JP2013540916A5 - - Google Patents
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- Publication number
- JP2013540916A5 JP2013540916A5 JP2013536766A JP2013536766A JP2013540916A5 JP 2013540916 A5 JP2013540916 A5 JP 2013540916A5 JP 2013536766 A JP2013536766 A JP 2013536766A JP 2013536766 A JP2013536766 A JP 2013536766A JP 2013540916 A5 JP2013540916 A5 JP 2013540916A5
- Authority
- JP
- Japan
- Prior art keywords
- pulp
- diallyl
- copolymer
- acrylic acid
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 45
- 229920001577 copolymer Polymers 0.000 claims description 38
- 229920006037 cross link polymer Polymers 0.000 claims description 25
- 239000011859 microparticle Substances 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 22
- 239000000123 paper Substances 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 12
- 125000000129 anionic group Chemical group 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- -1 dimethyl acrylate Chemical compound 0.000 claims description 8
- 239000011087 paperboard Substances 0.000 claims description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000000701 coagulant Substances 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical compound C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000010419 fine particle Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 claims description 2
- ZJQIXGGEADDPQB-UHFFFAOYSA-N 1,2-bis(ethenyl)-3,4-dimethylbenzene Chemical group CC1=CC=C(C=C)C(C=C)=C1C ZJQIXGGEADDPQB-UHFFFAOYSA-N 0.000 claims description 2
- YKKDJUGGSDWUKX-UHFFFAOYSA-N 1,2-bis(ethenyl)-3-ethylbenzene Chemical compound CCC1=CC=CC(C=C)=C1C=C YKKDJUGGSDWUKX-UHFFFAOYSA-N 0.000 claims description 2
- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 claims description 2
- JQGGYGKXKWTXTF-UHFFFAOYSA-N 1-ethenoxy-3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propane Chemical compound C=CCOCC(COCC=C)(COCC=C)COC=C JQGGYGKXKWTXTF-UHFFFAOYSA-N 0.000 claims description 2
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 claims description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 2
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims description 2
- KHAHWKLZGBIAKT-UHFFFAOYSA-N 4-(4-methylpyrimidin-2-yl)benzaldehyde Chemical compound CC1=CC=NC(C=2C=CC(C=O)=CC=2)=N1 KHAHWKLZGBIAKT-UHFFFAOYSA-N 0.000 claims description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims description 2
- 239000004641 Diallyl-phthalate Substances 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 2
- JQRRFDWXQOQICD-UHFFFAOYSA-N biphenylen-1-ylboronic acid Chemical compound C12=CC=CC=C2C2=C1C=CC=C2B(O)O JQRRFDWXQOQICD-UHFFFAOYSA-N 0.000 claims description 2
- ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 claims description 2
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 claims description 2
- VPPSHXIFIAJKMX-UHFFFAOYSA-N bis(prop-2-enyl) 2,3-dihydroxybutanedioate Chemical compound C=CCOC(=O)C(O)C(O)C(=O)OCC=C VPPSHXIFIAJKMX-UHFFFAOYSA-N 0.000 claims description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 2
- HABAXTXIECRCKH-UHFFFAOYSA-N bis(prop-2-enyl) butanedioate Chemical compound C=CCOC(=O)CCC(=O)OCC=C HABAXTXIECRCKH-UHFFFAOYSA-N 0.000 claims description 2
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 claims description 2
- FPODCVUTIPDRTE-UHFFFAOYSA-N bis(prop-2-enyl) hexanedioate Chemical compound C=CCOC(=O)CCCCC(=O)OCC=C FPODCVUTIPDRTE-UHFFFAOYSA-N 0.000 claims description 2
- BKXRKRANFLFTFU-UHFFFAOYSA-N bis(prop-2-enyl) oxalate Chemical compound C=CCOC(=O)C(=O)OCC=C BKXRKRANFLFTFU-UHFFFAOYSA-N 0.000 claims description 2
- AOESAXAWXYJFNC-UHFFFAOYSA-N bis(prop-2-enyl) propanedioate Chemical compound C=CCOC(=O)CC(=O)OCC=C AOESAXAWXYJFNC-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 claims description 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229940015043 glyoxal Drugs 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- AYGYHGXUJBFUJU-UHFFFAOYSA-N n-[2-(prop-2-enoylamino)ethyl]prop-2-enamide Chemical compound C=CC(=O)NCCNC(=O)C=C AYGYHGXUJBFUJU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical group C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- NZHHDFRSEQSGLN-ZRDIBKRKSA-N tris(prop-2-enyl) (e)-prop-1-ene-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)C\C(C(=O)OCC=C)=C/C(=O)OCC=C NZHHDFRSEQSGLN-ZRDIBKRKSA-N 0.000 claims description 2
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 claims description 2
- 229960000834 vinyl ether Drugs 0.000 claims description 2
- JHSWSKVODYPNDV-UHFFFAOYSA-N 2,2-bis(prop-2-enoxymethyl)propane-1,3-diol Chemical compound C=CCOCC(CO)(CO)COCC=C JHSWSKVODYPNDV-UHFFFAOYSA-N 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 229920005601 base polymer Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- FYRWKWGEFZTOQI-UHFFFAOYSA-N 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol Chemical compound C=CCOCC(CO)(COCC=C)COCC=C FYRWKWGEFZTOQI-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical compound OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
- 229920005603 alternating copolymer Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 150000003863 ammonium salts Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ABBZJHFBQXYTLU-UHFFFAOYSA-N but-3-enamide Chemical group NC(=O)CC=C ABBZJHFBQXYTLU-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40826210P | 2010-10-29 | 2010-10-29 | |
| US61/408,262 | 2010-10-29 | ||
| PCT/US2011/057798 WO2012058258A1 (en) | 2010-10-29 | 2011-10-26 | Papermaking and products made thereby with ionic crosslinked polymeric microparticle |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013540916A JP2013540916A (ja) | 2013-11-07 |
| JP2013540916A5 true JP2013540916A5 (enExample) | 2014-11-27 |
| JP5961619B2 JP5961619B2 (ja) | 2016-08-02 |
Family
ID=45994363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013536766A Expired - Fee Related JP5961619B2 (ja) | 2010-10-29 | 2011-10-26 | イオン性架橋ポリマー微粒子を用いて紙を作製する方法及び該方法により作製された製品 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8480853B2 (enExample) |
| EP (1) | EP2633120A4 (enExample) |
| JP (1) | JP5961619B2 (enExample) |
| CN (1) | CN103282582B (enExample) |
| AU (1) | AU2011319981B2 (enExample) |
| BR (1) | BR112013010261A2 (enExample) |
| CA (1) | CA2814988A1 (enExample) |
| MX (1) | MX342259B (enExample) |
| NZ (1) | NZ609491A (enExample) |
| WO (1) | WO2012058258A1 (enExample) |
| ZA (1) | ZA201302640B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8932433B2 (en) * | 2004-12-29 | 2015-01-13 | Solenis Technologies, L.P. | Retention and drainage in the manufacture of paper |
| EP2633120A4 (en) * | 2010-10-29 | 2015-08-26 | Buckman Labor Inc | PAPER MANUFACTURE AND PRODUCTS MANUFACTURED BY THIS MANUFACTURE WITH NETWORKED IONIC POLYMER MICROPARTICLES |
| US9133583B2 (en) * | 2011-04-05 | 2015-09-15 | P.H. Glatfelter Company | Process for making a stiffened paper |
| US9200408B2 (en) * | 2012-11-02 | 2015-12-01 | Ecolab Usa Inc. | Method of delivering a pigment dispersion and retention aid to a papermaking process |
| CN104594113A (zh) * | 2014-12-25 | 2015-05-06 | 合肥丹盛包装有限公司 | 一种含有改性聚苯醚树脂的瓦楞纸及其制备方法 |
| BR112018007308B1 (pt) | 2015-10-12 | 2023-03-07 | Solenis Technologies, L.P. | Método para aumentar o desempenho de drenagem de uma pasta de polpa e produto de papel |
| TW201739983A (zh) * | 2016-01-14 | 2017-11-16 | 亞齊羅馬Ｉｐ公司 | 丙烯酸酯共聚物之用途、使用其之具有纖維素纖維之基材之製造方法及其基板 |
| CN105820290B (zh) * | 2016-05-04 | 2019-06-07 | 山东源根化学技术研发有限公司 | 一种提升细小纤维-碳酸钙留着率的乳液聚合物的制备方法 |
| CN107447582B (zh) * | 2016-06-01 | 2022-04-12 | 艺康美国股份有限公司 | 用于在高电荷需求系统中造纸的高效强度方案 |
| US10463205B2 (en) * | 2016-07-01 | 2019-11-05 | Mercer International Inc. | Process for making tissue or towel products comprising nanofilaments |
| US10570261B2 (en) | 2016-07-01 | 2020-02-25 | Mercer International Inc. | Process for making tissue or towel products comprising nanofilaments |
| WO2018046794A1 (en) * | 2016-09-07 | 2018-03-15 | Kemira Oyj | Method for manufacture of paper, board or the like and use of the composition |
| CN106723287B (zh) * | 2017-03-08 | 2018-12-04 | 湖北中烟工业有限责任公司 | 一种造纸法再造烟叶助留助滤剂的制备方法 |
| US10731295B2 (en) | 2017-06-29 | 2020-08-04 | Mercer International Inc | Process for making absorbent towel and soft sanitary tissue paper webs |
| CN109252415B (zh) * | 2018-10-16 | 2019-07-19 | 山鹰国际控股股份公司 | 一种牛皮箱板纸及其制造方法 |
| US11028538B2 (en) * | 2019-02-28 | 2021-06-08 | Solenis Technologies, L.P. | Composition and method for increasing wet and dry paper strength |
| CN112726247B (zh) * | 2021-01-05 | 2022-12-23 | 浙江上峰包装新材料有限公司 | 一种印刷包装用透明纸及其制备方法 |
| BR102022010729A2 (pt) * | 2022-06-01 | 2023-12-12 | Petróleo Brasileiro S.A. - Petrobras | Método de tratamento de água produzida por floculação química usando tensoativo aniônico e polieletrólito catiônico e uso do mesmo |
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-
2011
- 2011-10-26 EP EP11836977.6A patent/EP2633120A4/en not_active Withdrawn
- 2011-10-26 AU AU2011319981A patent/AU2011319981B2/en not_active Withdrawn - After Issue
- 2011-10-26 MX MX2013004529A patent/MX342259B/es active IP Right Grant
- 2011-10-26 CN CN201180062990.6A patent/CN103282582B/zh not_active Expired - Fee Related
- 2011-10-26 US US13/281,597 patent/US8480853B2/en not_active Expired - Fee Related
- 2011-10-26 WO PCT/US2011/057798 patent/WO2012058258A1/en not_active Ceased
- 2011-10-26 CA CA2814988A patent/CA2814988A1/en not_active Abandoned
- 2011-10-26 JP JP2013536766A patent/JP5961619B2/ja not_active Expired - Fee Related
- 2011-10-26 NZ NZ609491A patent/NZ609491A/en not_active IP Right Cessation
- 2011-10-26 BR BR112013010261A patent/BR112013010261A2/pt not_active IP Right Cessation
-
2013
- 2013-04-12 ZA ZA2013/02640A patent/ZA201302640B/en unknown
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