JP2013072096A - 有機無機複合物およびその製造方法 - Google Patents
有機無機複合物およびその製造方法 Download PDFInfo
- Publication number
- JP2013072096A JP2013072096A JP2011210082A JP2011210082A JP2013072096A JP 2013072096 A JP2013072096 A JP 2013072096A JP 2011210082 A JP2011210082 A JP 2011210082A JP 2011210082 A JP2011210082 A JP 2011210082A JP 2013072096 A JP2013072096 A JP 2013072096A
- Authority
- JP
- Japan
- Prior art keywords
- organic
- inorganic composite
- gold
- substrate
- fine particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 58
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 11
- -1 thiol compound Chemical class 0.000 claims abstract description 52
- 229910052751 metal Inorganic materials 0.000 claims abstract description 39
- 239000002184 metal Substances 0.000 claims abstract description 38
- 239000000758 substrate Substances 0.000 claims abstract description 38
- 229910000077 silane Inorganic materials 0.000 claims abstract description 10
- 239000010419 fine particle Substances 0.000 claims description 78
- 239000003990 capacitor Substances 0.000 claims description 12
- 239000007784 solid electrolyte Substances 0.000 claims description 10
- VRVRGVPWCUEOGV-UHFFFAOYSA-N 2-aminothiophenol Chemical compound NC1=CC=CC=C1S VRVRGVPWCUEOGV-UHFFFAOYSA-N 0.000 claims description 9
- WCDSVWRUXWCYFN-UHFFFAOYSA-N 4-aminobenzenethiol Chemical compound NC1=CC=C(S)C=C1 WCDSVWRUXWCYFN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 24
- 229920001940 conductive polymer Polymers 0.000 abstract description 20
- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- 230000001590 oxidative effect Effects 0.000 abstract description 7
- 239000011859 microparticle Substances 0.000 abstract description 5
- 239000006185 dispersion Substances 0.000 abstract description 3
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000013528 metallic particle Substances 0.000 abstract 1
- 239000010931 gold Substances 0.000 description 52
- 229910052737 gold Inorganic materials 0.000 description 52
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 45
- 239000000463 material Substances 0.000 description 24
- 239000002245 particle Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 19
- 239000002923 metal particle Substances 0.000 description 17
- 239000007864 aqueous solution Substances 0.000 description 15
- 238000001179 sorption measurement Methods 0.000 description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000001878 scanning electron micrograph Methods 0.000 description 9
- 229910052709 silver Inorganic materials 0.000 description 9
- 239000004332 silver Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 229920000767 polyaniline Polymers 0.000 description 8
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- SWEDAZLCYJDAGW-UHFFFAOYSA-N Thiophene-2-thiol Chemical compound SC1=CC=CS1 SWEDAZLCYJDAGW-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 5
- 150000002343 gold Chemical class 0.000 description 5
- AQXLMAYNBMTBHD-UHFFFAOYSA-N 2-methyl-3-thiophenethiol Chemical compound CC=1SC=CC=1S AQXLMAYNBMTBHD-UHFFFAOYSA-N 0.000 description 4
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LTQBNYCMVZQRSD-UHFFFAOYSA-N (4-ethenylphenyl)-trimethoxysilane Chemical compound CO[Si](OC)(OC)C1=CC=C(C=C)C=C1 LTQBNYCMVZQRSD-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 3
- OTARVPUIYXHRRB-UHFFFAOYSA-N diethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](C)(OCC)CCCOCC1CO1 OTARVPUIYXHRRB-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000123 polythiophene Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 3
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- IHTLZNZYAZTKSG-UHFFFAOYSA-N 5-methylthiophene-2-thiol Chemical compound CC1=CC=C(S)S1 IHTLZNZYAZTKSG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- 239000012448 Lithium borohydride Substances 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 2
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 2
- UDUKMRHNZZLJRB-UHFFFAOYSA-N triethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OCC)(OCC)OCC)CCC2OC21 UDUKMRHNZZLJRB-UHFFFAOYSA-N 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- HRBMEPMLYZZHKC-UHFFFAOYSA-N 2-aminobenzenethiol;gold Chemical compound [Au].NC1=CC=CC=C1S HRBMEPMLYZZHKC-UHFFFAOYSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- BEJDETDZZZNPDG-UHFFFAOYSA-J O.O.O.[Cl-].[Cl-].[Cl-].[Cl-].[Au+4] Chemical compound O.O.O.[Cl-].[Cl-].[Cl-].[Cl-].[Au+4] BEJDETDZZZNPDG-UHFFFAOYSA-J 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 1
- XRJMSNBQLMFVGI-UHFFFAOYSA-N aniline;gold Chemical compound [Au].NC1=CC=CC=C1 XRJMSNBQLMFVGI-UHFFFAOYSA-N 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000002801 charged material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910003471 inorganic composite material Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- WHRAZOIDGKIQEA-UHFFFAOYSA-L iron(2+);4-methylbenzenesulfonate Chemical compound [Fe+2].CC1=CC=C(S([O-])(=O)=O)C=C1.CC1=CC=C(S([O-])(=O)=O)C=C1 WHRAZOIDGKIQEA-UHFFFAOYSA-L 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001028 reflection method Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
- H01G9/0036—Formation of the solid electrolyte layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/12—Gold compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
- C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/90—Applications
- C08G2261/96—Applications coating of particles
- C08G2261/964—Applications coating of particles coating of inorganic particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Power Engineering (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Conductive Materials (AREA)
Abstract
【解決手段】表面にチオール化合物を配位させた金属微粒子であり、シラン化合物を介して基板に吸着し、表面のチオール化合物を酸化重合することにより、導電性高分子503が金属微粒子502表面に配位結合した構造をとることを特徴とする。
【選択図】図1
Description
比較例として、金属粒子を導電性高分子が被覆しているが、配位していない有機無機複合物を作製した。アニリンの水溶液に0.03%の塩化金錯体水溶液200mlを加えた後、65℃で30分攪拌することで、アニリン中に金微粒子が取り込まれた、アニリンと金微粒子が化学的に結合していない、アニリン−金微粒子複合材料を得た。この材料の電気伝導度を測定したところ、3.0×10-2Scm-1であった。
比較例として、チオール化合物が金属粒子に配位子しているが、重合していない有機無機複合物を作製した。金コロイド溶液22.5ml中に基板を浸漬し、攪拌した。その後、3.1mmol和光純薬工業(株)製2−アミノチオフェノールを投入し、溶液の色が無色透明になるまで攪拌し、2−アミノチオフェノール−金微粒子複合材料を得た。この材料の電気伝導度を測定したところ、833Scm-1であった。
比較例として、固体電解質層に導電性高分子として、ポリエチレンジオキシチオフェンを使用してコンデンサを作製した。周波数100kHzにおける等価回路抵抗は0.25Ωであった。
500(b) ポリアニリン−金微粒子複合物の拡大像
501、502、505 金微粒子
503 ポリアニリン
504 ポリアニリン−ブタンチオール金微粒子複合物の全体像
506 ポリアニリン−ブタンチオール修飾金微粒子複合物の断面のSEM像
507 埋め込み樹脂
508 基板
509 金粒子
510 コンデンサ断面
511 外装
512 陰極端子
513 銀ペースト
514 固体電解質層
515 誘電体酸化層
516 絶縁層
517 陽極
518 陽極用リード
519 陽極端子
520 有機−無機複合物接着面
521 シランカップリング剤
522 金属微粒子
523 導電性高分子
Claims (7)
- 金属微粒子と、
各金属微粒子表面に配位する2−または4−アミノチオフェノールと、2−または5−チエニルのうちのいずれかのチオール化合物の重合物からなる有機無機複合物。 - 請求項1に記載の有機無機複合物であって、
シラン化合物により表面処理された基板を有する有機無機複合物。 - 請求項1または2に記載の有機無機複合物であって、
直鎖状のチオール化合物を有する有機無機複合物。 - 請求項1乃至3のいずれかに記載の有機無機複合物から構成される固体電解質層を有するコンデンサ。
- 金属微粒子を分散させた溶液に基板を浸漬する工程と、
前記溶液に2−または4−アミノチオフェノールと、2−または5−チエニルのうちのいずれかのチオール化合物を入れて攪拌する工程と、
前記チオール化合物を酸化重合する工程を有する有機無機複合物の製造方法。 - 請求項5に記載の有機無機複合物の製造方法であって、
前記基板を浸漬する工程の前に、前記基板をシラン化合物により表面処理する工程を有する有機無機複合物の製造方法。 - 請求項5または6に記載の有機無機複合物の製造方法であって、
前記シラン化合物はエポキシ基を有している有機無機複合物の製造方法。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011210082A JP2013072096A (ja) | 2011-09-27 | 2011-09-27 | 有機無機複合物およびその製造方法 |
CN201280039936.4A CN103732797A (zh) | 2011-09-27 | 2012-08-02 | 有机无机复合物及其制造方法 |
US14/238,910 US20140211373A1 (en) | 2011-09-27 | 2012-08-02 | Organic-inorganic composite and method for manufacturing the same |
PCT/JP2012/069685 WO2013046917A1 (ja) | 2011-09-27 | 2012-08-02 | 有機無機複合物およびその製造方法 |
EP12837085.5A EP2762610A1 (en) | 2011-09-27 | 2012-08-02 | Organic-inorganic composite and method for manufacturing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011210082A JP2013072096A (ja) | 2011-09-27 | 2011-09-27 | 有機無機複合物およびその製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2013072096A true JP2013072096A (ja) | 2013-04-22 |
Family
ID=47994971
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011210082A Pending JP2013072096A (ja) | 2011-09-27 | 2011-09-27 | 有機無機複合物およびその製造方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20140211373A1 (ja) |
EP (1) | EP2762610A1 (ja) |
JP (1) | JP2013072096A (ja) |
CN (1) | CN103732797A (ja) |
WO (1) | WO2013046917A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105002488A (zh) * | 2015-04-10 | 2015-10-28 | 深圳市美克科技有限公司 | 一种线路板和焊接组件的金属镀层表面防护封孔方法 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140170427A1 (en) * | 2012-12-13 | 2014-06-19 | Carestream Health, Inc. | Anticorrosion agents for transparent conductive film |
ITUB20152574A1 (it) * | 2015-07-29 | 2017-01-29 | Hft Smartsensors Inc | Sensore elettrochimico organico per la misurazione di parametri corporei |
KR101929623B1 (ko) | 2016-10-28 | 2018-12-14 | 고려대학교 산학협력단 | 플렉시블 전극 및 이의 제조방법 |
CN108975383B (zh) * | 2018-08-29 | 2020-08-11 | 淮阴师范学院 | 多孔Ag/AgBr纳米材料的制备方法 |
CN110014167A (zh) * | 2019-04-22 | 2019-07-16 | 重庆大学 | 金基银球表面增强材料和变压器油中糠醛的检测方法 |
CN115522206B (zh) * | 2022-09-30 | 2023-08-15 | 深圳市豪龙新材料技术有限公司 | 一种腔体滤波器表面处理方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01123825A (ja) * | 1987-11-09 | 1989-05-16 | Fujikura Ltd | 導電性有機重合体の製法 |
JP3276922B2 (ja) * | 1998-06-09 | 2002-04-22 | 三ツ星ベルト株式会社 | 金属微粒子修飾基板の製造方法 |
JP2003335969A (ja) * | 2002-02-28 | 2003-11-28 | Osaka Industrial Promotion Organization | 複合化導電性高分子およびその製造方法並びにそれを用いたガスセンサー |
JP2004098246A (ja) * | 2002-09-11 | 2004-04-02 | Japan Science & Technology Corp | ナノスケール山谷構造基板を用いた金ナノ粒子一次元鎖列の製造法 |
JP2007531802A (ja) * | 2004-03-19 | 2007-11-08 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性有機ポリマー/ナノ粒子複合材料およびその使用方法 |
JP2010095688A (ja) * | 2008-10-20 | 2010-04-30 | Three M Innovative Properties Co | 導電性高分子複合体及び導電性高分子材料を用いた熱電素子 |
JP2011071087A (ja) * | 2009-03-12 | 2011-04-07 | Sanyo Electric Co Ltd | 導電性高分子膜、電子デバイス、及びこれらの製造方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1160581A (ja) | 1997-08-21 | 1999-03-02 | Mitsui Chem Inc | 金超微粒子反応試剤 |
TW557237B (en) * | 2001-09-14 | 2003-10-11 | Sekisui Chemical Co Ltd | Coated conductive particle, coated conductive particle manufacturing method, anisotropic conductive material, and conductive connection structure |
-
2011
- 2011-09-27 JP JP2011210082A patent/JP2013072096A/ja active Pending
-
2012
- 2012-08-02 WO PCT/JP2012/069685 patent/WO2013046917A1/ja active Application Filing
- 2012-08-02 EP EP12837085.5A patent/EP2762610A1/en not_active Withdrawn
- 2012-08-02 CN CN201280039936.4A patent/CN103732797A/zh active Pending
- 2012-08-02 US US14/238,910 patent/US20140211373A1/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01123825A (ja) * | 1987-11-09 | 1989-05-16 | Fujikura Ltd | 導電性有機重合体の製法 |
JP3276922B2 (ja) * | 1998-06-09 | 2002-04-22 | 三ツ星ベルト株式会社 | 金属微粒子修飾基板の製造方法 |
JP2003335969A (ja) * | 2002-02-28 | 2003-11-28 | Osaka Industrial Promotion Organization | 複合化導電性高分子およびその製造方法並びにそれを用いたガスセンサー |
JP2004098246A (ja) * | 2002-09-11 | 2004-04-02 | Japan Science & Technology Corp | ナノスケール山谷構造基板を用いた金ナノ粒子一次元鎖列の製造法 |
JP2007531802A (ja) * | 2004-03-19 | 2007-11-08 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性有機ポリマー/ナノ粒子複合材料およびその使用方法 |
JP2010095688A (ja) * | 2008-10-20 | 2010-04-30 | Three M Innovative Properties Co | 導電性高分子複合体及び導電性高分子材料を用いた熱電素子 |
JP2011071087A (ja) * | 2009-03-12 | 2011-04-07 | Sanyo Electric Co Ltd | 導電性高分子膜、電子デバイス、及びこれらの製造方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105002488A (zh) * | 2015-04-10 | 2015-10-28 | 深圳市美克科技有限公司 | 一种线路板和焊接组件的金属镀层表面防护封孔方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103732797A (zh) | 2014-04-16 |
EP2762610A1 (en) | 2014-08-06 |
WO2013046917A1 (ja) | 2013-04-04 |
US20140211373A1 (en) | 2014-07-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2013046917A1 (ja) | 有機無機複合物およびその製造方法 | |
JP6193245B2 (ja) | カプセル化バリアスタック | |
AU2014260477B2 (en) | Encapsulation barrier stack comprising dendrimer encapsulated nanoparticles | |
Jin et al. | Annealing-free and strongly adhesive silver nanowire networks with long-term reliability by introduction of a nonconductive and biocompatible polymer binder | |
Tong et al. | Graphene based materials and their composites as coatings | |
KR101224020B1 (ko) | 유연 전자소자용 전도성 고분자-금속 나노입자 하이브리드 투명전극필름 및 이의 제조방법 | |
Wang et al. | Transparent conductive thin films based on polyaniline nanofibers | |
CN104973805A (zh) | 导电聚合物-石墨烯复合电致变色薄膜及其制备方法 | |
CN102577638B (zh) | 用于自组装单层(sam)的介电保护层 | |
JP2002298936A (ja) | 光電変換素子、及びその製造方法 | |
Martin-Gallego et al. | Gold-functionalized graphene as conductive filler in UV-curable epoxy resin | |
Yang et al. | Fabrication and characterization of core/shell structured TiO2/polyaniline nanocomposite | |
US20210324208A1 (en) | Copper based conductive paste and its preparation method | |
Zhang et al. | A facile and economical process for high-performance and flexible transparent conductive film based on reduced graphene oxides and silver nanowires | |
JP4318414B2 (ja) | 気相重合法による伝導性高分子の合成方法及びその製造物 | |
Chen et al. | Fabrication of PTCA-PANI composites for electromagnetic wave absorption and corrosion protection | |
TW201044463A (en) | Transparent conductive film encapsulating mesh-like structure formed from metal microparticles, substrate on which transparent conductive film is laminated, and method for producing the same | |
EP3421545A1 (en) | Composite material, conductive material, conductive particles, and conductive film | |
US10854352B1 (en) | Conducting films and methods for forming them | |
Kim et al. | Influence of dispersion of multi-walled carbon nanotubes on the electrochemical performance of PEDOT–PSS films | |
Zhang et al. | Preparation of silver-coated silica microspheres with high electrical conductivity through Pyrogallol-Fe (Ш) coordinated surface functionalization | |
Xie et al. | Well encapsulated hollow borosilicate glass sphere@ polypyrrole composite with low density, designable thickness and conductivity | |
CN104584161B (zh) | 有机导电体、有机导电体的制造方法、电子设备、及固体电解电容器 | |
Fallahian et al. | Preparation of conductive, flexible and transparent films by in situ deposition of polypyrrole nanoparticles on polyethylene terephthalate | |
JP2017188378A (ja) | 有機導電膜およびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130305 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140401 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140530 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150106 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150220 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20150707 |