JP2020007274A - Emulsifier used for hair care or skin external preparations, and external preparation compositions thereof - Google Patents

Abstract

To provide a novel emulsifier that can emulsify unlimited oily components, does not give color or odor, and is easy to handle.SOLUTION: An emulsifier has hydrogenated sunflower seed oil polyglyceryl-3 esters, hydrogenated sunflower seed oil glyceryl esters, cetearyl alcohol, stearoyl lactylate Na and has a globular appearance.SELECTED DRAWING: None

Description

  TECHNICAL FIELD The present invention relates to a vegetable emulsifier which is excellent in emulsifying action and is easy to handle, and to an external preparation for hair care or skin containing the emulsifier. Here, the external preparation composition for hair care or skin refers to face wash, lotion, cream, skin care cosmetics such as packs, foundation, lipstick, makeup cosmetics such as mascara, shampoo, rinse, hair styling agent, hair restorer, Hair care cosmetics such as hair color and permanent waving agent, body soap, slimming agent, UV care agent, bath agent, body care cosmetics such as antiperspirant, fragrance cosmetics such as perfume and cologne, legal cosmetics, Including quasi-drugs and pharmaceuticals.

  When preparing a hair care or skin external preparation composition containing an oily component as a compounding component, an emulsifier is necessary to obtain a stable preparation. Therefore, the prescription designer selects an appropriate surfactant and a cosurfactant while considering the properties and the amount of the oily component to be contained, and mixes it as an emulsifier.

  Properly selecting an emulsifier from among many surfactants and cosurfactants is a very complicated task, and a formulation designer has conventionally had to put a lot of effort into this task. In recent years, many emulsifiers in which a surfactant and a cosurfactant are specified and combined have come to be marketed in order to reduce this work as much as possible.

  If these emulsifiers are used, it is much easier to select a surfactant and a cosurfactant alone, but the oily component to be emulsified is limited, and there is coloring and odor. There have been problems such as difficulty in handling because the properties are in the form of pellets or flakes, and the origin of the raw materials does not conform to the formulation concept. Until now, it has been hardly satisfactory.

  The present invention has been made under the above circumstances, and by blending a specific vegetable surfactant and an emulsifier consisting of a cosa factor, for hair care or skin external use as intended by a formulation designer. The present invention provides an agent composition easily.

  What is claimed in claim 1 of the present invention is hydrogenated sunflower seed oil polyglyceryl-3 esters (Hydrogenated Sunflower Seed Oil Polyglyceryl-3 Esters), hydrogenated sunflower seed oil glyceryl esters (Hydrogenated Sunflower Seed Oil Glyceryl Esters), cetearyl. An emulsifier containing alcohol (Cetearyl Alcohol) and sodium stearoyl lactylate (Sodium Stearoyl Lactylate), and having a small spherical particle appearance.

  According to claim 2 of the present invention, the hydrogenated sunflower seed oil polyglyceryl-3 esters are 35 to 85% by mass, the hydrogenated sunflower seed oil glyceryl esters are 5 to 30% by mass, and the cetearyl alcohol is 5 to 30% by mass. The emulsifier according to claim 1, wherein the content of sodium stearoyl lactylate is 1 to 20% by mass and has a melting point of 40 to 70C.

  According to a third aspect of the present invention, there is provided an external preparation for hair care or skin, comprising 0.1 to 10% by mass of the emulsifier according to the first or second aspect.

  When preparing the composition for external use for hair care or skin, if the emulsifier of the present invention is used, it is very unlikely that the oily component to be emulsified is limited to the required properties such as HLB, so that various purposes and touches can be obtained. Is obtained. In addition, since the properties are small spherical particles, they are easy to handle because they have good fluidity at the manufacturing site, and furthermore, in the step of heating and melting, the surface area is large, so that the heating and melting time can be shortened. Further, when the emulsifier of the present invention is blended, the resulting external preparation for hair care or skin has no sticky feeling and is easily stretched, and particularly exhibits effective water retention on the skin.

  Hereinafter, the present invention will be described in detail. The emulsifier of the present invention is a nonionic surfactant hydrogenated sunflower seed oil polyglyceryl-3 esters, hydrogenated sunflower seed oil glyceryl esters and higher alcohol cetearyl alcohol, and an anionic surfactant stearoyl lactylate Na It contains. The two components of the nonionic surfactant and the anionic surfactant component are the main components exhibiting the O / W type emulsifying function, and the higher alcohol greatly contributes to the stabilization of the emulsification as a cosurfactant.

  In the emulsifier of the present invention, it is important that these components are melted and uniformly mixed, and finally solidified to have a small spherical particle appearance. Since the particles are in the form of small spheres, large fluidity is obtained, so that the handling is easy, unlike the lumps, pellets, or flakes. In addition, fine powder does not scatter as in the case of powder. Further, when the particles are small spheres, the surface area is large, so that the melting is quick, and the heating time can be shortened.

  The emulsifier of the present invention comprises 35 to 85% by mass of hydrogenated sunflower seed oil polyglyceryl-3 esters, 5 to 30% by mass of hydrogenated sunflower seed oil glyceryl esters, 5 to 30% by mass of cetearyl alcohol, stearoyl lactylate Na has a component ratio of 1 to 20% by mass. In the emulsifier of the present invention, it is important that this component ratio and the melting point be 40 to 70 ° C. When the melting point is from 40 to 70 ° C., while maintaining the original emulsifying function, when it is blended into a hair care or skin external preparation composition, the preparation becomes easy by an operation such as mixing with other raw materials. .

  The source of each component of the emulsifier of the present invention is not particularly limited. However, as the emulsifier (composition) of the present invention, a commercially available product "Emulsun (FLORATECH) Co., Ltd." ) "Can be obtained.

  The compounding amount of the emulsifier of the present invention in the external preparation composition for hair care or skin is 0.1 to 10% by mass, preferably 2.0 to 8.0% by mass in the whole amount using the above-mentioned commercial products. It is. Within this content range, it is possible to design formulations of various external preparation compositions. If the amount is less than 0.1% by mass, the emulsifying effect is not exhibited, and even if the amount exceeds 10.0% by mass, an effect corresponding to the blending amount cannot be expected.

  The main effect of the emulsifier of the present invention is in the emulsifying function. Therefore, a further effect can be expected when it is combined with the following surfactants, higher alcohols, polymer compounds and the like. The main effect of the composition for external use for hair care or skin is to improve the feeling of use, and particularly to the external use composition for skin, the water retention is increased. Therefore, further effects can be expected in combination with the following moisturizing components such as polyhydric alcohols and emollient components.

  The hair care or skin external preparation composition of the present invention may contain, in addition to the above essential components, other components usually used in hair care or skin external preparation compositions such as cosmetics and pharmaceuticals. . The following components are exemplified as such other components. The external preparation composition for hair care or skin of the present invention is produced according to a conventional method by mixing one or more of these essential ingredients with the above essential ingredients.

  The following can be mentioned as oily components. Avocado oil, apricot kernel oil, olive oil, cocoa butter, beef tallow, sesame oil, wheat germ oil, sacha oil, safflower oil, hydrogenated moringa oil, soybean oil, teaseed oil, evening primrose oil, camellia oil, glycolipid, trifatty acid (C10-18) glyceryl, peppermint oil, palm kernel oil, palm oil, castor oil, sunflower seed oil, boswellia serrata oil, macadamia seed oil, manuka oil, horse fat, melia azaziracta seed oil, cottonseed oil, mocro, Fats and oils such as moringa oil, (moringa oil / hydrogenated moringa oil) esters, coconut oil, lemon peel oil, phospholipid, and wasabi tree seed oil. Waxes such as carnauba wax, candelilla wax, rice bran wax, hydrogenated jojoba oil, sunflower seed wax, Fusa acacia flower wax, partially hydrogenated jojoba oil, jojoba ester, jojoba seed oil, beeswax, and lanolin. Hydrocarbons such as isoparaffin, hydrogenated polyisobutene, squalane, squalene, ceresin, paraffin, microcrystalline wax, liquid paraffin, and petrolatum. Higher fatty acids such as isostearic acid, oleic acid, stearic acid, palmitic acid, hydroxystearic acid, behenic acid, myristic acid, lauric acid, linoleic acid and linolenic acid. Higher alcohols such as isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, cholesterol, stearyl alcohol, cetyl alcohol, cetearyl alcohol, soy sterol, phytosterols, behenyl alcohol, jojoba alcohol, myristyl alcohol and lanolin alcohol. Alkyl glyceryl ethers such as Kimyl alcohol and butyl alcohol Isostearyl isostearate, phytostearyl isostearate, PG isostearate, cetyl 2-ethylhexanoate, ethoxydiglycol behenate, ethoxydiglycol oleate, hydrolyzed jojoba ester, triethyl citrate, diethylene glycol monoethyl ether, dinonanoic acid Propylene glycol, cholesteryl stearate, stearyl stearate, glyceryl tri (caprylate / caprate), glyceryl tri-2-hexanoate, ethylhexyl palmitate, pentaerythritol tetraester, jojoba fatty acid isopropyl, (jojoba oil / macadamia seed oil) esters , Macadamia nut fatty acid ethyl, Macadamia nut fatty acid phytosteryl, isopropyl myristate, octyl myristate Sill, coconut oil fatty acid-butylene glycol, propylene glycol laurate, esters such as diisostearyl malate. Silicones such as amino-modified silicone, alkyl-modified silicone, cyclic dimethyl silicone oil, silicone rubber, methyl hydrogen polysiloxane, methyl phenyl polysiloxane, and methyl polysiloxane.

  The following can be mentioned as polyhydric alcohols. Ethoxydiglycol, octanediol, glycerin, diethylene glycol, diglycerin, dipropylene glycol, 1,3-butylene glycol, propylene glycol, hexanediol, heptanediol, pentanediol, polyethylene glycol and the like.

  The following can be mentioned as saccharides. Xylitol, sucrose, sorbitol, trehalose, lactose, fructose, maltitol, mannitol, rhamnose and the like.

  The following can be mentioned as the polymer compound. Alkalinenes production polysaccharide, alginic acid, casein, curdlan, carrageenan, agar, xanthan gum, chitosan, guar gum, quince seed, collagen, sclerotium gum, gelatin, dextrin, starch, hyaluronic acid, pullulan, pectin, mannan, etc. molecule. Natural polymer derivatives such as ethylcellulose, cationized guar gum, cationized cellulose, carboxymethylcellulose, stearoxyhydroxypropylmethylcellulose, nitrocellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyquaternium-10, polyquaternium-67, and methylcellulose. POE / POP copolymer, alkyl acrylate copolymer, acrylic acid / acrylic amide / ethyl acrylate copolymer, acrylic resin alkanolamine, alkyl acrylate / vinyl acetate copolymer, acrylate copolymer Na, carboxyvinyl Polymer, Highly polymerized polyethylene glycol, High molecular silicone, Silicone resin, (Styrene / Acrylates) copolymer, Vinyl methyl ether / ethyl maleate copolymer, Polyacrylamide, Sodium acrylate, Polydimethylpiperidinium chloride, Poly Synthetic polymers such as oxypropylene butyl ether, polyvinyl acetate, polyvinyl alcohol, and polyvinylpyrrolidone.

  The following may be mentioned as surfactants. Acyl N-methyltaurate, POE alkyl ether carboxylate, POE alkyl ether sulfate, alkyl ether phosphate, alkylbenzene sulfonate, alkyl sulfate, N-acyl amino acid salt, α-olefin sulfonate, Anionic surfactants such as higher fatty acid soaps and stearoyl lactylate Na. Cationic surfactants such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride and benzalkonium chloride. Amphoteric surfactants such as alkylamidopropyldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, alkyldimethylaminoacetic acid betaine, hydrogenated lecithin, lysolecithin and lecithin. POE alkylamine / fatty acid amide, POE alkyl ether, POE / POP alkyl ether alkylamine oxide, PEG-6 isostearate, polyglyceryl-6 isostearate, ethoxydiglycol, PEG-8 (caprylic / capric acid) glyceryls, ( Candelilla / jojoba / rice bran) polyglyceryl-3 esters, glycerin fatty acid ester, POE glycerin fatty acid ester, polyglyceryl-3 diisostearate, polyglyceryl-3 dioleate, polyglyceryl-6 distearate, PEG fatty acid ester, PEG-40 hydrogenated castor oil, PEG-6 stearate, PEG-32 stearate, PEG-75 stearate, glyceryl stearate, polyglyceryl-6 stearate, stearie Polyglyceryl-10, steareth-20, ceteth-20, sorbitan fatty acid ester, POE sorbitan fatty acid ester, POE sorbite fatty acid ester, triisostearin PEG-6 esters, tribehenine PEG-20 esters, POE castor oil / hardened castor oil, PEG- 10 sunflower glycerides, glyceryl behenate, jojoba wachs PEG-80 esters, jojoba waks PEG-120 esters, jojoba oil PEG-150 esters, polyoxyethylene beeswax, polyglyceryl-3 beeswax, polysorbate 80, PEG-16 macadamia glycerides, PEG- Nonionic surfactants such as 8 beeswax.

  The following can be mentioned as coloring materials, powders, and granules. Coloring materials such as inorganic pigments such as yellow iron oxide, carbon black, black iron oxide, red iron oxide and ultramarine blue, pearl pigments, organic pigments, tar pigments and natural pigments. Zinc white, alumina, (alumina / iron oxide / titanium oxide / mica) composite, (alumina / titanium oxide / Na silicate / silica) composite, (alumina / titanium oxide / silica) composite, (alumina / titanium oxide) / Silica / dimethicone) composite, (alumina / silica) composite, (alumina / silica / talc) composite, mica, titanium mica, kaolin, aluminum magnesium silicate, titanium oxide, (titanium oxide / zirconium oxide / silica) Composite, (titanium oxide / silica) composite, (titanium oxide / talc) composite, iron oxide, (iron oxide / titanium oxide / silica / mica) composite, (iron oxide / titanium oxide / mica) composite, (Iron oxide / silica) complex, (iron oxide / silica / dimethicone) complex, silica, (silica / polyurethane-15 / mica) complex, Rika / Mica) complexes, zeolites, talc, hectorite, bentonite, mica, (mica / polyurethane -15) complex, an inorganic powder such as sodium magnesium silicate. Organic powders such as silk powder, cellulose powder, nylon powder, and polyethylene powder. Granules of fatty acid esters, cellulose, natural products, nylon, polyethylene, wax, etc.

  The following can be mentioned as components derived from natural products. Animals such as elastin, hydrolyzed casein, hydrolyzed keratin, hydrolyzed collagen, hydrolyzed silk, hydrolyzed pearl, chitin, chitosan, collagen, sodium chondroitin sulfate, water-soluble collagen, lactose, sodium hyaluronate, whey protein, and peptides; Microbial origin. Acacia Victoria fruit extract, Acacia Victoria seed extract, Actinidia delisiosa fruit extract, Acronicia acidula fruit extract, Asparagopsis almata extract, Acerola fruit extract, Anigozanthus mangresi flower extract, Anigozanthus flavidus flower / Leaf extract, Anetrea anisata leaf extract, Alaria esculenta extract, Arctiumajus root extract, Arnica flower extract, Aloe ferox leaf extract, Aloe vera leaf extract, Italian cypress leaf / fruit / stalk oil, Strawberry fruit extract, Ginkgo biloba extract, iris root extract, Witania somnifera root extract, Ulticadio squid extract, Uwaurushi leaf extract, Econia radiata extract, Ezohaebi strawberry fruit extract, Oakaku extract, Pterodactyla flower / leaf / stalk extract, Oooo Wheat seed extract, Panax ginseng root extract, Oris ginseng extract, Holland senichi flower extract, orange fruit extract, orange fruit water, chamomile flower extract, chamomile extract, hydrolyzed wheat protein, hydrolyzed soy protein, oat grain extract, guarana seed extract , Carrot extract, β-carotene, licorice root extract, raspberry extract, raspberry fruit extract, kiwi extract, kiwi fruit water, kigeria africana fruit extract, kibana holland senichi extract, caviar lime extract, cucumber fruit extract, ginkgo biloba / Leaf extract, Kiraya bark extract, Guava fruit extract, Wolfberry fruit extract, Clara root extract, Cranberry fruit water, Grevillea speciosa flower extract, Grapefruit fruit water, Kunzeapomifera fruit extract, Caper Fruit extract, coconut water, yeast extract, rice bran water, sanshikisumire extract, santalum acuminatum fruit extract, sicon extract, sydgeum levulina fruit extract, citrusgrauka fruit extract, ginger water, birch extract, cedar extract, cedar bud extract, cedar extract Fruit water, Spirulina platensis extract, Aesculus oleracea leaf / stalk extract, Aesculus cinnamon seed extract, Aesculus bark extract, Acacia edulis flower extract, Achillea millefolium extract, Acacia edulis extract, Sage leaf extract, Xenopus flower / leaf / stalk extract, Centifolia rose flower extract, Sokei flower / leaf extract, Tasmanian lanceorata fruit extract, Tasmanian lanceorata fruit / leaf extract, Davidsonia plurien fruit extract, dulse extract, tea leaf Sugar beetwort flower extract, Tradescantia extract, Tea tree leaf extract, Tea tree leaf oil, Terminaria ferdinandiana fruit extract, Touki extract, Calendula flower extract, Tochaka extract, Tomato fruit / leaf / stalk extract, Perilla root extract, Carrot root extract, garlic root extract, pineapple fruit extract, hibiscus flower extract, Bachousia anisata leaf extract, lotus root water, lotus flower extract, papaya fruit extract, hamamelis extract, hamamelis bark / leaf / branch extract, banksia serrata flower Extract, Bambusa Arundinaceae stem, daisies flower extract, hinokitiol, hibamata extract, hinantaria elongata extract, loquat leaf extract, grape fruit water, grape leaf extract, beech tree germ extract, plumeria flower extract, pleoginii Timolense fruit extract, loofah extract, safflower extract, pepo pumpkin fruit extract, persian walnut seed extract, henna flower / fruit / leaf extract, podocalps elatus fruit extract, Madake extract, mango fruit extract, microcitrus australasia fruit extract, micro Citrus ostris fruit extract, Mimosa tenui flora bark extract, Moso bamboo mushroom water, peach leaf extract, cornflower flower extract, vegetable oil, willow orchid flower / leaf / stalk extract, eucalyptus extract, European birch bark extract, European beech bud extract, ranunculus Ficaria extract, Labantula hybrida oil, Rabdanum oil, Lavender flower / leaf / stalk extract, Apple fruit extract, Apple fruit water, Lumex Occidentalis extract, Lemon fruit extract, Lemon fruit Plant-based products such as water, rose water, rosemary leaf extract, lowbush blueberry fruit extract, and wine extract. Mineral origins such as olivine, malachite, hematite, hematite, rhodochrosite and extracts of rhodochrosite.

  The following can be mentioned as a disinfectant / preservative. Benzoic acid and its salts, benzalkonium chloride, isopropylmethylphenol, chlorhexidine, salicylic acid and its salts, sorbic acid and its salts, dehydroacetic acid and its salts, triclosan, 4-terpineol, trichlorocarbanilide, paraoxybenzoate ( Methylparaben, ethylparaben, butylparaben), phenoxyethanol, hexachlorophen, methylisothiazolinone, methylchloroisothiazolinone and the like.

  The following can be mentioned as antioxidants. Sodium bisulfite, vitamin C and its derivatives, vitamin E (tocopherol) s, butylhydroxyanisole, butylhydroxytoluene, gallic acid ester and the like. Antioxidant aids such as ascorbic acid, citric acid, kephalin, succinic acid, phytic acid, malonic acid, maleic acid and phosphoric acid.

  The following can be mentioned as sequestering agents. Edetate, citrate, hydroxyethanediphosphonate, phytic acid, malate and the like.

  The following may be mentioned as the UV protection agent. Urocanic acid, octrylene, ethylhexyl salicylate, paraaminobenzoic acid, octyl paradimethylaminobenzoate, bisethylhexyloxyphenol methoxyphenyl triazine, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, Phenylbenzimidazolesulfonic acid, t-butylmethoxydibenzoylmethane, homosalate, polysilicone-15, methylenebisbenzotriazolyltetramethylbutylphenol, ethylhexyl methoxycinnamate and the like.

  The following may be mentioned as pH adjusters. Organic and inorganic alkaline agents such as aminomethylpropanol, aminomethylpropanediol, aqueous ammonia, potassium hydroxide, sodium hydroxide, sodium carbonate, triethanolamine, tromethamine, monoethanolamine, and arginine. Organic and inorganic acids such as citric acid, lactic acid, phosphoric acid, malic acid and HCl.

The following can be mentioned as various physiologically active ingredients. Polyhydric alcohols such as glycerin and POE methyl glucoside, and sugars such as trehalose and pullulan for the purpose of preventing rough skin. Biopolymers such as elastin, chitin / chitosan, sodium chondroitin sulfate, and sodium hyaluronate. Humectants such as amino acids, sodium lactate, urea, betaine, and PCA-Na. Lipid components such as cholesterol, sphingolipid, ceramide, and phospholipid. Anti-inflammatory agents such as ε-aminocaproic acid, allantoin, lysozyme chloride, guaiazulene, glycyrrhizic acid derivatives, β-glycyrrhetinic acid and hydrocortisone. Other allantoin, antihistamines, etc. Various UV protection agents for the purpose of preventing aging. Acetylcysteine, oxothiazolidine, ethyl bis Aminoiminomethyl guaiacol manganese chloride, caffeic acid derivatives, carotenoids, glutathione, tannins, vitamins _{(B 2, C, E)} , hydroxyethyl methyl thio propenamide, flavonoids, ubiquinones, lignans, lycopene, etc. Antioxidants. Cell activators such as α-hydroxy acids. Blood flow enhancers such as γ-oryzanol, vitamin E and derivatives thereof. Derivatives such as vitamin C, sodium ascorbate, magnesium ascorbate phosphate, and glucoside ascorbate for whitening. Melanin inhibitors such as arbutin, ellagic acid, kojic acid, linoleic acid, linolenic acid, lactic acid and tranexamic acid. Other aminoethyl phosphinic acids, sulfur, glutathione, placenta extract, etc. Α-hydroxy acids such as citric acid, glycolic acid, tartaric acid, lactic acid, and malic acid, and retinoids (vitamin A derivatives) for the purpose of preventing wrinkles. Vasodilators such as capronium chloride and nicotinic acid benzyl ester for hair growth. Topical stimulants such as pepper tincture and ginger tincture. Female hormones such as estradiol and ethinylestradiol. Sebum secretion inhibitors such as pyridoxine hydrochloride. Cell activators such as photosensitizer 301, pantothenic acid and its derivatives, biotin, and pentadecanoic acid glyceride. Zinc pyrithione pyroctoolamine, etc. for the purpose of preventing dandruff and itch. For the purpose of preventing acne, keratolytic and exfoliating agents such as sulfur, salicylic acid and resorcin, and disinfectants such as benzalkonium chloride and halocarban. Antiperspirants such as aluminum chloride, chlorohydroxyaluminum, and zinc oxide for the purpose of preventing armpit odor. For the purpose of various other physiological activities, pantothenic acid, pantethine, vitamin A and its derivatives, vitamin B2 and its derivatives, vitamin B6 hydrochloride, vitamin B6 dioctanoate, vitamin B6 tripalmitate, vitamin B12, vitamin B15 and its derivatives, etc. Vitamin B, ascorbic acid, aspartic acid dipalmitate, vitamin C such as ascorbic acid phosphate (salt), vitamin D, α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E acetate, vitamin E nicotinate, etc. Vitamins such as vitamin Es and vitamin H. Asparagine, aspartic acid, acetylcitrulamide arginine, alanine, arginine, carboxyethylaminobutyric acid, glycine, glutamylamidoethylimidazole, glutamineamidoethylindole, glutamine, serine, taurine, tyrosine, decarboxycarnosine HCl, threonine, valine, histidine Amino acids and derivatives thereof, such as hydroxyproline, pyroglutamylamidoethylindole, phenylalanine, prolinamidoethylindole, methylpropylamidoacetylmethionine, leucine. Protein-related substances such as acetyltetrapeptide-2, acetylhexapeptide-1, trifluoroacetyltripeutide-2, tripeptide-1, nanopeptide-1, palmitoyl peptide-1 and the like. Ascorbyl methylsilanol pectin, methylsilanol hydroxyproline aspartate, siloxanetriol alginate, silanetriol glutamate, silanediol salicylate, dioleylcotolylmethylsilanol, dimethyloxobenzodioxasilane, silanetriol, silanetriol alginate, silanetriol trehalose ether, Silanol derivatives such as dimethylsilanol hyaluronate, polysilicone-3, methylsilanol acetyltyrosine, sodium methylsilanol lactate, acefilin methylsilanol mannuronate, methylsilanol mannuronate, lysine silane triol, and PCA copper methylsilanol. Slimming-related ingredients such as caffeine.

  The dosage form of the external preparation composition for hair care or skin of the present invention is usually a liquid, emulsion, cream, gel, mist, aerosol foam, solid, powder dispersion, etc. It can take the form used as an object.

  Next, the present invention will be described more specifically with reference to examples. Note that the present invention is not limited to only these examples. Unless otherwise specified, the amounts are shown in mass%.

＊）エマルサン：（フローラテック社商品）水添ヒマワリ種子油ポリグリセリル−３エステルズ、水添ヒマワリ種子油グリセリルエステルズ、セテアリルアルコール、ステアロイルラクチレートＮａ Example 1 Table 1 illustrates the formulation of a moisturizing cream.

*) Emulsan: (Products of Floratech) hydrogenated sunflower seed oil polyglyceryl-3 esters, hydrogenated sunflower seed oil glyceryl esters, cetearyl alcohol, stearoyl lactylate Na

Example 2 Table 2 illustrates the formulation of the night cream.

Example 3 Table 3 illustrates the formulation of the emulsion.

Example 4 Table 4 illustrates the formulation of the lotion.

Example 5 Table 5 illustrates the formulation of the serum.

Example 6 Table 6 illustrates the formulation of the moisturizing gel.

Example 7 Table 7 illustrates the formulation of the hair cream.

Example 8 Table 8 illustrates the hair treatment formula.

Example 9 Table 9 illustrates the formulation of the color control cream.

Example 10 Table 10 illustrates the formulation of the cleansing cream.

Claims (3)

  An emulsifier comprising hydrogenated sunflower seed oil polyglyceryl-3 esters, hydrogenated sunflower seed oil glyceryl esters, cetearyl alcohol, and stearoyl lactylate Na, and having a spherical appearance.   35-85% by mass of hydrogenated sunflower seed oil polyglyceryl-3 esters, 5-30% by mass of hydrogenated sunflower seed oil glyceryl esters, 5-30% by mass of cetearyl alcohol, 1-20% by mass of stearoyl lactylate Na The emulsifier according to claim 1, wherein the emulsifier has a melting point of 40-70 ° C. An external preparation composition for hair care or skin, comprising the emulsifier according to claim 1 or 2 in an amount of 0.1 to 10% by mass.