JP2011504532A - 皮革および皮膚のなめし剤およびなめし方法 - Google Patents
皮革および皮膚のなめし剤およびなめし方法 Download PDFInfo
- Publication number
- JP2011504532A JP2011504532A JP2010534482A JP2010534482A JP2011504532A JP 2011504532 A JP2011504532 A JP 2011504532A JP 2010534482 A JP2010534482 A JP 2010534482A JP 2010534482 A JP2010534482 A JP 2010534482A JP 2011504532 A JP2011504532 A JP 2011504532A
- Authority
- JP
- Japan
- Prior art keywords
- tanning
- leather
- deglycosylated
- skin
- iridoids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/10—Vegetable tanning
- C14C3/12—Vegetable tanning using purified or modified vegetable tanning agents
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/10—Vegetable tanning
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Chemical Treatment Of Metals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Cosmetics (AREA)
Abstract
Description
酸性触媒の存在下、水溶液中で、誘導体(4E)-4-ホルミル-3-(1-ホルミル-2-メトキシ-2-オキソエチル)ヘキサ-4-エン酸および(4E)-4-ホルミル-3-(2-オキソエチル)ヘキサ-4-エン酸を、代表例として形成する。特に、リン酸、しかし硫酸および塩酸も、オレウロペインからの該誘導体の製造に好適である。
脱灰した(delimed)ウシ皮革をゲニピンと共に、28℃およびpH6で23時間インキュベーションした。なめした皮革の収縮温度は75℃(左手側、1%ゲニピン)および63℃(右手側、0.5%ゲニピン)であった。典型的な暗青色が見られる。
Claims (15)
- ゲニピンを含有するなめし剤を除く、脱グリコシル化イリドイドおよび/または脱グリコシル化セコイリドイドを含有するなめし剤で皮革および皮膚を処理することを特徴とする、皮革および皮膚のなめし方法。
- なめし剤としてオレウロペインジアール(oleuropeindial)、リグストロシドジアール(ligustrosidedial)および/またはリグスタロシドジアール(ligustalosidedial)が用いられることを特徴とする請求項1に記載の方法。
- なめし剤としてデカルボメトキシオレウロペインジアールおよびデカルボメトキシリグストロシドジアールが用いられることを特徴とする請求項1に記載の方法。
- なめし剤として(4E)-4-ホルミル-3-(1-ホルミル-2-メトキシ-2-オキソエチル)ヘキサ-4-エン酸および(4E)-4-ホルミル-3-(2-オキソエチル)ヘキサ-4-エン酸またはそれらの塩が用いられることを特徴とする請求項1に記載の方法。
- なめし剤は、0.1〜25重量%の濃度、好ましくは、0.5〜10重量%の濃度の水溶液として存在することを特徴とする請求項1〜4のいずれか1項に記載の方法。
- 前記方法は、1.5〜11のpH、好ましくは、2〜7のpHで行われることを特徴とする請求項1〜4のいずれか1項に記載の方法。
- 前記方法は、4〜70℃の温度、好ましくは、10〜40℃の温度で行われることを特徴とする請求項1〜4のいずれか1項に記載の方法。
- 前記イリドイドおよびセコイリドイド並びにそれらのアグリコンは植物起源であることを特徴とする請求項1〜7のいずれか1項に記載の方法。
- 前記イリドイドおよびセコイリドイド並びにそれらのアグリコンはオリーブ葉、オリーブ廃水および搾りかすより得られたものであることを特徴とする請求項1〜7のいずれか1項に記載の方法。
- 前記イリドイドおよびセコイリドイド並びにそれらのアグリコンは、合成的に、酵素的にまたは発酵によって調製されることを特徴とする請求項1〜7のいずれか1項に記載の方法。
- なめしは、適当な助剤の添加によって促進されることを特徴とする請求項1〜10のいずれか1項に記載の方法。
- なめしは、タンパク質、ペプチド、タンパク質加水分解物、ポリアミン、キトサンまたはポリリシンの添加によって促進されることを特徴とする請求項1〜10のいずれか1項に記載の方法。
- 前記方法は、鉱物、植物および酵素なめしと組み合わせられることを特徴とする請求項1〜10のいずれか1項に記載の方法。
- 皮革および皮膚が暗化しないことを特徴とする請求項1〜13のいずれか1項に記載の方法。
- ゲニピンまたはその混合物を除く、0.1〜25重量%の脱グリコシル化イリドイドおよび/または脱グリコシル化セコイリドイドを含有する、なめし剤。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07121380A EP2062985A1 (de) | 2007-11-23 | 2007-11-23 | Mittel und Verfahren zur Gerbung von Häuten und Fellen |
EP07121380.5 | 2007-11-23 | ||
PCT/EP2008/065954 WO2009065915A1 (de) | 2007-11-23 | 2008-11-21 | Mittel und verfahren zur gerbung von häuten und fellen |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011504532A true JP2011504532A (ja) | 2011-02-10 |
JP5302327B2 JP5302327B2 (ja) | 2013-10-02 |
Family
ID=39294048
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010534482A Active JP5302327B2 (ja) | 2007-11-23 | 2008-11-21 | 皮革および皮膚のなめし剤およびなめし方法 |
Country Status (20)
Country | Link |
---|---|
US (1) | US9328394B2 (ja) |
EP (2) | EP2062985A1 (ja) |
JP (1) | JP5302327B2 (ja) |
KR (1) | KR101415399B1 (ja) |
CN (1) | CN101868555B (ja) |
AT (1) | ATE505563T1 (ja) |
AU (1) | AU2008327902B2 (ja) |
BR (1) | BRPI0820540B1 (ja) |
CA (1) | CA2706325C (ja) |
DE (1) | DE502008003215D1 (ja) |
DK (1) | DK2215274T3 (ja) |
ES (1) | ES2364529T3 (ja) |
HR (1) | HRP20110504T1 (ja) |
MX (1) | MX2010005455A (ja) |
PL (1) | PL2215274T3 (ja) |
PT (1) | PT2215274E (ja) |
RU (1) | RU2520657C2 (ja) |
SI (1) | SI2215274T1 (ja) |
WO (1) | WO2009065915A1 (ja) |
ZA (1) | ZA201003405B (ja) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6310561B2 (ja) | 2014-08-04 | 2018-04-11 | シチズン時計株式会社 | 皮革又は革製品およびこれらの製造方法、6価クロム処理剤、粗皮革又は粗革製品中の6価クロムの処理方法 |
IT201600081688A1 (it) * | 2016-08-03 | 2018-02-03 | Tannow S R L | Impiego di acque di vegetazione olearia nell'industria conciaria |
CN106755629B (zh) * | 2016-12-30 | 2018-09-14 | 广州市骏腾皮革制品有限公司 | 一种皮革复鞣剂的制备方法 |
CN107354246A (zh) * | 2017-08-29 | 2017-11-17 | 安徽乐踏鞋业有限公司 | 一种皮鞋的防霉变方法 |
CN112755970B (zh) * | 2021-01-11 | 2023-10-03 | 陕西科技大学 | 基于天然生物质水凝胶的含铬制革废水治理及资源化利用方法 |
EP4379068A1 (en) | 2022-12-01 | 2024-06-05 | Institut National Des Sciences Appliquées De Rouen | Iridoid or seco-iridoid derivatives and their use in a tanning process |
EP4379067A1 (en) | 2022-12-01 | 2024-06-05 | Institut National Des Sciences Appliquées De Rouen | Iridoid derivatives and their use in a tanning process |
CN116656888B (zh) * | 2023-05-17 | 2024-05-14 | 烟台和壹博物馆有限公司 | 一种绿色环保型皮张的制备方法及其鞣制剂组合物和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62115100A (ja) * | 1985-11-13 | 1987-05-26 | カセラ・アクチエンゲゼルシヤフト | なめし剤およびその製造方法 |
JP2001026518A (ja) * | 1999-07-13 | 2001-01-30 | Dhc Co | 皮膚外用剤組成物 |
JP2001181198A (ja) * | 1999-10-14 | 2001-07-03 | Nisshin Oil Mills Ltd:The | 美肌剤、皮膚の抗老化剤、美白剤および皮膚外用剤 |
EP1489135A1 (en) * | 2003-06-17 | 2004-12-22 | NIZO food research | Use of secoiridoids, preferably oleuropein, for cross-linking biopolymers |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB563288A (en) * | 1942-11-30 | 1944-08-08 | Ici Ltd | Improvements in or relating to the production of leather and of compositions for usetherein |
SU735636A1 (ru) | 1978-04-12 | 1980-05-25 | За витель 735636 (И) | Растительное сырье дл производства дубителей |
SU1141115A1 (ru) | 1983-09-28 | 1985-02-23 | Центральный научно-исследовательский институт кожевенно-обувной промышленности | Способ дублени кож дл низа обуви |
JPS63258641A (ja) * | 1987-04-16 | 1988-10-26 | Suntory Ltd | マイクロカプセルの製造方法 |
DE19507572A1 (de) * | 1995-03-03 | 1996-09-12 | Helmut Geihsler | Verfahren zur Zurichtung von tierischen Häuten oder Fellen |
AU2003209672A1 (en) | 2002-02-28 | 2003-09-09 | Council Of Scientific And Industrial Research | A process for making chrome tanned leathers |
US20050229324A1 (en) * | 2002-06-28 | 2005-10-20 | Jens Fennen | Process and auxiliaries for the treatment of organically tanned leather |
RU2225451C1 (ru) | 2003-03-31 | 2004-03-10 | ФГУП "Центральный научно-исследовательский институт кожевенно-обувной промышленности" | Способ выработки натуральной ворсовой кожи |
-
2007
- 2007-11-23 EP EP07121380A patent/EP2062985A1/de not_active Withdrawn
-
2008
- 2008-11-21 PL PL08852678T patent/PL2215274T3/pl unknown
- 2008-11-21 RU RU2010125621/13A patent/RU2520657C2/ru active
- 2008-11-21 SI SI200830293T patent/SI2215274T1/sl unknown
- 2008-11-21 AU AU2008327902A patent/AU2008327902B2/en active Active
- 2008-11-21 BR BRPI0820540-0A patent/BRPI0820540B1/pt active IP Right Grant
- 2008-11-21 PT PT08852678T patent/PT2215274E/pt unknown
- 2008-11-21 EP EP08852678A patent/EP2215274B1/de active Active
- 2008-11-21 JP JP2010534482A patent/JP5302327B2/ja active Active
- 2008-11-21 CA CA2706325A patent/CA2706325C/en active Active
- 2008-11-21 CN CN2008801171772A patent/CN101868555B/zh active Active
- 2008-11-21 WO PCT/EP2008/065954 patent/WO2009065915A1/de active Application Filing
- 2008-11-21 MX MX2010005455A patent/MX2010005455A/es active IP Right Grant
- 2008-11-21 ES ES08852678T patent/ES2364529T3/es active Active
- 2008-11-21 DE DE502008003215T patent/DE502008003215D1/de active Active
- 2008-11-21 KR KR1020107013801A patent/KR101415399B1/ko active IP Right Grant
- 2008-11-21 DK DK08852678.5T patent/DK2215274T3/da active
- 2008-11-21 AT AT08852678T patent/ATE505563T1/de active
- 2008-11-21 US US12/744,183 patent/US9328394B2/en active Active
-
2010
- 2010-05-14 ZA ZA2010/03405A patent/ZA201003405B/en unknown
-
2011
- 2011-07-06 HR HR20110504T patent/HRP20110504T1/hr unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62115100A (ja) * | 1985-11-13 | 1987-05-26 | カセラ・アクチエンゲゼルシヤフト | なめし剤およびその製造方法 |
JP2001026518A (ja) * | 1999-07-13 | 2001-01-30 | Dhc Co | 皮膚外用剤組成物 |
JP2001181198A (ja) * | 1999-10-14 | 2001-07-03 | Nisshin Oil Mills Ltd:The | 美肌剤、皮膚の抗老化剤、美白剤および皮膚外用剤 |
EP1489135A1 (en) * | 2003-06-17 | 2004-12-22 | NIZO food research | Use of secoiridoids, preferably oleuropein, for cross-linking biopolymers |
Also Published As
Publication number | Publication date |
---|---|
CA2706325A1 (en) | 2009-05-28 |
KR20100111271A (ko) | 2010-10-14 |
JP5302327B2 (ja) | 2013-10-02 |
EP2062985A1 (de) | 2009-05-27 |
KR101415399B1 (ko) | 2014-07-04 |
ZA201003405B (en) | 2011-03-30 |
ATE505563T1 (de) | 2011-04-15 |
SI2215274T1 (sl) | 2011-08-31 |
MX2010005455A (es) | 2010-06-02 |
EP2215274A1 (de) | 2010-08-11 |
HRP20110504T1 (hr) | 2011-08-31 |
EP2215274B1 (de) | 2011-04-13 |
CN101868555B (zh) | 2013-07-10 |
CA2706325C (en) | 2016-01-05 |
US20100275380A1 (en) | 2010-11-04 |
CN101868555A (zh) | 2010-10-20 |
PT2215274E (pt) | 2011-07-13 |
AU2008327902B2 (en) | 2013-08-22 |
ES2364529T3 (es) | 2011-09-06 |
AU2008327902A1 (en) | 2009-05-28 |
PL2215274T3 (pl) | 2011-09-30 |
RU2520657C2 (ru) | 2014-06-27 |
RU2010125621A (ru) | 2011-12-27 |
BRPI0820540B1 (pt) | 2019-05-21 |
DK2215274T3 (da) | 2011-08-01 |
DE502008003215D1 (de) | 2011-05-26 |
BRPI0820540A2 (pt) | 2015-06-16 |
US9328394B2 (en) | 2016-05-03 |
WO2009065915A1 (de) | 2009-05-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5302327B2 (ja) | 皮革および皮膚のなめし剤およびなめし方法 | |
Dettmer et al. | Environmentally friendly hide unhairing: enzymatic hide processing for the replacement of sodium sulfide and delimig | |
Beghetto et al. | The leather industry: a chemistry insight Part I: an overview of the industrial process | |
Wang et al. | An integrated cleaner beamhouse process for minimization of nitrogen pollution in leather manufacture | |
Sinkiewicz et al. | Solubilization of keratins and functional properties of their isolates and hydrolysates | |
US8002846B2 (en) | Method for manufacturing protein filling agent for leather utilizing animal hairs | |
EP3494237A1 (en) | Use of olive mill waste waters in the leather tanning industry | |
Saranya et al. | Value addition of fish waste in the leather industry for dehairing | |
EP3425069B1 (en) | A deliming process | |
Zhang et al. | An integrated pickling-bating technology for reducing ammonia-nitrogen and chloride pollution in leather manufacturing | |
CN103060487A (zh) | 减小皮革损伤的脱毛酶制剂 | |
CN103555866B (zh) | 一种采用新型酶法脱毛的生态汽车革制造方法 | |
KR100441377B1 (ko) | 단백질 분해효소를 이용한 피혁의 제조방법 및 피혁제조공정 폐기물의 처리방법 | |
WO2015104716A1 (en) | A composition for water free, pickle free chrome tanning of hides/skins | |
US20220347069A1 (en) | Process for Dehairing and Liming of Hides, Skins or Pelts | |
AU2002308063B2 (en) | Improvements in leather processing | |
CN107893134B (zh) | 一种环保型醛酸皮革鞣剂的制备方法 | |
US20100263134A1 (en) | Leather processing | |
HAILE | COLLEGE OF BIOLOGICAL AND CHEMICAL ENGINEERING ENVIRONMENTAL ENGINEERING DEPARTMENT | |
Krishnamoorthy et al. | USE OF GREENER CHEMICALS FOR ENVIRONMENTAL FRIENDLY TANNING PROCESSES. | |
KR20060117339A (ko) | 석회 설파이드가 없는 탈모 및 섬유 개방 방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110920 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20121112 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20121127 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130227 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130403 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130611 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130620 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 5302327 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |