JP2014517765A - シュウ酸アルキルエステルの水素添加によるエチレングリコールを合成するための複合担体触媒及びその製造方法 - Google Patents

シュウ酸アルキルエステルの水素添加によるエチレングリコールを合成するための複合担体触媒及びその製造方法 Download PDF

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JP2014517765A
JP2014517765A JP2014506739A JP2014506739A JP2014517765A JP 2014517765 A JP2014517765 A JP 2014517765A JP 2014506739 A JP2014506739 A JP 2014506739A JP 2014506739 A JP2014506739 A JP 2014506739A JP 2014517765 A JP2014517765 A JP 2014517765A
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ethylene glycol
hydrogenation
solution
catalyst
composite
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博 張
揚 計
念 軍 駱
彦 鵬 毛
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上海浦景化工技術有限公司
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8437—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2014506739A 2011-04-29 2012-04-16 シュウ酸アルキルエステルの水素添加によるエチレングリコールを合成するための複合担体触媒及びその製造方法 Pending JP2014517765A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN2011101102225A CN102225338B (zh) 2011-04-29 2011-04-29 草酸烷基酯加氢合成乙二醇用复合载体催化剂及制备方法
CN201110110222.5 2011-04-29
PCT/CN2012/074092 WO2012146135A2 (zh) 2011-04-29 2012-04-16 草酸烷基酯加氢合成乙二醇用复合载体催化剂及制备方法

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JP (1) JP2014517765A (zh)
CN (1) CN102225338B (zh)
WO (1) WO2012146135A2 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017532192A (ja) * 2014-09-05 2017-11-02 ビーエーエスエフ コーポレーション 燃焼機関の排ガス流を処理するための触媒における白金族金属支持体としての、チタニアがドープされたジルコニア
JP2022553535A (ja) * 2019-11-22 2022-12-23 クラリアント・インターナシヨナル・リミテツド 水素化反応のための水および酸安定性クロムフリー触媒

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* Cited by examiner, † Cited by third party
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CN102225338B (zh) * 2011-04-29 2013-04-24 上海浦景化工技术有限公司 草酸烷基酯加氢合成乙二醇用复合载体催化剂及制备方法
CN102814184B (zh) * 2012-09-12 2014-12-17 西北化工研究院 一种草酸酯加氢制乙二醇的催化剂及制备方法
CN103816915B (zh) * 2014-02-25 2016-04-13 神华集团有限责任公司 一种由草酸二甲酯和甲醇加氢制取乙二醇单甲醚的催化剂及其工艺
CN106607036B (zh) * 2015-10-21 2020-01-03 中国石油化工股份有限公司 草酸酯加氢催化剂、制备方法及用途
CN106607044A (zh) * 2015-10-22 2017-05-03 中国石油化工股份有限公司 1,6-己二酸二烷基酯加氢制备1,6-己二醇的催化剂及方法
CN109569629B (zh) * 2017-09-28 2021-11-19 中国石油化工股份有限公司 用于醋酸酯加氢的催化剂及其制备方法和醋酸酯加氢制醇的方法
CN109569622B (zh) * 2017-09-29 2021-11-30 中国石油化工股份有限公司 催化剂组合物、合成方法及其用途
CN109569619B (zh) * 2017-09-29 2021-11-30 中国石油化工股份有限公司 催化剂组合物、制造方法及用途
CA3107987A1 (en) * 2018-07-31 2020-02-06 China Petroleum & Chemical Corporation Nanocage-confined catalyst, preparation process and use thereof
CN111298791B (zh) * 2019-11-27 2023-02-03 大连瑞克科技有限公司 一种草酸二甲酯加氢制乙二醇的复合载体催化剂的制备方法
CN112898124B (zh) * 2019-12-03 2023-02-03 天津普莱化工技术有限公司 一种对苯二甲醇和对甲基苯甲醇的联产制备方法
CN111790390A (zh) * 2020-06-18 2020-10-20 北京化工大学 一种具有界面协同作用的铜基催化剂的制备方法及其应用
CN114054022A (zh) * 2021-12-14 2022-02-18 河南能源化工集团研究总院有限公司 一种催化剂、制备方法及应用
CN116459846B (zh) * 2023-05-09 2024-03-26 中国科学院兰州化学物理研究所 一种羟基酯加氢纳米Cu基催化剂及其制备方法与应用

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JPH01127042A (ja) * 1987-07-29 1989-05-19 Davy Mckee London Ltd 触媒
JPH07100381A (ja) * 1993-10-04 1995-04-18 Kao Corp 水素化反応用触媒前駆体、その製造法、及びアルコールの製造法

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CN101485984B (zh) * 2009-02-11 2010-12-08 中国科学院山西煤炭化学研究所 一种co低温氧化催化剂及其制备方法
CN101829579B (zh) * 2010-05-25 2012-05-23 上海应用技术学院 负载氧化铜的铈锆复合氧化物催化剂的制备方法及其应用
CN101856615B (zh) * 2010-06-04 2012-08-22 天津大学 用于草酸酯加氢制乙二醇的催化剂及其制备方法
CN102225338B (zh) * 2011-04-29 2013-04-24 上海浦景化工技术有限公司 草酸烷基酯加氢合成乙二醇用复合载体催化剂及制备方法

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JPS54157789A (en) * 1978-02-24 1979-12-12 Chevron Res Catalyst composition
JPH01127042A (ja) * 1987-07-29 1989-05-19 Davy Mckee London Ltd 触媒
JPH07100381A (ja) * 1993-10-04 1995-04-18 Kao Corp 水素化反応用触媒前駆体、その製造法、及びアルコールの製造法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017532192A (ja) * 2014-09-05 2017-11-02 ビーエーエスエフ コーポレーション 燃焼機関の排ガス流を処理するための触媒における白金族金属支持体としての、チタニアがドープされたジルコニア
JP2022553535A (ja) * 2019-11-22 2022-12-23 クラリアント・インターナシヨナル・リミテツド 水素化反応のための水および酸安定性クロムフリー触媒
JP7457109B2 (ja) 2019-11-22 2024-03-27 クラリアント・インターナシヨナル・リミテツド 水素化反応のための水および酸安定性クロムフリー触媒

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WO2012146135A2 (zh) 2012-11-01
WO2012146135A3 (zh) 2012-11-22
CN102225338A (zh) 2011-10-26
CN102225338B (zh) 2013-04-24

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