JP2012515087A5 - - Google Patents
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- JP2012515087A5 JP2012515087A5 JP2011546345A JP2011546345A JP2012515087A5 JP 2012515087 A5 JP2012515087 A5 JP 2012515087A5 JP 2011546345 A JP2011546345 A JP 2011546345A JP 2011546345 A JP2011546345 A JP 2011546345A JP 2012515087 A5 JP2012515087 A5 JP 2012515087A5
- Authority
- JP
- Japan
- Prior art keywords
- alumina
- palladium
- catalyst
- layer
- surface area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 105
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 71
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 65
- 239000003054 catalyst Substances 0.000 claims description 59
- 229910052763 palladium Inorganic materials 0.000 claims description 49
- 239000010457 zeolite Substances 0.000 claims description 48
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 45
- 229910021536 Zeolite Inorganic materials 0.000 claims description 44
- 229910052697 platinum Inorganic materials 0.000 claims description 32
- 239000011148 porous material Substances 0.000 claims description 29
- 239000002131 composite material Substances 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 24
- 229910044991 metal oxide Inorganic materials 0.000 claims description 22
- 150000004706 metal oxides Chemical class 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000003870 refractory metal Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 229910000510 noble metal Inorganic materials 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 229910052746 lanthanum Inorganic materials 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002808 molecular sieve Substances 0.000 claims description 6
- 230000002000 scavenging effect Effects 0.000 claims description 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004071 soot Substances 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims 6
- 238000007254 oxidation reaction Methods 0.000 claims 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 238000006722 reduction reaction Methods 0.000 claims 2
- 230000004913 activation Effects 0.000 claims 1
- 238000010531 catalytic reduction reaction Methods 0.000 claims 1
- 238000003475 lamination Methods 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 claims 1
- 238000011105 stabilization Methods 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 description 24
- 239000000758 substrate Substances 0.000 description 18
- 238000000151 deposition Methods 0.000 description 17
- 229910052878 cordierite Inorganic materials 0.000 description 16
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 16
- 239000002245 particle Substances 0.000 description 13
- 238000011068 loading method Methods 0.000 description 11
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 239000007900 aqueous suspension Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000010970 precious metal Substances 0.000 description 6
- 239000010948 rhodium Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 4
- -1 silicalite Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- AQBOUNVXZQRXNP-UHFFFAOYSA-L azane;dichloropalladium Chemical compound N.N.N.N.Cl[Pd]Cl AQBOUNVXZQRXNP-UHFFFAOYSA-L 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14541209P | 2009-01-16 | 2009-01-16 | |
| US61/145,412 | 2009-01-16 | ||
| US12/687,597 | 2010-01-14 | ||
| US12/687,597 US8329607B2 (en) | 2009-01-16 | 2010-01-14 | Layered diesel oxidation catalyst composites |
| PCT/US2010/021107 WO2010083357A2 (en) | 2009-01-16 | 2010-01-15 | Layered diesel oxidation catalyst composites |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012515087A JP2012515087A (ja) | 2012-07-05 |
| JP2012515087A5 true JP2012515087A5 (https=) | 2014-04-24 |
| JP5787768B2 JP5787768B2 (ja) | 2015-09-30 |
Family
ID=42340295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011546345A Active JP5787768B2 (ja) | 2009-01-16 | 2010-01-15 | 積層ディーゼル酸化触媒複合材料 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8329607B2 (https=) |
| EP (1) | EP2387463B2 (https=) |
| JP (1) | JP5787768B2 (https=) |
| KR (1) | KR101598647B1 (https=) |
| CN (1) | CN102355951B (https=) |
| BR (1) | BRPI1007322B1 (https=) |
| ES (1) | ES2573407T3 (https=) |
| PL (1) | PL2387463T3 (https=) |
| WO (1) | WO2010083357A2 (https=) |
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-
2010
- 2010-01-14 US US12/687,597 patent/US8329607B2/en active Active
- 2010-01-15 EP EP10732120.0A patent/EP2387463B2/en active Active
- 2010-01-15 JP JP2011546345A patent/JP5787768B2/ja active Active
- 2010-01-15 PL PL10732120.0T patent/PL2387463T3/pl unknown
- 2010-01-15 WO PCT/US2010/021107 patent/WO2010083357A2/en not_active Ceased
- 2010-01-15 CN CN201080011977.3A patent/CN102355951B/zh active Active
- 2010-01-15 BR BRPI1007322-1A patent/BRPI1007322B1/pt not_active IP Right Cessation
- 2010-01-15 ES ES10732120.0T patent/ES2573407T3/es active Active
- 2010-01-15 KR KR1020117018903A patent/KR101598647B1/ko active Active
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