JP2011252176A - ポリウレタン樹脂製造用の触媒組成物及びポリウレタン樹脂の製造方法 - Google Patents
ポリウレタン樹脂製造用の触媒組成物及びポリウレタン樹脂の製造方法 Download PDFInfo
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- JP2011252176A JP2011252176A JP2011205224A JP2011205224A JP2011252176A JP 2011252176 A JP2011252176 A JP 2011252176A JP 2011205224 A JP2011205224 A JP 2011205224A JP 2011205224 A JP2011205224 A JP 2011205224A JP 2011252176 A JP2011252176 A JP 2011252176A
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- Prior art keywords
- catalyst
- foam
- producing
- catalyst composition
- amine compound
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- 229910052757 nitrogen Inorganic materials 0.000 claims description 56
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Landscapes
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Abstract
Description
で示されるアミン化合物、(B)分子内に少なくとも1つのヒドロキシアルキル基を有する第3級アミン化合物、及び(C)トリエチレンジアミンからなるポリウレタン樹脂製造用の触媒組成物。
本発明の触媒組成物、及び参考例、比較例の触媒を用い硬質ポリウレタンフォームを製造した例を以下に示す。
200mlの硝子製サンプル瓶に、表1、表2に示す組成で、表3に示す触媒を、それらの全量が100gとなるように量り取った。次いでそれらを良く混合し、溶解させた後、触媒混合液を20℃程度に温度調節して、相溶性を以下のとおり判定した
○:均一な透明溶液、×:結晶が析出。
表1、表2に示す触媒組成物又は触媒を用い、表4に示す硬質ポリウレタンフォーム処方を実施し、それらの反応性及びフォーム物性を評価した。
クリームタイム:フォームが上昇を開始する時間を目視にて測定
ゲルタイム:反応が進行し液状物質より、樹脂状物質に変わる時間を測定
ライズタイム:フォームの上昇が停止する時間を目視にて測定。
フォームコア密度:モールド成型フォームの中心部を20×20×5cmの寸法にカットし、寸法、重量を正確に測定してコア密度を算出した。
◎:殆ど臭い無し、○:微かに臭気あり、△:臭気有り、×:強い臭気有り。
比較例1〜比較例3から明らかなとおり、(A)上記一般式(1)で示されるアミン化合物単独では、触媒活性が低いため触媒使用量を多くする必要がある。これに対し、実施例から明らかなとおり、本発明の触媒組成物では、触媒活性が高くなるため、触媒使用量を低減することができる。
フォームコア密度:実施例におけるフォームコア密度は、比較例1〜比較例3及び比較例7〜比較例12におけるフォームコア密度の約10〜20%程度低くなっており、これは本発明の触媒組成物がフォームの低密度化に有効であることを示している。
200mlの硝子製サンプル瓶に、表6に示す組成で、表3に示す触媒を、それらの全量が100gとなるように量り取った。次いでそれらを良く混合し、溶解させた後、触媒混合液を20℃程度に温度調節して、相溶性を以下のとおり判定した
○:均一な透明溶液、×:結晶が析出。
表5に示す触媒組成物又は触媒を用い表6に示す硬質ポリウレタンフォーム処方を実施し、それらの反応性及びフォーム物性を評価した。
◎:ボイド無し、○:微かにボイドあり、×:ボイド全面にあり。
比較例14、比較例15から明らかなとおり、(A)分子内に炭素数8〜18の範囲の長鎖脂肪族モノアミン化合物、又は(B)分子内にヒドロキシアルキル基を有する第3級アミン化合物単独では触媒活性が低くため、触媒使用量を多くする必要がある。また、比較例19から明らかなとおり、(A)分子内に炭素数8〜18の範囲の長鎖脂肪族モノアミン化合物と(B)分子内にヒドロキシアルキル基を有する第3級アミン化合物又は(C)トリエチレンジアミン以外のアミン化合物との触媒組成物も、触媒活性が低いため、触媒使用量を多くする必要がある。これに対し、実施例から明らかなとおり、本発明の触媒組成物では、触媒活性が高くなるため、触媒使用量を低減することができる。
脱型時間:比較例14、比較例15から明らかなとおり、(A)分子内に炭素数8〜18の範囲の長鎖脂肪族モノアミン化合物、又は(B)分子内にヒドロキシアルキル基を有する第3級アミン化合物単独では脱型時間が長い。また、比較例19から明らかなとおり、(A)分子内に炭素数8〜18の範囲の長鎖脂肪族モノアミン化合物と(B)分子内にヒドロキシアルキル基を有する第3級アミン化合物又は(C)トリエチレンジアミン以外のアミン化合物の触媒組成物も脱型時間が長くなっている。これに対し、実施例から明らかなとおり、本発明の触媒組成物は脱型時間を大幅に短縮することができる。
Claims (7)
- (A)一般式(1)で示されるアミン化合物、(B)分子内に少なくとも1つのヒドロキシアルキル基を有する第3級アミン化合物、及び(C)トリエチレンジアミンの混合比率が10〜90/10〜90/20〜5(重量%)の範囲[ただし、(A)、(B)及び(C)の合計が100(重量%)を超えることはない。]であることを特徴とする請求項1に記載の触媒組成物。
- (A)一般式(1)で示されるアミン化合物が、ジメチルオクチルアミン、ジメチルノニルアミン、ジメチルデシルアミン、ジメチルウンデシルアミン、ジメチルドデシルアミン、ジメチルトリデシルアミン、ジメチルテトラデシルアミン、ジメチルペンタデシルアミン、ジメチルヘキサデシルアミン、ジメチルヘプタデシルアミン及びジメチルオクタデシルアミンからなる群より選ばれる1種又は2種以上のアミン化合物であることを特徴とする請求項1又は請求項2のいずれかに記載の触媒組成物。
- (B)分子内に少なくとも1つのヒドロキシアルキル基を有する第3級アミン化合物が、N,N−ジメチルエタノールアミン、N,N−ジメチルアミノエトキシエタノール、N,N−ジメチルアミノエチル−N’−メチルアミノエタノール、N,N−ジメチルアミノプロピル−N’−メチルアミノエタノール、N,N,N’−トリメチル−N’−ヒドロキシエチルビスアミノエチルエーテル、N,N−ジメチルアミノエチル−N’−メチルアミノエチル−N”−メチルアミノイソプロパノール、N,N−ビス(3−ジメチルアミノプロピル)−N−イソプロパノールアミン、N−(3−ジメチルアミノプロピル)−N,N−ジイソプロパノールアミン、N−(2−ヒドロキシエチル)−N’−メチルピペラジン、N,N−ジメチルアミノヘキサノール、及び5−ジメチルアミノ−3−メチル−1−ペンタノール、1−(2−ヒドロキシプロピル)−2−メチルイミダゾールからなる群より選ばれる1種又は2種以上のアミン化合物であることを特徴とする請求項1乃至請求項3のいずれかに記載の触媒組成物。
- ポリオールとポリイソシアネートを請求項1乃至請求項4のいずれかに記載の触媒組成物の存在下に反応させることを特徴とするポリウレタン樹脂の製造方法。
- ポリオールとポリイソシアネートを触媒及び発泡剤の存在下に反応させて硬質ポリウレタンフォームを製造する方法において、触媒として、請求項1乃至請求項4のいずれかに記載の触媒組成物を使用することを特徴とする硬質ポリウレタンフォームの製造方法。
- ポリオールとポリイソシアネートを触媒及び発泡剤の存在下に反応させて軟質ポリウレタンフォームを製造する方法において、触媒として、請求項1乃至請求項4のいずれかに記載の触媒組成物を使用することを特徴とする軟質ポリウレタンフォームの製造方法。
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