JP2014214247A - ポリアミド樹脂および無機充填剤を含む組成物及びそれを用いて製造される成形品 - Google Patents
ポリアミド樹脂および無機充填剤を含む組成物及びそれを用いて製造される成形品 Download PDFInfo
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- JP2014214247A JP2014214247A JP2013093547A JP2013093547A JP2014214247A JP 2014214247 A JP2014214247 A JP 2014214247A JP 2013093547 A JP2013093547 A JP 2013093547A JP 2013093547 A JP2013093547 A JP 2013093547A JP 2014214247 A JP2014214247 A JP 2014214247A
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- Prior art keywords
- polyamide
- acid
- composition
- polyamide resin
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920006122 polyamide resin Polymers 0.000 title claims abstract description 59
- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000011256 inorganic filler Substances 0.000 title description 2
- 229910003475 inorganic filler Inorganic materials 0.000 title description 2
- 239000004952 Polyamide Substances 0.000 claims abstract description 54
- 229920002647 polyamide Polymers 0.000 claims abstract description 54
- 239000003365 glass fiber Substances 0.000 claims abstract description 34
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 24
- 239000011521 glass Substances 0.000 claims abstract description 23
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 23
- 239000011324 bead Substances 0.000 claims abstract description 20
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004327 boric acid Substances 0.000 claims abstract description 17
- 238000007747 plating Methods 0.000 claims abstract description 17
- 125000003277 amino group Chemical group 0.000 claims abstract description 16
- 229920002292 Nylon 6 Polymers 0.000 claims description 22
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 14
- 229920000299 Nylon 12 Polymers 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- 238000000465 moulding Methods 0.000 abstract description 9
- 239000000539 dimer Substances 0.000 abstract description 5
- 229920001281 polyalkylene Polymers 0.000 abstract description 5
- 229920000768 polyamine Polymers 0.000 abstract description 4
- 238000011109 contamination Methods 0.000 abstract description 2
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 abstract 1
- -1 ω-enantolactam Chemical compound 0.000 description 62
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 26
- 229920001577 copolymer Polymers 0.000 description 16
- 238000012360 testing method Methods 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 12
- 239000012756 surface treatment agent Substances 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 11
- 239000002253 acid Substances 0.000 description 11
- 239000000835 fiber Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 9
- 150000004985 diamines Chemical class 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 150000003951 lactams Chemical class 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 7
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- JKRZOJADNVOXPM-UHFFFAOYSA-N Oxalic acid dibutyl ester Chemical compound CCCCOC(=O)C(=O)OCCCC JKRZOJADNVOXPM-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- 150000004756 silanes Chemical class 0.000 description 6
- 150000003609 titanium compounds Chemical class 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 4
- 229920000571 Nylon 11 Polymers 0.000 description 4
- 229920000572 Nylon 6/12 Polymers 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000001845 chromium compounds Chemical class 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 241000694440 Colpidium aqueous Species 0.000 description 3
- ZDXPYRJPNDTMRX-GSVOUGTGSA-N D-glutamine Chemical compound OC(=O)[C@H](N)CCC(N)=O ZDXPYRJPNDTMRX-GSVOUGTGSA-N 0.000 description 3
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920000305 Nylon 6,10 Polymers 0.000 description 3
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 3
- UMHKOAYRTRADAT-UHFFFAOYSA-N [hydroxy(octoxy)phosphoryl] octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OP(O)(=O)OCCCCCCCC UMHKOAYRTRADAT-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 2
- GAGWMWLBYJPFDD-UHFFFAOYSA-N 2-methyloctane-1,8-diamine Chemical compound NCC(C)CCCCCCN GAGWMWLBYJPFDD-UHFFFAOYSA-N 0.000 description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 229920006152 PA1010 Polymers 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229960002684 aminocaproic acid Drugs 0.000 description 2
- 150000004984 aromatic diamines Chemical class 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical group OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
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- 238000007334 copolymerization reaction Methods 0.000 description 2
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- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
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- 238000013461 design Methods 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
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- 238000007710 freezing Methods 0.000 description 2
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- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 description 2
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- 239000007924 injection Substances 0.000 description 2
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- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
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- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 2
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- 239000005020 polyethylene terephthalate Substances 0.000 description 2
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- IEKHISJGRIEHRE-UHFFFAOYSA-N 16-methylheptadecanoic acid;propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O IEKHISJGRIEHRE-UHFFFAOYSA-N 0.000 description 1
- GBURUDXSBYGPBL-UHFFFAOYSA-N 2,2,3-trimethylhexanedioic acid Chemical compound OC(=O)C(C)(C)C(C)CCC(O)=O GBURUDXSBYGPBL-UHFFFAOYSA-N 0.000 description 1
- DPQHRXRAZHNGRU-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diamine Chemical compound NCC(C)CC(C)(C)CCN DPQHRXRAZHNGRU-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
塗装やメッキを樹脂の成形品に行う場合、樹脂の成形品の表面との密着性が重要であるが、ポリアミド樹脂の場合、十分とはいえない。そこで、塗装及び金属メッキの密着性を向上させる為に、特許文献1にあるような、ポリアミド樹脂にダイマー酸−ポリアルキレンポリアミン系ポリアミドを添加する組成物が挙げられる。
本発明に用いるポリアミド樹脂は、末端アミノ基濃度が、ポリアミド樹脂1kgあたり50ミリ当量以上あるポリアミド樹脂である。
本発明に用いる無機化合物は、ガラスビーズ、ホウ素を含まないガラス繊維及び長さ方向に直角の断面において長径と短径の比が1.2〜10を有する非円形断面のガラス繊維よりなる群から選択される少なくとも1種である。
本発明に用いるガラスビーズは、球状のガラスであれば、特に限定されないが、道路用ガラスビーズ、工業用ガラスビーズ、反射用ガラスビーズと分類される中、工業用ガラスビーズが好ましい。
ホウ酸を含まないガラス繊維は、長さ方向に直角の断面において、ほぼ円形の断面を有する。
ガラス繊維の平均繊維径はJIS R3420で測定することができる。
本発明の組成物は、ポリアミド樹脂および無機化合物を含む組成物であって、
組成物全量に対し、前記ポリアミド樹脂を55質量%以上90質量%以下、前記無機化合物を10質量%以上45質量%以下含み、前記ポリアミド樹脂の末端アミノ基濃度が、前記ポリアミド樹脂1kgあたり50ミリ当量以上であり、前記無機化合物が、ガラスビーズ、ホウ酸を含まないガラス繊維及び長さ方向に直角の断面において長径と短径の比が1.2〜10を有する非円形断面のガラス繊維よりなる群から選択される少なくとも1種を含む組成物である。
本発明の組成物を成形体にする方法としては、例えば、射出成形、押出成形、中空成形、プレス成形、ロール成形、発泡成形、真空・圧空成形、延伸成形などが挙げられ、これらの中でも、射出成形による方法が好ましい。
(1)凝固点温度
セイコーインスツル株式会社製EXATAR6000 DSC6220を用いて、得られたペレットをN2雰囲気下で20〜30℃の室温から20℃/minで280℃まで昇温し、その後、20℃/minで30℃まで降温する条件で測定し、凝固点温度を求めた。
JIS K-7202の規格に準拠し、株式会社明石製作所製の電動デジタルロックウェル硬度計 型式ARD−Pを用いて、常温(23℃)でロックウェル硬度(Rスケール)を測定した。
株式会社東京精密製の表面粗さ計であるハンディサーフE−30Aを用いて、カットオフ2.5mm測定長さ12.5mmの条件で中心線平均粗さ(Ra)を測定し、それを表面粗さとして評価した。
住友重機械工業株式会社製の電動射出成形機SE100D-C160Sを用いてシリンダー温度290℃、金型温度80℃の条件で、長さ125mm、幅75mm、厚さ3mmの平板を作製し、この平板にウレタン樹脂塗料をエアスプレー塗装し、室温で10分間放置後、80℃で30分加熱硬化し塗装物を得た。その後、1mm角碁盤目試験を行い、剥離しない碁盤目の数(/100碁盤目)より判定を行った。
◎ :95/100〜100/100
○ :80/100〜94/100
× :0/100〜79/100
住友重機械工業株式会社製の電動射出成形機SE100D-C160Sを用いてシリンダー温度290℃、金型温度80℃の条件で、長さ60mm、幅60mm、厚さ2mmの平板であるISO Type-D2試験片を作製した。
水溶液1Lに対し塩酸が258ml含まれる30℃の水溶液中に、試験片を10分浸漬させるエッチング処理を行った。
エッチング処理した試験片を、水溶液1Lに対し塩酸が80ml含まれる30℃の水溶液中に、3分浸漬させるポストエッチング処理を行った。
ポストエッチング処理した試験片を、水溶液1Lに対し塩酸が120ml及び奥野製薬工業株式会社製キャタリストCが30ml含まれる30℃の水溶液中に、5分浸漬させるキャタリスト処理を行った。
キャタリスト処理した試験片を、水溶液1Lに対し濃硫酸が35ml含まれる50℃の水溶液中に、4分浸漬させるアクセレーター処理を行った。
アクセレーター処理した試験片を、純粋1Lに対し水酸化ナトリウムが20g含まれる30℃の溶液中に、2分浸漬させるポストアクセレーター処理を行った。
ポストアクセレーター処理した試験片を、純粋4容に対し、奥野製薬工業株式会社製TMP化学ニッケルA液1容、奥野製薬工業株式会社製TMP化学ニッケルB液1容の割合の35℃の溶液中に、7分浸漬させる化学ニッケルメッキ処理を行った。
化学ニッケルメッキ処理した試験片を、水溶液1Lに対し塩酸が奥野製薬工業株式会社製トップサンが50g含まれる常温の溶液中に、5分浸漬させる活性化処理を行った。
活性化処理した試験片を電気銅メッキ処理を行ない、その外観を目視で観察して未着部数よりメッキ性を評価した。
◎ : 試験片に対し、凸凹が3個以下。
○ : 試験片に対し、凸凹が4〜10個。
× : 試験片に対し、凸凹が11個以上。
(1)ポリアミド樹脂
・ポリアミド6(以下、A−1ともいう。)
70リットルのオートクレブに重合モノマーとしてε−カプロラクタム20kgに対し水0.5kg、メタキシリレンジアミンを1/290(eq/molラクタム)となるよう仕込み、槽内を窒素置換した後、100℃まで加熱し槽内が均一になるよう攪拌した。
次いで槽内を260℃、1.7MPaで重合を行い、A−1を得た。得られたA−1の相対粘度は2.50、末端アミノ基濃度は87ミリ当量/kg、末端カルボキシル基濃度は30ミリ当量/kg、末端カルボキシル基濃度に対する末端アミノ基濃度の比は、2.9であった。
実施例1において、メタキシリレンジアミンを1/400(eq/molラクタム)とした以外は、実施例1と同様にして、A−2を得た。得られたA−2の相対粘度は2.50、末端アミノ基濃度45ミリ当量/kg、末端カルボキシル基濃度は59ミリ当量/kg、末端カルボキシル基濃度に対する末端アミノ基濃度の比は、0.8であった。
(2−1)ガラスビーズ(以下、B−1ともいう。)
B−1は、ポッタズ・バロティーニ株式会社製の平均粒径32μmのGB731Aを用いた。
B−2は、オーウェンス・コーニング株式会社製の平均径11μmのCS983−10P 4mm 2406#GBB ADVを用いた。
長さ方向に直角の断面において長径と短径の比が1.2〜10を有する非円形断面のガラス繊維(以下、B−3ともいう。)としては、日東紡績株式会社製の、短繊維径7μm、長繊維径28μmの長径と短径の比が4である長さ3mmの扁平型E−ガラス繊維CSG3P A−820を用いた。
B−4は、日本電気硝子株式会社製の断面形状が丸型のホウ酸を含まないガラス繊維であるECS 03T-249Hを用いた。
B−5は、日本タルク株式会社製のシムゴンMを用いた。
表1に記載のポリアミド樹脂と無機化合物を、表1に記載の割合で二軸押出機を用い混練し、ペレタイザーにて、組成物のペレットを得た。得られた組成物のペレットを用いて、上記の評価方法にて評価した。その結果を表1に示す。
Claims (6)
- ポリアミド樹脂および無機化合物を含む組成物であって、
組成物全量に対し、前記ポリアミド樹脂を55質量%以上90質量%以下、前記無機化合物を10質量%以上45質量%以下含み、
前記ポリアミド樹脂の末端アミノ基濃度が、前記ポリアミド樹脂1kgあたり50ミリ当量以上、
前記無機化合物が、ガラスビーズ、ホウ酸を含まない円形断面のガラス繊維及び長さ方向に直角の断面において長径と短径の比が1.2〜10を有する非円形断面のガラス繊維よりなる群から選択される少なくとも1種を含む組成物。 - 前記ポリアミド樹脂の末端アミノ基濃度が、前記ポリアミド樹脂1kgあたり80ミリ当量以上110ミリ当量以下である請求項1に記載の組成物。
- 前記ポリアミド樹脂がポリアミド6、ポリアミド66、ポリアミド6/66、ポリアミド6/66/12、ポリアミド12及びポリアミド92よりなる群から選択される少なくとも1種である請求項1又は2に記載の組成物。
- 請求項1〜3のいずれか1項に記載の塗装用及び/又はメッキ用の組成物。
- 請求項1〜4のいずれか1項に記載の組成物からなる成形体。
- 塗装及び/又はメッキされた請求項5に記載の成形体。
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