JP2015511945A5 - - Google Patents
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- JP2015511945A5 JP2015511945A5 JP2014557051A JP2014557051A JP2015511945A5 JP 2015511945 A5 JP2015511945 A5 JP 2015511945A5 JP 2014557051 A JP2014557051 A JP 2014557051A JP 2014557051 A JP2014557051 A JP 2014557051A JP 2015511945 A5 JP2015511945 A5 JP 2015511945A5
- Authority
- JP
- Japan
- Prior art keywords
- solution
- mineralizer
- structurant
- source
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000243 solution Substances 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims 15
- 150000001875 compounds Chemical class 0.000 claims 7
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims 6
- 229910021536 Zeolite Inorganic materials 0.000 claims 6
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 6
- 239000010457 zeolite Substances 0.000 claims 6
- 239000002243 precursor Substances 0.000 claims 5
- 238000002425 crystallisation Methods 0.000 claims 4
- 230000008025 crystallization Effects 0.000 claims 4
- 238000002360 preparation method Methods 0.000 claims 4
- 230000033444 hydroxylation Effects 0.000 claims 3
- 238000005805 hydroxylation reaction Methods 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- 239000012690 zeolite precursor Substances 0.000 claims 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- 230000032683 aging Effects 0.000 claims 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims 2
- 239000000010 aprotic solvent Substances 0.000 claims 2
- 238000001354 calcination Methods 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 230000003301 hydrolyzing effect Effects 0.000 claims 2
- 239000011261 inert gas Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000007800 oxidant agent Substances 0.000 claims 2
- 230000001590 oxidative effect Effects 0.000 claims 2
- 239000003586 protic polar solvent Substances 0.000 claims 2
- 239000011343 solid material Substances 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 claims 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1251496A FR2987046B1 (fr) | 2012-02-17 | 2012-02-17 | Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation |
| FR1251496 | 2012-02-17 | ||
| PCT/EP2013/053054 WO2013120986A1 (fr) | 2012-02-17 | 2013-02-15 | Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018151151A Division JP2019001711A (ja) | 2012-02-17 | 2018-08-10 | 芳香族化合物のヒドロキシル化のための方法、ヒドロキシル化触媒および触媒を調製するための方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015511945A JP2015511945A (ja) | 2015-04-23 |
| JP2015511945A5 true JP2015511945A5 (enExample) | 2018-10-11 |
| JP6509561B2 JP6509561B2 (ja) | 2019-05-08 |
Family
ID=47716054
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014557051A Expired - Fee Related JP6509561B2 (ja) | 2012-02-17 | 2013-02-15 | 芳香族化合物のヒドロキシル化のための方法、ヒドロキシル化触媒および触媒を調製するための方法 |
| JP2018151151A Pending JP2019001711A (ja) | 2012-02-17 | 2018-08-10 | 芳香族化合物のヒドロキシル化のための方法、ヒドロキシル化触媒および触媒を調製するための方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018151151A Pending JP2019001711A (ja) | 2012-02-17 | 2018-08-10 | 芳香族化合物のヒドロキシル化のための方法、ヒドロキシル化触媒および触媒を調製するための方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US9682909B2 (enExample) |
| EP (1) | EP2814606A1 (enExample) |
| JP (2) | JP6509561B2 (enExample) |
| CN (2) | CN104302395A (enExample) |
| FR (1) | FR2987046B1 (enExample) |
| WO (1) | WO2013120986A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102242799B1 (ko) | 2017-01-09 | 2021-04-21 | 에보니크 오퍼레이션즈 게엠베하 | 분무 열분해에 의해 금속 산화물을 제조하는 방법 |
| EP3424883A1 (de) | 2017-07-05 | 2019-01-09 | Evonik Degussa GmbH | Sprühverdampfung eines flüssigen rohstoffes zur herstellung von siliciumdioxid und metalloxiden |
| CN107597173B (zh) * | 2017-10-11 | 2020-07-21 | 中国天辰工程有限公司 | 一种苯酚羟基化合成苯二酚的催化剂及其制备方法 |
| EP3495321A1 (de) | 2017-12-07 | 2019-06-12 | Evonik Degussa GmbH | Herstellung von pulverförmigen, porösen kristallinen metallsilikaten mittels flammensprühpyrolyse |
| FR3075198B1 (fr) * | 2017-12-15 | 2020-04-03 | Rhodia Operations | Procede d'hydroxylation d'un compose aromatique |
| WO2019182035A1 (ja) * | 2018-03-23 | 2019-09-26 | 宇部興産株式会社 | 芳香族ヒドロキシ化合物の製造方法 |
| US11654426B2 (en) | 2018-05-21 | 2023-05-23 | Mitsui Chemicals, Inc. | Method for manufacturing modified aluminosilicate, modified aluminosilicate, and method for manufacturing aromatic dihydroxy compound using the same |
| EP3841063A4 (en) * | 2018-08-24 | 2022-06-01 | Rhodia Operations | ALUMINOTITANOSILICATE MICROPOROUS CRYSTALLINE ZEOLITE, METHOD FOR PREPARATION AND APPLICATIONS |
| EP3628642A1 (en) * | 2018-09-25 | 2020-04-01 | Evonik Operations GmbH | Process for the manufacture of pulverulent, porous crystalline metal silicates employing flame spray pyrolysis |
| FR3095199B1 (fr) * | 2019-04-19 | 2021-10-29 | Ifp Energies Now | Procédé de synthèse rapide d'une zeolithe de type structural AFX avec une source de faujasite |
| JP7574216B2 (ja) * | 2019-04-29 | 2024-10-28 | ビーエーエスエフ ソシエタス・ヨーロピア | 骨格型ｍｆｉを有するゼオライト材料を含む成形品 |
| JP7556686B2 (ja) * | 2019-12-26 | 2024-09-26 | 日揮触媒化成株式会社 | アルコキシ基を含む原料を使用しないチタノシリケートゼオライトの製造方法 |
| CN112871206B (zh) * | 2021-01-19 | 2022-04-08 | 中国科学院大连化学物理研究所 | 一种低成本高活性苯酚羟基化钛硅分子筛催化剂的制备方法 |
| CN112717998B (zh) * | 2021-01-19 | 2022-03-11 | 中国科学院大连化学物理研究所 | 一种高活性苯酚羟基化钛硅分子筛催化剂及其制备方法 |
| CN114634404B (zh) * | 2022-04-01 | 2023-09-15 | 北京化工大学 | 一种苯氧化制备苯酚的方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2071464A5 (enExample) | 1969-12-30 | 1971-09-17 | Rhone Poulenc Sa | |
| IT1127311B (it) * | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
| IT1150699B (it) | 1982-03-19 | 1986-12-17 | Anic Spa | Procedimento per la ossidrilazione di idrocarburi aromatici |
| IT1207519B (it) * | 1985-12-19 | 1989-05-25 | Eniricerche Spa | Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio. |
| IT1222868B (it) | 1987-10-12 | 1990-09-12 | Montedipe Spa | Metodo per la preparazione di titanio silicaliti |
| JP2866715B2 (ja) * | 1990-07-04 | 1999-03-08 | 三井化学株式会社 | 芳香族ヒドロキシ化合物の製造法 |
| DE4419195A1 (de) * | 1993-07-12 | 1995-01-19 | Degussa | Strukturierter Katalysator, bestehend aus mikroporösen Oxiden von Silicium, Aluminium und Titan |
| JPH07100387A (ja) * | 1993-08-11 | 1995-04-18 | Mitsubishi Gas Chem Co Inc | 改良されたチタノシリケート触媒、その製造方法及びこれを触媒として使用する過酸化水素を利用した有機合成反応 |
| DE69426907T2 (de) * | 1993-08-11 | 2001-09-27 | Mitsubishi Gas Chemical Co., Inc. | Titanosilikate Katalysatorteilchen |
| JP3697737B2 (ja) * | 1995-03-14 | 2005-09-21 | 東ソー株式会社 | 合成ゼオライト物質 |
| CN1050584C (zh) | 1996-06-05 | 2000-03-22 | 中国石油化工总公司 | 一种钛硅分子筛(ts-1)的制备方法 |
| CN1063106C (zh) * | 1996-10-22 | 2001-03-14 | 中国石油化工总公司上海石油化工研究院 | 钛硅分子筛的合成方法 |
| FR2784672B1 (fr) * | 1998-10-19 | 2000-12-29 | Rhodia Chimie Sa | Procede de preparation d'une silicalite de titane de type mel, produit obtenu et ses applications en catalyse |
| CN1076724C (zh) * | 1999-03-30 | 2001-12-26 | 中国石油化工集团公司 | 一种苯酚羟基化的方法 |
| EP1129991A1 (de) * | 2000-03-02 | 2001-09-05 | Degussa AG | Verfahren zur Herstellung eines titanhaltigen Zeolithen |
| EP1195368A3 (en) * | 2000-09-25 | 2002-05-15 | Haldor Topsoe A/S | Process for the catalytic selective oxidation of a hydrocarbon compound in presence of mesoporous zeolite |
| US7211239B2 (en) * | 2005-04-22 | 2007-05-01 | Basf Aktiengesellschaft | Process for preparing a nanosized zeolitic material |
| DE102007049743A1 (de) | 2007-10-16 | 2009-04-23 | Evonik Degussa Gmbh | Silicium-Titan-Mischoxidpulver, Dispersion hiervon und daraus hergestellter titanhaltiger Zeolith |
| CN101612586B (zh) * | 2008-06-25 | 2011-06-29 | 中国科学院大连化学物理研究所 | 一种分子筛催化剂及其制备和应用 |
| US8124555B2 (en) | 2010-02-01 | 2012-02-28 | Lyondell Chemical Technology L.P. | Process for making titanium-MWW zeolite |
| CN101913620B (zh) * | 2010-07-20 | 2012-05-30 | 大连理工大学 | 一种廉价体系中快速合成小晶粒钛硅分子筛的方法 |
-
2012
- 2012-02-17 FR FR1251496A patent/FR2987046B1/fr not_active Expired - Fee Related
-
2013
- 2013-02-15 EP EP13704443.4A patent/EP2814606A1/fr not_active Withdrawn
- 2013-02-15 CN CN201380009890.6A patent/CN104302395A/zh active Pending
- 2013-02-15 CN CN201810264001.5A patent/CN108435247A/zh active Pending
- 2013-02-15 US US14/378,656 patent/US9682909B2/en not_active Expired - Fee Related
- 2013-02-15 JP JP2014557051A patent/JP6509561B2/ja not_active Expired - Fee Related
- 2013-02-15 WO PCT/EP2013/053054 patent/WO2013120986A1/fr not_active Ceased
-
2017
- 2017-05-18 US US15/598,400 patent/US10173954B2/en not_active Expired - Fee Related
-
2018
- 2018-08-10 JP JP2018151151A patent/JP2019001711A/ja active Pending
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