JP2013513020A - 熱可塑性マトリックス中のｃｎｔ浸出繊維 - Google Patents
熱可塑性マトリックス中のｃｎｔ浸出繊維 Download PDFInfo
- Publication number
- JP2013513020A JP2013513020A JP2012543264A JP2012543264A JP2013513020A JP 2013513020 A JP2013513020 A JP 2013513020A JP 2012543264 A JP2012543264 A JP 2012543264A JP 2012543264 A JP2012543264 A JP 2012543264A JP 2013513020 A JP2013513020 A JP 2013513020A
- Authority
- JP
- Japan
- Prior art keywords
- cnt
- cnts
- fiber material
- composite material
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011159 matrix material Substances 0.000 title claims abstract description 54
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 53
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 52
- 239000000835 fiber Substances 0.000 title description 130
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 416
- 239000002131 composite material Substances 0.000 claims abstract description 105
- 239000000463 material Substances 0.000 claims description 205
- 238000000034 method Methods 0.000 claims description 97
- 239000003365 glass fiber Substances 0.000 claims description 29
- 238000004519 manufacturing process Methods 0.000 claims description 26
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 14
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 14
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 14
- 229920002530 polyetherether ketone Polymers 0.000 claims description 14
- 239000008188 pellet Substances 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 239000004697 Polyetherimide Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims 2
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 229920006258 high performance thermoplastic Polymers 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 472
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract description 409
- 239000002657 fibrous material Substances 0.000 abstract description 138
- 229920000049 Carbon (fiber) Polymers 0.000 description 202
- 239000004917 carbon fiber Substances 0.000 description 201
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 185
- 239000003054 catalyst Substances 0.000 description 119
- 238000000576 coating method Methods 0.000 description 80
- 230000004888 barrier function Effects 0.000 description 76
- 239000011248 coating agent Substances 0.000 description 73
- 230000008569 process Effects 0.000 description 72
- 229910052799 carbon Inorganic materials 0.000 description 59
- 230000015572 biosynthetic process Effects 0.000 description 47
- 238000004513 sizing Methods 0.000 description 47
- 238000003786 synthesis reaction Methods 0.000 description 42
- 238000002386 leaching Methods 0.000 description 40
- 239000003795 chemical substances by application Substances 0.000 description 38
- 239000007789 gas Substances 0.000 description 37
- 210000002381 plasma Anatomy 0.000 description 31
- 238000012545 processing Methods 0.000 description 25
- 238000005229 chemical vapour deposition Methods 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000000203 mixture Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 238000010924 continuous production Methods 0.000 description 14
- 238000000151 deposition Methods 0.000 description 14
- 230000006870 function Effects 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 239000002048 multi walled nanotube Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- 229910052723 transition metal Inorganic materials 0.000 description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 239000002105 nanoparticle Substances 0.000 description 12
- 238000009832 plasma treatment Methods 0.000 description 12
- 150000003624 transition metals Chemical class 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000010926 purge Methods 0.000 description 11
- 239000000758 substrate Substances 0.000 description 11
- 238000011282 treatment Methods 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 230000008021 deposition Effects 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 230000008859 change Effects 0.000 description 8
- 238000003618 dip coating Methods 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 238000005470 impregnation Methods 0.000 description 8
- 239000011261 inert gas Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 230000002787 reinforcement Effects 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000002109 single walled nanotube Substances 0.000 description 8
- 230000005684 electric field Effects 0.000 description 7
- -1 polypropylene Polymers 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- 238000001878 scanning electron micrograph Methods 0.000 description 7
- 229910021524 transition metal nanoparticle Inorganic materials 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000002079 double walled nanotube Substances 0.000 description 6
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 6
- 239000001307 helium Substances 0.000 description 6
- 229910052734 helium Inorganic materials 0.000 description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 6
- 230000003993 interaction Effects 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 239000002071 nanotube Substances 0.000 description 6
- 150000003839 salts Chemical group 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920002239 polyacrylonitrile Polymers 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000004071 soot Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002759 woven fabric Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 238000007605 air drying Methods 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000007306 functionalization reaction Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 230000001404 mediated effect Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000010453 quartz Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- 238000007788 roughening Methods 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 238000009827 uniform distribution Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical group C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000003917 TEM image Methods 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011554 ferrofluid Substances 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 238000009730 filament winding Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 125000002524 organometallic group Chemical class 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001601 polyetherimide Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 230000005483 Hooke's law Effects 0.000 description 1
- 229910001374 Invar Inorganic materials 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010036790 Productive cough Diseases 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910021387 carbon allotrope Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 238000002789 length control Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011234 nano-particulate material Substances 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 229940031182 nanoparticles iron oxide Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000007261 regionalization Effects 0.000 description 1
- 239000011208 reinforced composite material Substances 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 210000003802 sputum Anatomy 0.000 description 1
- 208000024794 sputum Diseases 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/42—Coatings containing inorganic materials
- C03C25/44—Carbon, e.g. graphite
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Conductive Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26779409P | 2009-12-08 | 2009-12-08 | |
| US61/267,794 | 2009-12-08 | ||
| PCT/US2010/059565 WO2011072071A1 (en) | 2009-12-08 | 2010-12-08 | Cnt-infused fibers in thermoplastic matrices |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013513020A true JP2013513020A (ja) | 2013-04-18 |
| JP2013513020A5 JP2013513020A5 (https=) | 2014-01-23 |
Family
ID=44145902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012543264A Pending JP2013513020A (ja) | 2009-12-08 | 2010-12-08 | 熱可塑性マトリックス中のｃｎｔ浸出繊維 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20110297892A1 (https=) |
| EP (1) | EP2509918A4 (https=) |
| JP (1) | JP2013513020A (https=) |
| KR (1) | KR20120124404A (https=) |
| CN (1) | CN102648155A (https=) |
| AU (1) | AU2010328139B2 (https=) |
| BR (1) | BR112012013904A2 (https=) |
| CA (1) | CA2779709A1 (https=) |
| WO (1) | WO2011072071A1 (https=) |
| ZA (1) | ZA201203339B (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7382460B1 (ja) | 2022-07-14 | 2023-11-16 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| WO2024053535A1 (ja) * | 2022-09-08 | 2024-03-14 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| WO2025109800A1 (ja) * | 2023-11-21 | 2025-05-30 | 住友ゴム工業株式会社 | ラケット用ストリング |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8941094B2 (en) * | 2010-09-02 | 2015-01-27 | Nantero Inc. | Methods for adjusting the conductivity range of a nanotube fabric layer |
| BRPI1007300A2 (pt) * | 2009-02-17 | 2019-09-24 | Applied Nanostructured Sols | compósitos compreendendo nanotubos de carbono sobre fibra |
| BRPI1016244A2 (pt) | 2009-04-24 | 2016-04-26 | Applied Nanostructured Sols | compósito de proteção contra emi infundido com cnt e revestimento. |
| US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
| JP5744008B2 (ja) | 2009-04-27 | 2015-07-01 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーＡｐｐｌｉｅｄ Ｎａｎｏｓｔｒｕｃｔｕｒｅｄｓｏｌｕｔｉｏｎｓ， Ｌｌｃ | 複合材料構造体を除氷するためのｃｎｔベース抵抗加熱 |
| US20110089958A1 (en) * | 2009-10-19 | 2011-04-21 | Applied Nanostructured Solutions, Llc | Damage-sensing composite structures |
| CN102596715A (zh) | 2009-11-23 | 2012-07-18 | 应用纳米结构方案公司 | Cnt特制复合材料地面基结构 |
| BR112012012979A2 (pt) | 2009-12-14 | 2019-09-24 | Applied Nanostructured Sols | materias compostos resistentes à chama e artigos contendo materiais de fibra infundidos de nanotubo de carbono. |
| US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| AU2011256789A1 (en) | 2010-02-02 | 2012-07-12 | Applied Nanostructured Solutions, Llc | Fiber containing parallel-aligned carbon nanotubes |
| JP2013521656A (ja) | 2010-03-02 | 2013-06-10 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニー | カーボン・ナノチューブ浸出電極材料を含む螺旋に巻き付けられた電気機器及びその生産方法並びに生産装置 |
| EP2543052B1 (en) | 2010-03-02 | 2019-11-27 | Applied NanoStructured Solutions, LLC | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US9017854B2 (en) | 2010-08-30 | 2015-04-28 | Applied Nanostructured Solutions, Llc | Structural energy storage assemblies and methods for production thereof |
| WO2012040038A2 (en) | 2010-09-23 | 2012-03-29 | Applied Nanostructured Solutions, Llc | Cnt-infused fiber as a self shielding wire for enhanced power transmission line |
| US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
| CN104379254B (zh) * | 2012-06-22 | 2017-03-22 | 国立大学法人东京大学 | 碳纳米管合成用含碳金属催化剂粒子及其制造方法、以及催化剂负载支承体、碳纳米管的制造方法 |
| WO2014039509A2 (en) | 2012-09-04 | 2014-03-13 | Ocv Intellectual Capital, Llc | Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media |
| CN102924910B (zh) * | 2012-11-16 | 2014-04-30 | 华东理工大学 | 一种高性能玻璃纤维增强聚酰胺导电复合材料的制备方法 |
| KR101674242B1 (ko) * | 2013-03-15 | 2016-11-08 | 롯데첨단소재(주) | 전자파 차폐특성이 우수한 열가소성 수지조성물 |
| US9802373B2 (en) * | 2014-06-11 | 2017-10-31 | Applied Nanostructured Solutions, Llc | Methods for processing three-dimensional printed objects using microwave radiation |
| KR101903300B1 (ko) | 2014-07-22 | 2018-10-01 | 어드밴스드 테크놀러지 머티리얼즈, 인코포레이티드 | 연성 재료를 갖는 성형 플루오로중합체 브레이크 실 |
| KR20160026764A (ko) * | 2014-08-29 | 2016-03-09 | 삼성에스디아이 주식회사 | 전도성 열가소성 수지 조성물 |
| US9908978B2 (en) | 2015-04-08 | 2018-03-06 | Arevo Inc. | Method to manufacture polymer composite materials with nano-fillers for use in additive manufacturing to improve material properties |
| US11369050B2 (en) | 2015-06-09 | 2022-06-21 | 3M Innovative Properties Company | High frequency electromagnetic interference (EMI) composites |
| US11117311B2 (en) | 2015-10-05 | 2021-09-14 | Arevo, Inc. | Amorphous polyaryletherketone and blends thereof for use in additive manufacturing |
| US11058039B2 (en) | 2015-12-29 | 2021-07-06 | 3M Innovative Properties Company | Composites for high frequency electromagnetic interference (EMI) applications |
| KR101777945B1 (ko) | 2016-02-04 | 2017-09-12 | 고려대학교 산학협력단 | 플라즈마 처리를 통한 표면이 개질된 탄소섬유를 구비한 탄소 섬유 강화 폴리머 복합재 및 그 제조 방법 |
| CN107541038A (zh) * | 2016-06-27 | 2018-01-05 | 汉达精密电子(昆山)有限公司 | 碳纤维阻燃聚碳酸酯复合材料及其产品 |
| CN107641305A (zh) * | 2016-07-21 | 2018-01-30 | 汉达精密电子(昆山)有限公司 | 纳米碳管改性的玻璃纤维聚碳酸酯复合材料及其产品 |
| CN107722586A (zh) * | 2016-08-11 | 2018-02-23 | 汉达精密电子(昆山)有限公司 | 碳纳米管增强聚碳酸酯/碳纤维复合材料及其成型品 |
| DE102017209357A1 (de) * | 2017-06-01 | 2018-12-06 | Albis Plastic Gmbh | Compound |
| DE102018208149A1 (de) * | 2018-05-24 | 2019-11-28 | Fresenius Medical Care Deutschland Gmbh | Verbundmaterial für verschleissarme mechanische bauteile der kraft- und bewegungsübertragung |
| EP3819424A4 (en) * | 2018-06-11 | 2022-05-11 | Nitta Corporation | COMPOSITE MATERIAL, PREPREG, CARBON FIBER REINFORCED MOLDED PRODUCT AND METHOD FOR PRODUCING THE COMPOSITE MATERIAL |
| KR102519880B1 (ko) * | 2021-02-17 | 2023-04-12 | 주식회사 삼양사 | 전자파 차폐 성능이 향상된 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006082829A1 (ja) * | 2005-02-02 | 2006-08-10 | Otsuka Chemical Co., Ltd. | カーボンナノチューブ担持無機粒子 |
| JP2007502246A (ja) * | 2003-07-28 | 2007-02-08 | ウィリアム・マーシュ・ライス・ユニバーシティ | ポリマー複合物を得るための、有機シランによるカーボンナノチューブのサイドウォール官能化 |
| JP2007523033A (ja) * | 2004-01-30 | 2007-08-16 | サーントル ナシオナル ドゥ ラ ルシェルシェ シャーンティフィク（セーエンヌエールエス） | 支持体に結合させたカーボンナノチューブ及びそれを含む複合体の製造方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6863942B2 (en) * | 1998-06-19 | 2005-03-08 | The Research Foundation Of State University Of New York | Free-standing and aligned carbon nanotubes and synthesis thereof |
| WO2002100931A1 (en) * | 2001-06-08 | 2002-12-19 | Eikos, Inc. | Nanocomposite dielectrics |
| BRPI0407495A (pt) * | 2003-02-13 | 2006-02-14 | Stichting Dutch Polymer Inst | polìmero reforçado |
| US20050062024A1 (en) * | 2003-08-06 | 2005-03-24 | Bessette Michael D. | Electrically conductive pressure sensitive adhesives, method of manufacture, and use thereof |
| CN105696138B (zh) * | 2004-11-09 | 2019-02-01 | 得克萨斯大学体系董事会 | 纳米纤维纱线、带和板的制造和应用 |
| US8148276B2 (en) * | 2005-11-28 | 2012-04-03 | University Of Hawaii | Three-dimensionally reinforced multifunctional nanocomposites |
| CN100591613C (zh) * | 2006-08-11 | 2010-02-24 | 清华大学 | 碳纳米管复合材料及其制造方法 |
| EP2089459A2 (en) * | 2006-12-04 | 2009-08-19 | Universite Catholique De Louvain | Polymer composite material structures comprising carbon based conductive loads |
| CN101582302B (zh) * | 2008-05-14 | 2011-12-21 | 清华大学 | 碳纳米管/导电聚合物复合材料 |
| US20100032629A1 (en) * | 2008-08-07 | 2010-02-11 | Benoit Brule | Adhesive composition containing carbon nanotubes and a copolyamide |
| US20110123735A1 (en) * | 2009-11-23 | 2011-05-26 | Applied Nanostructured Solutions, Llc | Cnt-infused fibers in thermoset matrices |
-
2010
- 2010-12-08 JP JP2012543264A patent/JP2013513020A/ja active Pending
- 2010-12-08 US US12/963,589 patent/US20110297892A1/en not_active Abandoned
- 2010-12-08 CA CA2779709A patent/CA2779709A1/en not_active Abandoned
- 2010-12-08 BR BR112012013904A patent/BR112012013904A2/pt not_active IP Right Cessation
- 2010-12-08 EP EP10836652.7A patent/EP2509918A4/en not_active Withdrawn
- 2010-12-08 CN CN2010800557617A patent/CN102648155A/zh active Pending
- 2010-12-08 WO PCT/US2010/059565 patent/WO2011072071A1/en not_active Ceased
- 2010-12-08 KR KR1020127017728A patent/KR20120124404A/ko not_active Withdrawn
- 2010-12-08 AU AU2010328139A patent/AU2010328139B2/en not_active Ceased
-
2012
- 2012-05-07 ZA ZA2012/03339A patent/ZA201203339B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007502246A (ja) * | 2003-07-28 | 2007-02-08 | ウィリアム・マーシュ・ライス・ユニバーシティ | ポリマー複合物を得るための、有機シランによるカーボンナノチューブのサイドウォール官能化 |
| JP2007523033A (ja) * | 2004-01-30 | 2007-08-16 | サーントル ナシオナル ドゥ ラ ルシェルシェ シャーンティフィク（セーエンヌエールエス） | 支持体に結合させたカーボンナノチューブ及びそれを含む複合体の製造方法 |
| WO2006082829A1 (ja) * | 2005-02-02 | 2006-08-10 | Otsuka Chemical Co., Ltd. | カーボンナノチューブ担持無機粒子 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7382460B1 (ja) | 2022-07-14 | 2023-11-16 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| WO2024014101A1 (ja) * | 2022-07-14 | 2024-01-18 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| JP2024011474A (ja) * | 2022-07-14 | 2024-01-25 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| WO2024053535A1 (ja) * | 2022-09-08 | 2024-03-14 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| JPWO2024053535A1 (https=) * | 2022-09-08 | 2024-03-14 | ||
| JP7568165B2 (ja) | 2022-09-08 | 2024-10-16 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| WO2025109800A1 (ja) * | 2023-11-21 | 2025-05-30 | 住友ゴム工業株式会社 | ラケット用ストリング |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2779709A1 (en) | 2011-06-16 |
| AU2010328139A1 (en) | 2012-05-31 |
| EP2509918A4 (en) | 2013-09-25 |
| US20110297892A1 (en) | 2011-12-08 |
| EP2509918A1 (en) | 2012-10-17 |
| AU2010328139B2 (en) | 2014-09-18 |
| BR112012013904A2 (pt) | 2016-04-26 |
| KR20120124404A (ko) | 2012-11-13 |
| ZA201203339B (en) | 2013-01-30 |
| CN102648155A (zh) | 2012-08-22 |
| WO2011072071A1 (en) | 2011-06-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2013513020A (ja) | 熱可塑性マトリックス中のｃｎｔ浸出繊維 | |
| JP5937009B2 (ja) | Ｃｎｔ導入アラミド繊維材料及びそのための方法 | |
| JP5823404B2 (ja) | Ｃｎｔ導入金属繊維材料及びそのための方法 | |
| JP2013511413A (ja) | 熱硬化性マトリックス中のｃｎｔ浸出繊維 | |
| CN102639771B (zh) | 并入cnt的陶瓷纤维材料及其方法 | |
| JP2013509507A5 (https=) | ||
| JP2013509504A5 (https=) | ||
| JP2015502311A (ja) | 再利用可能な基材上にカーボンナノチューブを連続的に製造するためのシステム及び方法 | |
| CN102598875A (zh) | 碳-碳复合材料中的并入cnt的纤维 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131202 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131202 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140716 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140826 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141126 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20150602 |