JP2013544824A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2013544824A5 JP2013544824A5 JP2013541001A JP2013541001A JP2013544824A5 JP 2013544824 A5 JP2013544824 A5 JP 2013544824A5 JP 2013541001 A JP2013541001 A JP 2013541001A JP 2013541001 A JP2013541001 A JP 2013541001A JP 2013544824 A5 JP2013544824 A5 JP 2013544824A5
- Authority
- JP
- Japan
- Prior art keywords
- formula
- group
- alkyl
- unsaturated
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 20
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 17
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 125000003107 substituted aryl group Chemical group 0.000 claims description 13
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- -1 R 21 Chemical compound 0.000 claims description 9
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 33
- 239000000203 mixture Substances 0.000 claims 14
- KTRQRAQRHBLCSQ-UHFFFAOYSA-N 1,2,4-tris(ethenyl)cyclohexane Chemical compound C=CC1CCC(C=C)C(C=C)C1 KTRQRAQRHBLCSQ-UHFFFAOYSA-N 0.000 claims 10
- 239000003054 catalyst Substances 0.000 claims 10
- 239000012018 catalyst precursor Substances 0.000 claims 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- 229920000570 polyether Polymers 0.000 claims 6
- 239000012190 activator Substances 0.000 claims 5
- 125000000524 functional group Chemical group 0.000 claims 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 4
- 239000003638 chemical reducing agent Substances 0.000 claims 4
- 125000003342 alkenyl group Chemical group 0.000 claims 3
- 150000001412 amines Chemical class 0.000 claims 3
- 150000001450 anions Chemical group 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 239000011541 reaction mixture Substances 0.000 claims 3
- 239000002904 solvent Substances 0.000 claims 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 2
- NWRZGFYWENINNX-UHFFFAOYSA-N 1,1,2-tris(ethenyl)cyclohexane Chemical compound C=CC1CCCCC1(C=C)C=C NWRZGFYWENINNX-UHFFFAOYSA-N 0.000 claims 2
- XNCKMOIUKBSPTB-UHFFFAOYSA-N 1H-anthracen-1-ide Chemical compound [C-]1=CC=CC2=CC3=CC=CC=C3C=C21 XNCKMOIUKBSPTB-UHFFFAOYSA-N 0.000 claims 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 claims 2
- BLHLJVCOVBYQQS-UHFFFAOYSA-N ethyllithium Chemical compound [Li]CC BLHLJVCOVBYQQS-UHFFFAOYSA-N 0.000 claims 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims 2
- 150000002430 hydrocarbons Chemical group 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- QLUMLEDLZDMGDW-UHFFFAOYSA-N sodium;1h-naphthalen-1-ide Chemical compound [Na+].[C-]1=CC=CC2=CC=CC=C21 QLUMLEDLZDMGDW-UHFFFAOYSA-N 0.000 claims 2
- ZWUBFMWIQJSEQS-UHFFFAOYSA-N 1,1-bis(ethenyl)cyclohexane Chemical compound C=CC1(C=C)CCCCC1 ZWUBFMWIQJSEQS-UHFFFAOYSA-N 0.000 claims 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims 1
- VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 claims 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims 1
- UWRZIZXBOLBCON-UHFFFAOYSA-N 2-phenylethenamine Chemical compound NC=CC1=CC=CC=C1 UWRZIZXBOLBCON-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000001345 alkine derivatives Chemical class 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 150000008378 aryl ethers Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- GKIRPKYJQBWNGO-OCEACIFDSA-N clomifene Chemical compound C1=CC(OCCN(CC)CC)=CC=C1C(\C=1C=CC=CC=1)=C(\Cl)C1=CC=CC=C1 GKIRPKYJQBWNGO-OCEACIFDSA-N 0.000 claims 1
- 150000001924 cycloalkanes Chemical class 0.000 claims 1
- 239000000412 dendrimer Substances 0.000 claims 1
- 229920000736 dendritic polymer Polymers 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 239000012705 liquid precursor Substances 0.000 claims 1
- 125000005394 methallyl group Chemical group 0.000 claims 1
- SWGZAKPJNWCPRY-UHFFFAOYSA-N methyl-bis(trimethylsilyloxy)silicon Chemical group C[Si](C)(C)O[Si](C)O[Si](C)(C)C SWGZAKPJNWCPRY-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 239000010703 silicon Chemical group 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 125000005401 siloxanyl group Chemical group 0.000 claims 1
- 239000011593 sulfur Chemical group 0.000 claims 1
- 229910052717 sulfur Chemical group 0.000 claims 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical group CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical group O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 description 1
- JJRDHFIVAPVZJN-UHFFFAOYSA-N cyclotrisiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]1 JJRDHFIVAPVZJN-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41708410P | 2010-11-24 | 2010-11-24 | |
| US41706110P | 2010-11-24 | 2010-11-24 | |
| US61/417,061 | 2010-11-24 | ||
| US61/417,084 | 2010-11-24 | ||
| PCT/US2011/061746 WO2012071358A2 (en) | 2010-11-24 | 2011-11-22 | In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013544824A JP2013544824A (ja) | 2013-12-19 |
| JP2013544824A5 true JP2013544824A5 (cg-RX-API-DMAC7.html) | 2015-01-29 |
| JP5991981B2 JP5991981B2 (ja) | 2016-09-14 |
Family
ID=45319390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013541001A Active JP5991981B2 (ja) | 2010-11-24 | 2011-11-22 | ヒドロシリル化触媒として使用される三座窒素配位子を有する金属錯体のｉｎ−ｓｉｔｕ活性化 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8765987B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2643329B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5991981B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101890606B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN103339135B (cg-RX-API-DMAC7.html) |
| BR (1) | BR112013012733A2 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI473654B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012071358A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101896423B1 (ko) * | 2010-11-24 | 2018-10-04 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 폴리불포화 화합물의 금속-촉매 모노-하이드로실릴화 |
| CN103347889A (zh) * | 2010-11-24 | 2013-10-09 | 莫门蒂夫性能材料股份有限公司 | 氢化硅烷化催化剂 |
| WO2013043846A1 (en) * | 2011-09-20 | 2013-03-28 | Dow Corning Corporation | Metal containing hydrosilylation catalysts and compositions containing the catalysts |
| CN104024267A (zh) * | 2011-09-20 | 2014-09-03 | 道康宁公司 | 含铁硅氢加成催化剂及含有该催化剂的组合物 |
| CN103946228A (zh) * | 2011-09-20 | 2014-07-23 | 道康宁公司 | 含钴硅氢加成催化剂及含有该催化剂的组合物 |
| CN103814040B (zh) * | 2011-09-20 | 2016-08-31 | 道康宁公司 | 含镍硅氢加成催化剂及含有该催化剂的组合物 |
| CN103958059B (zh) | 2011-12-01 | 2017-04-26 | 道康宁公司 | 硅氢加成反应催化剂和可固化组合物及它们的制备和使用方法 |
| US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| BR102013016146A2 (pt) * | 2012-08-16 | 2016-09-13 | Momentive Performance Mat Inc | processo para produzir um produto sililado, por desidrogenação, composição, composto e processo para produzir um material reticulado |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| JP6125222B2 (ja) * | 2012-08-16 | 2017-05-10 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒を用いる脱水素シリル化および架橋 |
| US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| US20140121427A1 (en) * | 2012-10-29 | 2014-05-01 | The Regents Of The University Of California | Methods of Activating Metal Complexes for Catalysts |
| US9890182B2 (en) | 2013-05-06 | 2018-02-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| TWI623544B (zh) * | 2013-05-15 | 2018-05-11 | 摩曼帝夫特性材料公司 | 使用矽氫之金屬鹽的活化及其在矽氫化反應之用途 |
| WO2014201082A1 (en) | 2013-06-12 | 2014-12-18 | Arizona Board Of Regents On Behalf Of Arizona State University | First-row transition metal hydrogenation and hydrosilylation catalysts |
| EP3071585B1 (en) * | 2013-11-19 | 2018-11-07 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| EP3071584B1 (en) * | 2013-11-19 | 2017-11-08 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| US10112961B2 (en) * | 2013-11-19 | 2018-10-30 | The Trustees Of Princeton University | Hydroboration and borylation with cobalt catalysts |
| JP6308547B2 (ja) * | 2014-02-20 | 2018-04-11 | 公立大学法人大阪市立大学 | 有機ケイ素化合物の製造方法 |
| WO2015171881A1 (en) * | 2014-05-08 | 2015-11-12 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| JP2015231965A (ja) * | 2014-06-10 | 2015-12-24 | 国立研究開発法人産業技術総合研究所 | 有機ケイ素化合物の製造方法及び触媒組成物 |
| JP6515930B2 (ja) | 2014-08-12 | 2019-05-22 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| EP3195932B1 (en) | 2014-08-12 | 2024-08-21 | Kyushu University, National University Corporation | Hydrosilylation reaction catalyst |
| JP6761997B2 (ja) | 2014-08-19 | 2020-09-30 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒 |
| US20180200703A1 (en) * | 2015-07-14 | 2018-07-19 | Kyushu University, National University Corporation | Hydrosilylation reaction catalyst |
| CN108026126B (zh) * | 2015-07-24 | 2021-04-20 | 莫门蒂夫性能材料股份有限公司 | 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联 |
| JP6620823B2 (ja) | 2016-01-22 | 2019-12-18 | 信越化学工業株式会社 | 新規イソシアニド化合物及びヒドロシリル化反応触媒 |
| WO2018159595A1 (ja) | 2017-02-28 | 2018-09-07 | 国立大学法人九州大学 | ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒 |
| WO2019018357A1 (en) * | 2017-07-17 | 2019-01-24 | Dow Silicones Corporation | CATALYST AND ASSOCIATED METHODS INVOLVING HYDROSILYLATION AND DEHYDROGENANT SILYLATION |
| JP2019064950A (ja) | 2017-09-29 | 2019-04-25 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
| US11273432B2 (en) | 2018-05-31 | 2022-03-15 | Arizona Board Of Regents On Behalf Of Arizona State University | Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation |
| JP7630783B2 (ja) * | 2019-08-29 | 2025-02-21 | 公立大学法人大阪 | 錯体固定化触媒 |
| JP7777817B2 (ja) * | 2020-10-08 | 2025-12-01 | 公立大学法人大阪 | ヒドロシリル化反応触媒助剤 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3159601A (en) | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
| US3220972A (en) | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
| US3775452A (en) | 1971-04-28 | 1973-11-27 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
| US4729821A (en) | 1986-11-03 | 1988-03-08 | Board Of Regents, The University Of Texas System | In situ activation of catalysts by applied electrical potentials |
| KR930703402A (ko) * | 1990-12-13 | 1993-11-30 | 게리 리 그리스울드 | 방사선-활성화된 하이드로실릴화 반응 |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| WO1999046302A1 (en) | 1998-03-12 | 1999-09-16 | Bp Chemicals Limited | Polymerisation catalysts |
| US5986022A (en) * | 1998-04-01 | 1999-11-16 | Witco Corporation | Continuous manufacture of silicone coploymers |
| GB9819847D0 (en) | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
| JP4883253B2 (ja) * | 2001-01-11 | 2012-02-22 | 信越化学工業株式会社 | シリコーンゴム用ポリウレタン系樹脂コート剤及びシリコーンゴム部材 |
| EP1542797B1 (en) | 2002-09-25 | 2006-05-31 | Shell Internationale Researchmaatschappij B.V. | Catalyst systems for ethylene oligomerisation to linear alpha olefins |
| WO2006010065A2 (en) | 2004-07-09 | 2006-01-26 | E.I. Dupont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| US7696269B2 (en) * | 2006-12-28 | 2010-04-13 | Momentive Performance Materials Inc. | Silated core polysulfides, their preparation and use in filled elastomer compositions |
| US8415443B2 (en) | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
-
2011
- 2011-11-22 CN CN201180065874.XA patent/CN103339135B/zh active Active
- 2011-11-22 EP EP11794589.9A patent/EP2643329B1/en active Active
- 2011-11-22 US US13/302,236 patent/US8765987B2/en active Active
- 2011-11-22 KR KR1020137016385A patent/KR101890606B1/ko active Active
- 2011-11-22 JP JP2013541001A patent/JP5991981B2/ja active Active
- 2011-11-22 BR BR112013012733A patent/BR112013012733A2/pt not_active Application Discontinuation
- 2011-11-22 WO PCT/US2011/061746 patent/WO2012071358A2/en not_active Ceased
- 2011-11-23 TW TW100142964A patent/TWI473654B/zh active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2013544824A5 (cg-RX-API-DMAC7.html) | ||
| JP2014502271A5 (cg-RX-API-DMAC7.html) | ||
| JP6211531B2 (ja) | 非貴金属系ヒドロシリル化触媒 | |
| JP5969387B2 (ja) | ヒドロシリル化触媒 | |
| JP5991981B2 (ja) | ヒドロシリル化触媒として使用される三座窒素配位子を有する金属錯体のｉｎ−ｓｉｔｕ活性化 | |
| JP2014503507A5 (cg-RX-API-DMAC7.html) | ||
| JP6059987B2 (ja) | ヒドロシリル化触媒 | |
| JP2012532884A5 (cg-RX-API-DMAC7.html) | ||
| US9381506B2 (en) | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation | |
| JP2014502271A (ja) | 多価不飽和化合物の金属触媒モノヒドロシリル化 | |
| JP2015501842A5 (cg-RX-API-DMAC7.html) | ||
| JP2016520083A5 (cg-RX-API-DMAC7.html) | ||
| US12296325B2 (en) | Catalyst for hydrosilylation reaction, hydrogenation reaction, and hydrosilane reduction reaction | |
| JP6689005B2 (ja) | シクロジエン添加剤を使用する白金触媒ヒドロシリル化反応 | |
| US20240368199A1 (en) | Hydrosilylation process catalysed by a cobalt complex | |
| US20240287255A1 (en) | Hydrosilylation method catalysed by an iron complex | |
| JP6486924B2 (ja) | コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用 | |
| CN106536046A (zh) | 二烷基钴催化剂及它们用于氢化硅烷化和脱氢硅烷化的用途 | |
| JP2016537377A (ja) | コバルト触媒を用いる脱水素シリル化、ヒドロシリル化、及び架橋結合 |