JP2012525388A - 効率的で環境に優しい、重油のメタノール及び誘導生成物への加工 - Google Patents
効率的で環境に優しい、重油のメタノール及び誘導生成物への加工 Download PDFInfo
- Publication number
- JP2012525388A JP2012525388A JP2012508507A JP2012508507A JP2012525388A JP 2012525388 A JP2012525388 A JP 2012525388A JP 2012508507 A JP2012508507 A JP 2012508507A JP 2012508507 A JP2012508507 A JP 2012508507A JP 2012525388 A JP2012525388 A JP 2012525388A
- Authority
- JP
- Japan
- Prior art keywords
- heavy oil
- hydrogen
- catalyst
- methanol
- carbon monoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/302—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/308—Gravity, density, e.g. API
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
【選択図】なし
Description
メタノールは、単細胞タンパク質の源として使用することができる。単細胞タンパク質(SCP)は、微生物によって生成されるタンパク質を指し、それは、エネルギーを得る間に炭化水素基質を分解する。タンパク質含有量は微生物(例えば細菌、酵母、カビ、等)のタイプによって異なる。SCPは食料および動物の餌としての用途を含む、多くの用途を有する。
以下の実施例は、本発明を限定すること無しに本発明の好ましい実施形態を示す。
従来の精製法を利用せずに、重炭化水素油(heavy hydrocarbon oils)と水および二酸化炭素とを反応させる双改質プロセスを使用した、メタノールまたはジメチルエーテルへ変換するために、硫黄および金属不純物の除去と同時に、超重質アスファルテンおよび超重質マルテン成分を熱または触媒分解することによる、タールサンド、シェールオイル(頁岩油)、重残渣のような様々な供給源から回収された、重原油の利用。
任意の供給源から生成され精製された重原油が、約800〜1100℃、好ましくは800〜850℃の間で、NiOのような触媒の存在下で、フロー反応器内において双改質プロセスに供される。触媒は、単体金属、金属酸化物、またはそれらの組み合わせとして使用されるV、Ti、Ga、Mg、Cu、Ni、Mo、Bi、Fe、Mn、Co、Nb、Zr、またはSnのような様々な金属および金属酸化物を含む。それらは適切な担体、好適には、燻蒸シリカまたはアルミニウムのような適切な大きさのナノ構造の表面上に担持され得る。好ましい触媒は、溶融アルミナ担持体上のNiOである。その処理は、COとH2との混合物を提供する。
メタノールを生成するのに適したモル比2:1のCOおよびH2の合成物を提供するための、実施例2において得られた混合物の調整。
約2:1の比率で生成された水素および一酸化炭素を、通常の銅および関連する触媒を使用した触媒反応条件下でメタノールへ変換する。
実施例4で生成したメタノールを、ナフィオンH(Nafion H)のような固体酸触媒を使用して、100〜200℃の間でジメチルエーテルへ脱水する。
メタノールからジメチルエーテルへ脱水する際に形成された水を重炭化水素油の双改質において再利用する。
Claims (14)
- 重油を処理して、粘度を減少させ有害な不純物を除去すること、
約2:1のモル比で水素と一酸化炭素との混合物を形成するのに十分な反応条件下で、水および二酸化炭素と、処理された前記重油とを反応させること、および
メタノールを生成するのに十分な条件下で、水素と一酸化炭素との混合物を反応させることを含む
メタノールを生成する方法。 - 前記重油が、タールサンド、油頁岩、様々な重油の沈殿物またはそれらの残渣を含む、任意の適切な供給源から得られ、
粘度が低減されるように、ならびに、硫黄および金属が取り除かれるように前記重油が処理される
請求項1に記載の方法。 - 30〜40のAPI指数を有するように、ならびに、硫黄および金属の少なくとも99.8%を除去するように前記重油が処理される
請求項2に記載の方法。 - 水素と一酸化炭素との混合物を形成するのに十分な蒸気改質反応条件の下で、処理された前記重油を反応させること、
水素と一酸化炭素との混合物を形成するのに十分な乾燥改質反応の条件下で、処理された前記重油と二酸化炭素とを反応させること、および、
前記蒸気改質および乾燥改質の工程で生成された水素と一酸化炭素との混合物を組み合わせること、
によって水素と一酸化炭素との前記混合物が得られる
請求項1に記載の方法。 - 生成される一酸化炭素に対する水素のモル比がおよそ2:1である
請求項1に記載の方法。 - 一酸化炭素に対する水素の前記モル比が2:1〜2.1:1の間である
請求項5に記載の方法。 - 前記メタノールを形成するのに適切な温度かつ適切なモル比の単一工程で、重油、水および二酸化炭素を反応させる
請求項1に記載の方法。 - 約800℃〜1100℃の温度の触媒の存在下における単一工程で、重油、蒸気および二酸化炭素を反応させる
請求項7に記載の方法。 - 前記触媒が、単一の金属触媒、単一の金属酸化物触媒、金属および金属酸化物の混合触媒、または少なくとも1つの金属酸化物と他の金属酸化物との混合触媒を含み、前記触媒は酸化物担持体上に随意に提供される
請求項8に記載の方法。 - 前記触媒は、高表面積またはナノ構造の、燻蒸アルミナまたは燻蒸シリカで担持される
請求項9に記載の方法。 - 前記触媒が、V、Ti、Ga、Mg、Cu、Ni、Mo、Bi、Fe、Mn、Co、Nb、Zr、La、もしくはSnまたはそれらの酸化物を含む
請求項10に記載の方法。 - 前記触媒が、NiO、または、NiOとV2O5:Ni2O3とNi2V2O7とNi3V2O5との混合触媒である、請求項11に記載の方法。
- 前記触媒が、燻蒸アルミナ上に担持されたNiO、または燻蒸シリカ上に担持されたNiO/V2O5である、請求項12に記載の方法。
- 部分的な油の燃焼を含む任意の利用可能なエネルギーにより、または、代替もしくは原子のエネルギーにより、前記重油がその場でガス化され、水素および一酸化炭素が生成される
請求項1に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17351309P | 2009-04-28 | 2009-04-28 | |
US61/173,513 | 2009-04-28 | ||
PCT/US2010/030254 WO2010129129A1 (en) | 2009-04-28 | 2010-04-07 | Efficient and environmentally friendly processing of heavy oils to methanol and derived products |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2012525388A true JP2012525388A (ja) | 2012-10-22 |
JP2012525388A5 JP2012525388A5 (ja) | 2013-05-30 |
Family
ID=42358501
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012508507A Pending JP2012525388A (ja) | 2009-04-28 | 2010-04-07 | 効率的で環境に優しい、重油のメタノール及び誘導生成物への加工 |
Country Status (8)
Country | Link |
---|---|
US (1) | US8816137B2 (ja) |
EP (1) | EP2424960A1 (ja) |
JP (1) | JP2012525388A (ja) |
KR (1) | KR20120004449A (ja) |
CN (1) | CN102414155A (ja) |
AU (1) | AU2010245167A1 (ja) |
CA (1) | CA2756417A1 (ja) |
WO (1) | WO2010129129A1 (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102380387B (zh) * | 2011-09-01 | 2014-01-15 | 华北电力大学 | 基于介孔氧化锆载体的镍基焦油转化催化剂及制备方法 |
FR3020356A1 (fr) * | 2014-04-29 | 2015-10-30 | Univ Lille Sciences Tech | Procede de reformage sec d'au moins un alcane. |
CN110639527B (zh) * | 2019-10-15 | 2021-05-18 | 嘉兴学院 | 生物油水蒸气重整制氢整体式催化剂及其制备方法 |
US11426708B2 (en) | 2020-03-02 | 2022-08-30 | King Abdullah University Of Science And Technology | Potassium-promoted red mud as a catalyst for forming hydrocarbons from carbon dioxide |
US11420915B2 (en) | 2020-06-11 | 2022-08-23 | Saudi Arabian Oil Company | Red mud as a catalyst for the isomerization of olefins |
US11495814B2 (en) | 2020-06-17 | 2022-11-08 | Saudi Arabian Oil Company | Utilizing black powder for electrolytes for flow batteries |
US12000056B2 (en) | 2020-06-18 | 2024-06-04 | Saudi Arabian Oil Company | Tandem electrolysis cell |
US11724943B2 (en) | 2021-01-04 | 2023-08-15 | Saudi Arabian Oil Company | Black powder catalyst for hydrogen production via dry reforming |
US11820658B2 (en) | 2021-01-04 | 2023-11-21 | Saudi Arabian Oil Company | Black powder catalyst for hydrogen production via autothermal reforming |
US11814289B2 (en) | 2021-01-04 | 2023-11-14 | Saudi Arabian Oil Company | Black powder catalyst for hydrogen production via steam reforming |
US11718522B2 (en) | 2021-01-04 | 2023-08-08 | Saudi Arabian Oil Company | Black powder catalyst for hydrogen production via bi-reforming |
US11427519B2 (en) | 2021-01-04 | 2022-08-30 | Saudi Arabian Oil Company | Acid modified red mud as a catalyst for olefin isomerization |
US12018392B2 (en) | 2022-01-03 | 2024-06-25 | Saudi Arabian Oil Company | Methods for producing syngas from H2S and CO2 in an electrochemical cell |
CN114956246B (zh) * | 2022-05-30 | 2023-09-12 | 榆林学院 | 一种改性气化细渣处理兰炭废水副产一氧化碳和氢气的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003064016A (ja) * | 2001-08-29 | 2003-03-05 | Ube Ind Ltd | 可燃性廃棄物からのジメチルエーテルの製造方法 |
JP2007112923A (ja) * | 2005-10-21 | 2007-05-10 | Hitachi Zosen Corp | 重質油の粘度低減方法 |
WO2008157673A1 (en) * | 2007-06-21 | 2008-12-24 | University Of Southern California | Conversion of carbon dioxide to methanol using bi-reforming of methane or natural gas |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3265614A (en) * | 1964-01-13 | 1966-08-09 | Petrolite Corp | Removal of sulfur bodies |
US3862899A (en) * | 1972-11-07 | 1975-01-28 | Pullman Inc | Process for the production of synthesis gas and clean fuels |
US3993457A (en) * | 1973-07-30 | 1976-11-23 | Exxon Research And Engineering Company | Concurrent production of methanol and synthetic natural gas |
GB1545329A (en) | 1976-06-21 | 1979-05-10 | Mobil Oil Corp | Utilization of low btu natural gas to produce methanol or liquid hydrocarbons |
US4098339A (en) * | 1976-06-21 | 1978-07-04 | Mobil Oil Corporation | Utilization of low BTU natural gas |
NZ194405A (en) * | 1979-08-02 | 1982-05-25 | Dut Pty Ltd | Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock |
CA1241667A (en) | 1984-04-25 | 1988-09-06 | Martin F.M. Post | Process for the preparation of hydrocarbons |
US4589973A (en) * | 1985-07-15 | 1986-05-20 | Breckinridge Minerals, Inc. | Process for recovering oil from raw oil shale using added pulverized coal |
US5599638A (en) * | 1993-10-12 | 1997-02-04 | California Institute Of Technology | Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane |
US6187465B1 (en) * | 1997-11-07 | 2001-02-13 | Terry R. Galloway | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
US7132183B2 (en) * | 2002-06-27 | 2006-11-07 | Intellergy Corporation | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
US20050025701A1 (en) * | 2003-07-30 | 2005-02-03 | Millennium Research Laboratories, Inc. | Steam reforming catalyst composition and process |
JP2006176721A (ja) | 2004-12-24 | 2006-07-06 | Idemitsu Kosan Co Ltd | 有機硫黄化合物含有燃料油用脱硫剤及び燃料電池用水素の製造方法 |
US7608743B2 (en) * | 2005-04-15 | 2009-10-27 | University Of Southern California | Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products |
EP1871732B1 (en) | 2005-04-15 | 2012-07-18 | University Of Southern California | Selective oxidative conversion of methane to methanol, dimethyl ether and derived products |
EP1910255A4 (en) * | 2005-08-01 | 2009-12-02 | Dalian Chemical Physics Inst | INTEGRATED PROCESS FOR THE CO-PRODUCTION OF METHANOL AND DIMETHYL ETHER FROM SYNTHESIS GAS CONTAINING NITROGEN |
ITMI20060465A1 (it) * | 2006-03-15 | 2007-09-16 | Prometeus Di Daniele Quartieri | Dispositivo e procedimento dio iniezione per l'alimentazione di motori tipo diesel con miscele idro-alcoliche |
JP2008094665A (ja) * | 2006-10-12 | 2008-04-24 | Idemitsu Kosan Co Ltd | 水素含有ガスの製造方法 |
-
2010
- 2010-04-07 KR KR1020117024215A patent/KR20120004449A/ko not_active Application Discontinuation
- 2010-04-07 US US12/755,997 patent/US8816137B2/en not_active Expired - Fee Related
- 2010-04-07 JP JP2012508507A patent/JP2012525388A/ja active Pending
- 2010-04-07 CA CA2756417A patent/CA2756417A1/en not_active Abandoned
- 2010-04-07 WO PCT/US2010/030254 patent/WO2010129129A1/en active Application Filing
- 2010-04-07 CN CN2010800182419A patent/CN102414155A/zh active Pending
- 2010-04-07 AU AU2010245167A patent/AU2010245167A1/en not_active Abandoned
- 2010-04-07 EP EP10715382A patent/EP2424960A1/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003064016A (ja) * | 2001-08-29 | 2003-03-05 | Ube Ind Ltd | 可燃性廃棄物からのジメチルエーテルの製造方法 |
JP2007112923A (ja) * | 2005-10-21 | 2007-05-10 | Hitachi Zosen Corp | 重質油の粘度低減方法 |
WO2008157673A1 (en) * | 2007-06-21 | 2008-12-24 | University Of Southern California | Conversion of carbon dioxide to methanol using bi-reforming of methane or natural gas |
Also Published As
Publication number | Publication date |
---|---|
EP2424960A1 (en) | 2012-03-07 |
KR20120004449A (ko) | 2012-01-12 |
CN102414155A (zh) | 2012-04-11 |
US20100274060A1 (en) | 2010-10-28 |
WO2010129129A1 (en) | 2010-11-11 |
AU2010245167A1 (en) | 2011-10-13 |
CA2756417A1 (en) | 2010-11-11 |
US8816137B2 (en) | 2014-08-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2012525388A (ja) | 効率的で環境に優しい、重油のメタノール及び誘導生成物への加工 | |
Dalena et al. | Methanol production and applications: an overview | |
Basile et al. | Methanol: science and engineering | |
KR101579051B1 (ko) | 메탄 또는 천연 가스의 이중 개질을 이용하여 이산화탄소를 디메틸 에테르로 전환시키는 방법 | |
EP3577064B1 (en) | Process for the production of hydrogen | |
CN102388011A (zh) | 使天然气成为环境上二氧化碳中性燃料和再生碳源 | |
US20070100003A1 (en) | Hybrid system for Gasification of Biomass and conversion to synthesis gas suitable for fuel synthesis, with 3 potential applications | |
CN102388005A (zh) | 使煤炭成为环境上二氧化碳中性燃料和再生碳源 | |
US20100261937A1 (en) | Rendering petroleum oil as an environmentally carbon dioxide neutral source material for fuels, derived products and as a regenerative carbon source | |
JP2009179591A (ja) | メタノールの製造方法 | |
Speight | Liquid fuels from natural gas | |
JP2024513288A (ja) | 二酸化炭素及び水素からの液体燃料の直接生成のための効率的な2段階プロセス | |
CN104098419B (zh) | 煤、天然气联用甲醇制低碳烯烃系统及方法 | |
CA3171759A1 (en) | Production of hydrocarbons from carbon dioxide and hydrogen | |
EP2443217A1 (en) | Integrated coal-to-liquids process | |
JP7398370B2 (ja) | メタンおよび軽質炭化水素を液体炭化水素燃料に改質するためのプロセスおよびシステム | |
WO2022211109A1 (ja) | 有用炭化水素の製造方法および有用炭化水素の製造装置 | |
Demirbaş et al. | Catalytic steam reforming of biomass and heavy oil residues to hydrogen | |
CN102659076A (zh) | 一种以天然气、煤和石油为原料联产多种化工产品的方法 | |
Djinović et al. | Energy carriers made from hydrogen | |
CN102906226A (zh) | 工程化的燃料贮存、再造和运输 | |
WO2019021129A1 (en) | APPARATUS AND METHOD RELATED TO THE USE OF SYNTHESIS GAS IN OLEFIN PRODUCTION | |
Kesarwani et al. | Extraction Techniques of Gas‐to‐Liquids (GtL) Fuels | |
Tuli et al. | An overview of some futurist advanced biofuels and their conversion technologies | |
JP7331070B2 (ja) | メタンおよび軽質炭化水素を液体炭化水素燃料に改質するためのプロセスおよびシステム |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130408 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130408 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140328 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140408 |
|
RD01 | Notification of change of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7426 Effective date: 20140516 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20140516 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20141028 |