JP2016032884A - 感熱記録体 - Google Patents
感熱記録体 Download PDFInfo
- Publication number
- JP2016032884A JP2016032884A JP2014155832A JP2014155832A JP2016032884A JP 2016032884 A JP2016032884 A JP 2016032884A JP 2014155832 A JP2014155832 A JP 2014155832A JP 2014155832 A JP2014155832 A JP 2014155832A JP 2016032884 A JP2016032884 A JP 2016032884A
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- JP
- Japan
- Prior art keywords
- layer
- styrene
- heat
- sizing agent
- sensitive recording
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004513 sizing Methods 0.000 claims abstract description 73
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- 229920001577 copolymer Polymers 0.000 claims abstract description 28
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- 239000003086 colorant Substances 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 claims abstract description 7
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- 108010010803 Gelatin Proteins 0.000 description 2
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- XVSRGZPKJKLORS-UHFFFAOYSA-N 1-(4-methylphenyl)sulfonyl-3-[4-[[4-[(4-methylphenyl)sulfonylcarbamoylamino]phenyl]methyl]phenyl]urea Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)NC(C=C1)=CC=C1CC(C=C1)=CC=C1NC(=O)NS(=O)(=O)C1=CC=C(C)C=C1 XVSRGZPKJKLORS-UHFFFAOYSA-N 0.000 description 1
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000004148 curcumin Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical compound C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 description 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- OJLOUXPPKZRTHK-UHFFFAOYSA-N dodecan-1-ol;sodium Chemical compound [Na].CCCCCCCCCCCCO OJLOUXPPKZRTHK-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 125000001487 glyoxylate group Chemical class O=C([O-])C(=O)[*] 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 229920006276 ketonic resin Polymers 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- ZSYJMXLJNPEAGP-UHFFFAOYSA-N methyl n-cyanocarbamate Chemical compound COC(=O)NC#N ZSYJMXLJNPEAGP-UHFFFAOYSA-N 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- RQAQWBFHPMSXKR-UHFFFAOYSA-N n-(4-chlorophenyl)-3-(phosphonooxy)naphthalene-2-carboxamide Chemical compound OP(O)(=O)OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=C(Cl)C=C1 RQAQWBFHPMSXKR-UHFFFAOYSA-N 0.000 description 1
- MJGLMEMIYDUEHA-UHFFFAOYSA-N n-(4-methylphenyl)-3-oxobutanamide Chemical compound CC(=O)CC(=O)NC1=CC=C(C)C=C1 MJGLMEMIYDUEHA-UHFFFAOYSA-N 0.000 description 1
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 description 1
- 125000002004 n-butylamino group Chemical group [H]N(*)C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DVVFBRPYROBXHJ-UHFFFAOYSA-N n-octadecanoylbenzamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NC(=O)C1=CC=CC=C1 DVVFBRPYROBXHJ-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 1
- QHDYIMWKSCJTIM-UHFFFAOYSA-N phenyl 1-hydroxynaphthalene-2-carboxylate Chemical compound C1=CC2=CC=CC=C2C(O)=C1C(=O)OC1=CC=CC=C1 QHDYIMWKSCJTIM-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N salicylic acid benzyl ester Natural products OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- SOEVVANXSDKPIY-UHFFFAOYSA-M sodium glyoxylate Chemical compound [Na+].[O-]C(=O)C=O SOEVVANXSDKPIY-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007651 thermal printing Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
Description
・アンカー層用塗液の調製
焼成カオリン(商品名:アンシレックス93、BASF社製)の50%水分散液130部、プラスチック中空粒子分散液(商品名:ローペイクSN−1055、中空率:55%、平均粒子径1.0μm、ダウコーティングマテリアルズ社製、固形分濃度26.5%)48部、スチレン−ブタジエン系ラテックス(商品名:L−1571、旭化成ケミカルズ社製、固形分濃度48%)29部、スチレン−アクリル系エマルジョン型サイズ剤(商品名:ポリマロンE−100、荒川化学工業社製、固形分濃度30%)12.8部、カルボキシメチルセルロース(商品名:セロゲンAGガム、第一工業製薬社製)2.3部、ジオクチルスルホコハク酸ナトリウム塩(商品名:SNウェットOT−70、サンノプコ社製)の10%水溶液0.2部、天然油脂系消泡剤(商品名:ノプコ1407H、サンノプコ社製)の5%エマルジョン1部、炭酸ジルコニウムアンモニウム塩(商品名:ベイコート20、日本軽金属社製)の45%水溶液4部、及び水73部からなる組成物を混合攪拌し、アンカー層用塗液を得た。
プラスチック中空粒子分散液(商品名:ローペイクSN−1055、前出)293部、スチレン−ブタジエン系ラテックス(商品名:L−1571、前出)22部、スチレン−無水マレイン酸共重合体のブチルエステル(商品名:ポリマロンHAM−15、荒川化学工業社製、固形分濃度15%)26部、カルボキシメチルセルロース(商品名:セロゲンAGガム、前出)2.4部、ジオクチルスルホコハク酸ナトリウム塩(商品名:SNウェットOT−70、前出)の10%水溶液0.2部、天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン1部、及び炭酸ジルコニウムアンモニウム塩(商品名:ベイコート20、前出)の45%水溶液4部からなる組成物を混合攪拌し、下塗り層用塗液を得た。
3−ジ(n−ブチル)−6−メチル−7−アニリノフルオラン100部、スルホン変性ポリビニルアルコール(商品名:ゴーセランL−3266、日本合成化学社製)の20%水溶液50部、天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン10部、及び水90部からなる組成物を、サンドミルで平均粒子径が0.5μmとなるまで粉砕してA液を得た。
4,4’−ジヒドロキシジフェニルスルホン100部、スルホン変性ポリビニルアルコール(商品名:ゴーセランL−3266、前出)の20%水溶液50部、天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン10部、及び水90部からなる組成物を、サンドミルで平均粒子径が1.0μmとなるまで粉砕してB液を得た。
ジフェニルスルホン100部、スルホン変性ポリビニルアルコール(商品名:ゴーセランL−3266、前出)の20%水溶液50部、天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン10部、及び水90部からなる組成物を、サンドミルで平均粒子径が1.0μmとなるまで粉砕してC液を得た。
4,4’−ビス[(4−メチル−3−フェノキシカルボニルアミノフェニル)ウレイド]ジフェニルスルホン100部、珪酸マグネシウム5部、スルホン変性ポリビニルアルコール(商品名:ゴーセランL−3266、前出)の20%水溶液50部、天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン10部、及び水90部からなる組成物を、サンドミルで平均粒子径が1.0μmとなるまで粉砕してD液を得た。
A液38部、B液106部、C液30部、D液11部、カオリン(商品名:HG90、KaMin LLC社製)の50%水分散液11部、軽質炭酸カルシウム(商品名:ブリリアントS−15、白石工業社製)の60%水分散液6部、ポリビニルアルコール(PVA−124、クラレ社製、重合度2400)の8%水溶液42部、スチレン−ブタジエン系ラテックス(商品名:L−1571、前出)3.9部、アジピン酸ジヒドラジドの35%水分散液7.5部、ジオクチルスルホコハク酸ナトリウム塩(商品名:SNウェットOT−70、前出)の10%水溶液2.6部、天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン1.4部、及び水70部からなる組成物を混合撹拌して感熱記録層用塗液を得た。
カオリン(商品名:HG90、前出)の50%水分散液108部、水酸化アルミニウム(商品名:ハイジライトH−42、昭和電工社製)7.4部、ジアセトン変性ポリビニルアルコール(商品名:DF−20、日本酢ビ・ポバール社製、重合度2000)の10%水溶液270部、ポリビニルアルコール(商品名:JC−40、日本酢ビ・ポバール社製、重合度4000)の6%水溶液112部、ステアリン酸亜鉛の水分散物(商品名:ハイドリンZ−8−36、固形分濃度36%、中京油脂社製)4.7部、ポリエチレンディスパージョン(商品名:ケミパールW400、三井化学社製、固形分濃度40%)2.6部、疎水性ポリカルボン酸共重合体のアンモニウム塩(商品名:オロタン165A、ダウコーティングマテリアルズ社製、固形分濃度21.8%)、ジオクチルスルホコハク酸ナトリウム塩(商品名:SNウェットOT−70、前出)の10%水溶液1.1部、及び天然油脂系消泡剤(商品名:ノプコ1407H、前出)の5%エマルジョン20部を混合攪拌して保護層用塗液を得た。
坪量50g/m2、マイクロトポグラフによる20kg/cm2加圧下での表面粗さが8μmの紙支持体上に、乾燥後の塗布量が6.0g/m2となるようにアンカー層用塗液を塗布及び乾燥してアンカー層を形成した。得られたアンカー層上に乾燥後の塗布量が3.0g/m2となるように下塗り層用塗液を塗布及び乾燥して下塗り層を形成した。得られた下塗り層上に乾燥後の塗布量が3.0g/m2となるように感熱記録層用塗液を塗布及び乾燥して感熱記録層を形成した。更に感熱記録層上に乾燥後の塗布量が2.5g/m2となるように保護層用塗液を塗布及び乾燥して保護層を形成した。その後、線圧78N/mの加圧条件でスーパーカレンダーによって平滑化処理し、感熱記録体を得た。なお、支持体のステキヒトサイズ度は、10秒であった。
実施例1のアンカー層用塗液の調製において、焼成カオリンの量を130部に代えて62部とし、プラスチック中空粒子分散液の量を48部に代えて176部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1のアンカー層用塗液の調製において、スチレン−アクリル系エマルジョン型サイズ剤の量を12.8部に代えて3.3部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1のアンカー層用塗液の調製において、スチレン−アクリル系エマルジョン型サイズ剤の量を12.8部に代えて30部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の下塗り層用塗液の調製において、スチレン−無水マレイン酸共重合体のブチルエステルの量を26部に代えて40部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の下塗り層用塗液の調製において、プラスチック中空粒子分散液の量を293部に代えて176部とし、焼成カオリン(商品名:アンシレックス93、前出)の50%水分散液62部を追加した以外は、実施例1と同様にして感熱記録体を得た。
実施例1の感熱記録体の作製において、坪量50g/m2、マイクロトポグラフによる20kg/cm2加圧下での表面粗さが8μmの紙支持体に代えて、坪量50g/m2、マイクロトポグラフによる20kg/cm2加圧下での表面粗さが15μmの紙支持体を用いた以外は、実施例1と同様にして感熱記録体を得た。なお、支持体のステキヒトサイズ度は、7秒であった。
実施例1のアンカー層用塗液の調製において、スチレン−アクリル系エマルジョン型サイズ剤に代えて、スチレン−マレイン酸共重合体アンモニウム塩(商品名:ポリマロン385、荒川化学工業社製、固形分濃度25%)を用いた以外は、実施例1と同様にして感熱記録体を得た。
実施例1の下塗り層用塗液の調製において、スチレン−無水マレイン酸共重合体のブチルエステルの26部に代えて、オレフィン−マレイン酸共重合体塩(ポリマロン1329、荒川化学工業社製、固形分濃度25%)の16部を用いた以外は、実施例1と同様にして感熱記録体を得た。
実施例1のアンカー層用塗液の調製において、焼成カオリンの量を130部に代えて110部とし、プラスチック中空粒子分散液の量を48部に代えて90部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1の下塗り層用塗液の調製において、スチレン−無水マレイン酸共重合体のブチルエステルの量を26部に代えて16部とした以外は、実施例1と同様にして感熱記録体を得た。
実施例1のアンカー層用塗液の調製において、スチレン−アクリル系エマルジョン型サイズ剤を用いなかった以外は、実施例1と同様にして感熱記録体を得た。
実施例1の下塗り層用塗液の調製において、プラスチック中空粒子分散液の293部に代えて、焼成カオリン(商品名:アンシレックス93、前出)の50%水分散液155部を用いた以外は、実施例1と同様にして感熱記録体を得た。
ラベルプリンタ(商品名:L−2000、株式会社イシダ製)を用いて市松パターンを記録し、記録部の反射濃度(記録濃度)を分光測色型光学濃度計(商品名:X−rite 939型、X−rite社製)にて測定した。数値が大きい程、印字濃度が濃いことを示して好ましく、記録部については、実用上、1.20以上であることが好ましい。
ラベルプリンタ(商品名:L−2000、株式会社イシダ製)を用いてバーコードを記録し、その記録画質を目視で観察し、下記の基準で評価した。
○:画質の白抜けやバーコードの太りがなく、全く問題ない。
△:画質の白抜けやバーコードの太りがほとんどなく、実用上問題ない。
×:画像の白抜けやバーコードの太りがあり、実用上問題となる。
感熱記録評価機(商品名:TH−PMH、大倉電機社製)を用いて、1画面中に地肌部(未記録部)の反射濃度レベルから飽和濃度(記録部)までの連続階調を記録し、その中間調における記録画質を目視で観察し、下記の基準で評価した。
◎:発色ムラがなく、画質が均一である。
○:発色ムラがほとんどなく、実用上問題がない。
△:筋状の発色ムラが目立ち、実用上問題がある。
×:発色ムラが著しく、画質が不均一である。
印字再現率(%)=(ラベル加工後に保存した後の記録濃度/ラベル加工前の記録濃度)×100
○:印字再現率が85%以上であれば全く問題ない。
△:印字再現率が70%以上85%未満であれば実用上問題ない。
×:印字再現率が70%未満であれば実用上問題となる。
前記「記録性能2:発色性」と同様の方法によりラベル加工後に保存した後、前記「記録性能1:画質1」と同様の方法により評価した。
Claims (11)
- 紙支持体よりなる支持体上に少なくとも、プラスチック中空粒子とスチレンを含有する共重合体を主成分とするサイズ剤とを含有するアンカー層、アンカー層上にプラスチック中空粒子を含有する下塗り層、下塗り層上にロイコ染料と呈色剤を含有する感熱記録層を備えたことを特徴とする感熱記録体。
- 前記スチレンを含有する共重合体を主成分とするサイズ剤がスチレン−アクリル系サイズ剤及びスチレン−マレイン酸系サイズ剤からなる群から選ばれる少なくとも1種である、請求項1〜3のいずれか1項に記載の感熱記録体。
- 前記アンカー層に含有されるスチレンを含有する共重合体を主成分とするサイズ剤の含有割合がアンカー層の全固形量中、固形分換算で1〜9質量%である、請求項1または2に記載の感熱記録体。
- 前記アンカー層に含有されるプラスチック中空粒子/スチレンを含有する共重合体を主成分とするサイズ剤の質量比率が固形分換算で95/5〜50/50である、請求項1〜3のいずれか1項に記載の感熱記録体。
- 前記スチレンを含有する共重合体を主成分とするサイズ剤がスチレン−アクリル系サイズ剤である、請求項1〜4のいずれか1項に記載の感熱記録体。
- 前記スチレンを含有する共重合体を主成分とするサイズ剤がスチレン−アクリル系エマルジョン型サイズ剤である、請求項1〜5のいずれか1項に記載の感熱記録体。
- 前記下塗り層に含有されるプラスチック中空粒子の含有割合が下塗り層の全固形量中、40〜95質量%である、請求項1〜6のいずれか1項に記載の感熱記録体。
- 前記アンカー層中のプラスチック中空粒子/下塗り層中のプラスチック中空粒子の質量比率が20/80〜60/40である、請求項1〜7のいずれか1項に記載の感熱記録体。
- 前記支持体表面のマイクロトポグラフによる20kg/cm2加圧下での表面粗さが6μm以上である、請求項1〜8のいずれか1項に記載の感熱記録体。
- 前記支持体のステキヒトサイズ度が15秒以下である、請求項1〜9のいずれか1項に記載の感熱記録体。
- 前記感熱記録層とは反対側の支持体上に粘着剤層を備えた、請求項1〜10のいずれか1項に記載の感熱記録体。
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JPH07304999A (ja) * | 1994-05-11 | 1995-11-21 | Sakata Corp | 防滑剤組成物 |
WO2007023687A1 (ja) * | 2005-08-25 | 2007-03-01 | Oji Paper Co., Ltd. | 感熱記録体及びその製造方法 |
JP2011062874A (ja) * | 2009-09-16 | 2011-03-31 | Oji Paper Co Ltd | 感熱記録材料 |
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