JP2015040332A - スカンジウム回収方法 - Google Patents
スカンジウム回収方法 Download PDFInfo
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- JP2015040332A JP2015040332A JP2013172261A JP2013172261A JP2015040332A JP 2015040332 A JP2015040332 A JP 2015040332A JP 2013172261 A JP2013172261 A JP 2013172261A JP 2013172261 A JP2013172261 A JP 2013172261A JP 2015040332 A JP2015040332 A JP 2015040332A
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- scandium
- amide derivative
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- acidic solution
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- 229910052706 scandium Inorganic materials 0.000 title claims abstract description 111
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 title claims abstract description 100
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 60
- 229920005989 resin Polymers 0.000 claims abstract description 60
- 238000011084 recovery Methods 0.000 claims abstract description 48
- 239000003929 acidic solution Substances 0.000 claims abstract description 32
- 239000000243 solution Substances 0.000 claims abstract description 28
- 150000001408 amides Chemical class 0.000 claims abstract description 23
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 11
- 239000011575 calcium Substances 0.000 claims abstract description 11
- 239000011777 magnesium Substances 0.000 claims abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 9
- BEBCJVAWIBVWNZ-UHFFFAOYSA-N glycinamide Chemical class NCC(N)=O BEBCJVAWIBVWNZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- UMMQVDUMUMBTAV-YFKPBYRVSA-N (2s)-2-amino-3-(1h-imidazol-5-yl)propanamide Chemical class NC(=O)[C@@H](N)CC1=CN=CN1 UMMQVDUMUMBTAV-YFKPBYRVSA-N 0.000 claims abstract description 5
- PMLJIHNCYNOQEQ-REOHCLBHSA-N L-aspartic 1-amide Chemical class NC(=O)[C@@H](N)CC(O)=O PMLJIHNCYNOQEQ-REOHCLBHSA-N 0.000 claims abstract description 5
- HKXLAGBDJVHRQG-YFKPBYRVSA-N L-lysinamide Chemical class NCCCC[C@H](N)C(N)=O HKXLAGBDJVHRQG-YFKPBYRVSA-N 0.000 claims abstract description 5
- 235000001014 amino acid Nutrition 0.000 claims abstract description 4
- 150000001413 amino acids Chemical class 0.000 claims abstract description 4
- 125000003277 amino group Chemical group 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- 238000002386 leaching Methods 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 11
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 4
- -1 alkyl phosphate ester Chemical class 0.000 description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000012535 impurity Substances 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 238000000605 extraction Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 238000006386 neutralization reaction Methods 0.000 description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 10
- 239000002244 precipitate Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000004471 Glycine Substances 0.000 description 7
- 239000013522 chelant Substances 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000003480 eluent Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000000638 solvent extraction Methods 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000003456 ion exchange resin Substances 0.000 description 3
- 229920003303 ion-exchange polymer Polymers 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- SAIKULLUBZKPDA-UHFFFAOYSA-N Bis(2-ethylhexyl) amine Chemical compound CCCCC(CC)CNCC(CC)CCCC SAIKULLUBZKPDA-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920006222 acrylic ester polymer Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N lysine Chemical group NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- CNDWHJQEGZZDTQ-UHFFFAOYSA-N 2-(2-amino-2-oxoethoxy)acetamide Chemical compound NC(=O)COCC(N)=O CNDWHJQEGZZDTQ-UHFFFAOYSA-N 0.000 description 1
- KOHUSHSNNOEPFN-UHFFFAOYSA-N 2-[2-(dioctylamino)-2-oxoethoxy]acetic acid Chemical compound CCCCCCCCN(C(=O)COCC(O)=O)CCCCCCCC KOHUSHSNNOEPFN-UHFFFAOYSA-N 0.000 description 1
- VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical group OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 239000004472 Lysine Chemical group 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Chemical group OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 125000000487 histidyl group Chemical group [H]N([H])C(C(=O)O*)C([H])([H])C1=C([H])N([H])C([H])=N1 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000011504 laterite Substances 0.000 description 1
- 229910001710 laterite Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- OMMFSGNJZPSNEH-UHFFFAOYSA-H oxalate;scandium(3+) Chemical compound [Sc+3].[Sc+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O OMMFSGNJZPSNEH-UHFFFAOYSA-H 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- DVMZCYSFPFUKKE-UHFFFAOYSA-K scandium chloride Chemical compound Cl[Sc](Cl)Cl DVMZCYSFPFUKKE-UHFFFAOYSA-K 0.000 description 1
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
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- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
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- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
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Abstract
【解決手段】前記酸性溶液を下記一般式で表されるアミド誘導体が含浸されたスカンジウム回収樹脂に1時間以上接触させる。式中、R1及びR2は、それぞれ同一又は別異のアルキル基を示す。アルキル基は直鎖でも分鎖でも良い。R3は水素原子又はアルキル基を示す。R4は水素原子、又はアミノ酸としてα炭素に結合される、アミノ基以外の任意の基を示す。アミド誘導体は、グリシンアミド誘導体、ヒスチジンアミド誘導体、リジンアミド誘導体及びアスパラギン酸アミド誘導体のいずれか1以上であることが好ましい。
【選択図】なし
Description
本発明では、カルシウム、マグネシウム及びスカンジウムを含有する酸性溶液を特定のアミド誘導体が含浸されたスカンジウム回収樹脂に1時間以上接触させる。
アルキルアセトアミドを加え、求核置換反応によりグリシン又はN−アルキルグリシン誘導体の水素原子の一つを(N,N−ジ)アルキルアセトアミド基に置換する。これら2段階の反応によってグリシンアルキルアミド誘導体を合成できる。
樹脂は、多孔質樹脂であれば特に限定されるものでなく、アクリルエステルポリマー、スチレン系ポリマー等が挙げられる。本明細書において、多孔質とは、溶剤が浸入できる程度に細孔を有することをいう。多くの抽出剤を浸入できるようにするため、多孔質樹脂は比表面積の大きいものが好ましい。
本発明において、スカンジウム回収樹脂は、次のようにして得られる。まず、上記アミド誘導体をトルエン等の揮発しやすい溶剤に溶解させ、低粘性の液体とする。これに上記樹脂を浸した後、溶剤を留去させる。これらの工程を経ることでスカンジウム回収樹脂が得られる。
上記スカンジウム回収樹脂を用いたスカンジウムの回収は、次のようにして行われる。まず、上記スカンジウム回収樹脂にスカンジウムイオンを吸着させる。続いて、溶離液を用いて、スカンジウム回収樹脂に吸着したスカンジウムイオンを回収する。
[アミド誘導体の合成]
アミド又はアミド誘導体からなるスカンジウム抽出剤の一例として、上記一般式(I)
で表されるグリシンアミド誘導体、すなわち、2つの2−エチルヘキシル基を導入したN,N−ジ(2−エチルヘキシル)アセトアミド−2−グリシン(N,N−di(2−ethylhexyl)acetamic−2−glycine,以下「D2EHAG」という。)を合成した。
上記アミド誘導体30gを100mlのトルエンに溶解させ、アミド誘導体のトルエン希釈液を得た。この液にアクリルエステルポリマーの多孔質樹脂(製品名:アンバーライトXAD−7HP,Dow chemical社製)30gを添加し、樹脂中に抽出剤を含浸させた。その後、60℃に温度を保持しながら、減圧状態でトルエンを留去してD2EHAGを含浸させることで、スカンジウム回収樹脂(含浸樹脂)を得た。
スカンジウムを含有する酸性溶液は、公知の技術に従って作製したものを用いた。具体的には、ニッケル酸化鉱石を硫酸溶液と共に混合し、加圧装置に装入して240〜250℃に加熱し、浸出スラリーを得た。その後、浸出スラリーに消石灰を添加して中和し、次いで、中和後液に硫化剤を添加し、中和後液からニッケル、コバルト、亜鉛等を除いた。ニッケル等を除いた後の中和後液を酸性溶液とした。
Claims (3)
- 前記アミド誘導体がグリシンアミド誘導体、ヒスチジンアミド誘導体、リジンアミド誘導体及びアスパラギン酸アミド誘導体のいずれか1以上である、請求項1に記載のスカンジウム回収方法。
- 前記酸性溶液は、ニッケル酸化鉱石に硫酸を混合してニッケルを浸出した溶液である、請求項1又は2に記載のスカンジウム回収方法。
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CN201480009136.7A CN104995320A (zh) | 2013-08-22 | 2014-04-08 | 钪回收方法 |
US14/437,466 US9404169B2 (en) | 2013-08-22 | 2014-04-08 | Method for recovering scandium |
PCT/JP2014/060149 WO2015025558A1 (ja) | 2013-08-22 | 2014-04-08 | スカンジウム回収方法 |
EP14837943.1A EP2902512B1 (en) | 2013-08-22 | 2014-04-08 | Method for collecting scandium |
CA2889046A CA2889046C (en) | 2013-08-22 | 2014-04-08 | Method for recovering scandium |
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WO2017104629A1 (ja) * | 2015-12-16 | 2017-06-22 | 住友金属鉱山株式会社 | スカンジウムの回収方法 |
WO2021059940A1 (ja) * | 2019-09-24 | 2021-04-01 | 住友金属鉱山株式会社 | スカンジウムの回収方法、並びにイオン交換処理方法 |
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JP6409791B2 (ja) | 2016-02-05 | 2018-10-24 | 住友金属鉱山株式会社 | スカンジウム回収方法 |
CN110541081A (zh) * | 2019-09-02 | 2019-12-06 | 中国恩菲工程技术有限公司 | 处理红土镍矿的方法 |
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JPH01246328A (ja) | 1988-03-28 | 1989-10-02 | Agency Of Ind Science & Technol | スカンジウムの補集方法 |
JP3322952B2 (ja) * | 1993-10-01 | 2002-09-09 | 史朗 松本 | 希土類元素除去用吸着剤及びそれを用いた吸着分離法 |
JP3275681B2 (ja) | 1995-12-26 | 2002-04-15 | 大平洋金属株式会社 | 高純度酸化スカンジュウムの製造法 |
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JP3430973B2 (ja) * | 1999-04-26 | 2003-07-28 | 大平洋金属株式会社 | 酸化鉱石からニッケルとスカンジウムを回収する方法 |
US20050124765A1 (en) * | 2003-11-25 | 2005-06-09 | Japan Atomic Energy Research Institute | Adsorbent for recovering useful rare metals by adsorption |
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JP5279938B1 (ja) * | 2011-11-09 | 2013-09-04 | 国立大学法人九州大学 | 有価金属抽出剤及びこの抽出剤を用いた有価金属抽出方法 |
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WO2017104629A1 (ja) * | 2015-12-16 | 2017-06-22 | 住友金属鉱山株式会社 | スカンジウムの回収方法 |
JP2017110257A (ja) * | 2015-12-16 | 2017-06-22 | 住友金属鉱山株式会社 | スカンジウムの回収方法 |
US20180371579A1 (en) | 2015-12-16 | 2018-12-27 | Sumitomo Metal Mining Co., Ltd. | Method for recovering scandium |
US10570482B2 (en) | 2015-12-16 | 2020-02-25 | Sumitomo Metal Mining Co., Ltd. | Method for recovering scandium |
WO2021059940A1 (ja) * | 2019-09-24 | 2021-04-01 | 住友金属鉱山株式会社 | スカンジウムの回収方法、並びにイオン交換処理方法 |
JP2021050377A (ja) * | 2019-09-24 | 2021-04-01 | 住友金属鉱山株式会社 | スカンジウムの回収方法、並びにイオン交換処理方法 |
JP7276042B2 (ja) | 2019-09-24 | 2023-05-18 | 住友金属鉱山株式会社 | スカンジウムの回収方法、並びにイオン交換処理方法 |
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PH12015500820A1 (en) | 2015-06-08 |
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