JP2013537245A5 - - Google Patents
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- Publication number
- JP2013537245A5 JP2013537245A5 JP2013527572A JP2013527572A JP2013537245A5 JP 2013537245 A5 JP2013537245 A5 JP 2013537245A5 JP 2013527572 A JP2013527572 A JP 2013527572A JP 2013527572 A JP2013527572 A JP 2013527572A JP 2013537245 A5 JP2013537245 A5 JP 2013537245A5
- Authority
- JP
- Japan
- Prior art keywords
- metal cyanide
- aqueous solution
- catalyst
- double metal
- cyanide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 25
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 20
- 239000003446 ligand Substances 0.000 claims description 14
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 13
- 125000002947 alkylene group Chemical group 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 12
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 claims description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- 239000001569 carbon dioxide Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000007858 starting material Substances 0.000 claims description 10
- -1 carbonate polyol Chemical class 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000000536 complexating effect Effects 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 150000002825 nitriles Chemical class 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 230000004913 activation Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 8
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical class CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- QXLPXWSKPNOQLE-UHFFFAOYSA-N methylpentynol Chemical compound CCC(C)(O)C#C QXLPXWSKPNOQLE-UHFFFAOYSA-N 0.000 description 4
- 229940102001 zinc bromide Drugs 0.000 description 4
- 239000011592 zinc chloride Substances 0.000 description 4
- 235000005074 zinc chloride Nutrition 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- CEBKHWWANWSNTI-UHFFFAOYSA-N 2-methylbut-3-yn-2-ol Chemical compound CC(C)(O)C#C CEBKHWWANWSNTI-UHFFFAOYSA-N 0.000 description 2
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N 3-Buten-1-ol Chemical compound OCCC=C ZSPTYLOMNJNZNG-UHFFFAOYSA-N 0.000 description 2
- HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- OTJZCIYGRUNXTP-UHFFFAOYSA-N but-3-yn-1-ol Chemical compound OCCC#C OTJZCIYGRUNXTP-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- MKUWVMRNQOOSAT-UHFFFAOYSA-N methylvinylmethanol Natural products CC(O)C=C MKUWVMRNQOOSAT-UHFFFAOYSA-N 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- AWDBHOZBRXWRKS-UHFFFAOYSA-N tetrapotassium;iron(6+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] AWDBHOZBRXWRKS-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- BZAZNULYLRVMSW-UHFFFAOYSA-N 2-Methyl-2-buten-3-ol Natural products CC(C)=C(C)O BZAZNULYLRVMSW-UHFFFAOYSA-N 0.000 description 1
- HFYAEUXHCMTPOL-UHFFFAOYSA-N 3-Methyl-1-penten-3-ol Chemical compound CCC(C)(O)C=C HFYAEUXHCMTPOL-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910021575 Iron(II) bromide Inorganic materials 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- XIHJHSXDSHKTKE-UHFFFAOYSA-N [K].N#C[Co](C#N)(C#N)(C#N)(C#N)C#N Chemical compound [K].N#C[Co](C#N)(C#N)(C#N)(C#N)C#N XIHJHSXDSHKTKE-UHFFFAOYSA-N 0.000 description 1
- OKYCYSABLCQQEL-UHFFFAOYSA-N [Li].N#C[Co](C#N)(C#N)(C#N)(C#N)C#N Chemical compound [Li].N#C[Co](C#N)(C#N)(C#N)(C#N)C#N OKYCYSABLCQQEL-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- INDBQWVYFLTCFF-UHFFFAOYSA-L cobalt(2+);dithiocyanate Chemical compound [Co+2].[S-]C#N.[S-]C#N INDBQWVYFLTCFF-UHFFFAOYSA-L 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010040517.5 | 2010-09-09 | ||
| DE102010040517A DE102010040517A1 (de) | 2010-09-09 | 2010-09-09 | Verfahren zur Herstellung von Polyetherpolyolen |
| PCT/EP2011/065364 WO2012032028A1 (de) | 2010-09-09 | 2011-09-06 | Verfahren zur herstellung von polyethercarbonatpolyolen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013537245A JP2013537245A (ja) | 2013-09-30 |
| JP2013537245A5 true JP2013537245A5 (cg-RX-API-DMAC7.html) | 2014-10-23 |
| JP5792310B2 JP5792310B2 (ja) | 2015-10-07 |
Family
ID=44653291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013527572A Expired - Fee Related JP5792310B2 (ja) | 2010-09-09 | 2011-09-06 | ポリエーテルカーボネートポリオールの製造方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9045592B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2614102B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5792310B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR20130102588A (cg-RX-API-DMAC7.html) |
| CN (1) | CN103189417B (cg-RX-API-DMAC7.html) |
| BR (1) | BR112013005783A2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2810559A1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE102010040517A1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2506440T3 (cg-RX-API-DMAC7.html) |
| MX (1) | MX2013002484A (cg-RX-API-DMAC7.html) |
| RU (1) | RU2013115633A (cg-RX-API-DMAC7.html) |
| SG (1) | SG188278A1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012032028A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2548908A1 (de) * | 2011-07-18 | 2013-01-23 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyetherpolyolen |
| US9790328B2 (en) * | 2013-06-13 | 2017-10-17 | Covestro Deutschland Ag | Polyethercarbonate-polyoxymethylene block copolymers |
| EP2837648A1 (en) | 2013-08-12 | 2015-02-18 | Repsol, S.A. | Process for preparing polyether carbonate polyols |
| EP2845871A1 (de) * | 2013-09-05 | 2015-03-11 | Bayer MaterialScience AG | Vernetzung von Doppelbindungen enthaltenden Polyethercarbonatpolyolen durch Addition von Mercaptanen |
| EP2865700A1 (de) * | 2013-10-23 | 2015-04-29 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| US9527958B2 (en) | 2014-05-02 | 2016-12-27 | Covestro Llc | Process for purification of polyether carbonate polyols |
| SG11201610701TA (en) * | 2014-07-03 | 2017-01-27 | Covestro Deutschland Ag | Method for producing polyether carbonate polyols |
| US10119223B2 (en) | 2016-07-15 | 2018-11-06 | Covestro Llc | Carpet and synthetic turf backings prepared from a polyether carbonate polyol |
| US10040903B2 (en) | 2016-09-13 | 2018-08-07 | Covestro Llc | Polymer polyol quality |
| HUE061193T2 (hu) | 2016-11-11 | 2023-05-28 | Dow Global Technologies Llc | Polikarbonát alapú poliolok |
| GB201703323D0 (en) * | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyols |
| CN110964191B (zh) * | 2018-09-29 | 2021-02-02 | 杭州普力材料科技有限公司 | 一种混合酸改性的锌钴双金属氰化物催化剂及其制备方法 |
| WO2021018753A1 (de) * | 2019-07-31 | 2021-02-04 | Covestro Deutschland Ag | Verfahren zur herstellung von polyethercarbonatpolyolen |
| CN115003413B (zh) * | 2020-01-21 | 2024-02-27 | 科思创德国股份有限公司 | 制备双金属氰化物催化剂的方法 |
| KR102717144B1 (ko) * | 2021-07-15 | 2024-10-11 | 아주대학교산학협력단 | 하이드로젠 헥사시아노코발테이트와 아연 카복실레이트의 조합으로 제조된 더블메탈시아나이드 촉매 및 이를 이용한 프로필렌 옥사이드 중합 |
| KR20230036995A (ko) | 2021-09-08 | 2023-03-15 | 주식회사 엘지화학 | 이중 금속 시아나이드 촉매, 이의 제조방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트의 제조방법 |
| CN114524929B (zh) * | 2021-09-24 | 2023-07-25 | 山东联欣环保科技有限公司 | 一种二氧化碳基四元共聚物的制备方法 |
| EP4273183A4 (en) * | 2021-09-29 | 2024-07-17 | Lg Chem, Ltd. | METHOD FOR MANUFACTURING POLYALKYLENE POLYCARBONATE RESIN |
| CN114381252B (zh) * | 2022-01-19 | 2023-02-10 | 成都理工大学 | 一种超高温下耐多价金属阳离子无固相修井液的制备方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| JP2653236B2 (ja) | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| EP1034035B1 (de) * | 1997-10-13 | 2003-06-04 | Bayer Ag | Kristalline doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen |
| US6376645B1 (en) | 1999-07-09 | 2002-04-23 | The Dow Chemical Company | Complexing agent-modified hexacyanometallate hexanitrometallate catalysts |
| DE19958355A1 (de) | 1999-12-03 | 2001-06-07 | Bayer Ag | Verfahren zur Herstellung von DMC-Katalysatoren |
| US6835687B2 (en) | 2000-04-20 | 2004-12-28 | Bayer Aktiengesellschaft | Method for producing double metal cyanide (DMC) catalysts |
| DE10122019A1 (de) | 2001-05-07 | 2002-11-14 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE10147712A1 (de) | 2001-09-27 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung aliphatischer Polycarbonate |
| US6762278B2 (en) | 2002-02-04 | 2004-07-13 | Basf Corporation | Process for the copolymerization of alkylene oxides and carbon dioxide using suspensions of multi-metal cyanide compounds |
| DE10219028A1 (de) | 2002-04-29 | 2003-11-06 | Bayer Ag | Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten |
| WO2004044034A1 (en) | 2002-11-07 | 2004-05-27 | Dow Global Technologies, Inc. | Method for preparing metal cyanide catalysts using polymerizable complexing agents |
| CA2518201A1 (en) | 2003-03-07 | 2004-09-23 | Dow Global Technologies Inc. | Continuous process and system of producing polyether polyols |
| US20050101477A1 (en) * | 2003-11-07 | 2005-05-12 | George Combs | Unsaturated tertiary alcohols as ligands for active dmc catalysts |
| US20060223973A1 (en) | 2005-03-29 | 2006-10-05 | Basf Corporation | Method of forming a polyethercarbonate polyol |
| US7977501B2 (en) | 2006-07-24 | 2011-07-12 | Bayer Materialscience Llc | Polyether carbonate polyols made via double metal cyanide (DMC) catalysis |
-
2010
- 2010-09-09 DE DE102010040517A patent/DE102010040517A1/de not_active Withdrawn
-
2011
- 2011-09-06 MX MX2013002484A patent/MX2013002484A/es active IP Right Grant
- 2011-09-06 SG SG2013013461A patent/SG188278A1/en unknown
- 2011-09-06 CA CA2810559A patent/CA2810559A1/en not_active Abandoned
- 2011-09-06 JP JP2013527572A patent/JP5792310B2/ja not_active Expired - Fee Related
- 2011-09-06 EP EP11757815.3A patent/EP2614102B1/de not_active Not-in-force
- 2011-09-06 WO PCT/EP2011/065364 patent/WO2012032028A1/de not_active Ceased
- 2011-09-06 ES ES11757815.3T patent/ES2506440T3/es active Active
- 2011-09-06 KR KR1020137008882A patent/KR20130102588A/ko not_active Ceased
- 2011-09-06 US US13/821,254 patent/US9045592B2/en active Active
- 2011-09-06 BR BR112013005783A patent/BR112013005783A2/pt unknown
- 2011-09-06 CN CN201180043627.XA patent/CN103189417B/zh not_active Expired - Fee Related
- 2011-09-06 RU RU2013115633/04A patent/RU2013115633A/ru not_active Application Discontinuation
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