EP2822923A4 - PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS - Google Patents

PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS

Info

Publication number
EP2822923A4
EP2822923A4 EP13758082.5A EP13758082A EP2822923A4 EP 2822923 A4 EP2822923 A4 EP 2822923A4 EP 13758082 A EP13758082 A EP 13758082A EP 2822923 A4 EP2822923 A4 EP 2822923A4
Authority
EP
European Patent Office
Prior art keywords
beta
alpha
esters
preparation
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13758082.5A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2822923A1 (en
Inventor
A Cenan Ozmeral
Joseph P Glas
Rajesh Dasari
Setrak Tanielyan
Ramesh Deoram Bhagat
Mohan Reddy Kasireddy
Ramnik Singh
Vijay Gnanadesikan
Robert L Augustine
Santosh More
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Myriant Corp
Original Assignee
Myriant Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Myriant Corp filed Critical Myriant Corp
Publication of EP2822923A1 publication Critical patent/EP2822923A1/en
Publication of EP2822923A4 publication Critical patent/EP2822923A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/605Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP13758082.5A 2012-03-07 2013-03-06 PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS Withdrawn EP2822923A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261608053P 2012-03-07 2012-03-07
US201313819035A 2013-02-26 2013-02-26
PCT/US2013/029368 WO2013134385A1 (en) 2012-03-07 2013-03-06 Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof

Publications (2)

Publication Number Publication Date
EP2822923A1 EP2822923A1 (en) 2015-01-14
EP2822923A4 true EP2822923A4 (en) 2015-11-04

Family

ID=49117293

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13758082.5A Withdrawn EP2822923A4 (en) 2012-03-07 2013-03-06 PREPARATION OF ALPHA, BETA-UNSATURATED CARBOXYLIC ACIDS AND THEIR ESTERS

Country Status (7)

Country Link
EP (1) EP2822923A4 (enExample)
JP (1) JP2015510885A (enExample)
KR (1) KR20140131589A (enExample)
CN (1) CN104159883A (enExample)
CA (1) CA2866003A1 (enExample)
IN (1) IN2014DN07484A (enExample)
WO (1) WO2013134385A1 (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9452967B2 (en) * 2012-04-11 2016-09-27 The Procter & Gamble Company Process for production of acrylic acid or its derivatives
CN105705647B (zh) 2013-09-03 2020-03-27 Ptt全球化学公众有限公司 从1,3-丙二醇制造丙烯酸、丙烯腈和1,4-丁二醇的方法
WO2015058118A1 (en) 2013-10-17 2015-04-23 Cargill, Incorporated Method for producing alkyl hydroxyalkanoates
CA2949512C (en) * 2014-05-19 2020-08-18 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
WO2016061356A1 (en) 2014-10-17 2016-04-21 Cargill, Incorporated Methods for producing an ester of an alpha, beta-unsaturated carboxylic acid
MX2017007215A (es) * 2014-12-02 2018-01-30 Archer Daniels Midland Co Procedimiento para la elaborar acido acrilico a partir de dextrosa.
US10544082B2 (en) * 2015-06-10 2020-01-28 Ptt Global Chemical Public Company Limited Method to produce acrylic acid with acetaldehyde as the main by-product
JP6694641B2 (ja) * 2015-06-30 2020-05-20 国立研究開発法人産業技術総合研究所 アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法
CN106582784B (zh) * 2015-10-14 2019-11-08 中国石油化工股份有限公司 丙烯酸酯催化剂
WO2017108890A1 (en) * 2015-12-21 2017-06-29 Purac Biochem Bv Process for manufacturing acrylic acid
CN106905155B (zh) * 2017-03-29 2020-04-10 万华化学集团股份有限公司 一种裂解丙烯酸丁酯重组分生成丙烯酸丁酯的方法
US10308568B2 (en) 2017-05-01 2019-06-04 Chevron Phillips Chemical Company Lp Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
US11273434B2 (en) 2017-10-06 2022-03-15 The Procter & Gamble Company Regeneration method of solid catalyst
JP2021503444A (ja) * 2017-11-17 2021-02-12 ピュラック バイオケム ビー. ブイ. 乳酸メチルからアクリル酸メチルを製造する方法
CN111253239B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化丙酮醛制备乳酸的方法
CN111253259B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化二羟基丙酮和/或甘油醛制备乳酸酯的方法
CN111253238B (zh) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 一种制备乳酸的方法
CN111253251B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种制备乳酸酯的方法
CN111253252B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种催化糖制备乳酸酯的方法
CN111253248B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种催化丙酮醛制备乳酸酯的方法
CN111250157B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化糖制备乳酸的方法
CN111253226B (zh) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 一种催化二羟基丙酮和/或甘油醛制备乳酸的方法
CN111253237B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化糖制备丙酮醛的方法
CN110201716B (zh) * 2019-05-21 2022-04-19 南京工业大学 一种醇胺基团改性的有序介孔C/SiO2负载杂多酸催化剂及其制备方法和应用
CN111905802B (zh) * 2020-06-15 2022-01-18 厦门大学 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法
CN115608406B (zh) * 2021-07-13 2023-12-08 中国石油化工股份有限公司 用于合成甲基丙烯酸甲酯的催化剂及其制备方法和应用
CN119793523A (zh) * 2023-10-10 2025-04-11 中国石油化工股份有限公司 酯化催化剂及其制备方法以及在甲基丙烯酸甲酯合成反应中的应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617405A (en) * 1984-09-25 1986-10-14 A. E. Staley Manufacturing Company Preparation of alpha, beta-unsaturated carbonyl compounds
US4729978A (en) * 1987-05-04 1988-03-08 Texaco Inc. Catalyst for dehydration of lactic acid to acrylic acid
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2884817B1 (fr) * 2005-04-25 2007-06-22 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
CN101352688A (zh) * 2007-07-23 2009-01-28 湖南大学 乳酸脱水制丙烯酸催化剂及反应工艺
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
BR112013004935A2 (pt) * 2010-09-07 2016-08-02 Myriant Corp "desitratação catalítica de ácido láctico e ésteres de ácido láctico".

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
No further relevant documents disclosed *

Also Published As

Publication number Publication date
CA2866003A1 (en) 2013-09-12
JP2015510885A (ja) 2015-04-13
KR20140131589A (ko) 2014-11-13
CN104159883A (zh) 2014-11-19
IN2014DN07484A (enExample) 2015-04-24
EP2822923A1 (en) 2015-01-14
WO2013134385A1 (en) 2013-09-12

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