポレーション | 選択的触媒還元物品およびシステム |
| TWI619539B (zh) | 2016-10-14 | 2018-04-01 | 財團法人工業技術研究院 | 淨化含氮氧化物氣體的組成物及裝置 |
| KR101879695B1 (ko) * | 2016-12-02 | 2018-07-18 | 희성촉매 주식회사 | 2가 구리 이온들을 특정비율로 담지한 제올라이트, 이의 제조방법 및 이를 포함하는 촉매조성물 |
| US20200047168A1 (en) * | 2017-03-13 | 2020-02-13 | Mitsubishi Chemical Corporation | Transition metal-carrying zeolite and production method therefor, and nitrogen oxide purification catalyst and method for using same |
| CN107262145B (zh) * | 2017-07-24 | 2020-11-27 | 安徽纳蓝环保科技有限公司 | 一种沸石碳氢吸附重整催化剂的制备方法 |
| CN108212208B (zh) * | 2018-04-03 | 2020-08-25 | 兰州理工大学 | 一种atn型铁基磷酸铝分子筛催化剂的制备方法 |
| FR3081340B1 (fr) * | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur comprenant un melange d'une zeolithe de type structural afx et d'une zeolithe de type structural bea et au moins un metal de transition pour la reduction selective de nox |
| US12104517B2 (en) * | 2019-01-18 | 2024-10-01 | Cummins Emission Solutions Inc. | Treated SCR catalysts with enhanced sulfur resistance |
| CN109999895B (zh) * | 2019-04-16 | 2021-06-29 | 上海交通大学 | 一种低温催化去除氮氧化物的催化剂及其制备方法 |
| CN110833831B (zh) * | 2019-11-07 | 2022-11-01 | 上海纳米技术及应用国家工程研究中心有限公司 | 铬钴基一氧化氮常温常压催化剂的制备方法及其产品和应用 |
| EP3919165B1 (en) * | 2020-06-03 | 2025-08-13 | Johnson Matthey Public Limited Company | Method for forming a catalyst article |
| CN114345402B (zh) * | 2021-08-30 | 2024-09-17 | 武汉科技大学 | 一种铁基分子筛催化剂的制备方法 |
| JP7677496B2 (ja) * | 2023-05-12 | 2025-05-15 | 東ソー株式会社 | 鉄含有fer型ゼオライト及びその製造方法 |
| WO2024251821A1 (en) | 2023-06-06 | 2024-12-12 | Basf Corporation | Catalytic materials comprising fe-containing zeolitic material for the treatment of an exhaust gas |
| CN116786135B (zh) * | 2023-08-18 | 2024-01-02 | 四川大学 | 氧化锰矿烟气脱硫尾渣资源化制备低温脱硝催化剂的方法 |
| CN120004287A (zh) * | 2025-04-18 | 2025-05-16 | 长春理工大学 | 一种Cu-SSZ-13分子筛制备方法和分子筛的应用 |
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| US4255349A (en) * | 1978-12-18 | 1981-03-10 | Mobil Oil Corporation | Conversion of synthesis gas with iron-containing catalyst |
| EP0756891A1 (en) * | 1995-07-26 | 1997-02-05 | Corning Incorporated | Iron zeolite for conversion of NOx |
| US6033641A (en) * | 1996-04-18 | 2000-03-07 | University Of Pittsburgh Of The Comonwealth System Of Higher Education | Catalyst for purifying the exhaust gas from the combustion in an engine or gas turbines and method of making and using the same |
| FR2789911B1 (fr) | 1999-02-18 | 2001-05-04 | Grande Paroisse Sa | Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent |
| DK3278863T3 (da) * | 2007-04-26 | 2020-02-17 | Johnson Matthey Plc | Overgangsmetal/aei-zeolit-scr-katalysator |
| EP2107942A2 (en) * | 2007-05-15 | 2009-10-14 | Corning Incorporated | Calcined ferrous gluconate impregnated zeolite |
| CN102764590B (zh) * | 2007-08-13 | 2015-05-13 | Pq公司 | 含铁铝硅酸盐沸石及其制备和使用方法 |
| KR20110010711A (ko) * | 2008-05-07 | 2011-02-07 | 우미코레 아게 운트 코 카게 | 분자체에 기초하는 scr 촉매를 사용하여 탄화수소 함유 배기 가스 내의 산화질소를 감소시키기 위한 방법 |
| EP2412677A4 (en) * | 2009-03-27 | 2013-01-16 | Univ Okayama Nat Univ Corp | ORGANIC INORGANIC COMPOSITE MATERIAL AND METHOD OF MANUFACTURING THEREOF |
| JP5573453B2 (ja) * | 2010-07-21 | 2014-08-20 | 三菱樹脂株式会社 | 窒素酸化物浄化用触媒及びその製造方法 |
| US20120134916A1 (en) * | 2011-02-28 | 2012-05-31 | Fedeyko Joseph M | High-temperature scr catalyst |
| JP6104882B2 (ja) * | 2011-04-04 | 2017-03-29 | ピーキュー コーポレイション | Fe−SAPO−34触媒及びその製造方法 |
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- 2015-02-27 EP EP15708040.9A patent/EP3110548A1/en not_active Withdrawn
- 2015-02-27 WO PCT/GB2015/050579 patent/WO2015128668A1/en not_active Ceased
- 2015-02-27 US US14/633,658 patent/US20150246345A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210109196A (ko) | 2020-02-27 | 2021-09-06 | 한국화학연구원 | 잔류염소 제거방법 및 그 방법에 의한 질소산화물 저감용 촉매 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2017512630A (ja) | 2017-05-25 |
| GB201616359D0 (en) | 2016-11-09 |
| EP3110548A1 (en) | 2017-01-04 |
| RU2016138282A (ru) | 2018-04-02 |
| GB2543166A (en) | 2017-04-12 |
| DE112015001008T5 (de) | 2017-04-20 |
| WO2015128668A1 (en) | 2015-09-03 |
| RU2016138282A3 (enExample) | 2018-09-19 |
| CN106029227A (zh) | 2016-10-12 |
| US20150246345A1 (en) | 2015-09-03 |
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