JP2012500310A5 - - Google Patents
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- Publication number
- JP2012500310A5 JP2012500310A5 JP2011523337A JP2011523337A JP2012500310A5 JP 2012500310 A5 JP2012500310 A5 JP 2012500310A5 JP 2011523337 A JP2011523337 A JP 2011523337A JP 2011523337 A JP2011523337 A JP 2011523337A JP 2012500310 A5 JP2012500310 A5 JP 2012500310A5
- Authority
- JP
- Japan
- Prior art keywords
- alkadiene
- vinyl aromatic
- polymerization
- functionalized poly
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000178 monomer Substances 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 229920001971 elastomer Polymers 0.000 claims description 10
- 239000000806 elastomer Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000012071 phase Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000012454 non-polar solvent Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000011258 core-shell material Substances 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- 125000001979 organolithium group Chemical group 0.000 claims description 3
- 230000002194 synthesizing Effects 0.000 claims description 3
- VMKOFRJSULQZRM-UHFFFAOYSA-N 1-bromooctane Chemical group CCCCCCCCBr VMKOFRJSULQZRM-UHFFFAOYSA-N 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- ZUZSFMQBICMDEZ-UHFFFAOYSA-N prop-1-enylbenzene;styrene Chemical group C=CC1=CC=CC=C1.CC=CC1=CC=CC=C1 ZUZSFMQBICMDEZ-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N α-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- IJOOHPMOJXWVHK-UHFFFAOYSA-N Trimethylsilyl chloride Chemical group C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241001237745 Salamis Species 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N Silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- JIMMILCKVYOFET-UHFFFAOYSA-N hexadecan-4-ol Chemical compound CCCCCCCCCCCCC(O)CCC JIMMILCKVYOFET-UHFFFAOYSA-N 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 230000000977 initiatory Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- -1 palmitic acid ester Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 235000015175 salami Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2008A001524 | 2008-08-20 | ||
| ITMI2008A001524A IT1391109B1 (it) | 2008-08-20 | 2008-08-20 | Procedimento per la sintesi di poli(1,3-alcadieni) funzionalizzati e loro impiego nella preparazione di polimeri vinilaromatici ad alta resistenza all'urto |
| PCT/EP2009/005893 WO2010020374A1 (en) | 2008-08-20 | 2009-08-07 | Process for the synthesis of functionalized poly(1,3-alkadienes) and use thereof in the preparation of high impact vinyl aromatic polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012500310A JP2012500310A (ja) | 2012-01-05 |
| JP2012500310A5 true JP2012500310A5 (US20080242721A1-20081002-C00053.png) | 2014-05-29 |
| JP5642677B2 JP5642677B2 (ja) | 2014-12-17 |
Family
ID=40802003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011523337A Active JP5642677B2 (ja) | 2008-08-20 | 2009-08-07 | 官能化ポリ（１，３−アルカジエン）の合成方法および耐衝撃性ビニル芳香族ポリマーの調製におけるその使用 |
Country Status (13)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20121018A1 (it) * | 2012-06-12 | 2013-12-13 | Versalis Spa | Procedimento per la preparazione di copolimeri elastomerici funzionalizzati e ramificati e loro impiego in composizioni elastomeriche vulcanizzabili |
| TWI674295B (zh) * | 2015-08-20 | 2019-10-11 | 日商日本瑞翁股份有限公司 | 含腈基之共聚橡膠、交聯性橡膠組合物及橡膠交聯物 |
| US10882940B2 (en) | 2016-04-29 | 2021-01-05 | Sabic Global Technologies B.V. | Process for the production of copolymers |
| RU2666724C1 (ru) * | 2018-05-15 | 2018-09-12 | Публичное Акционерное Общество "Нижнекамскнефтехим" | Способ получения полимеров бутадиена или сополимеров бутадиена со стиролом с низким содержанием 1,2-звеньев в бутадиеновой части |
| TW202330677A (zh) | 2021-12-10 | 2023-08-01 | 義大利商佛沙里斯股份有限公司 | 橡膠強化的乙烯芳香族(共)聚合物及其製備方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2730241B1 (fr) * | 1995-02-07 | 1997-02-28 | Atofina | Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable |
| IT1274361B (it) * | 1995-02-16 | 1997-07-17 | Enichem Spa | Procedimento per la preparazione di copolimeri vinilaromatici rinforzati con gomma |
| CA2245686C (en) * | 1996-03-29 | 2005-04-05 | The Dow Chemical Company | In situ block copolymer formation during polymerization of a vinyl aromatic monomer |
| FR2768739B1 (fr) * | 1997-09-19 | 2004-08-06 | Atochem Elf Sa | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
| IT1318479B1 (it) * | 2000-04-20 | 2003-08-25 | Enichem Spa | Procedimento per la preparazione di gomme sbr con miglioratalavorabilita' e minore resistenza al rotolamento. |
| ITMI20031420A1 (it) * | 2003-07-11 | 2005-01-12 | Polimeri Europa Spa | Polimeri vinilaromatici rinforzati con gomma |
| ITMI20040752A1 (it) * | 2004-04-16 | 2004-07-16 | Polimeri Europa Spa | Procedimento per la preparazione di co polimeri vinilaromatici aggraffati su elastometro in modo controllato |
| US7125934B1 (en) * | 2005-06-28 | 2006-10-24 | The Goodyear Tire & Rubber Company | Functionalization of living rubbery polymers with nitrones |
| JP4286300B2 (ja) * | 2007-04-16 | 2009-06-24 | 横浜ゴム株式会社 | 変性ポリマー |
| US8048960B2 (en) * | 2007-04-18 | 2011-11-01 | Styron Europe Gmbh | Monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers |
-
2008
- 2008-08-20 IT ITMI2008A001524A patent/IT1391109B1/it active
-
2009
- 2009-08-07 PT PT97778740T patent/PT2315784T/pt unknown
- 2009-08-07 EP EP09777874.0A patent/EP2315784B1/en active Active
- 2009-08-07 ES ES09777874.0T patent/ES2616517T3/es active Active
- 2009-08-07 HU HUE09777874A patent/HUE033188T2/hu unknown
- 2009-08-07 DK DK09777874.0T patent/DK2315784T3/en active
- 2009-08-07 PL PL09777874T patent/PL2315784T3/pl unknown
- 2009-08-07 CN CN2009801371400A patent/CN102164968B/zh active Active
- 2009-08-07 JP JP2011523337A patent/JP5642677B2/ja active Active
- 2009-08-07 BR BRPI0917857A patent/BRPI0917857B1/pt active IP Right Grant
- 2009-08-07 RU RU2011107115/04A patent/RU2493174C2/ru active
- 2009-08-07 WO PCT/EP2009/005893 patent/WO2010020374A1/en active Application Filing
- 2009-08-07 US US13/059,533 patent/US9029479B2/en active Active
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