JP2016524033A - 熱硬化性樹脂組成物及びその用途 - Google Patents
熱硬化性樹脂組成物及びその用途 Download PDFInfo
- Publication number
- JP2016524033A JP2016524033A JP2016526403A JP2016526403A JP2016524033A JP 2016524033 A JP2016524033 A JP 2016524033A JP 2016526403 A JP2016526403 A JP 2016526403A JP 2016526403 A JP2016526403 A JP 2016526403A JP 2016524033 A JP2016524033 A JP 2016524033A
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- JP
- Japan
- Prior art keywords
- thermosetting resin
- resin composition
- tungsten
- composition according
- total mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 91
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 89
- 150000003658 tungsten compounds Chemical class 0.000 claims abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 239000011256 inorganic filler Substances 0.000 claims abstract description 33
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 33
- 229920005989 resin Polymers 0.000 claims abstract description 29
- 239000011347 resin Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 25
- 239000011521 glass Substances 0.000 claims description 18
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 15
- 229910052721 tungsten Inorganic materials 0.000 claims description 15
- 239000010937 tungsten Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 13
- -1 dithiolatotungsten Chemical compound 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 229910001593 boehmite Inorganic materials 0.000 claims description 10
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims description 6
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 claims description 6
- KKUANYDOAOHBGB-UHFFFAOYSA-J Br[W](Br)(Br)(Br)=O Chemical compound Br[W](Br)(Br)(Br)=O KKUANYDOAOHBGB-UHFFFAOYSA-J 0.000 claims description 5
- YOUIDGQAIILFBW-UHFFFAOYSA-J Tungsten(IV) chloride Inorganic materials Cl[W](Cl)(Cl)Cl YOUIDGQAIILFBW-UHFFFAOYSA-J 0.000 claims description 5
- BGRYSGVIVVUJHH-UHFFFAOYSA-N prop-2-ynyl propanoate Chemical compound CCC(=O)OCC#C BGRYSGVIVVUJHH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- YXPHMGGSLJFAPL-UHFFFAOYSA-J tetrabromotungsten Chemical compound Br[W](Br)(Br)Br YXPHMGGSLJFAPL-UHFFFAOYSA-J 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- MSMKDUSAHXCISY-UHFFFAOYSA-N N[S+]=P([O-])(O)O Chemical compound N[S+]=P([O-])(O)O MSMKDUSAHXCISY-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 claims description 4
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims description 4
- 229910002113 barium titanate Inorganic materials 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
- 239000000347 magnesium hydroxide Substances 0.000 claims description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 4
- NIAAGQAEVGMHPM-UHFFFAOYSA-N 4-methylbenzene-1,2-dithiol Chemical compound CC1=CC=C(S)C(S)=C1 NIAAGQAEVGMHPM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052582 BN Inorganic materials 0.000 claims description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- DJZHPOJZOWHJPP-UHFFFAOYSA-N magnesium;dioxido(dioxo)tungsten Chemical compound [Mg+2].[O-][W]([O-])(=O)=O DJZHPOJZOWHJPP-UHFFFAOYSA-N 0.000 claims description 3
- MGJYZNJAQSLHOL-UHFFFAOYSA-M n,n-dioctylcarbamodithioate Chemical compound CCCCCCCCN(C([S-])=S)CCCCCCCC MGJYZNJAQSLHOL-UHFFFAOYSA-M 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- SDDGNMXIOGQCCH-UHFFFAOYSA-N 3-fluoro-n,n-dimethylaniline Chemical compound CN(C)C1=CC=CC(F)=C1 SDDGNMXIOGQCCH-UHFFFAOYSA-N 0.000 claims description 2
- 239000012990 dithiocarbamate Substances 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- MGRWKWACZDFZJT-UHFFFAOYSA-N molybdenum tungsten Chemical compound [Mo].[W] MGRWKWACZDFZJT-UHFFFAOYSA-N 0.000 claims description 2
- 239000012779 reinforcing material Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 11
- 239000011248 coating agent Substances 0.000 abstract description 10
- 230000005540 biological transmission Effects 0.000 abstract description 2
- 238000005470 impregnation Methods 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 22
- 229910052802 copper Inorganic materials 0.000 description 15
- 239000010949 copper Substances 0.000 description 15
- 238000002834 transmittance Methods 0.000 description 14
- 239000000853 adhesive Substances 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 12
- 239000011229 interlayer Substances 0.000 description 12
- 230000001070 adhesive effect Effects 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000000945 filler Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 7
- 239000006229 carbon black Substances 0.000 description 7
- 239000011889 copper foil Substances 0.000 description 7
- 229920000767 polyaniline Polymers 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000005553 drilling Methods 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910001930 tungsten oxide Inorganic materials 0.000 description 3
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 2
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229910021487 silica fume Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
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- 230000007547 defect Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- PARWUHTVGZSQPD-UHFFFAOYSA-N phenylsilane Chemical class [SiH3]C1=CC=CC=C1 PARWUHTVGZSQPD-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
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Abstract
Description
A−1 二硫化タングステン、長沙市華京粉末材料科技有限公司製
A−2 テトラチオタングステン酸アンモニウム、昊睿化学有限公司製
A−3 アルキル(アリール)アミノチオリン酸タングステン、上海東理科技有限公司製
B−1 溶融球状マイクロシリカ、電気化学工業株式会社製、SFP30M、平均粒子径0.5μm
B−2 溶融不規則シリカ、Sibelco Asia社製、525、平均粒子径2μm
B−3 複合マイクロシリカ、Sibelco Asia社製、G2C、平均粒子径2μm
B−4 ベーマイト、Nabaltec製、AOH30
B−5 ベーマイト、Nabaltec製、AOH60
C−1 カーボンブラックパウダー、ドイツデグサ社製、FW200
C−2 アニリンブラック、ドイツデグサ社製、BS890
タングステン化合物をカーボンブラックパウダーに変更する以外に、実施例1と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表2に示す。
タングステン化合物をアニリンブラックに変更する以外に、実施例1と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表2に示す。
タングステン化合物を添加しない以外に、実施例1と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表2に示す。
タングステン化合物、無機フィラー及び顔料を添加しない以外に、実施例1と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表2に示す。
エッチング液で銅張積層板の銅箔を除去した後、5mm×5mm角のサイズの試験片に切り出す。TMA試験装置を用いて10℃/minの加熱速度で、30〜260℃での該試験片のZ軸方向(ガラス布に垂直な方向)における平均線熱膨張係数を測定する。熱膨張率が小さいほど、効果が高い。
エッチング液で銅張積層板の銅箔を除去した後、100mm×100mmの試験片に切り出す。波長365nmの3kWの紫外線ランプで照射する。照度計プローブを光源のガラスプラットフォームに載せて紫外線に合わせ、光度計に表示される光強度が25mv/cm2になった時の値を記録し、空白サンプルの値をA、テストサンプルの値をBにして、下式に基づき紫外線透過率を算出する:γ=B/A×100%、透過率が小さいほど、紫外線遮断能力が高い。
米国ラブスフェア社製の透過反射率試験装置を用いて積分球法でテストする。
積層板を剥離した後に5mm角のサイズに切り、導電性接着剤に載せて、金をスプレー塗装し、観察用試験片を製造する。走査電子顕微鏡を用いて、フィラーと樹脂との界面を観察して、評価する。
積層板を5mm角のサイズに切り、樹脂を用いて注型し、導電性接着剤に載せ、金をスプレー塗装し、観察用試験片を製造する。走査電子顕微鏡を用いて、フィラーの樹脂における分散状況を観察し、更に評価する。
100mlの樹脂組成物を100mlの栓付きメスシリンダー内に投入し、25℃の室温で静置し、沈殿物が沈降管の底部に沈降するまでの時間を測定し、安定性を評価する。
積層板を100mm×100mmの試験片に切り出し、その表面における銅箔を特定のパターンに作製し、高温で処理した後、メグオーム計を用いて試験片に500Vの直流電圧を印加し且つ60s安定させた後に値を読み取り、更に体積抵抗率を算出し、値が大きいほど、体積抵抗率が大きく、積層板の電気絶縁性に優れる。
6軸ボール盤の二つの効果の近いドリル軸を用いて孔を開け、一枚の基板に対して6つの新しいカッターを使用し、各カッターで基板において3000個の孔を開けた後、検査顕微鏡でドリル刃部を観察し、刃先の摩損後退量を測定し更に垂直線と中軸線との交点と摩損上縁との距離を測定してドリルカッターの寸法とし、下式に基づきドリルカッターの摩損率を計算してドリル加工性を評価する。
100重量部の臭素化ビスフェノールAエポキシ樹脂(ダウ・ケミカル製、エポキシ当量435、臭素含有量19%、商品名DER530)、24重量部のノボラック樹脂(日本群栄製、ヒドロキシ当量105、商品名TD2090)、0.05重量部の2−メチルイミダゾール、タングステン化合物を、有機溶媒に溶解させ、機械的撹拌して乳化させて65wt%の接着剤を調製し、次にガラス繊維布を含浸させ、加熱乾燥後にプリプレグ(prepreg)を形成し、両面に銅箔を載せ、加圧・加熱して銅箔基板を得る。
タングステン化合物をカーボンブラックパウダーに変更する以外に、実施例7と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表4に示す。
タングステン化合物をアニリンブラックに変更する以外に、実施例7と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表4に示す。
タングステン化合物を添加しない以外に、実施例7と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表4に示す。
タングステン化合物、無機フィラー及び顔料を添加しない以外に、実施例7と同様な方法で、樹脂組成物を用いた銅張積層板を製造する。測定結果、評価結果を表4に示す。
Claims (24)
- 熱硬化性樹脂、無機フィラー及びタングステン化合物を含む、ことを特徴とする熱硬化性樹脂組成物。
- 前記タングステン化合物は有機タングステン化合物又は/及び無機タングステン化合物から選ばれる、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記タングステン化合物は二硫化タングステン、テトラチオタングステン酸アンモニウム、四臭化酸化タングステン、四塩化タングステン、四臭化タングステン、タングステン酸亜鉛、タングステン酸カルシウム、タングステン酸マグネシウム、タングステン酸アンモニウム、セレン化タングステン、酸化タングステン、ジオクチルジチオカルバミン酸タングステン、ジチオラトタングステン、トルエン−3,4−ジチオールタングステン、アミノジイソプロピルジチオリン酸タングステン、有機タングステンモリブデン錯体、ジチオカルバミン酸タングステン化合物、芳香族炭化水素タングステン化合物又はアルキル(アリール)アミノチオリン酸タングステンから選ばれる任意の1種又は少なくとも2種の混合物である、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記タングステン化合物はS元素とP元素を含む、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記タングステン化合物は二硫化タングステン、テトラチオタングステン酸アンモニウム、四臭化酸化タングステン、四塩化タングステン、四臭化タングステン又はアルキル(アリール)アミノチオリン酸タングステンから選ばれる任意の1種又は少なくとも2種の混合物である、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記タングステン化合物の含有量は熱硬化性樹脂組成物の全質量に対し0.001〜30wt%である、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記タングステン化合物の含有量は熱硬化性樹脂組成物の全質量に対し0.1〜15wt%である、ことを特徴とする請求項6に記載の熱硬化性樹脂組成物。
- 前記無機フィラーはシリカ、ベーマイト、アルミナ、タルク、雲母、カオリン、水酸化アルミニウム、水酸化マグネシウム、ホウ酸亜鉛、錫酸亜鉛、酸化亜鉛、酸化チタン、窒化ホウ素、炭酸カルシウム、硫酸バリウム、チタン酸バリウム、ホウ酸アルミニウム、チタン酸カリウム、Eガラスパウダー、Sガラスパウダー、Dガラスパウダー、NEガラスパウダー、中空微粉末又はベーマイトから選ばれる任意の1種又は少なくとも2種の混合物である、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記無機フィラーの含有量は熱硬化性樹脂組成物の全質量に対し10〜80wt%である、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記無機フィラーの含有量は熱硬化性樹脂組成物の全質量に対し20〜60wt%である、ことを特徴とする請求項9に記載の熱硬化性樹脂組成物。
- 前記無機フィラーの平均粒子径は0.1〜100μmである、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記無機フィラーの平均粒子径は0.5〜20μmである、ことを特徴とする請求項11に記載の熱硬化性樹脂組成物。
- 前記熱硬化性樹脂は熱硬化性樹脂組成物の全質量の20〜70wt%を占める、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記熱硬化性樹脂は熱硬化性樹脂組成物の全質量の25〜65wt%を占める、ことを特徴とする請求項13に記載の熱硬化性樹脂組成物。
- 前記熱硬化性樹脂は熱硬化性樹脂組成物の全質量の30〜60wt%を占める、ことを特徴とする請求項14に記載の熱硬化性樹脂組成物。
- 前記熱硬化性樹脂組成物は、更に熱硬化性樹脂組成物の全質量に対して1〜30wt%の硬化剤を含む、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記硬化剤は熱硬化性樹脂組成物の全質量の4〜25wt%を占める、ことを特徴とする請求項16に記載の熱硬化性樹脂組成物。
- 前記硬化剤は熱硬化性樹脂組成物の全質量の10〜20wt%を占める、ことを特徴とする請求項17に記載の熱硬化性樹脂組成物。
- 前記熱硬化性樹脂組成物は、更に熱硬化性樹脂組成物の全質量に対して0(0を除く)〜10wt%の促進剤を含む、ことを特徴とする請求項1に記載の熱硬化性樹脂組成物。
- 前記促進剤は熱硬化性樹脂組成物の全質量の1〜10wt%を占める、ことを特徴とする請求項19に記載の熱硬化性樹脂組成物。
- 前記促進剤は熱硬化性樹脂組成物の全質量の2〜8wt%を占める、ことを特徴とする請求項20に記載の熱硬化性樹脂組成物。
- 請求項1−21のいずれか一項に記載の熱硬化性樹脂組成物を溶媒に溶解又は分散させて得る、ことを特徴とする樹脂溶液。
- 強化材と、浸漬乾燥後にそれに付着される請求項1−21のいずれか一項に記載の熱硬化性樹脂組成物とを含む、ことを特徴とするプリプレグ。
- 少なくとも請求項23に記載のプリプレグを一枚含む、ことを特徴とする積層板。
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