JP2013501728A5 - - Google Patents
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- Publication number
- JP2013501728A5 JP2013501728A5 JP2012523956A JP2012523956A JP2013501728A5 JP 2013501728 A5 JP2013501728 A5 JP 2013501728A5 JP 2012523956 A JP2012523956 A JP 2012523956A JP 2012523956 A JP2012523956 A JP 2012523956A JP 2013501728 A5 JP2013501728 A5 JP 2013501728A5
- Authority
- JP
- Japan
- Prior art keywords
- optionally substituted
- benzyl
- phenyl
- alkyl
- ring system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 34
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 28
- 125000004122 cyclic group Chemical group 0.000 claims description 24
- -1 C 1 -C 4 alkoxy Chemical group 0.000 claims description 18
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical class C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 16
- 229920006395 saturated elastomer Polymers 0.000 claims description 16
- 125000005842 heteroatom Chemical group 0.000 claims description 14
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims description 12
- 235000010290 biphenyl Nutrition 0.000 claims description 8
- 239000004305 biphenyl Substances 0.000 claims description 8
- 125000001624 naphthyl group Chemical class 0.000 claims description 8
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 claims description 4
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000006559 (C1-C3) alkylamino group Chemical group 0.000 claims description 2
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims description 2
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims description 2
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims description 2
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims description 2
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 claims description 2
- 125000006771 (C1-C6) haloalkylthio group Chemical group 0.000 claims description 2
- 125000005103 alkyl silyl group Chemical group 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims 6
- 244000053095 fungal pathogen Species 0.000 claims 2
- 235000017060 Arachis glabrata Nutrition 0.000 claims 1
- 244000105624 Arachis hypogaea Species 0.000 claims 1
- 235000010777 Arachis hypogaea Nutrition 0.000 claims 1
- 235000018262 Arachis monticola Nutrition 0.000 claims 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims 1
- 241000530549 Cercospora beticola Species 0.000 claims 1
- 240000008790 Musa x paradisiaca Species 0.000 claims 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims 1
- 241001281801 Mycosphaerella arachidis Species 0.000 claims 1
- 241001329956 Nothopassalora personata Species 0.000 claims 1
- 241000087479 Pseudocercospora fijiensis Species 0.000 claims 1
- 235000021536 Sugar beet Nutrition 0.000 claims 1
- 241000209140 Triticum Species 0.000 claims 1
- 235000021307 Triticum Nutrition 0.000 claims 1
- 241000228452 Venturia inaequalis Species 0.000 claims 1
- 241001360088 Zymoseptoria tritici Species 0.000 claims 1
- 239000012876 carrier material Substances 0.000 claims 1
- 230000002538 fungal effect Effects 0.000 claims 1
- 230000000855 fungicidal effect Effects 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 235000020232 peanut Nutrition 0.000 claims 1
- 230000008635 plant growth Effects 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23220409P | 2009-08-07 | 2009-08-07 | |
| US61/232,204 | 2009-08-07 | ||
| PCT/US2010/044592 WO2011017547A1 (en) | 2009-08-07 | 2010-08-05 | N1-sulfonyl-5-fluoropyrimidinone derivatives |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013501728A JP2013501728A (ja) | 2013-01-17 |
| JP2013501728A5 true JP2013501728A5 (enExample) | 2015-03-12 |
| JP5784603B2 JP5784603B2 (ja) | 2015-09-24 |
Family
ID=43535295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012523956A Active JP5784603B2 (ja) | 2009-08-07 | 2010-08-05 | Ｎ１−スルホニル−５−フルオロピリミジノン誘導体 |
Country Status (28)
| Country | Link |
|---|---|
| US (2) | US9006259B2 (enExample) |
| EP (1) | EP2462134B1 (enExample) |
| JP (1) | JP5784603B2 (enExample) |
| KR (1) | KR101743791B1 (enExample) |
| CN (1) | CN102574831B (enExample) |
| AU (1) | AU2010279411B2 (enExample) |
| BR (1) | BR112012002830B1 (enExample) |
| CA (1) | CA2769073C (enExample) |
| CL (1) | CL2012000309A1 (enExample) |
| CO (1) | CO6491082A2 (enExample) |
| CR (1) | CR20120029A (enExample) |
| DK (1) | DK2462134T3 (enExample) |
| EA (1) | EA022289B1 (enExample) |
| EC (1) | ECSP12011650A (enExample) |
| ES (1) | ES2471371T3 (enExample) |
| HN (1) | HN2012000263A (enExample) |
| IL (1) | IL217956A (enExample) |
| IN (1) | IN2012DN00692A (enExample) |
| MX (1) | MX2012001622A (enExample) |
| NI (1) | NI201200020A (enExample) |
| NZ (1) | NZ597644A (enExample) |
| PE (1) | PE20120691A1 (enExample) |
| PL (1) | PL2462134T3 (enExample) |
| PT (1) | PT2462134E (enExample) |
| RS (1) | RS53395B (enExample) |
| UA (1) | UA106764C2 (enExample) |
| WO (1) | WO2011017547A1 (enExample) |
| ZA (1) | ZA201200820B (enExample) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2549379T3 (es) * | 2008-01-22 | 2015-10-27 | Dow Agrosciences Llc | Derivados de 4-amino5-fluoropirimidina como fungicidas |
| UA112284C2 (uk) * | 2009-08-07 | 2016-08-25 | ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі | Похідні 5-фторпіримідинону |
| MX2012001622A (es) | 2009-08-07 | 2012-04-11 | Dow Agrosciences Llc | Derivados de n1-sulfonil-5-fluoropirimidinona. |
| UA107671C2 (en) | 2009-08-07 | 2015-02-10 | Dow Agrosciences Llc | N1-substityted-5-fluoro-2-oxopyrimidinone-1(2h)-carboxamide derivatives |
| UA106889C2 (uk) * | 2009-08-07 | 2014-10-27 | ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі | Похідні n1-ацил-5-фторпіримідинону |
| HUE042624T2 (hu) | 2009-10-07 | 2019-07-29 | Dow Agrosciences Llc | Szinergetikus fungicid keverékek gombák kontrollálására gabonafélékben |
| PT2521452E (pt) * | 2010-01-07 | 2015-02-24 | Dow Agrosciences Llc | Tiazolo[5,4-d]pirimidinas e a sua utilização como agroquímicos |
| JP5784705B2 (ja) | 2010-04-26 | 2015-09-24 | ダウ アグロサイエンシィズ エルエルシー | Ｎ３置換−ｎ１−スルホニル−５−フルオロピリミジノン誘導体 |
| WO2012108873A1 (en) * | 2011-02-11 | 2012-08-16 | Dow Agrosciences Llc | Stable agrochemical oil dispersions |
| EP2775842B1 (en) * | 2011-08-17 | 2017-10-04 | Adama Makhteshim Ltd. | 1-substituted-5-fluoro-3,6-dihydro-6-imino-2(1H)-pyrimidinone derivatives as fungicidal agents for use in plant protection |
| CA2888225A1 (en) * | 2012-11-12 | 2014-05-15 | Dow Agrosciences Llc | Pesticidal pyrimidine compounds |
| JP6336480B2 (ja) | 2012-12-28 | 2018-06-06 | アダマ・マクテシム・リミテッド | １−（置換ベンゾイル）−５−フルオロ−４−イミノ−３−メチル−３，４−ジヒドロピリミジン−２（１ｈ）−オンの誘導体 |
| LT2938191T (lt) | 2012-12-28 | 2018-05-10 | Dow Agrosciences Llc | Sinergistiniai fungicidiniai mišiniai, skirti grybelių kontrolei javuose |
| MX2015008444A (es) | 2012-12-28 | 2015-09-23 | Dow Agrosciences Llc | Derivados de n-(sustituido)-5-flouro-4-imino-3-metil-2-oxo-3,4-dih idropirimidin-1 (2h)-carboximida. |
| AU2013370493B2 (en) | 2012-12-28 | 2017-08-17 | Adama Makhteshim Ltd. | N-(substituted)-5-fluoro-4-imino-3-methyl-2-oxo-3,4-dihydropyrimidine-1 (2H)-carboxylate derivatives |
| DK2938190T3 (en) | 2012-12-31 | 2018-02-05 | Dow Agrosciences Llc | MACROCYCLIC PICOLINAMIDS AS FUNGICIDES |
| KR102309245B1 (ko) * | 2012-12-31 | 2021-10-06 | 아다마 마켓심 리미티드 | 살진균제로서의 3-알킬-5-플루오로-4-치환된-이미노-3,4-디히드로피리미딘-2(1h)-온 유도체 |
| DE102013007733A1 (de) * | 2013-05-07 | 2014-11-27 | Rainer Pommersheim | Verfahren und technischer Prozess zur kontinuierlichen Synthese von unterschiedlichen lonischen Flüssigkeiten |
| WO2015100184A1 (en) | 2013-12-26 | 2015-07-02 | Dow Agrosciences Llc | Use of macrocyclic picolinamides as fungicides |
| US9549555B2 (en) | 2013-12-26 | 2017-01-24 | Dow Agrosciences Llc | Macrocyclic picolinamide compounds with fungicidal activity |
| EA036389B1 (ru) * | 2013-12-31 | 2020-11-03 | Адама Мактешим Лтд. | 5-фтор-4-имино-3-(алкил/замещенный алкил)-1-(арилсульфонил)-3,4-дигидропиримидин-2(1h)-он и способы их получения |
| FI3096619T3 (fi) * | 2013-12-31 | 2025-09-03 | Adama Makhteshim Ltd | Synergistisiä sienituhoaineseoksia sienten torjuntaan viljakasveissa |
| WO2015171408A1 (en) | 2014-05-06 | 2015-11-12 | Dow Agrosciences Llc | Macrocyclic picolinamides as fungicides |
| EP3166936A4 (en) | 2014-07-08 | 2017-11-22 | Dow AgroSciences LLC | Macrocyclic picolinamides as fungicides |
| CN106470983A (zh) | 2014-07-08 | 2017-03-01 | 美国陶氏益农公司 | 作为杀真菌剂的大环吡啶酰胺 |
| WO2016048643A1 (en) | 2014-09-26 | 2016-03-31 | The Chemours Company Fc, Llc | Isocyanate derived organosilanes |
| WO2016109640A1 (en) | 2014-12-30 | 2016-07-07 | Dow Agrosciences Llc | Fungicidal compositions |
| US20170290333A1 (en) | 2014-12-30 | 2017-10-12 | Dow Agrosciences Llc | Picolinamide compounds with fungicidal activity |
| AU2015374375B2 (en) | 2014-12-30 | 2019-03-21 | Dow Agrosciences Llc | Picolinamides with fungicidal activity |
| EP3240412A4 (en) | 2014-12-30 | 2018-04-25 | Dow Agrosciences LLC | Use of picolinamide compounds with fungicidal activity |
| NZ732812A (en) | 2014-12-30 | 2019-01-25 | Dow Agrosciences Llc | Use of picolinamides and other compounds as fungicides |
| CA2972408A1 (en) | 2014-12-30 | 2016-07-07 | Dow Agrosciences Llc | Use of picolinamide compounds with fungicidal activity |
| JP6922272B2 (ja) | 2016-03-11 | 2021-08-18 | 住友化学株式会社 | 植物病害防除組成物及び植物病害防除方法 |
| JP6862939B2 (ja) | 2016-03-11 | 2021-04-21 | 住友化学株式会社 | 植物病害防除組成物及び植物病害防除方法 |
| JP6922271B2 (ja) * | 2016-03-11 | 2021-08-18 | 住友化学株式会社 | 植物病害防除組成物及び植物病害防除方法 |
| WO2018044987A1 (en) | 2016-08-30 | 2018-03-08 | Dow Agrosciences Llc | Thiopicolinamide compounds with fungicidal activity |
| WO2018045003A1 (en) | 2016-08-30 | 2018-03-08 | Dow Agrosciences Llc | Picolinamide n-oxide compounds with fungicidal activity |
| US10214490B2 (en) | 2016-08-30 | 2019-02-26 | Dow Agrosciences Llc | Picolinamides as fungicides |
| US10334852B2 (en) | 2016-08-30 | 2019-07-02 | Dow Agrosciences Llc | Pyrido-1,3-oxazine-2,4-dione compounds with fungicidal activity |
| BR102018000183B1 (pt) | 2017-01-05 | 2023-04-25 | Dow Agrosciences Llc | Picolinamidas, composição para controle de um patógeno fúngico, e método para controle e prevenção de um ataque por fungos em uma planta |
| TW201842851A (zh) | 2017-05-02 | 2018-12-16 | 美商陶氏農業科學公司 | 用於穀類中的真菌防治之協同性混合物 |
| TWI774761B (zh) | 2017-05-02 | 2022-08-21 | 美商科迪華農業科技有限責任公司 | 用於穀物中的真菌防治之協同性混合物 |
| CN110996665B (zh) | 2017-05-02 | 2021-10-26 | 陶氏益农公司 | 无环吡啶酰胺化合物作为针对草坪草上的真菌病害的杀真菌剂的用途 |
| EP3655396A1 (en) | 2017-07-17 | 2020-05-27 | Adama Makhteshim Ltd. | Polymorphs of 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one |
| BR102019004480B1 (pt) | 2018-03-08 | 2023-03-28 | Dow Agrosciences Llc | Picolinamidas como fungicidas |
| US11639334B2 (en) | 2018-10-15 | 2023-05-02 | Corteva Agriscience Llc | Methods for synthesis of oxypicolinamides |
| US12414559B2 (en) | 2018-11-05 | 2025-09-16 | Adama Makhteshim Ltd. | Mixtures and compositions comprising 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2-one, and methods of use thereof |
| WO2021059160A1 (en) | 2019-09-23 | 2021-04-01 | Adama Makhteshim Ltd. | Process for preparing 5-(fluoro-4-imino-3-methyl)-1-tosyl-3,4 dihydropyrimidine -(1h)-one |
| EP4044811A4 (en) | 2019-10-18 | 2023-09-27 | Corteva Agriscience LLC | METHOD FOR SYNTHESIS OF PICOLINAMIDS |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3309359A (en) * | 1965-10-22 | 1967-03-14 | Hoffmann La Roche | N-mono-acyl-5-fluorocytosine derivatives and process |
| US3368938A (en) * | 1966-01-13 | 1968-02-13 | Hoffmann La Roche | Controlling fungi with 5-fluorocytosine |
| US3868373A (en) * | 1970-01-27 | 1975-02-25 | Hoffmann La Roche | 4-Amino-5-fluoro-2-tri(lower alkyl) silyloxypyrimidines |
| CH579057A5 (enExample) | 1973-09-07 | 1976-08-31 | Hoffmann La Roche | |
| FR2530636A1 (fr) | 1982-07-23 | 1984-01-27 | Rhone Poulenc Agrochimie | Nouveaux derives de la tetrahydro-2,3,6,7 5h-thiazolo (3,2-a) pyrimidine, leur preparation et leur utilisation comme herbicides |
| GR80171B (en) | 1983-08-29 | 1985-01-02 | Ciba Geigy Ag | N-(2-nitrophenyl)-4-aminopyrimidine derivatives process for the preparation thereof and use |
| US4845081A (en) * | 1984-10-18 | 1989-07-04 | University Of Florida | Aminomethyl derivatives of biologically active substances, and enhanced delivery thereof across topical membranes |
| DE58908159D1 (de) | 1988-03-09 | 1994-09-15 | Ciba Geigy Ag | Mittel zum Schutz von Pflanzen gegen Krankheiten. |
| DE3821711A1 (de) * | 1988-06-28 | 1990-02-08 | Bayer Ag | Thiazolopyrimidin-derivate, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
| JP3109012B2 (ja) | 1992-06-18 | 2000-11-13 | クミアイ化学工業株式会社 | チアゾロ［５，４−ｄ］ピリミジン誘導体及び農園芸用殺菌剤 |
| JP3217191B2 (ja) * | 1992-07-16 | 2001-10-09 | ビーエーエスエフ アクチェンゲゼルシャフト | ヘテロ芳香族化合物およびこれを含有する植物保護剤 |
| DE69618959T2 (de) * | 1995-07-05 | 2002-08-29 | E.I. Du Pont De Nemours And Co., Wilmington | Pyrimidone und ihre verwendug als fungizide |
| US6262058B1 (en) | 1996-03-11 | 2001-07-17 | Syngenta Crop Protection, Inc. | Pyrimidin-4-one derivatives as pesticide |
| HRP970239B1 (en) * | 1997-05-09 | 2004-04-30 | Inst Ru Er Bouekovic | Process for the preparation of sulfonyl-pyrimidine derivatives with antitumor activity |
| GT199900185A (es) * | 1998-11-06 | 2001-04-18 | Novedosa pirimidin-4-enamina como fungicida. | |
| MXPA03003278A (es) * | 2000-10-13 | 2005-07-01 | Shire Biochem Inc | Analogos de dioxolano para suministro intercelular mejorado. |
| US7914799B2 (en) * | 2001-08-27 | 2011-03-29 | Immunitor USA, Inc. | Anti-fungal composition |
| US20080269238A1 (en) * | 2004-04-01 | 2008-10-30 | Takeda Pharmaceutical Company Limited | Thiazolopyrimidine Derivative |
| US20080004253A1 (en) * | 2006-06-30 | 2008-01-03 | Bryan James Branstetter | Thiazolopyrimidine modulators of TRPV1 |
| US20100056468A1 (en) * | 2007-01-08 | 2010-03-04 | University Health Network | Pyrimidine Derivatives As Anticancer Agents |
| ES2549379T3 (es) * | 2008-01-22 | 2015-10-27 | Dow Agrosciences Llc | Derivados de 4-amino5-fluoropirimidina como fungicidas |
| PL2317851T3 (pl) | 2008-08-01 | 2014-06-30 | Dow Agrosciences Llc | Zastosowanie 5-fluorocytozyny jako fungicydu |
| DK2389375T3 (en) | 2009-01-23 | 2015-08-24 | Euro Celtique Sa | Hydroxamsyrederivater |
| MX2012001622A (es) | 2009-08-07 | 2012-04-11 | Dow Agrosciences Llc | Derivados de n1-sulfonil-5-fluoropirimidinona. |
| UA106889C2 (uk) * | 2009-08-07 | 2014-10-27 | ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі | Похідні n1-ацил-5-фторпіримідинону |
| UA107671C2 (en) * | 2009-08-07 | 2015-02-10 | Dow Agrosciences Llc | N1-substityted-5-fluoro-2-oxopyrimidinone-1(2h)-carboxamide derivatives |
| UA112284C2 (uk) * | 2009-08-07 | 2016-08-25 | ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі | Похідні 5-фторпіримідинону |
| ES2506169T3 (es) * | 2009-08-07 | 2014-10-13 | Dow Agrosciences Llc | Derivados de 5-fluoro-2-oxopirimidina-1(2H)-carboxilato como fungicidas |
| JP5784705B2 (ja) * | 2010-04-26 | 2015-09-24 | ダウ アグロサイエンシィズ エルエルシー | Ｎ３置換−ｎ１−スルホニル−５−フルオロピリミジノン誘導体 |
-
2010
- 2010-08-05 MX MX2012001622A patent/MX2012001622A/es active IP Right Grant
- 2010-08-05 NZ NZ597644A patent/NZ597644A/en unknown
- 2010-08-05 CA CA2769073A patent/CA2769073C/en active Active
- 2010-08-05 CN CN201080045334.0A patent/CN102574831B/zh active Active
- 2010-08-05 BR BR112012002830-8A patent/BR112012002830B1/pt active IP Right Grant
- 2010-08-05 ES ES10807177.0T patent/ES2471371T3/es active Active
- 2010-08-05 PL PL10807177T patent/PL2462134T3/pl unknown
- 2010-08-05 KR KR1020127005933A patent/KR101743791B1/ko not_active Expired - Fee Related
- 2010-08-05 AU AU2010279411A patent/AU2010279411B2/en active Active
- 2010-08-05 RS RS20140342A patent/RS53395B/sr unknown
- 2010-08-05 US US12/851,357 patent/US9006259B2/en active Active
- 2010-08-05 WO PCT/US2010/044592 patent/WO2011017547A1/en not_active Ceased
- 2010-08-05 PT PT108071770T patent/PT2462134E/pt unknown
- 2010-08-05 JP JP2012523956A patent/JP5784603B2/ja active Active
- 2010-08-05 EP EP10807177.0A patent/EP2462134B1/en active Active
- 2010-08-05 UA UAA201202729A patent/UA106764C2/uk unknown
- 2010-08-05 IN IN692DEN2012 patent/IN2012DN00692A/en unknown
- 2010-08-05 EA EA201270257A patent/EA022289B1/ru not_active IP Right Cessation
- 2010-08-05 PE PE2012000168A patent/PE20120691A1/es not_active Application Discontinuation
- 2010-08-05 DK DK10807177.0T patent/DK2462134T3/da active
-
2012
- 2012-01-18 CR CR20120029A patent/CR20120029A/es unknown
- 2012-01-26 CO CO12011674A patent/CO6491082A2/es active IP Right Grant
- 2012-02-02 ZA ZA2012/00820A patent/ZA201200820B/en unknown
- 2012-02-02 HN HN2012000263A patent/HN2012000263A/es unknown
- 2012-02-03 NI NI201200020A patent/NI201200020A/es unknown
- 2012-02-05 IL IL217956A patent/IL217956A/en active IP Right Grant
- 2012-02-06 CL CL2012000309A patent/CL2012000309A1/es unknown
- 2012-02-07 EC ECSP12011650 patent/ECSP12011650A/es unknown
-
2015
- 2015-03-18 US US14/661,274 patent/US9862686B2/en active Active
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