JP2015510885A5 - - Google Patents
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- Publication number
- JP2015510885A5 JP2015510885A5 JP2014561076A JP2014561076A JP2015510885A5 JP 2015510885 A5 JP2015510885 A5 JP 2015510885A5 JP 2014561076 A JP2014561076 A JP 2014561076A JP 2014561076 A JP2014561076 A JP 2014561076A JP 2015510885 A5 JP2015510885 A5 JP 2015510885A5
- Authority
- JP
- Japan
- Prior art keywords
- type zeolite
- modified
- combination
- dehydroxylation
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 claims 17
- 239000010457 zeolite Substances 0.000 claims 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 9
- 229910021536 Zeolite Inorganic materials 0.000 claims 8
- 239000003054 catalyst Substances 0.000 claims 7
- 238000005906 dihydroxylation reaction Methods 0.000 claims 7
- 239000002253 acid Substances 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 4
- 229910017053 inorganic salt Inorganic materials 0.000 claims 4
- 239000000376 reactant Substances 0.000 claims 4
- 239000003377 acid catalyst Substances 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 3
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 3
- 239000001488 sodium phosphate Substances 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 238000005886 esterification reaction Methods 0.000 claims 2
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims 2
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- ZQKXOSJYJMDROL-UHFFFAOYSA-H aluminum;trisodium;diphosphate Chemical compound [Na+].[Na+].[Na+].[Al+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZQKXOSJYJMDROL-UHFFFAOYSA-H 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000012159 carrier gas Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims 1
- 229910000397 disodium phosphate Inorganic materials 0.000 claims 1
- 235000019800 disodium phosphate Nutrition 0.000 claims 1
- 230000032050 esterification Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims 1
- 235000019799 monosodium phosphate Nutrition 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229910001414 potassium ion Inorganic materials 0.000 claims 1
- 229910000160 potassium phosphate Inorganic materials 0.000 claims 1
- 235000011009 potassium phosphates Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims 1
- 229910001415 sodium ion Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000007790 solid phase Substances 0.000 claims 1
- 229940071182 stannate Drugs 0.000 claims 1
- 125000005402 stannate group Chemical group 0.000 claims 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims 1
- 235000019801 trisodium phosphate Nutrition 0.000 claims 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261608053P | 2012-03-07 | 2012-03-07 | |
| US61/608,053 | 2012-03-07 | ||
| US201313819035A | 2013-02-26 | 2013-02-26 | |
| US13/819,035 | 2013-02-26 | ||
| PCT/US2013/029368 WO2013134385A1 (en) | 2012-03-07 | 2013-03-06 | Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015510885A JP2015510885A (ja) | 2015-04-13 |
| JP2015510885A5 true JP2015510885A5 (enExample) | 2016-04-28 |
Family
ID=49117293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014561076A Withdrawn JP2015510885A (ja) | 2012-03-07 | 2013-03-06 | アルファ，ベータ−不飽和カルボン酸およびそのエステルの調製 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2822923A4 (enExample) |
| JP (1) | JP2015510885A (enExample) |
| KR (1) | KR20140131589A (enExample) |
| CN (1) | CN104159883A (enExample) |
| CA (1) | CA2866003A1 (enExample) |
| IN (1) | IN2014DN07484A (enExample) |
| WO (1) | WO2013134385A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9452967B2 (en) * | 2012-04-11 | 2016-09-27 | The Procter & Gamble Company | Process for production of acrylic acid or its derivatives |
| CN105705647B (zh) | 2013-09-03 | 2020-03-27 | Ptt全球化学公众有限公司 | 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法 |
| US9944586B2 (en) | 2013-10-17 | 2018-04-17 | Cargill, Incorporated | Methods for producing alkyl hydroxyalkanoates |
| KR102455978B1 (ko) * | 2014-05-19 | 2022-10-17 | 아이오와 콘 프로모션 보드 | 탄수화물로부터의 에틸렌 글리콜의 연속 생산을 위한 방법 |
| US10239819B2 (en) | 2014-10-17 | 2019-03-26 | Cargill, Incorporated | Methods for producing an ester of an alpha, beta-unsaturated carboxylic acid |
| US10308582B2 (en) * | 2014-12-02 | 2019-06-04 | Archer Daniels Midland Company | Process for making acrylic acid from dextrose |
| WO2016201181A1 (en) * | 2015-06-10 | 2016-12-15 | Myriant Corporation | Novel method to produce acrylic acid with acetaldehyde as the main by-product |
| JP6694641B2 (ja) * | 2015-06-30 | 2020-05-20 | 国立研究開発法人産業技術総合研究所 | アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法 |
| CN106582784B (zh) * | 2015-10-14 | 2019-11-08 | 中国石油化工股份有限公司 | 丙烯酸酯催化剂 |
| US10570085B2 (en) | 2015-12-21 | 2020-02-25 | Purac Biochem B.V. | Process for manufacturing acrylic acid |
| CN106905155B (zh) * | 2017-03-29 | 2020-04-10 | 万华化学集团股份有限公司 | 一种裂解丙烯酸丁酯重组分生成丙烯酸丁酯的方法 |
| US10308568B2 (en) | 2017-05-01 | 2019-06-04 | Chevron Phillips Chemical Company Lp | Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity |
| US11273434B2 (en) | 2017-10-06 | 2022-03-15 | The Procter & Gamble Company | Regeneration method of solid catalyst |
| KR102474492B1 (ko) * | 2017-11-17 | 2022-12-06 | 푸락 바이오켐 비.브이. | 메틸 락테이트로부터 메틸 아크릴레이트의 제조 방법 |
| CN111253251B (zh) * | 2018-11-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种制备乳酸酯的方法 |
| CN111253248B (zh) * | 2018-11-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种催化丙酮醛制备乳酸酯的方法 |
| CN111253238B (zh) * | 2018-11-30 | 2023-03-10 | 中国石油化工股份有限公司 | 一种制备乳酸的方法 |
| CN111253237B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化糖制备丙酮醛的方法 |
| CN111253226B (zh) * | 2018-11-30 | 2023-03-10 | 中国石油化工股份有限公司 | 一种催化二羟基丙酮和/或甘油醛制备乳酸的方法 |
| CN111253239B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化丙酮醛制备乳酸的方法 |
| CN111250157B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化糖制备乳酸的方法 |
| CN111253252B (zh) * | 2018-11-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种催化糖制备乳酸酯的方法 |
| CN111253259B (zh) * | 2018-11-30 | 2023-04-07 | 中国石油化工股份有限公司 | 一种催化二羟基丙酮和/或甘油醛制备乳酸酯的方法 |
| CN110201716B (zh) * | 2019-05-21 | 2022-04-19 | 南京工业大学 | 一种醇胺基团改性的有序介孔C/SiO2负载杂多酸催化剂及其制备方法和应用 |
| CN111905802B (zh) * | 2020-06-15 | 2022-01-18 | 厦门大学 | 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法 |
| CN115608406B (zh) * | 2021-07-13 | 2023-12-08 | 中国石油化工股份有限公司 | 用于合成甲基丙烯酸甲酯的催化剂及其制备方法和应用 |
| CN119793523A (zh) * | 2023-10-10 | 2025-04-11 | 中国石油化工股份有限公司 | 酯化催化剂及其制备方法以及在甲基丙烯酸甲酯合成反应中的应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4617405A (en) * | 1984-09-25 | 1986-10-14 | A. E. Staley Manufacturing Company | Preparation of alpha, beta-unsaturated carbonyl compounds |
| US4729978A (en) * | 1987-05-04 | 1988-03-08 | Texaco Inc. | Catalyst for dehydration of lactic acid to acrylic acid |
| FR2882053B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acrolene |
| FR2884817B1 (fr) * | 2005-04-25 | 2007-06-22 | Arkema Sa | Procede de preparation d'acide acrylique a partir de glycerol |
| FR2884818B1 (fr) * | 2005-04-25 | 2007-07-13 | Arkema Sa | Procede de preparation d'acide acrylique a partir de glycerol |
| CN101352688A (zh) * | 2007-07-23 | 2009-01-28 | 湖南大学 | 乳酸脱水制丙烯酸催化剂及反应工艺 |
| EP2695672B1 (en) * | 2009-09-18 | 2023-09-06 | Arkema France | Process for preparing acrolein by dehydration of glycerin in the presence of a catalyst |
| WO2012033845A2 (en) * | 2010-09-07 | 2012-03-15 | Myriant Corporation | Catalytic dehydration of lactic acid and lactic acid esters |
-
2013
- 2013-03-06 CA CA2866003A patent/CA2866003A1/en not_active Abandoned
- 2013-03-06 WO PCT/US2013/029368 patent/WO2013134385A1/en not_active Ceased
- 2013-03-06 EP EP13758082.5A patent/EP2822923A4/en not_active Withdrawn
- 2013-03-06 IN IN7484DEN2014 patent/IN2014DN07484A/en unknown
- 2013-03-06 KR KR20147028049A patent/KR20140131589A/ko not_active Withdrawn
- 2013-03-06 CN CN201380013134.0A patent/CN104159883A/zh active Pending
- 2013-03-06 JP JP2014561076A patent/JP2015510885A/ja not_active Withdrawn
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