JP2016210764A - External composition, and makeup cosmetics using the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide external compositions not only suppressing color transfer but having an excellent feeling of use, and to provide makeup cosmetics using the same.SOLUTION: The invention provides an external composition containing dimethicone crosspolymer (A), a silicone elastomer type surfactant (B), an organic pigment (C), and 5% by weight or less of water (D); and a makeup cosmetic using the same. Preferably, the composition also contains alkyl-modified silicone crosspolymer (E). Preferably, the content of the above organic pigment (C) is 0.1-6% by weight in the composition.SELECTED DRAWING: Figure 1

Description

  TECHNICAL FIELD The present invention relates to an external composition and a makeup cosmetic using the same, and in particular, an external composition that not only suppresses color transfer but also has an excellent feeling of use, and a cosmetic for makeup using the composition. It is about.

  So far, in terms of its excellent adhesion to the skin, its durability, water resistance, etc., in makeup cosmetics such as lipstick, eye color, eyeliner, cheek color, face color, etc. Oily cosmetics have been widely used.

  However, since the oily cosmetics have a high oil content, they usually have a drawback of causing a feeling of stickiness or a heavy feeling of use. In order to solve these drawbacks and obtain an oily cosmetic material having a good feeling of use, it has been proposed to use a silicone polymer having a three-dimensional crosslinked structure (Patent Document 1).

Japanese Patent No. 2561857

  However, the oily cosmetics are still not sticky, squeaky, squeezed, etc., and are not sufficiently satisfactory in terms of use. Conventionally, makeup cosmetics, etc., may cause color transfer when hands or clothing touch the application site, causing not only makeup collapse but also contamination of clothing etc. was there.

  The present invention has been made in view of such circumstances, and an object of the present invention is to provide an external composition that not only suppresses color transfer but also has an excellent feeling of use, and a cosmetic for makeup using the same.

  In order to achieve the above object, the present invention provides a composition for external use containing a dimethicone cross polymer (A), a silicone elastomer type surfactant (B), an organic pigment (C), and 5% by weight or less of water (D). Is the first gist.

  Further, the present invention has a second gist that the composition for external use further contains an alkyl-modified silicone cross polymer (E), and further, the content of the organic pigment (C) is in the composition for external use. The third aspect is that the content is 0.1 to 6% by weight. And the cosmetics for makeup using these external compositions are made into the 4th summary.

  That is, the present inventors have intensively studied in order to obtain an external composition that suppresses color transfer to hands, clothes, and the like, and a makeup cosmetic using the composition. As a result, as an external composition, the external composition containing dimethicone crosspolymer (A), silicone elastomer type surfactant (B), organic pigment (C), 5% by weight or less of water (D), The present inventors have found that not only the color transfer is suppressed but also the usability is improved.

  The external composition of the present invention is an external composition containing dimethicone crosspolymer (A), silicone elastomer type surfactant (B), organic pigment (C), and 5% by weight or less of water (D). In addition to suppressing color transfer, it is excellent in use feeling.

  Further, when the above-mentioned external composition further contains an alkyl-modified silicone cross polymer (E), the external composition is difficult to phase separate and has excellent stability.

  And when content of the said organic pigment (C) is 0.1 to 6 weight% in an external composition, the external composition excellent in coloring on skin is obtained, suppressing color transfer.

  Furthermore, when the above-mentioned composition for external use is used, a cosmetic for make-up that suppresses color transfer and has an excellent feeling of use can be obtained.

In the color transfer test, (a) is the product of Example 1, (b) is the product of Example 2, (c) is the product of Example 3, (d) is the product of Example 4, and (e) is the product. (F) of the product of Example 5 is a photograph of the product of Example 6 taken with the result of color transfer to white fine paper. In the color transfer test, (a) is a photograph of the product of Comparative Example 1 and (b) is a photograph of the result of color transfer to white fine paper of Comparative Example 2.

  Next, embodiments of the present invention will be described in detail. However, the present invention is not limited to the following embodiments.

<External composition>
The composition for external use of the present invention contains a dimethicone cross polymer (A), a silicone elastomer type surfactant (B), an organic pigment (C), and 5% by weight or less of water (D). Hereinafter, each component which comprises the composition for external use is demonstrated in order.

  Here, the composition for external use means a composition that is directly applied to the skin, such as an external medicine, an external medicine quasi-drug, and a cosmetic.

[Dimethicone cross polymer (A)]
The dimethicone cross polymer (A) represents a paste or particles in which a siloxane skeleton is three-dimensionally cross-linked, and is a component having sebum absorbability due to the elastic feel unique to the elastic body and the cross-linked body. This has no emulsifying ability and is useful for obtaining a good feel of the formulation.

  The dimethicone cross polymer (A) may have a particle shape or may have a shape of an oil dispersion without having a shape. It is preferable that the primary particle diameter is in the range of 0.1 to 50 μm and the shape of the primary particles is selected from spherical powders. Furthermore, it is preferable that the silicone elastomer having a particle shape is blended into the preparation in one or more forms selected from those kneaded in an oil agent, finely pulverized by a pulverizer, or an aqueous dispersion. The surface of the silicone elastomer may or may not be surface-treated with a different silicone compound.

  As the dimethicone cross polymer (A), a commercially available one can be used, or it can be produced by a known method.

As a specific example of the dimethicone cross polymer (A), those provided as a mixture with an oil agent are preferable. Specifically, 9040 Silicone Elastomer Blend, 9045 Silicone Elastomer Blend, EL-9240 Silicone Elastomer Blend Blend, 9041 Silicone Elastomer Blend 80, manufactured by Toray Dow Corning Silicone. Examples include, but are not limited to, HIP Emulsion, 9027 Silicone Elastomer Blend, 9546 Silicone Elastomer Blend (each of which is a trade name). Among these, 9040 Silicone Elastomer Blend and 9045 Silicone Elastomer Blend are preferable.
The said dimethicone cross polymer (A) can be used individually or in combination of 2 or more types.

  The blending amount of the dimethicone cross polymer (A) is usually 0.1 to 20% by weight, preferably 0.1 to 15% by weight with respect to 100% by weight of the composition for external use, from the viewpoint of stability and usability. %, More preferably 1 to 11% by weight.

[Silicone elastomer type surfactant (B)]
The silicone elastomer type surfactant (B) is a silicone elastomer derivative generally modified with a functional group such as an alkylene oxide group on polysiloxane, and has a surface active ability (emulsifying ability and powder dispersing ability). Ingredients.

  As the silicone elastomer type surfactant (B), a commercially available one can be used, or it can be produced by a known method.

Examples of the silicone elastomer type surfactant (B) include, but are not limited to, a polyglycerin-modified silicone elastomer type surfactant and a polyether-modified silicone elastomer type surfactant. Specific examples of the silicone elastomer type surfactant (B) include (Lauryl dimethicone / polyglycerin-3) crosspolymer (trade names: KSG-810, KSG-820, KSG-830, KSG-, manufactured by Shin-Etsu Silicone Co., Ltd.). 840), (polyglyceryl-3 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (trade names: KSG-820Z, KSG-850Z), (dimethicone / polyglycerin-3) crosspolymer (trade name: KSG-710), etc. Polyglycerin-modified silicone elastomer type surfactant, (PEG-15 / lauryl dimethicone) crosspolymer (trade names: KSG-310, KSG-320, KSG-330, KSG-340), (PEG-15 / lauryl polydimethylsiloxy) Ethyl dimethicone) black Polyether-modified silicone elastomers such as polymers (trade names: KSG-320Z, KSG-350Z, KSG-360Z), (dimethicone / (PEG-10 / 15)) crosspolymers (trade names: KSG-210, KSG-240) Examples include, but are not limited to, type surfactants. Among them, (lauryl dimethicone / polyglycerin-3) crosspolymer is preferable.
The silicone elastomer type surfactant (B) can be used alone or in combination of two or more.

  The content of the silicone elastomer type surfactant (B) used in the present invention is usually 0.01 to 10% by weight, preferably 0.1 to 10% in 100% by weight of the composition for external use from the viewpoint of formulation stability. It is 8% by weight, more preferably 0.1 to 5% by weight.

  In the composition for external use, the silicone elastomer type surfactant (B) is 0.0001 to 1.5 parts by weight, further 0.001 to 1 part by weight, based on 1 part by weight of the dimethicone cross polymer (A). In particular, it is preferably blended in an amount of 0.01 to 0.5 parts by weight. When the amount of the component (B) is too much for the component (A), the retention tends to be inferior, and when the amount of the component (B) is too small, the retention of the composition for external use is inferior and tends to be sticky. Seen.

[Organic pigment (C)]
Examples of organic pigments include organic dyes Red 201, Red 202, Red 204, Red 205, Red 206, Red 207, Red 218, Red 226, Yellow No. 4 aluminum lake, yellow No. 5 aluminum lake, yellow No. 203 aluminum lake, yellow No. 401, blue No. 1 aluminum lake, blue No. 404, orange No. 203 and the like.
These may be used alone or in combination of two or more.

  The content of the organic pigment (C) is usually 0.1% by weight or more, preferably 0.1 to 6% by weight, particularly preferably 100% by weight in the composition for external use from the viewpoint of formulation stability. Is 0.1 to 4% by weight, more preferably 0.1 to 2% by weight.

[Water (D)]
The water (D) is an optional component, and is preferably 5% by weight or less, preferably 1% by weight or less in the composition for external use from the viewpoint of color transfer and use feeling, and in particular, a non-aqueous composition for external use. It is preferable to use a product. Here, “non-aqueous” means a system that does not substantially contain water. “Substantially free of water” is not limited to a completely anhydrous state, for example, when a small amount of water contained in the raw material itself remains or when a small amount of water is contained by adding an extract, etc. Is intended to include this. However, the water content is desirably 0.5% by weight or less, more preferably 0.1% by weight or less, in the composition for external use.

  Moreover, it is also preferable that an external composition contains components, such as an alkyl-modified silicone crosspolymer (E), as an arbitrary component, in addition to water (D).

[Alkyl-modified silicone crosspolymer (E)]
The alkyl-modified silicone cross polymer (E) is a fine particle having a three-dimensional cross-linked structure by adding an alkyl group to a three-dimensional cross-linked siloxane skeleton, and is a component that gives a smooth and smooth feel. is there. In addition, the alkyl-modified silicone cross polymer (E) having a particle shape is kneaded with an oil agent, finely pulverized by a pulverizer, or one or more forms selected from aqueous dispersions. Is preferred.

  As the alkyl-modified silicone cross polymer (E), a commercially available product can be used, or it can be produced by a known method.

The alkyl-modified silicone cross polymer (E) is preferably an oil dispersion. Specific examples include (vinyl dimethicone / lauryl dimethicone) crosspolymer (trade names; KSG-41, KSG-42, KSG-43, KSG-44), (lauryl polydimethylsiloxyethyl dimethicone / bis) manufactured by Shin-Etsu Silicone. (Vinyl dimethicone) cross polymer (trade names: KSG-042Z, KSG-045Z), (cetearyl dimethicone / vinyl dimethicone) cross polymer (trade name: SILSOFT Silicone Gel) manufactured by Momentive Performance Materials, Inc., cetearyl dimethicone cross Examples thereof include, but are not limited to, polymers (VELVESIL DM), alkyl (C30-45) cetearyl dimethicone crosspolymers (VELVESIL125, VELVESIL034), and the like. Among them, (vinyl dimethicone / lauryl dimethicone) cross polymer is preferable.
The alkyl-modified silicone cross polymer (E) can be used alone or in combination of two or more.

  The content of the alkyl-modified silicone cross polymer (E) is 0.001 to 20% by weight in 100% by weight of the composition for external use from the viewpoints of dispersion stability, formulation stability, stickiness and the like, and further 0.01 to It is preferably 10% by weight, particularly 0.1 to 8% by weight.

  In the composition for external use, the alkyl-modified silicone cross polymer (E) is preferably 0.01 to 100 parts by weight, more preferably 0.05 to 50 parts by weight with respect to 1 part by weight of the dimethicone cross polymer (A).

[At least one of (dimethicone / vinyl dimethicone) crosspolymer and (dimethicone / phenylvinyldimethicone) crosspolymer (F)]
From the viewpoint of the feeling of use, it is preferable that at least one of (dimethicone / vinyl dimethicone) cross polymer and (dimethicone / phenylvinyl dimethicone) cross polymer (F) is further included.

  Specific examples (product names) of at least one of (dimethicone / vinyl dimethicone) cross polymer and (dimethicone / phenyl vinyl dimethicone) cross polymer (product name) include, for example, KSG-15, KSG-1510, manufactured by Shin-Etsu Silicone Co., Ltd. Examples thereof include KSG-16, KSG-1610, KSG-18A, KSG-19, KSG-016F, and among them, (dimethicone / vinyl dimethicone) crosspolymer (KSG-16) is preferable.

  The blending amount of at least one of (dimethicone / vinyl dimethicone) cross polymer and (dimethicone / phenyl vinyl dimethicone) cross polymer (F) is usually based on 100% by weight of the composition for external use from the viewpoint of stability and feeling of use. It is 0.1 to 20 weight%, Preferably it is 0.1 to 15 weight%, More preferably, it is 1 to 11 weight%.

[Other ingredients]
The composition for external use of the present invention contains the dimethicone crosspolymer (A) described above, a silicone elastomer type surfactant (B), an organic pigment (C), and 5% by weight or less of water (D), if necessary. In addition, it contains at least one of alkyl-modified silicone crosspolymer (E), (dimethicone / vinyl dimethicone) cross polymer and (dimethicone / phenylvinyl dimethicone) cross polymer (F), and in addition, UV protection according to various purposes. Agent, moisturizing component, polyhydric alcohol, scrub agent, anti-inflammatory agent, astringent component, vitamins, peptide or derivative thereof, amino acid or derivative thereof, cleaning component, antibacterial component, keratin soft component, cell activation component, anti-aging component In addition, other components such as a blood circulation promoting component and a whitening component may be included as long as the effects of the present invention are not impaired. In addition, you may use these other components individually or in combination of 2 or more types.

  Examples of the UV protection agent include UV absorbers and UV scattering agents. These are used alone or in combination of two or more, and it is particularly preferable to blend both an oil-soluble ultraviolet absorber and an ultraviolet scattering agent as the ultraviolet protective agent.

  When these ultraviolet protective agents are blended, 0.1 to 60% by weight, further 0.1 to 40% by weight, particularly 1 to 25% by weight is preferably blended in 100% by weight of the composition for external use.

  The oil-soluble ultraviolet absorber is an ultraviolet absorber that does not dissolve in water and is a component having an ultraviolet protection effect. As the oil-soluble ultraviolet absorber, a commercially available one can be used, or it can be produced by a known method.

Examples of the oil-soluble ultraviolet absorber include 2,4-bis-{[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3. , 5-triazine, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, 2- [4- (diethylamino) -2-hydroxybenzoyl] hexyl benzoate Examples include, but are not limited to, ester, 2-ethylhexyl paramethoxycinnamate, 4-tert-butyl-4′-methoxy-dibenzoylmethane, octocrylene, and polysilicone-15. Of these, 2-ethylhexyl paramethoxycinnamate and polysilicone-15 are preferred.
The oil-soluble ultraviolet absorbers can be used alone or in combination of two or more.

  The content of the oil-soluble ultraviolet absorber is from 0.1 to 20% by weight, more preferably from 0.1 to 10% by weight, especially from 100% by weight of the composition for external use, from the viewpoints of UV protection effect, usability, and preparation stability. It is preferably 0.5 to 10% by weight.

  Moreover, it is preferable that 0.001-200 weight part and further 0.001-150 weight part of an oil-soluble ultraviolet absorber are mix | blended with respect to 1 weight part of dimethicone crosspolymer (A).

  Examples of the ultraviolet scattering agent include metal powder in which a metal such as titanium oxide or zinc oxide is finely divided. The metal powder used for this invention can use what is marketed, or can be manufactured by a well-known method.

  Specific examples of ultraviolet scattering agents include inorganic compounds such as zinc oxide, titanium oxide, iron oxide, cerium oxide, zirconium oxide, titanium silicate, zinc silicate, anhydrous silicic acid, cerium silicate, and hydrous silicic acid. These inorganic compounds are coated with inorganic powders such as hydrous silicic acid, aluminum hydroxide, mica, or talc, and these inorganic compounds are compounded with resin powders such as polyamide, polyethylene, polyester, polystyrene, or nylon. And those obtained by treating or coating these inorganic compounds with silicone oil, fatty acid aluminum salts, or the like. The ultraviolet scattering agent can be used alone or in combination of two or more.

  Among the ultraviolet scattering agents, zinc oxide and titanium oxide are preferable because they have a high ultraviolet scattering effect, and titanium oxide, iron oxide and the like can be suitably used as a pigment.

  The content of the ultraviolet light scattering agent is 0.1 to 50% by weight, more preferably 0.1 to 30% by weight, particularly 0.1 to 30% by weight in 100% by weight of the composition for external use, from the viewpoints of ultraviolet protective effect, usability and preparation stability. It is preferably 5 to 20% by weight.

  Moreover, it is preferable to mix | blend 0.001-200 weight part and further 0.001-150 weight part of an ultraviolet-ray scattering agent with respect to 1 weight part of dimethicone crosspolymer (A).

  Examples of the moisturizing component include diglycerin trehalose; high molecular compounds such as sodium hyaluronate, heparin-like substance, sodium chondroitin sulfate, collagen, elastin, keratin, chitin, chitosan; amino acids such as glycine, aspartic acid, arginine; Natural moisturizing factors such as sodium, urea and sodium pyrrolidone carboxylate; lipids such as ceramide, cholesterol and phospholipid; plant extract extracts such as chamomile extract, hamamelis extract, tea extract and perilla extract.

  As said polyhydric alcohol, a C2-C10 thing is preferable, for example, For example, glycerol, diglycerol, triglycerol, propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, isoprene glycol, 1,3-butylene glycol Sorbitol, xylitol, erythritol, mannitol, pentanediol, hexanediol, octanediol, decanediol, neopentyl glycol and the like.

  Among these, glycerin, diglycerin, triglycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, ethylene glycol, diethylene glycol, isoprene glycol, sorbitol, xylitol, erythritol, mannitol, pentanediol, hexanediol, octanediol Glycerin, diglycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, diethylene glycol, isoprene glycol, sorbitol, xylitol, erythritol, mannitol, pentanediol, and hexanediol are more preferable.

  Examples of the scrub agent include apricot kernel powder, almond shell powder, apricot kernel powder, sodium chloride grain, olive kernel powder, dried sea water grain, candelilla wax, walnut shell powder, cherry core powder, coral powder, charcoal powder. , Hull paste powder, polyethylene powder, silicic anhydride and the like.

  Examples of the anti-inflammatory agent include glycyrrhetinic acid, glycyrrhizic acid derivatives, azulene, components derived from plants (eg, Comfrey), zinc oxide, tocopherol acetate, allantoin, aminocaproic acid, and hydrocortisone.

  Examples of the astringent component include zinc oxide, zinc sulfate, aluminum chloride, zinc sulfocolate and tannic acid.

  Examples of the vitamins include vitamin E such as dl-α-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol succinate, dl-α-tocopherol calcium succinate; riboflavin, flavin mononucleotide, flavin Vitamin B2 such as adenine dinucleotide, riboflavin butyrate, riboflavin tetrabutyrate, riboflavin 5'-phosphate sodium, riboflavin tetranicotinate; nicotinic acid, nicotinic acid dl-α-tocopherol, benzyl nicotinate, nicotinic acid Nicotinic acids such as methyl, β-butoxyethyl nicotinate, 1- (4-methylphenyl) ethyl nicotinate, nicotinamide; ascorbigen-A, ascorbic acid stearate, ascorb Vitamin C such as palmitate, dipalmitate L-ascorbyl; Vitamin D such as methyl hesperidin, ergocalciferol, cholecalciferol; Vitamin K such as phylloquinone, farnoquinone; γ-oryzanol, dibenzoylthiamine , Dibenzoyl thiamine hydrochloride; thiamine hydrochloride, thiamine cetyl hydrochloride, thiamine thiocyanate, thiamine lauryl hydrochloride, thiamine nitrate, thiamine monophosphate, thiamine lysine salt, thiamine triphosphate, thiamine monophosphate phosphate Vitamin B1 such as thiamine monophosphate, thiamine diphosphate, thiamine diphosphate hydrochloride, thiamine triphosphate, thiamine triphosphate monophosphate; pyridoxine hydrochloride, acetic acid Vitamin B6 such as redoxin, pyridoxal hydrochloride, 5′-pyridoxal phosphate, pyridoxamine hydrochloride; vitamin B12 such as cyanocobalamin, hydroxocobalamin, deoxyadenosylcobalamin; folic acid such as folic acid, pteroylglutamic acid; pantothenic acid, pantothenic acid Pantothenic acids such as calcium, pantothenyl alcohol (panthenol), D-panthecin, D-panthetin, coenzyme A, pantothenyl ethyl ether; biotins such as biotin and biocytin; ascorbic acid, sodium ascorbate, dehydroascorbic acid Vitamin Cs which are ascorbic acid derivatives such as sodium ascorbate phosphate, magnesium ascorbate phosphate; carnitine, ferulic acid, α-lipoic acid, orot Vitamin-like agents such as and the like.

  Examples of the peptide or derivative thereof include keratin degrading peptide, hydrolyzed keratin, collagen, collagen derived from fish, atelocollagen, gelatin, elastin, elastin degrading peptide, collagen degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, Elastin degrading peptide, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, hydrolyzed soy protein, wheat protein, wheat proteolytic peptide, hydrolyzed wheat protein, Casein degrading peptides, acylated peptides (palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides, etc.) and the like can be mentioned.

  Examples of the amino acids or derivatives thereof include betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, Examples include cystine, methionine, leucine, isoleucine, valine, histidine, taurine, γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid, carnitine, carnosine, and creatine.

  Examples of the cleaning component include soaps selected from alkali metal salts such as potassium laurate, potassium myristate, potassium palmitate or potassium stearate, alkanolamide salts or amino acid salts; cocoyl glutamate Na, cocoyl methyl taurine Na Amino acid surfactants such as ether sulfate salts such as laureth sulfate Na; ether carboxylates such as lauryl ether acetate Na; sulfosuccinate salts such as alkyl sulfosuccinate Na; coconut oil fatty acid monoethanolamide, coconut oil Fatty acid alkanolamides such as fatty acid diethanolamide; monoalkyl phosphoric acid ester salts such as sodium lauryl phosphate and polyoxyethylene lauryl ether sodium phosphate; coconut oil fatty acid amidopropyl dimethy Betaine types such as aminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, laurylhydroxysulfobetaine and lauroylamidoethylhydroxyethylcarboxymethylbetaine hydroxypropyl phosphate sodium Amphoteric surfactants; amino acid-type amphoteric surfactants such as sodium laurylaminopropionate.

  Examples of the antibacterial component include chlorhexidine, salicylic acid, benzalkonium chloride, acrinol, ethanol, benzethonium chloride, cresol, gluconic acid and derivatives thereof, popidone iodine, potassium iodide, iodine, isopropylmethylphenol, triclocarban, triclosan, photosensitive Element 101, photosensitive element 201, paraben, phenoxyethanol, 1,2-pentanediol, alkyldiaminoglycine hydrochloride, pyroctoolamine, miconazole and the like.

  Examples of the keratin soft component include lactic acid, salicylic acid, salicylic acid glycolic acid, gluconic acid, citric acid, malic acid, fruit acid, phytic acid, urea, sulfur and the like.

  Examples of the cell activation component include amino acids such as γ-aminobutyric acid and ε-aminocaproic acid; vitamins such as retinol, thiamine, riboflavin, pyridoxine hydrochloride and pantothenic acids; α-hydroxy acids such as glycolic acid and lactic acid Tannins, flavonoids, saponins, photosensitizer 301 and the like.

  Examples of the anti-aging component include pangamic acid, kinetin, ursolic acid, turmeric extract, sphingosine derivative, silicon, silicic acid, N-methyl-L-serine, mevalonolactone, and the like.

  Examples of the blood circulation promoting component include plants (for example, ginseng, ashitaba, arnica, ginkgo, fennel, entomop, Dutch oak, chamomile, roman chamomile, carrot, gentian, burdock, rice, hawthorn, shiitake, ginger, and hawthorn. , Spider, cucumber, thyme, thyme, clove, chimney, pepper, toki, tonin, spruce, carrot, garlic, butcher bloom, grape, button, maronier, melissa, yuzu, yokuinin, ryokcha, rosemary, rosehip, peach, Apricot, walnut, corn) component: acetylcholine, ictamol, cantalis tincture, gamma-oryzanol, cephalanthin, torazoline, tocopherol nicotinate, glucosi Hesperidin, and the like.

  Examples of the whitening component include tocopherol, ascorbic acid and / or their salts, ascorbic acid derivatives, tranexamic acid, arbutin, 4-alkylresorcinol and / or their salts, 4-methoxysalicylic acid, hydroquinone, Examples include kojic acid, placenta extract, and plant components having a whitening effect (for example, extracts such as buckwheat, yukinoshita, and aloe).

<Sunscreen composition>
The external composition of the present invention can be used as an external composition for sunscreen. The external composition for sunscreen can be suitably used as an external preparation for protecting skin and hair from ultraviolet rays, preventing sunburn and the like. The application amount and usage of the sunscreen external composition to the skin are not particularly limited, and it can be used by applying, for example, applying an appropriate amount to the skin several times a day. Moreover, it can have a function as a makeup base.

<Makeup cosmetics>
The composition for external use of the present invention can be applied to each part of the face such as lips, eyes, cheeks, and lip cosmetics such as lipstick, lip balm, cream, lip gloss, lip liner, eye color, eye liner, eye. It is preferably used for point makeup such as shadow, mascara, eyebrow, cheek color and face color. Among these, since the point which suppresses the color transfer which is the effect of this invention raises commercial value, it is more preferable to use for lipstick cosmetics and a cheek color. These cosmetics for makeup can be produced according to a conventional method. Here, “use” means not only the case of using only the material but also the case of using the material in combination with another material.

<Method for producing composition for external use>
The production method of the composition for external use of the present invention is not particularly limited, and in addition to dimethicone cross polymer (A), silicone elastomer type surfactant (B), organic pigment (C), water (D), alkyl-modified silicone cloth At least one of polymer (E), (dimethicone / vinyl dimethicone) cross polymer and (dimethicone / phenylvinyl dimethicone) cross polymer (F) and various other components necessary for producing a normal external composition (the above-mentioned other components, etc.) ) Are appropriately selected and blended, and can be produced by a conventional method.

<Formulation>
Examples of the preparation form of the composition for external use used in the present invention include pharmaceuticals, quasi-drugs, and cosmetics. In this case, the essential components and the other components described above are used as pharmaceuticals, quasi-drugs or It can be mixed according to a conventional method together with a base or carrier usually used in cosmetics and, if necessary, an additive to be described later, to obtain a composition in these preparation forms.

  The composition for external use may be either an Si / O type emulsion or an O / Si type emulsion, and may further contain water. For example, depending on the feeling of use and the performance to be imparted, Can be selected.

  Furthermore, as the base or carrier, fats and oils such as palm oil, olive oil, rice bran oil and shea butter; hydrocarbons such as petrolatum and liquid paraffin; waxes such as jojoba oil, miw wax, candelilla wax and lanolin; cetanol , Cetostearyl alcohol, stearyl alcohol, behenyl alcohol, octyldodecanol, higher alcohols such as isostearyl alcohol, phytosterol and cholesterol; cyclic silicones such as dimethicone and cyclopentasiloxane; silicones such as modified silicones; ethylcellulose, hydroxypropylcellulose, hydroxy Cellulose derivatives such as propylmethylcellulose; polyvinylpyrrolidone; carrageenan; polyvinyl butyrate; polyethylene glycol; dioxane; Glycol adipate polyester; diisopropyl adipate, isopropyl myristate, octyldodecyl myristate, isopropyl palmitate, cetyl palmitate, glyceryl tri-2-ethylhexanoate, polyglyceryl-2 triisostearate, isononyl isononanoate, tetra-2- Esters such as ethylhexanoate pentaerythritol and diisostearyl malate; polysaccharides such as dextrin and maltodextrin; vinyl polymers such as carboxyvinyl polymer and alkyl-modified carboxyvinyl polymer; lower alcohols such as ethanol and isopropanol; Examples include glycol ethers such as diethylene glycol monoethyl ether; water and the like. When the sunscreen composition of the present invention contains a polyhydric alcohol, the polyhydric alcohol may also serve as a base or carrier.

  The bases or carriers described above can be used singly or in combination of two or more, and the amount used thereof is appropriately selected from a range known to those skilled in the art.

〔Additive〕
In the composition for external use of the present invention, known additives added to pharmaceuticals, quasi drugs or cosmetics, for example, surfactants (except for the component (B)), as long as the effects of the present invention are not impaired. , Stabilizers, antioxidants, colorants other than organic pigments, pearl luster imparting agents, dispersants, chelating agents, pH adjusters, preservatives, thickeners, irritation reducing agents, fragrances, and the like can be added. . These additives can be used alone or in combination of two or more.

  Examples of the surfactant include sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, etc. Sorbitan fatty acid esters of propylene glycol fatty acid esters such as propylene glycol monostearate; polyoxyethylene hydrogenated castor oil 40 (HCO-40), polyoxyethylene hydrogenated castor oil 50 (HCO-50), polyoxyethylene hydrogenated castor Hardened castor oil derivatives such as oil 60 (HCO-60), polyoxyethylene hardened castor oil 80; polyoxyethylene (20) sorbitan (polysorbate 20) monolaurate, monostearate Polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene acid (20) sorbitan (polysorbate 60), polyoxyethylene monooleate (20) sorbitan (polysorbate 80), polyoxyethylene (20) sorbitan isostearate; polyoxy Examples thereof include ethylene monococonut oil fatty acid glyceryl; glycerin alkyl ether; alkyl glucoside; polyoxyalkylene alkyl ether such as polyoxyethylene cetyl ether; amines such as stearylamine and oleylamine.

  Examples of the stabilizer include sodium polyacrylate, dibutylhydroxytoluene, butylhydroxyanisole and the like.

  Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, sorbic acid, sodium sulfite, ascorbic acid, erythorbic acid, and L-cysteine hydrochloride.

  Examples of the colorant include inorganic pigments such as titanium oxide and iron oxide, extender pigments such as talc, mica, and silicone-treated synthetic phlogopite, and natural dyes.

  Examples of the pearl luster imparting agent include ethylene glycol distearate, ethylene glycol monostearate, triethylene glycol distearate, and nylon powder.

  Examples of the dispersant include sodium pyrophosphate, sodium hexametaphosphate, polyvinyl alcohol, polyvinyl pyrrolidone, methyl vinyl ether / maleic anhydride crosslinked copolymer, and organic acid.

  Examples of the chelating agent include EDTA · disodium salt and citric acid.

  Examples of the pH adjuster include inorganic acids (hydrochloric acid, sulfuric acid, etc.), organic acids (lactic acid, sodium lactate, citric acid, sodium citrate, succinic acid, sodium succinate, etc.), inorganic bases (potassium hydroxide, water, etc.). Sodium oxide), organic bases (triethanolamine, diisopropanolamine, triisopropanolamine, etc.).

  Examples of the preservative include benzoic acid, sodium benzoate, dehydroacetic acid, sodium dehydroacetate, parabens such as propylparaben, phenoxyethanol, and the like.

  Examples of the thickener include cellulose-based thickeners such as methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, carboxyethylcellulose, guar gum, pectin, pullulan, gelatin, locust bean Gum, carrageenan, agar, xanthan gum, polyvinyl alcohol, polyvinyl pyrrolidone, carboxyvinyl polymer, alkyl methacrylate copolymer, polyethylene glycol, bentonite, alginic acid, propylene glycol alginate, macrogol, sodium chondroitin sulfate, hyaluronic acid, hyaluronic acid Sodium, (hydroxyethyl acrylate / Acryloyl dimethyl taurine Na) copolymer, and the like (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer.

  Examples of the irritation reducing agent include licorice extract, sodium alginate, gum arabic, polyvinylpyrrolidone, licorice extract, sodium alginate and the like.

  EXAMPLES Hereinafter, although an Example demonstrates this invention together with a comparative example in detail, this invention is not limited at all by these.

[Examples 1-6, Comparative Examples 1 and 2]
The compositions for external use having the compositions shown in Table 1 below were uniformly mixed at room temperature (25 ° C.), and then stirred with a homomixer and mixed sufficiently uniformly to obtain the preparations of Examples and Comparative Examples.

<Test Example 1: Color transfer test>
30 mg of the preparation was uniformly applied to 4 cm square white artificial leather, the applied leather was placed on white fine paper, a load of 900 g was applied for 10 seconds, and a color transfer test was performed. After loading, the leather was removed, and the result of color transfer to white fine paper was photographed and observed to evaluate the degree of color transfer.

  In FIG. 1, (a) is the product of Example 1, (b) is the product of Example 2, (c) is the product of Example 3, (d) is the product of Example 4, and (e) is the example. (F) of 5 products shows the result of color transfer to white fine paper of the product of Example 6. In FIG. 2, (a) shows the result of color transfer to white fine paper of Comparative Example 1 and (b) of Comparative Example 2.

  As a result of the color transfer test, (a) to (f) in FIGS. 1A and 1B showing the color transfer of the products of Examples 1 to 6 have a light color of white fine paper and little color transfer, while Comparative Example 1 and In FIGS. 2A and 2B showing the color transfer of the two products, it was found that the color of the white fine paper was strong and the color was transferred.

<Test Example 2: Usability Test>
The foundation was applied to the inner side of the upper arm of the subject, and each of the examples and comparative examples were applied thereon. The feeling of use (difficulty in unevenness, softness of color, smooth feeling, and color transfer) was scored in each of the following 5 levels, and the average of the scores was 4 or more, “◎”, 3 The results are shown in Table 2 where “5” or more and less than 4 were evaluated as “◯”, 3 or more and less than 3.5 as “Δ”, and 2.5 or more and less than 3 as “x”. The number of subjects is five.

(Five-step evaluation method for feeling of use)
Score 5: Very Feeling Score 4: Feeling Score 3: Normal Score 2: Less Feeling Score 1: No Feeling

  From Table 2, the products of Examples 1 to 6 are ◎ or ○ in most items of the usability test, whereas in Comparative Examples 1 and 2 are only “x” or “Δ”, compared to the products of Example. It was found that the feeling of use was greatly inferior.

  In addition, the strength with which point makeup colors the skin is largely due to the fashion of the times, but nowadays natural color is required, and this example product blends the same pigments but has a natural coloring. Yes, it was easy to apply evenly.

  Below, the formulation example of the external composition of this invention and the cosmetics for makeup is shown.

  The composition for external use of the present invention is very useful for cosmetics for makeup because it not only suppresses color transfer but also has an excellent feeling of use.

Claims (4)

  An external composition containing dimethicone cross polymer (A), silicone elastomer type surfactant (B), organic pigment (C), and 5% by weight or less of water (D).   The external composition according to claim 1, further comprising an alkyl-modified silicone cross polymer (E) in the external composition.   The external composition according to claim 1 or 2, wherein the content of the organic pigment (C) is 0.1 to 6% by weight in the external composition.   Cosmetics for makeup using the composition for external use as described in any one of Claims 1-3.