JP2016504261A - 耐火板ガラスおよび耐火グレージングアセンブリ - Google Patents
耐火板ガラスおよび耐火グレージングアセンブリ Download PDFInfo
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- JP2016504261A JP2016504261A JP2015545723A JP2015545723A JP2016504261A JP 2016504261 A JP2016504261 A JP 2016504261A JP 2015545723 A JP2015545723 A JP 2015545723A JP 2015545723 A JP2015545723 A JP 2015545723A JP 2016504261 A JP2016504261 A JP 2016504261A
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- refractory
- layer
- glass
- float
- protective layer
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Abstract
Description
発明に係る耐火層は、有利には、アルカリケイ酸塩、好ましくはアルカリポリケイ酸塩を含有する。このような耐火層は、たとえば、EP 0 620 781 B1号またはEP 0192249 A2号により知られている。代替的な耐火層は、DE 35 30 968 C2号により知られるように、アルカリリン酸塩、アルカリタングステン酸塩、および/またはアルカリモリブデン酸塩を含有する。
保護層3.1は、各場合において、フロート板ガラス1.1上に直接配置されている。窒化ケイ素(3.1a)/酸化スズ−亜鉛(3.1b)という記載は、保護層3.1が、二重層構造からなることを示している。1番目に示された窒化ケイ素からなる保護(サブ)層3.1aは、フロート板ガラス1.1上に直接配置され、酸化スズ−亜鉛からなる第2の保護(サブ)層3.1bは、第1の保護(サブ)層3.1a上に直接配置されている。酸化スズ−亜鉛(3.1a)/窒化ケイ素(3.1b)の層順については、逆の順も適用される。
2、2.1、2.2 耐火層
3、3.1、3.2、3.3 保護層
3.1a、3.1b 保護(サブ)層、保護層、層
4 接着低下層
10、10.1、11 耐火板ガラス
100、101 耐火グレージングアセンブリ
I フロート板ガラスの大気側
II フロート板ガラスのスズ浴側
b フロート板ガラスの厚さ
d、da、db 保護層の厚さ
h 耐火層の厚さ
Claims (18)
- スズ浴側(II)を有する少なくとも1つのフロート板ガラス(1.1)と、
前記スズ浴側(II)に平面状に配置された少なくとも1つの保護層(3.1)と、
前記保護層(3.1)上に平面状に配置された少なくとも1つの耐火層(2.1)とを備え、
前記保護層(3.1)は、金属酸化物、金属窒化物、金属ケイ化物、および/またはこれらの混合物もしくは層状化合物を含有する、耐火板ガラス(10)。 - 前記耐火層(2.1)は、アルカリ性である、請求項1に記載の耐火板ガラス(10)。
- 前記耐火層(2.1)は、アルカリケイ酸塩、アルカリリン酸塩、アルカリタングステン酸塩、アルカリモリブデン酸塩、および/またはこれらの混合物もしくは層状化合物、
好ましくは、アルカリポリケイ酸塩、アルカリポリリン酸塩、アルカリポリタングステン酸塩、アルカリポリモリブデン酸塩、および/またはこれらの混合物もしくは層状化合物を含有し、前記アルカリ元素は、好ましくはナトリウム、カリウム、リチウム、および/またはこれらの混合物である、請求項1または2に記載の耐火板ガラス(10)。 - 前記耐火層(2.1)は、架橋されたモノマーおよび/またはポリマーのヒドロゲルを含有し、前記ヒドロゲルは、好ましくはポリアクリルアミド、ポリ−N−メチロールアクリルアミド、または重合化2−ヒドロキシ−3−メタクリロキシプロピルトリメチルアンモニウムクロリドを含有する、請求項1または2に記載の耐火板ガラス(10)。
- 前記保護層(3.1)は、酸化スズ、酸化亜鉛、酸化スズ−亜鉛、酸化インジウムスズ(ITO)、酸化チタン、窒化ケイ素、ケイ化タングステン、および/またはケイ化チタンを含有する、請求項1から4のいずれか1項に記載の耐火板ガラス(10)。
- 前記保護層(3.1)は、酸化スズ−亜鉛を含有し、亜鉛:スズの比は、5重量%:95重量%〜95重量%:5重量%の範囲であり、好ましくは、15重量%:85重量%〜70重量%:30重量%の範囲である、請求項5に記載の耐火板ガラス(10)。
- 前記保護層(3.1)は、少なくとも1つのドーパントを含有し、前記少なくとも1つのドーパントは、好ましくはアンチモン、フッ素、銀、ルテニウム、パラジウム、アルミニウム、およびタンタルであり、前記保護層の金属部分中の前記ドーパントの部分は、好ましくは、0重量%〜10重量%、特に好ましくは1重量%〜5重量%である、請求項5または6に記載の耐火板ガラス(10)。
- 前記保護層(3.1)は、複層であり、好ましくは二重層構造であり、1つの保護(サブ)層(3.1a)は、金属窒化物を含有するまたはこれからなり、前記金属窒化物は、好ましくは窒化ケイ素であり、1つの保護(サブ)層(3.1b)は、金属酸化物を含有するまたはこれからなり、前記金属酸化物は、好ましくは酸化スズ−亜鉛またはドープされた酸化スズ−亜鉛である、請求項1から7のいずれか1項に記載の耐火板ガラス(10)。
- 前記保護層(3.1)は、2nm〜500nm、好ましくは5nm〜50nm、特に好ましくは15nm〜30nmの厚さdを有する、請求項1から8のいずれか1項に記載の耐火板ガラス(10)。
- 前記フロート板ガラス(1.1)は、ホウケイ酸ガラス、アルミノケイ酸ガラス、アルカリ土類ケイ酸塩ガラス、またはソーダ石灰ガラスを含有し、好ましくは、EN572−1:2004に従うソーダ石灰ガラスを含有し、および/または、前記フロート板ガラス(1.1)は、熱強化または部分強化されている、請求項1から9のいずれか1項に記載の耐火板ガラス(10)。
- 前記フロート板ガラス(1.1)は、1mm〜25mm、好ましくは2mm〜12mmの厚さbを有し、および/または、前記耐火層(3.1)は、0.5mm〜70mmの厚さhを有する、請求項1から10のいずれか1項に記載の耐火板ガラス(10)。
- 少なくとも1つの接着改善層または1つの接着低下層(4)は、好ましくは、少なくとも1つの有機官能性シランまたは少なくとも1つのポリマーワックス、特に好ましくはポリエチレン主体のポリマーワックスを含有し、前記保護層(3.1)と前記耐火層(2.1)との間に配置される、請求項1から11のいずれか1項に記載の耐火板ガラス(10)。
- 少なくとも、
請求項1から12のいずれか1項に記載の1つの耐火板ガラス(10)と、
大気側(I)およびスズ浴側(II)を有する1つのフロート板ガラス(1.2)とを備え、
前記大気側(I)または、
前記スズ浴側(II)は、保護層(3.2)を介して、
前記耐火板ガラス(10)の前記耐火層(2.1)に平面状に結合される、耐火グレージングアセンブリ(100,101)。 - 前記耐火板ガラス(10)の前記フロート板ガラス(1.1)の前記大気側(I)は、耐火層(2.2)に平面状に結合され、前記耐火層(2.2)は、前記大気側(I)に平面状に結合される、または、第3のフロート板ガラス(1.3)の前記スズ浴側(II)に別の保護層(3.3)を介して平面状に結合される、請求項13に記載の耐火グレージングアセンブリ(101)。
- 前記フロート板ガラス(1.1)または前記フロート板ガラス(1.2)は、別の耐火層(2.2)および別のフロート板ガラス(1.3)からなる少なくとも1つの積層順(stack sequence)にわたって結合され、発明に係る別の保護層(3.2)は、各スズ浴側(II)と前記スズ浴側(II)のすぐ隣に配置された耐火層(2.2)との間に配置される、請求項13または14に記載の耐火グレージングアセンブリ(101)。
- 少なくとも、
a) 1つの保護層(3.1)をフロート板ガラス(1.1)のスズ浴側(II)に塗布し、
b) 前記フロート板ガラス(1.1)および第2のフロート板ガラス(1.2)を熱強化するまたは部分強化し、
c) 前記フロート板ガラス(1.1)の前記スズ浴側(II)と前記第2のフロート板ガラス(1.2)との間に空隙が形成されるように、前記フロート板ガラス(1.1)および第2のフロート板ガラス(1.2)を互いから一定の間隔で保持し、
d) 耐火層(2.1)を前記空隙内に投入し、硬化させる、耐火グレージングアセンブリ(100,101)を製造するための方法。 - 前記製造工程は、別のフロート板ガラス(1.3)および別の耐火層(2.2)を用いて、少なくとも1回繰返される、請求項16に記載の方法。
- 老化による前記フロート板ガラス(1.1)の曇りを減少させるための、請求項1から12のいずれか1項に記載の前記フロート板ガラス(1.1)の前記スズ浴側(II)と前記耐火層(2.1)との間における前記保護層(3.1)の使用。
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EP3159318A1 (en) * | 2015-10-20 | 2017-04-26 | Saint-Gobain Glass France | Fire resistant glazing and coating for a fire resistant glass |
PL242694B1 (pl) * | 2019-10-29 | 2023-04-11 | Ml System Spolka Akcyjna | Sposób otrzymywania selektywnej warstwy ognioodpornej modyfikowanej nanocząsteczkami półprzewodnikowymi oraz wypełniania tą aktywną warstwą komory lub komór szyby zespolonej i szyba zespolona zawierająca tą lub te warstwy |
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