JP2011512339A - ６−ヒドロキシカプロン酸エステルの製造方法 - Google Patents

６−ヒドロキシカプロン酸エステルの製造方法 Download PDF

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Publication number
JP2011512339A
JP2011512339A JP2010546284A JP2010546284A JP2011512339A JP 2011512339 A JP2011512339 A JP 2011512339A JP 2010546284 A JP2010546284 A JP 2010546284A JP 2010546284 A JP2010546284 A JP 2010546284A JP 2011512339 A JP2011512339 A JP 2011512339A
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JP
Japan
Prior art keywords
acid
catalyst
hydrogenation
aqueous phase
hydroxycaproic
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JP2010546284A
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English (en)
Japanese (ja)
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JP2011512339A5 (https=
Inventor
ピンコス ロルフ
ジルヒ ティルマン
テベン ゲルト−ディーター
フィッシャー ロルフ−ハルトムート
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BASF SE
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BASF SE
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Application filed by BASF SE filed Critical BASF SE
Publication of JP2011512339A publication Critical patent/JP2011512339A/ja
Publication of JP2011512339A5 publication Critical patent/JP2011512339A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2010546284A 2008-02-15 2009-01-29 ６−ヒドロキシカプロン酸エステルの製造方法 Pending JP2011512339A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP08101692 2008-02-15
PCT/EP2009/051000 WO2009100989A2 (de) 2008-02-15 2009-01-29 Verfahren zur herstellung von 6-hydroxycapronsäureestern

Publications (2)

Publication Number Publication Date
JP2011512339A true JP2011512339A (ja) 2011-04-21
JP2011512339A5 JP2011512339A5 (https=) 2012-03-15

Family

ID=40674192

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010546284A Pending JP2011512339A (ja) 2008-02-15 2009-01-29 ６−ヒドロキシカプロン酸エステルの製造方法

Country Status (9)

Country Link
US (1) US8183411B2 (https=)
EP (1) EP2244996B2 (https=)
JP (1) JP2011512339A (https=)
KR (1) KR20100127782A (https=)
CN (1) CN101945847B (https=)
CA (1) CA2714574A1 (https=)
ES (1) ES2393838T5 (https=)
MY (1) MY148679A (https=)
WO (1) WO2009100989A2 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015229646A (ja) * 2014-06-04 2015-12-21 宇部興産株式会社 カルボン酸並びにケトン及び／又はアルコールの製造方法

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2376414A2 (de) 2008-12-09 2011-10-19 Basf Se Verfahren zur reinigung von roh-polymethylolen
SG171403A1 (en) 2008-12-09 2011-07-28 Basf Se Method for purifying polymethylols
KR20110110303A (ko) 2009-01-12 2011-10-06 바스프 에스이 폴리메틸올의 제조 방법
SG174394A1 (en) 2009-04-07 2011-10-28 Basf Se Method for producing 1,6-hexanediol and caprolactone
EP2417088B1 (de) 2009-04-07 2013-05-29 Basf Se Verfahren zur herstellung von 1,6-hexandiol
CN102452919B (zh) * 2010-10-27 2014-10-01 中国石油化工股份有限公司 一种内酯催化氧化制备相应羟基酸的方法
PL227792B1 (pl) * 2012-03-23 2018-01-31 Korzeniowski Waclaw Chemenergia Sposób otrzymywania estrów syntetycznych
KR20220116501A (ko) * 2019-12-18 2022-08-23 바스프 에스이 시클로헥산올 및 시클로헥사논의 제조 방법
CN111892501A (zh) * 2020-07-15 2020-11-06 江西盛伟科技股份有限公司 一种6-羟基己酸甲酯的制备方法
CN112010753A (zh) * 2020-08-18 2020-12-01 青岛科技大学 一种6-羟基己酸酯的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4815314B1 (https=) * 1969-08-18 1973-05-14
JPS51108040A (https=) * 1975-03-06 1976-09-25 Celanese Corp
JPH10175909A (ja) * 1996-12-12 1998-06-30 Rhone Poulenc Fiber & Resin Intermediates シクロヘキサン酸化生成物の洗浄水から二酸を製造する方法
JP2006504780A (ja) * 2002-10-30 2006-02-09 ロディア・ポリアミド・インターミーディエッツ カルボン酸の製造方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1210785B (de) * 1963-11-27 1966-02-17 Basf Ag Verfahren zur Gewinnung von epsilon-Hydroxycapron-saeure
FR1505363A (fr) 1966-04-20 1967-12-15 Rhone Poulenc Sa Perfectionnement à la préparation des cycloalcanols et des mélanges cycloalcanols/cycloalcanones
FR1585375A (https=) * 1968-10-11 1970-01-16
US3772375A (en) * 1968-10-11 1973-11-13 Rhone Poulenc Sa Process for producing epsilon-hydroxycaproic acid
US3848003A (en) * 1970-06-26 1974-11-12 Celanese Corp Hydrogenolysis of carboxylic acids with cobalt catalysts
US3752861A (en) * 1970-08-17 1973-08-14 Celanese Corp Production of hydroxy compounds by hydrogenolysis of buffered carboxylate salts
CA1049041A (en) * 1972-11-23 1979-02-20 Stamicarbon B.V. Process for the preparation of cycloalkanones and/or cycloalkanols
DE3823695A1 (de) † 1988-07-13 1990-01-18 Basf Ag Verfahren zur herstellung von 6-hydroxycapronsaeureestern
MY118128A (en) † 1996-03-01 2004-09-30 Basf Ag The preparation of 1, 6-hexanediol and caprolactone
DE19738464A1 (de) 1997-09-03 1999-03-04 Basf Ag Verwendung von Formkörpern als Katalysator zur Herstellung von Caprolactam
DE19750532A1 (de) * 1997-11-14 1999-05-20 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol und 6-Hydroxycapronsäure bzw. deren Estern
US6063958A (en) * 1998-12-22 2000-05-16 China Petrochemical Development Corporation Method of recovering adipic acid and 6-hydroxycaproic acid from waste solution of alkali metal salts of organic acids coming from the process of cyclohexane oxidation
DE102009047193A1 (de) * 2009-11-26 2011-06-01 Basf Se Verfahren zur Herstellung von Diolen durch Hydrierung eines Carbonsäure enthaltenden Gemisches mittels Kobalt enthaltenden Katalysatoren

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4815314B1 (https=) * 1969-08-18 1973-05-14
JPS51108040A (https=) * 1975-03-06 1976-09-25 Celanese Corp
JPH10175909A (ja) * 1996-12-12 1998-06-30 Rhone Poulenc Fiber & Resin Intermediates シクロヘキサン酸化生成物の洗浄水から二酸を製造する方法
JP2006504780A (ja) * 2002-10-30 2006-02-09 ロディア・ポリアミド・インターミーディエッツ カルボン酸の製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015229646A (ja) * 2014-06-04 2015-12-21 宇部興産株式会社 カルボン酸並びにケトン及び／又はアルコールの製造方法

Also Published As

Publication number Publication date
US8183411B2 (en) 2012-05-22
KR20100127782A (ko) 2010-12-06
EP2244996A2 (de) 2010-11-03
EP2244996B2 (de) 2015-11-11
CN101945847A (zh) 2011-01-12
US20110015429A1 (en) 2011-01-20
EP2244996B1 (de) 2012-10-31
CN101945847B (zh) 2013-07-10
ES2393838T3 (es) 2012-12-28
ES2393838T5 (es) 2016-03-02
MY148679A (en) 2013-05-31
WO2009100989A2 (de) 2009-08-20
CA2714574A1 (en) 2009-08-20
WO2009100989A3 (de) 2009-11-19

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