JP2013023715A - 多孔質アルミニウム材料の製造方法 - Google Patents
多孔質アルミニウム材料の製造方法 Download PDFInfo
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- JP2013023715A JP2013023715A JP2011157709A JP2011157709A JP2013023715A JP 2013023715 A JP2013023715 A JP 2013023715A JP 2011157709 A JP2011157709 A JP 2011157709A JP 2011157709 A JP2011157709 A JP 2011157709A JP 2013023715 A JP2013023715 A JP 2013023715A
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- Prior art keywords
- aluminum
- water
- organic solvent
- porous
- soluble substance
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 126
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 119
- 239000000463 material Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000003960 organic solvent Substances 0.000 claims abstract description 57
- 239000000126 substance Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002659 electrodeposit Substances 0.000 claims abstract description 22
- 239000002245 particle Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 25
- 238000004070 electrodeposition Methods 0.000 claims description 14
- 239000013618 particulate matter Substances 0.000 claims description 14
- -1 aluminum halide Chemical class 0.000 claims description 12
- 238000005245 sintering Methods 0.000 abstract description 4
- 235000002639 sodium chloride Nutrition 0.000 description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 10
- 239000008187 granular material Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 8
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 8
- 229910001416 lithium ion Inorganic materials 0.000 description 8
- 239000011148 porous material Substances 0.000 description 7
- 238000000151 deposition Methods 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 4
- 150000003457 sulfones Chemical class 0.000 description 4
- 239000000758 substrate Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229910001508 alkali metal halide Inorganic materials 0.000 description 2
- 150000008045 alkali metal halides Chemical class 0.000 description 2
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- AIDFJGKWTOULTC-UHFFFAOYSA-N 1-butylsulfonylbutane Chemical compound CCCCS(=O)(=O)CCCC AIDFJGKWTOULTC-UHFFFAOYSA-N 0.000 description 1
- MBDUIEKYVPVZJH-UHFFFAOYSA-N 1-ethylsulfonylethane Chemical compound CCS(=O)(=O)CC MBDUIEKYVPVZJH-UHFFFAOYSA-N 0.000 description 1
- JEXYCADTAFPULN-UHFFFAOYSA-N 1-propylsulfonylpropane Chemical compound CCCS(=O)(=O)CCC JEXYCADTAFPULN-UHFFFAOYSA-N 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- CECABOMBVQNBEC-UHFFFAOYSA-K aluminium iodide Chemical compound I[Al](I)I CECABOMBVQNBEC-UHFFFAOYSA-K 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Electroplating Methods And Accessories (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Abstract
【解決手段】多孔質構造を有するアルミニウム材料を製造する方法であって、有機溶媒に対して不溶の水溶性物質の粒状物および当該有機溶媒の存在下でアルミニウムを電析させた後、当該アルミニウムの電析によって得られた電析物に含まれている水溶性物質の粒状物を水に溶解させ、当該水溶性物質の粒状物を電析物から除去することを特徴とする多孔質アルミニウム材料の製造方法。
【選択図】図1
Description
(1) 多孔質構造を有するアルミニウム材料を製造する方法であって、有機溶媒に対して不溶の水溶性物質の粒状物および当該有機溶媒の存在下でアルミニウムを電析させた後、当該アルミニウムの電析によって得られた電析物に含まれている水溶性物質の粒状物を水に溶解させ、当該水溶性物質の粒状物を電析物から除去することを特徴とする多孔質アルミニウム材料の製造方法、
(2) アルミニウム原料としてアルミニウムハロゲン化物を用い、当該アルミニウムハロゲン化物を前記有機溶媒に溶解させた溶液および当該有機溶媒に対して不溶の水溶性物質の粒状物の存在下でアルミニウムを電析させる前記(1)に記載の多孔質アルミニウム材料の製造方法、および
(3) 前記(1)または(2)に記載の製造方法によって得られた多孔質アルミニウム材料
に関する。
(R1)2SO2 (I)
(式中、R1は、それぞれ独立して1〜4のアルキル基を示す)
で表されるジアルキルスルホンが好ましい。ジアルキルスルホンとしては、例えば、ジメチルスルホン、ジエチルスルホン、ジプロピルスルホン、ジブチルスルホンなどが挙げられるが、本発明は、かかる例示のみに限定されるものではない。これらのジアルキルスルホンは、それぞれ単独で用いてもよく、2種類以上を併用してもよい。これらのジアルキルスルホンのなかでは、アルミニウムの電析を効率よく行なう観点から、ジメチルスルホンが好ましい。
ジメチルスルホンと塩化アルミニウムとをモル比で10:2の割合で混合し、得られた混合物をガラス製の電解槽内に入れ、110℃の温度に加熱し、塩化アルミニウムを溶解させることにより、塩化アルミニウム溶液を得た。
Claims (3)
- 多孔質構造を有するアルミニウム材料を製造する方法であって、有機溶媒および当該有機溶媒に対して不溶の水溶性物質の粒状物の存在下でアルミニウムを電析させた後、当該アルミニウムの電析によって得られた電析物に含まれている水溶性物質の粒状物を水に溶解させ、当該水溶性物質の粒状物を電析物から除去することを特徴とする多孔質アルミニウム材料の製造方法。
- アルミニウム原料としてアルミニウムハロゲン化物を用い、当該アルミニウムハロゲン化物を前記有機溶媒に溶解させた溶液および当該有機溶媒に対して不溶の水溶性物質の粒状物の存在下でアルミニウムを電析させる請求項1に記載の多孔質アルミニウム材料の製造方法。
- 請求項1または2に記載の製造方法によって得られた多孔質アルミニウム材料。
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Cited By (1)
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CN105895926A (zh) * | 2016-05-16 | 2016-08-24 | 张升亮 | 一种微孔铝箔的制备方法及由该方法制得的微孔铝箔 |
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CN102965707B (zh) * | 2012-07-23 | 2016-05-18 | 贵州航天精工制造有限公司 | 一种用二硫化钼液体润滑剂电着固体润滑膜的方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2006519312A (ja) * | 2003-03-05 | 2006-08-24 | グローバル イオニックス インコーポレイテッド | 非芳香族の有機溶媒からのアルミニウムおよび耐熱金属の電着 |
JP2006233272A (ja) * | 2005-02-24 | 2006-09-07 | Univ Waseda | メソポーラス金属膜の製造方法 |
JP2009280892A (ja) * | 2008-05-26 | 2009-12-03 | National Institute For Materials Science | 均一な孔大きさを有する大細孔径メソポーラス金属の製造方法 |
JP2010232171A (ja) * | 2009-03-05 | 2010-10-14 | Hitachi Metals Ltd | アルミニウム多孔質材およびその製造方法、アルミニウム多孔質材を電極集電体として用いた蓄電デバイス |
WO2011001932A1 (ja) * | 2009-06-29 | 2011-01-06 | 日立金属株式会社 | アルミニウム箔の製造方法 |
JP2012255185A (ja) * | 2011-06-08 | 2012-12-27 | Sumitomo Electric Ind Ltd | アルミニウム多孔体の製造方法及び製造装置 |
-
2011
- 2011-07-19 JP JP2011157709A patent/JP5737677B2/ja not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006519312A (ja) * | 2003-03-05 | 2006-08-24 | グローバル イオニックス インコーポレイテッド | 非芳香族の有機溶媒からのアルミニウムおよび耐熱金属の電着 |
JP2006233272A (ja) * | 2005-02-24 | 2006-09-07 | Univ Waseda | メソポーラス金属膜の製造方法 |
JP2009280892A (ja) * | 2008-05-26 | 2009-12-03 | National Institute For Materials Science | 均一な孔大きさを有する大細孔径メソポーラス金属の製造方法 |
JP2010232171A (ja) * | 2009-03-05 | 2010-10-14 | Hitachi Metals Ltd | アルミニウム多孔質材およびその製造方法、アルミニウム多孔質材を電極集電体として用いた蓄電デバイス |
WO2011001932A1 (ja) * | 2009-06-29 | 2011-01-06 | 日立金属株式会社 | アルミニウム箔の製造方法 |
JP2012255185A (ja) * | 2011-06-08 | 2012-12-27 | Sumitomo Electric Ind Ltd | アルミニウム多孔体の製造方法及び製造装置 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105895926A (zh) * | 2016-05-16 | 2016-08-24 | 张升亮 | 一种微孔铝箔的制备方法及由该方法制得的微孔铝箔 |
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