JP2014534075A - 蟻酸エステルを含有する無機鋳型及び中子のためのコーティング組成物及びその使用方法 - Google Patents
蟻酸エステルを含有する無機鋳型及び中子のためのコーティング組成物及びその使用方法 Download PDFInfo
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- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/02—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives
- B22C1/04—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by additives for special purposes, e.g. indicators, breakdown additives for protection of the casting, e.g. against decarbonisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/18—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
- B22C1/186—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents contaming ammonium or metal silicates, silica sols
- B22C1/188—Alkali metal silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/12—Treating moulds or cores, e.g. drying, hardening
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mold Materials And Core Materials (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011115024A DE102011115024A1 (de) | 2011-10-07 | 2011-10-07 | Beschichtungsmassen für anorganische Gießformen und Kerne umfassend Ameisensäureester und deren Verwendung |
| DE102011115024.6 | 2011-10-07 | ||
| PCT/DE2012/000973 WO2013050023A2 (de) | 2011-10-07 | 2012-10-05 | Beschichtungsmassen für anorganische giessformen und kerne umfassend ameisensäureester und deren verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2014534075A true JP2014534075A (ja) | 2014-12-18 |
Family
ID=47115089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014533769A Pending JP2014534075A (ja) | 2011-10-07 | 2012-10-05 | 蟻酸エステルを含有する無機鋳型及び中子のためのコーティング組成物及びその使用方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20140242269A1 (es) |
| EP (1) | EP2763806B1 (es) |
| JP (1) | JP2014534075A (es) |
| KR (1) | KR20140077196A (es) |
| CN (1) | CN103857480A (es) |
| BR (1) | BR112014008377A2 (es) |
| DE (1) | DE102011115024A1 (es) |
| IN (1) | IN2014KN00957A (es) |
| MX (1) | MX2014004211A (es) |
| RU (1) | RU2014118127A (es) |
| WO (1) | WO2013050023A2 (es) |
| ZA (1) | ZA201402090B (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190104577A (ko) * | 2017-01-04 | 2019-09-10 | 휴테네스 알베르투스 케미쉐 베르케 게엠베하 | 주조 산업에 사용하기 위한 유기 에스테르 화합물 및 입자상, 비정질 이산화 규소를 포함하는 코팅 조성물 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010013999A1 (de) * | 2010-04-07 | 2011-10-13 | Vautid Gmbh | Verfahren zur Herstellung eines zumindest bereichsweise einen erhöhten Verschleißschutz aufweisenden Gusswerkstücks |
| DE102016211930A1 (de) * | 2016-06-30 | 2018-01-04 | Wobben Properties Gmbh | Schlichtezusammensetzung zur Herstellung von Formüberzügen auf verlorenen Formen bzw. auf Kernen für den Eisen- und Stahlguss |
| DE102017107655A1 (de) * | 2017-01-04 | 2018-07-05 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Verwendung einer Säure enthaltenden Schlichtezusammensetzung in der Gießereiindustrie |
| DE102017107658A1 (de) | 2017-01-04 | 2018-07-05 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Schlichtezusammensetzung für die Gießereiindustrie, enthaltend partikuläres, amorphes Siliziumdioxid und Säure |
| BR112020001164A2 (pt) * | 2017-07-18 | 2020-07-21 | Ha-International, Llc | composições e métodos para revestimentos refratários com portadores de ester |
| CN108246977A (zh) * | 2018-01-16 | 2018-07-06 | 中国船舶重工集团公司第十二研究所 | 一种钛合金铸造用石墨型表面孔洞的修复方法 |
| DE102018117651A1 (de) | 2018-07-20 | 2020-01-23 | Ask Chemicals Gmbh | Schlichtezusammensetzung für Gießformen für den Metallguss deren Verwendung sowie mit der Schlichtezusammensetzung versehene Gießform |
| EP3981525A4 (en) * | 2019-06-07 | 2022-07-20 | NOF Corporation | SURFACTANT COMPOSITION FOR FOAM SAND |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB782205A (en) | 1955-03-07 | 1957-09-04 | Foundry Services Ltd | Improvements in or relating to sand cores |
| DE1810183A1 (de) * | 1968-11-21 | 1970-06-11 | Woellner Werke | Haerter fuer Giessereisande |
| AT301059B (de) * | 1970-06-17 | 1972-08-25 | Reichhold Chemie Ag | Schlichte für Gießereiformen und Kerne |
| US4093778A (en) * | 1976-09-10 | 1978-06-06 | Nalco Chemical Company | Ingot mold for producing steel ingots |
| FR2389409B1 (es) * | 1977-05-02 | 1980-02-01 | Rhone Poulenc Ind | |
| EP0244905B1 (en) * | 1986-04-29 | 1992-03-04 | Akzo N.V. | Water-reducible coating composition based on an epoxy resin |
| CN1003217B (zh) * | 1986-05-03 | 1989-02-08 | 国营红山铸造厂 | 水基压铸涂料 |
| US5027890A (en) * | 1988-01-12 | 1991-07-02 | Borden (Uk) Limited | Foundry moulding composition |
| US5234973A (en) * | 1988-04-08 | 1993-08-10 | Acme Resin Corporation | Compositions for foundry molding processes utilizing reclaimed sand |
| US5043412A (en) * | 1988-06-23 | 1991-08-27 | Borden, Inc. | Ambient temperature curing, high carbon contributing compositions |
| CN1014686B (zh) * | 1988-09-30 | 1991-11-13 | 太原矿山机器厂 | 熔模铸造用砂芯的生产方法 |
| IL93632A (en) * | 1989-03-13 | 1993-06-10 | Borden Uk Ltd | Phenolic resin compositions |
| GB2294040B (en) * | 1989-05-10 | 1996-07-03 | Remet Corp | Ceramic shell molds and cores for casting of reactive metals |
| JP2831830B2 (ja) * | 1990-09-25 | 1998-12-02 | 花王株式会社 | 鋳物砂用粘結剤組成物 |
| US5646199A (en) * | 1991-07-22 | 1997-07-08 | Kao Corporation | Composition for mold |
| JPH0647480A (ja) * | 1992-07-29 | 1994-02-22 | Hodogaya Ashiyurando Kk | 鋳物用砂型の連続的製造方法 |
| US5382289A (en) | 1993-09-17 | 1995-01-17 | Ashland Oil, Inc. | Inorganic foundry binder systems and their uses |
| US5474606A (en) | 1994-03-25 | 1995-12-12 | Ashland Inc. | Heat curable foundry binder systems |
| US6326418B1 (en) * | 1997-09-12 | 2001-12-04 | Kao Corporation | Acid-curable, refractory particulate material composition for forming mold |
| DE19925167A1 (de) | 1999-06-01 | 2000-12-14 | Luengen Gmbh & Co Kg As | Exotherme Speisermasse |
| DE19951622A1 (de) | 1999-10-26 | 2001-05-23 | Vaw Ver Aluminium Werke Ag | Bindemittelsystem auf Wasserglasbasis |
| JP4418081B2 (ja) * | 2000-04-28 | 2010-02-17 | アシュランドジャパン株式会社 | ガス硬化性鋳型用粘結剤組成物 |
| JP2002003697A (ja) * | 2000-06-20 | 2002-01-09 | Gun Ei Chem Ind Co Ltd | 水溶性フェノール樹脂用硬化剤組成物および鋳型の製造方法 |
| CN1255234C (zh) * | 2001-11-21 | 2006-05-10 | 沈阳汇亚通铸造材料有限责任公司 | 一种吹气硬化冷芯盒制芯的方法 |
| DE10158154A1 (de) * | 2001-11-28 | 2003-06-18 | Bayer Ag | Trennmittel und Verfahren zur Herstellung von Kunststoffformteilen |
| DE102004042535B4 (de) | 2004-09-02 | 2019-05-29 | Ask Chemicals Gmbh | Formstoffmischung zur Herstellung von Gießformen für die Metallverarbeitung, Verfahren und Verwendung |
| EP1900702A1 (en) * | 2006-09-15 | 2008-03-19 | Sika Technology AG | Mould Release Composition |
| CN101293271A (zh) * | 2007-04-24 | 2008-10-29 | 沈阳汇亚通铸造材料有限责任公司 | 一种吹气硬化制芯的方法 |
| CN100595002C (zh) * | 2008-12-06 | 2010-03-24 | 华中科技大学 | 消失模铸造用粉末涂料专用添加剂 |
| CN101428328B (zh) * | 2008-12-06 | 2010-06-30 | 华中科技大学 | 一种用于消失模铸造铸铁的粉末状涂料 |
| CN101947637B (zh) * | 2010-08-18 | 2012-10-10 | 沈阳汇亚通铸造材料有限责任公司 | 一种冷芯盒用改性水玻璃粘结剂及其制备 |
| DE102011115025A1 (de) * | 2011-10-07 | 2013-04-11 | Ask Chemicals Gmbh | Beschichtungsmassen für anorganische Gießformen und Kerne enthaltend Salze und deren Verwendung |
-
2011
- 2011-10-07 DE DE102011115024A patent/DE102011115024A1/de not_active Ceased
-
2012
- 2012-10-05 WO PCT/DE2012/000973 patent/WO2013050023A2/de active Application Filing
- 2012-10-05 EP EP12780403.7A patent/EP2763806B1/de active Active
- 2012-10-05 MX MX2014004211A patent/MX2014004211A/es unknown
- 2012-10-05 BR BR112014008377A patent/BR112014008377A2/pt not_active Application Discontinuation
- 2012-10-05 KR KR1020147012346A patent/KR20140077196A/ko not_active Application Discontinuation
- 2012-10-05 CN CN201280049484.8A patent/CN103857480A/zh active Pending
- 2012-10-05 IN IN957KON2014 patent/IN2014KN00957A/en unknown
- 2012-10-05 US US14/350,210 patent/US20140242269A1/en not_active Abandoned
- 2012-10-05 RU RU2014118127/02A patent/RU2014118127A/ru not_active Application Discontinuation
- 2012-10-05 JP JP2014533769A patent/JP2014534075A/ja active Pending
-
2014
- 2014-03-24 ZA ZA2014/02090A patent/ZA201402090B/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190104577A (ko) * | 2017-01-04 | 2019-09-10 | 휴테네스 알베르투스 케미쉐 베르케 게엠베하 | 주조 산업에 사용하기 위한 유기 에스테르 화합물 및 입자상, 비정질 이산화 규소를 포함하는 코팅 조성물 |
| JP2020504013A (ja) * | 2017-01-04 | 2020-02-06 | ヒュッテネス−アルベルトゥス ヒェーミッシェ ヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 鋳造産業において使用するための、有機エステル化合物および粒子状非晶質二酸化ケイ素を含むサイジング組成物 |
| JP7064223B2 (ja) | 2017-01-04 | 2022-05-10 | ヒュッテネス－アルベルトゥス ヒェーミッシェ ヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 鋳造産業において使用するための、有機エステル化合物および粒子状非晶質二酸化ケイ素を含むサイジング組成物 |
| KR102432071B1 (ko) * | 2017-01-04 | 2022-08-12 | 휴테네스 알베르투스 케미쉐 베르케 게엠베하 | 주조 산업에 사용하기 위한 유기 에스테르 화합물 및 입자상, 비정질 이산화 규소를 포함하는 코팅 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2763806A2 (de) | 2014-08-13 |
| WO2013050023A3 (de) | 2013-05-30 |
| BR112014008377A2 (pt) | 2017-04-11 |
| WO2013050023A2 (de) | 2013-04-11 |
| KR20140077196A (ko) | 2014-06-23 |
| MX2014004211A (es) | 2014-05-28 |
| RU2014118127A (ru) | 2015-11-20 |
| EP2763806B1 (de) | 2016-07-06 |
| IN2014KN00957A (es) | 2015-10-09 |
| ZA201402090B (en) | 2015-06-24 |
| CN103857480A (zh) | 2014-06-11 |
| DE102011115024A1 (de) | 2013-04-11 |
| US20140242269A1 (en) | 2014-08-28 |
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