JP2011528508A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2011528508A5 JP2011528508A5 JP2011518779A JP2011518779A JP2011528508A5 JP 2011528508 A5 JP2011528508 A5 JP 2011528508A5 JP 2011518779 A JP2011518779 A JP 2011518779A JP 2011518779 A JP2011518779 A JP 2011518779A JP 2011528508 A5 JP2011528508 A5 JP 2011528508A5
- Authority
- JP
- Japan
- Prior art keywords
- flow rate
- organosilicon precursor
- processing chamber
- gas mixture
- providing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 claims description 50
- 239000002243 precursor Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 8
- 239000011541 reaction mixture Substances 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- IFMSFIQUXYIQEM-UHFFFAOYSA-N 1,1,2,2-tetramethyl-1,3-disiletane Chemical compound CC1(C)[SiH2]C[Si]1(C)C IFMSFIQUXYIQEM-UHFFFAOYSA-N 0.000 claims 1
- CADNWBOFYYBQNV-UHFFFAOYSA-N 2,2,3,3-tetramethyl-1,2,5-oxadisilolane Chemical compound CC1(C)C[SiH2]O[Si]1(C)C CADNWBOFYYBQNV-UHFFFAOYSA-N 0.000 claims 1
- VZYQCUQOIPCDBA-UHFFFAOYSA-N 2,3,4,5-tetramethyloxadisilole Chemical compound CC1=C(C)[Si](C)=[Si](C)O1 VZYQCUQOIPCDBA-UHFFFAOYSA-N 0.000 claims 1
- 229910018540 Si C Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 229910010271 silicon carbide Inorganic materials 0.000 claims 1
- NIINUVYELHEORX-UHFFFAOYSA-N triethoxy(triethoxysilylmethyl)silane Chemical group CCO[Si](OCC)(OCC)C[Si](OCC)(OCC)OCC NIINUVYELHEORX-UHFFFAOYSA-N 0.000 claims 1
- CTERGEUBUIGWTM-UHFFFAOYSA-N trimethyl(1-trimethylsilyloxyethoxy)silane Chemical compound C[Si](C)(C)OC(C)O[Si](C)(C)C CTERGEUBUIGWTM-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 39
- 230000007704 transition Effects 0.000 description 24
- 230000008021 deposition Effects 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 210000002816 gill Anatomy 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Images
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/173,659 | 2008-07-15 | ||
| US12/173,659 US20100015816A1 (en) | 2008-07-15 | 2008-07-15 | Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors |
| PCT/US2009/049216 WO2010008930A2 (en) | 2008-07-15 | 2009-06-30 | Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011528508A JP2011528508A (ja) | 2011-11-17 |
| JP2011528508A5 true JP2011528508A5 (https=) | 2013-07-18 |
Family
ID=41530671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011518779A Pending JP2011528508A (ja) | 2008-07-15 | 2009-06-30 | 障壁層と多様な液体前駆体から堆積される多孔質低k膜との間の付着を促進するための方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20100015816A1 (https=) |
| JP (1) | JP2011528508A (https=) |
| KR (1) | KR20110039556A (https=) |
| CN (1) | CN102099897A (https=) |
| TW (1) | TW201025425A (https=) |
| WO (1) | WO2010008930A2 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110241200A1 (en) * | 2010-04-05 | 2011-10-06 | International Business Machines Corporation | Ultra low dielectric constant material with enhanced mechanical properties |
| WO2014143337A1 (en) * | 2013-03-14 | 2014-09-18 | Applied Materials, Inc. | Adhesion layer to minimize dilelectric constant increase with good adhesion strength in a pecvd process |
| CN104103572B (zh) * | 2013-04-02 | 2017-02-08 | 中芯国际集成电路制造(上海)有限公司 | 多孔低k介质层的形成方法及多孔低k介质层 |
| US10510852B2 (en) * | 2017-11-28 | 2019-12-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Low-k feature formation processes and structures formed thereby |
| CN113166937A (zh) * | 2018-11-27 | 2021-07-23 | 弗萨姆材料美国有限责任公司 | 1-甲基-1-异丙氧基-硅杂环烷烃和由其制备的致密有机硅膜 |
| US11430654B2 (en) * | 2019-11-27 | 2022-08-30 | Applied Materials, Inc. | Initiation modulation for plasma deposition |
| KR102913505B1 (ko) * | 2023-06-08 | 2026-01-16 | 에스케이트리켐 주식회사 | 저 유전율 실리콘 함유 박막 형성용 전구체 및 이를 이용한 저 유전율 실리콘 함유 박막 형성 방법. |
| KR20250016873A (ko) * | 2023-07-26 | 2025-02-04 | 에스케이트리켐 주식회사 | 저 유전율 박막 형성용 전구체 및 상기 전구체를 이용한 저 유전율 실리콘 함유 박막 형성 방법 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH043926A (ja) * | 1990-04-20 | 1992-01-08 | Sony Corp | 半導体装置の製造方法 |
| US6340435B1 (en) * | 1998-02-11 | 2002-01-22 | Applied Materials, Inc. | Integrated low K dielectrics and etch stops |
| JP2001035845A (ja) * | 1999-07-21 | 2001-02-09 | Nec Corp | 半導体装置の製造方法及びそれに使用されるプラズマ絶縁膜の成膜装置 |
| US6258735B1 (en) * | 2000-10-05 | 2001-07-10 | Applied Materials, Inc. | Method for using bypass lines to stabilize gas flow and maintain plasma inside a deposition chamber |
| SG98468A1 (en) * | 2001-01-17 | 2003-09-19 | Air Prod & Chem | Organosilicon precursors for interlayer dielectric films with low dielectric constants |
| US6518646B1 (en) * | 2001-03-29 | 2003-02-11 | Advanced Micro Devices, Inc. | Semiconductor device with variable composition low-k inter-layer dielectric and method of making |
| US6570256B2 (en) * | 2001-07-20 | 2003-05-27 | International Business Machines Corporation | Carbon-graded layer for improved adhesion of low-k dielectrics to silicon substrates |
| US6933586B2 (en) * | 2001-12-13 | 2005-08-23 | International Business Machines Corporation | Porous low-k dielectric interconnects with improved adhesion produced by partial burnout of surface porogens |
| US7056560B2 (en) * | 2002-05-08 | 2006-06-06 | Applies Materials Inc. | Ultra low dielectric materials based on hybrid system of linear silicon precursor and organic porogen by plasma-enhanced chemical vapor deposition (PECVD) |
| US7098149B2 (en) * | 2003-03-04 | 2006-08-29 | Air Products And Chemicals, Inc. | Mechanical enhancement of dense and porous organosilicate materials by UV exposure |
| US6913992B2 (en) * | 2003-03-07 | 2005-07-05 | Applied Materials, Inc. | Method of modifying interlayer adhesion |
| US8137764B2 (en) * | 2003-05-29 | 2012-03-20 | Air Products And Chemicals, Inc. | Mechanical enhancer additives for low dielectric films |
| WO2005053009A1 (ja) * | 2003-11-28 | 2005-06-09 | Nec Corporation | 多孔質絶縁膜及びその製造方法並びに多孔質絶縁膜を用いた半導体装置 |
| US7030041B2 (en) * | 2004-03-15 | 2006-04-18 | Applied Materials Inc. | Adhesion improvement for low k dielectrics |
| US7547643B2 (en) * | 2004-03-31 | 2009-06-16 | Applied Materials, Inc. | Techniques promoting adhesion of porous low K film to underlying barrier layer |
| US7102232B2 (en) * | 2004-04-19 | 2006-09-05 | International Business Machines Corporation | Structure to improve adhesion between top CVD low-k dielectric and dielectric capping layer |
| US7166544B2 (en) * | 2004-09-01 | 2007-01-23 | Applied Materials, Inc. | Method to deposit functionally graded dielectric films via chemical vapor deposition using viscous precursors |
| KR20070083745A (ko) * | 2004-09-22 | 2007-08-24 | 벤자민 데이비드 해튼 | 유기실리카 물질 내의 가교 유기 기의 변환방법 |
| US7501354B2 (en) * | 2005-01-18 | 2009-03-10 | Applied Materials, Inc. | Formation of low K material utilizing process having readily cleaned by-products |
| US20060156980A1 (en) * | 2005-01-19 | 2006-07-20 | Samsung Electronics Co., Ltd. | Apparatus including 4-way valve for fabricating semiconductor device, method of controlling valve, and method of fabricating semiconductor device using the apparatus |
| US7259111B2 (en) * | 2005-01-19 | 2007-08-21 | Applied Materials, Inc. | Interface engineering to improve adhesion between low k stacks |
| JP5324734B2 (ja) * | 2005-01-21 | 2013-10-23 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 誘電体材料とその製造方法 |
| US7265437B2 (en) * | 2005-03-08 | 2007-09-04 | International Business Machines Corporation | Low k dielectric CVD film formation process with in-situ imbedded nanolayers to improve mechanical properties |
| US7189658B2 (en) * | 2005-05-04 | 2007-03-13 | Applied Materials, Inc. | Strengthening the interface between dielectric layers and barrier layers with an oxide layer of varying composition profile |
| JP2006339506A (ja) * | 2005-06-03 | 2006-12-14 | Semiconductor Process Laboratory Co Ltd | 成膜方法及び半導体装置の製造方法 |
| US7390757B2 (en) * | 2005-11-15 | 2008-06-24 | Applied Materials, Inc. | Methods for improving low k FSG film gap-fill characteristics |
| US7381659B2 (en) * | 2005-11-22 | 2008-06-03 | International Business Machines Corporation | Method for reducing film stress for SiCOH low-k dielectric materials |
| JP5093479B2 (ja) * | 2005-11-24 | 2012-12-12 | 日本電気株式会社 | 多孔質絶縁膜の形成方法 |
| JP2007258403A (ja) * | 2006-03-23 | 2007-10-04 | United Microelectronics Corp | 多孔性低誘電率薄膜及びその製作方法 |
| US7297376B1 (en) * | 2006-07-07 | 2007-11-20 | Applied Materials, Inc. | Method to reduce gas-phase reactions in a PECVD process with silicon and organic precursors to deposit defect-free initial layers |
| US7598183B2 (en) * | 2006-09-20 | 2009-10-06 | Applied Materials, Inc. | Bi-layer capping of low-K dielectric films |
| US7799377B2 (en) * | 2006-12-07 | 2010-09-21 | Electronics And Telecommunications Research Institute | Organic/inorganic thin film deposition method |
| US7615482B2 (en) * | 2007-03-23 | 2009-11-10 | International Business Machines Corporation | Structure and method for porous SiCOH dielectric layers and adhesion promoting or etch stop layers having increased interfacial and mechanical strength |
-
2008
- 2008-07-15 US US12/173,659 patent/US20100015816A1/en not_active Abandoned
-
2009
- 2009-06-30 WO PCT/US2009/049216 patent/WO2010008930A2/en not_active Ceased
- 2009-06-30 CN CN2009801283109A patent/CN102099897A/zh active Pending
- 2009-06-30 JP JP2011518779A patent/JP2011528508A/ja active Pending
- 2009-06-30 KR KR1020117003518A patent/KR20110039556A/ko not_active Ceased
- 2009-07-15 TW TW098123972A patent/TW201025425A/zh unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2011528508A5 (https=) | ||
| US11776807B2 (en) | Plasma enhanced deposition processes for controlled formation of oxygen containing thin films | |
| US20230132743A1 (en) | FORMATION OF SiOC THIN FILMS | |
| CN110651064B (zh) | 电介质上氧化物的选择性peald | |
| US11501965B2 (en) | Plasma enhanced deposition processes for controlled formation of metal oxide thin films | |
| US20200286725A1 (en) | STRUCTURE INCLUDING SiOC LAYER AND METHOD OF FORMING SAME | |
| JP2008135755A5 (https=) | ||
| CN103109358A (zh) | 用于氧化硅原子层沉积的嵌入式催化剂 | |
| US20200002814A1 (en) | Tin-Containing Precursors and Methods of Depositing Tin-Containing Films | |
| CN107768244B (zh) | 非晶质硅膜的形成方法 | |
| CN116065134A (zh) | 选择性热沉积方法 | |
| US20200040454A1 (en) | Method to increase deposition rate of ald process |