EP2822923A4 - Préparation d'acides carboxyliques alpha,bêta-insaturés et de leurs esters - Google Patents

Préparation d'acides carboxyliques alpha,bêta-insaturés et de leurs esters

Info

Publication number
EP2822923A4
EP2822923A4 EP13758082.5A EP13758082A EP2822923A4 EP 2822923 A4 EP2822923 A4 EP 2822923A4 EP 13758082 A EP13758082 A EP 13758082A EP 2822923 A4 EP2822923 A4 EP 2822923A4
Authority
EP
European Patent Office
Prior art keywords
beta
alpha
esters
preparation
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13758082.5A
Other languages
German (de)
English (en)
Other versions
EP2822923A1 (fr
Inventor
A Cenan Ozmeral
Joseph P Glas
Rajesh Dasari
Setrak Tanielyan
Ramesh Deoram Bhagat
Mohan Reddy Kasireddy
Ramnik Singh
Vijay Gnanadesikan
Robert L Augustine
Santosh More
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Myriant Corp
Original Assignee
Myriant Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Myriant Corp filed Critical Myriant Corp
Publication of EP2822923A1 publication Critical patent/EP2822923A1/fr
Publication of EP2822923A4 publication Critical patent/EP2822923A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/605—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/64—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP13758082.5A 2012-03-07 2013-03-06 Préparation d'acides carboxyliques alpha,bêta-insaturés et de leurs esters Withdrawn EP2822923A4 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261608053P 2012-03-07 2012-03-07
US201313819035A 2013-02-26 2013-02-26
PCT/US2013/029368 WO2013134385A1 (fr) 2012-03-07 2013-03-06 Préparation d'acides carboxyliques alpha,bêta-insaturés et de leurs esters

Publications (2)

Publication Number Publication Date
EP2822923A1 EP2822923A1 (fr) 2015-01-14
EP2822923A4 true EP2822923A4 (fr) 2015-11-04

Family

ID=49117293

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13758082.5A Withdrawn EP2822923A4 (fr) 2012-03-07 2013-03-06 Préparation d'acides carboxyliques alpha,bêta-insaturés et de leurs esters

Country Status (7)

Country Link
EP (1) EP2822923A4 (fr)
JP (1) JP2015510885A (fr)
KR (1) KR20140131589A (fr)
CN (1) CN104159883A (fr)
CA (1) CA2866003A1 (fr)
IN (1) IN2014DN07484A (fr)
WO (1) WO2013134385A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9452967B2 (en) * 2012-04-11 2016-09-27 The Procter & Gamble Company Process for production of acrylic acid or its derivatives
CN105705647B (zh) 2013-09-03 2020-03-27 Ptt全球化学公众有限公司 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法
US9944586B2 (en) 2013-10-17 2018-04-17 Cargill, Incorporated Methods for producing alkyl hydroxyalkanoates
KR102455978B1 (ko) * 2014-05-19 2022-10-17 아이오와 콘 프로모션 보드 탄수화물로부터의 에틸렌 글리콜의 연속 생산을 위한 방법
WO2016061356A1 (fr) 2014-10-17 2016-04-21 Cargill, Incorporated Procédés pour la production d'un ester d'un acide carboxylique alpha-, bêta-insaturé
CA2969528C (fr) * 2014-12-02 2021-01-05 Archer Daniels Midland Company Procede de fabrication d'acide acrylique a partir de dextrose
WO2016201181A1 (fr) * 2015-06-10 2016-12-15 Myriant Corporation Nouveau procédé de production d'acide acrylique avec de l'acétaldéhyde comme sous-produit principal
JP6694641B2 (ja) * 2015-06-30 2020-05-20 国立研究開発法人産業技術総合研究所 アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法
CN106582784B (zh) * 2015-10-14 2019-11-08 中国石油化工股份有限公司 丙烯酸酯催化剂
US10570085B2 (en) 2015-12-21 2020-02-25 Purac Biochem B.V. Process for manufacturing acrylic acid
CN106905155B (zh) * 2017-03-29 2020-04-10 万华化学集团股份有限公司 一种裂解丙烯酸丁酯重组分生成丙烯酸丁酯的方法
US10308568B2 (en) 2017-05-01 2019-06-04 Chevron Phillips Chemical Company Lp Selective poisoning of aromatization catalysts to increase catalyst activity and selectivity
US11273434B2 (en) * 2017-10-06 2022-03-15 The Procter & Gamble Company Regeneration method of solid catalyst
KR102474492B1 (ko) * 2017-11-17 2022-12-06 푸락 바이오켐 비.브이. 메틸 락테이트로부터 메틸 아크릴레이트의 제조 방법
CN111253239B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化丙酮醛制备乳酸的方法
CN111253252B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种催化糖制备乳酸酯的方法
CN111253238B (zh) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 一种制备乳酸的方法
CN111253237B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化糖制备丙酮醛的方法
CN111250157B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化糖制备乳酸的方法
CN111253248B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种催化丙酮醛制备乳酸酯的方法
CN111253251B (zh) * 2018-11-30 2023-04-11 中国石油化工股份有限公司 一种制备乳酸酯的方法
CN111253226B (zh) * 2018-11-30 2023-03-10 中国石油化工股份有限公司 一种催化二羟基丙酮和/或甘油醛制备乳酸的方法
CN111253259B (zh) * 2018-11-30 2023-04-07 中国石油化工股份有限公司 一种催化二羟基丙酮和/或甘油醛制备乳酸酯的方法
CN110201716B (zh) * 2019-05-21 2022-04-19 南京工业大学 一种醇胺基团改性的有序介孔C/SiO2负载杂多酸催化剂及其制备方法和应用
CN111905802B (zh) * 2020-06-15 2022-01-18 厦门大学 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法
CN115608406B (zh) * 2021-07-13 2023-12-08 中国石油化工股份有限公司 用于合成甲基丙烯酸甲酯的催化剂及其制备方法和应用

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US4617405A (en) * 1984-09-25 1986-10-14 A. E. Staley Manufacturing Company Preparation of alpha, beta-unsaturated carbonyl compounds
US4729978A (en) * 1987-05-04 1988-03-08 Texaco Inc. Catalyst for dehydration of lactic acid to acrylic acid
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
FR2884817B1 (fr) * 2005-04-25 2007-06-22 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
CN101352688A (zh) * 2007-07-23 2009-01-28 湖南大学 乳酸脱水制丙烯酸催化剂及反应工艺
EP2477736A1 (fr) * 2009-09-18 2012-07-25 Nippon Kayaku Kabushiki Kaisha Catalyseur et procédé de préparation d'acroléine et/ou d'acide acrylique par réaction de déshydratation de glycérine
BR112013004935A2 (pt) * 2010-09-07 2016-08-02 Myriant Corp "desitratação catalítica de ácido láctico e ésteres de ácido láctico".

Non-Patent Citations (1)

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Title
No further relevant documents disclosed *

Also Published As

Publication number Publication date
JP2015510885A (ja) 2015-04-13
WO2013134385A1 (fr) 2013-09-12
CN104159883A (zh) 2014-11-19
CA2866003A1 (fr) 2013-09-12
IN2014DN07484A (fr) 2015-04-24
EP2822923A1 (fr) 2015-01-14
KR20140131589A (ko) 2014-11-13

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