JP2011207927A - 樹脂製マンドレル - Google Patents
樹脂製マンドレル Download PDFInfo
- Publication number
- JP2011207927A JP2011207927A JP2010074182A JP2010074182A JP2011207927A JP 2011207927 A JP2011207927 A JP 2011207927A JP 2010074182 A JP2010074182 A JP 2010074182A JP 2010074182 A JP2010074182 A JP 2010074182A JP 2011207927 A JP2011207927 A JP 2011207927A
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- JP
- Japan
- Prior art keywords
- resin
- containing compound
- mandrel
- polyester
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920005989 resin Polymers 0.000 title claims abstract description 38
- 239000011347 resin Substances 0.000 title claims abstract description 38
- 150000001875 compounds Chemical class 0.000 claims abstract description 43
- 229920000728 polyester Polymers 0.000 claims abstract description 30
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 25
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 229920001400 block copolymer Polymers 0.000 claims abstract description 21
- 229920001225 polyester resin Polymers 0.000 claims abstract description 19
- 239000004645 polyester resin Substances 0.000 claims abstract description 19
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000011342 resin composition Substances 0.000 claims abstract description 9
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 8
- 229920000570 polyether Polymers 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 7
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- 229920003232 aliphatic polyester Polymers 0.000 claims abstract description 6
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 3
- -1 polybutylene terephthalate Polymers 0.000 claims description 46
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 15
- 239000004593 Epoxy Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 9
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- 239000003822 epoxy resin Substances 0.000 claims description 6
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- 238000002844 melting Methods 0.000 abstract description 16
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- 239000002253 acid Substances 0.000 description 12
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 12
- 150000002148 esters Chemical class 0.000 description 10
- 150000002009 diols Chemical class 0.000 description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 238000004073 vulcanization Methods 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 239000000806 elastomer Substances 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 239000011162 core material Substances 0.000 description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
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- 239000011248 coating agent Substances 0.000 description 3
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- 239000000539 dimer Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- XLDBGFGREOMWSL-UHFFFAOYSA-N n,n'-bis[2,6-di(propan-2-yl)phenyl]methanediimine Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N=C=NC1=C(C(C)C)C=CC=C1C(C)C XLDBGFGREOMWSL-UHFFFAOYSA-N 0.000 description 3
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229920001610 polycaprolactone Polymers 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 3
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- FNGGVJIEWDRLFV-UHFFFAOYSA-N anthracene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=CC3=C(C(O)=O)C(C(=O)O)=CC=C3C=C21 FNGGVJIEWDRLFV-UHFFFAOYSA-N 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 239000002981 blocking agent Substances 0.000 description 2
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
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- 238000001816 cooling Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 2
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
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- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- MRDNMQDAPCZRNE-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) 2-heptadecylpropanedioate Chemical class C1OC1COC(=O)C(CCCCCCCCCCCCCCCCC)C(=O)OCC1CO1 MRDNMQDAPCZRNE-UHFFFAOYSA-N 0.000 description 1
- VKEFGOTVPWVWCH-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) 2-methylbenzene-1,4-dicarboxylate Chemical compound CC1=CC(C(=O)OCC2OC2)=CC=C1C(=O)OCC1CO1 VKEFGOTVPWVWCH-UHFFFAOYSA-N 0.000 description 1
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- ZXOATMQSUNJNNG-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,3-dicarboxylate Chemical compound C=1C=CC(C(=O)OCC2OC2)=CC=1C(=O)OCC1CO1 ZXOATMQSUNJNNG-UHFFFAOYSA-N 0.000 description 1
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- XFUOBHWPTSIEOV-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohexane-1,2-dicarboxylate Chemical compound C1CCCC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 XFUOBHWPTSIEOV-UHFFFAOYSA-N 0.000 description 1
- NFVGWOSADNLNHZ-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) decanedioate Chemical compound C1OC1COC(=O)CCCCCCCCC(=O)OCC1CO1 NFVGWOSADNLNHZ-UHFFFAOYSA-N 0.000 description 1
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- 125000004432 carbon atom Chemical group C* 0.000 description 1
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- HKZPXAWSERLSRM-UHFFFAOYSA-N n,n'-bis(2,6-diethylphenyl)methanediimine Chemical compound CCC1=CC=CC(CC)=C1N=C=NC1=C(CC)C=CC=C1CC HKZPXAWSERLSRM-UHFFFAOYSA-N 0.000 description 1
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- OTLDLKLSNZMTTA-UHFFFAOYSA-N octahydro-1h-4,7-methanoindene-1,5-diyldimethanol Chemical compound C1C2C3C(CO)CCC3C1C(CO)C2 OTLDLKLSNZMTTA-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- UHHKSVZZTYJVEG-UHFFFAOYSA-N oxepane Chemical compound C1CCCOCC1 UHHKSVZZTYJVEG-UHFFFAOYSA-N 0.000 description 1
- JUVGLPRIQOJMIR-VOTSOKGWSA-N oxiran-2-ylmethyl (e)-3-phenylprop-2-enoate Chemical compound C=1C=CC=CC=1/C=C/C(=O)OCC1CO1 JUVGLPRIQOJMIR-VOTSOKGWSA-N 0.000 description 1
- DTOBMOSGTHNELI-UHFFFAOYSA-N oxiran-2-ylmethyl 5-phenylpenta-2,4-dienoate Chemical compound C=1C=CC=CC=1C=CC=CC(=O)OCC1CO1 DTOBMOSGTHNELI-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920003224 poly(trimethylene oxide) Polymers 0.000 description 1
- 229920000921 polyethylene adipate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
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- 239000000454 talc Substances 0.000 description 1
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
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- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DQFBYFPFKXHELB-VAWYXSNFSA-N trans-chalcone Chemical compound C=1C=CC=CC=1C(=O)\C=C\C1=CC=CC=C1 DQFBYFPFKXHELB-VAWYXSNFSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
【解決手段】主として結晶性芳香族ポリエステルからなる高融点結晶性重合体セグメント(a1)と、主として脂肪族ポリエーテル単位および/または脂肪族ポリエステル単位からなる低融点重合体セグメント(a2)とを主たる構成成分とするポリエステルブロック共重合体(A)5〜70重量%とポリエステル樹脂(B)30〜95重量%からなる樹脂成分100重量部に対し、下記(I)式を満足する量のエポキシ基含有化合物(C)と、0.1〜10重量部のカルボジイミド基含有化合物(D)とを配合した熱可塑性樹脂組成物。Y/3000≦X≦Y/50・・・(I)(式中のXはエポキシ基含有化合物の配合量(重量部)を示し、Yはエポキシ基含有化合物のエポキシ当量(g/eq)を示す。)
【選択図】なし
Description
Y/3000≦X≦Y/50・・・(I)
(式中のXはエポキシ基含有化合物の配合量(重量部)を示し、Yはエポキシ基含有化合物のエポキシ当量(g/eq)を示す。)
前記ポリエステル樹脂(B)が、ポリブチレンテレフタレート、ポリブチレンナフタレート及び、それらの混合物からなる群より選ばれる少なくとも1種であること、
前記エポキシ基含有化合物(C)が、グリシジルエステル型エポキシ樹脂、グリシジル基含有ビニル系共重合体及び、それらの混合物からなる群より選ばれる少なくとも1種であること
ASTM D1238に記載された方法に従って測定したメルトインデックスが0.1〜15g/分であること、
JIS K7113に記載された方法に従って測定した23℃における引張弾性率が800MPa以上であること、
100℃熱水処理後における引張破断伸び(JIS K7113)保持率半減時間が200時間以上であること、
が、いずれも好ましい条件であり、これらの条件を適応することにより、一層優れた効果の取得を期待することができる。
(I) Y/3000≦X≦Y/50
(II) Y/1000≦X≦Y/75
(III) Y/ 500≦X≦Y/100
(式中のXはエポキシ基含有化合物の配合量(重量部)を示し、Yはエポキシ基含有化合物のエポキシ当量(g/eq)を示す。尚、エポキシ当量とはJIS K7236に準拠した方法にて測定されたものをさす。)
電気式射出成形機NEX−1000(日精樹脂工業株式会社製)を用いて成形温度270℃、金型温度50℃、射出速度30mm/秒、射出時間10秒、冷却時間10秒の条件で成形したJIS K7113 2号射出試験片(2mm厚)を用いて、JIS K7113に準じ測定した。尚、引張速度は50mm/分で実施した。
ASTM D−1238に従って温度250℃、荷重2,160gで、5分滞留後の重量を測定した。
上記引張試験評価と同様の手順で成形したJIS K7113 2号射出試験片(2mm厚)を、100℃熱水中で浸漬処理後、引張破断伸びを測定し、引張破断伸び保持率が50%となる処理時間を算出した。
表1に示す組成の樹脂組成物を40mm単軸押出機に投入し、250℃の温度で溶融混練し、サイジングダイから押出し、φ6mmとなるように吐出量(回転数)及び引き取り速度を調節することでマンドレルを成形した。このマンドレルを製造する際の状態を以下のように示した。
○・・・良好に成形可能
△・・・サイジングダイから自重で少したれるが、成形は可能
×・・・成形できず
上記の方法で成形されたφ6mmマンドレルを用いて、ゴムホースを成形、加硫後(140℃×1hr)、水圧にてマンドレルを引き抜く操作を繰り返し、表面にクラックが生じるまでの回数を測定した。
[ポリエーテルエステルブロック共重合体(A−1)の製造]
テレフタル酸1149部、1,4−ブタンジオール966部および数平均分子量約 1000のポリ(テトラメチレンオキシド)グリコール497部を、チタンテトラブトキシド2部と共にヘリカルリボン型撹拌翼を備えた反応容器に仕込み、225℃で3時間加熱して反応水を系外に留出しながらエステル化反応を行なった。反応混合物に”イルガノックス”1098(チバガイギー社製ヒンダ−ドフェノ−ル系酸化防止剤)0.5部を添加した後、245℃に昇温し、次いで50分かけて系内の圧力を27Paの減圧とし、その条件下で2時間45分重合を行わせた。得られたポリマを水中にストランド状で吐出し、カッティングを行なってペレットとした。
ジメチルテレフタル酸816部、1,4−ブタンジオール646部および数平均分子量約1000のポリ(テトラメチレンオキシド)グリコール78部を、チタンテトラブトキシド3部およびトリメリット酸無水物3部と共にヘリカルリボン型攪拌翼を備えた反応容器に仕込み、225℃で3時間加熱して、理論メタノール量の95%のメタノールを系外に留出させた。反応混合物に”イルガノックス”1098 ( チバガイギー社製ヒンダ−ドフェノ−ル系酸化防止剤)0.5部を添加した後、245 ℃に昇温し、次いで、 50分かけて系内の圧力を27Paの減圧とし、その条件下で1時間50分重合をおこなった。得られたポリマを水中にストランド状で吐出し、カッティングによりペレットとした。
ポリブチレンテレフタレート樹脂 固有粘度1.74 東レ(株)社製PBT樹脂“トレコン”1400Sを用いた。
ジャパンエポキシレジン(株)製 jER191P(エポキシ当量:172 g/eq)を用いた。
反応性エチレン系コポリマーである住友化学(株)製ボンドファーストE(エポキシ当量:1200 g/eq)を用いた。
下記実施例において使用したカルボジイミド化合物は以下のとおりである。
ビス(2,6−ジイソプロピルフェニル)カルボジイミド
参考例で得られたポリエステルブロック共重合体(A−1)、(A−2)に、ポリエステル樹脂 (B)、エポキシ基含有化合物(C−1)、(C−2)、カルボジイミド基を含有する化合物(D)を、表1に示す配合比率(重量%) でV−ブレンダーを用いて混合し、直径45mmで3条ネジタイプのスクリューを有する2軸押出機を用いて240℃で溶融混練し、ペレット化した。
表1に示す配合比率(重量%)で、実施例1〜5と同様に溶融混練し、ペレット化した。実施例1〜5と同様に物性を評価した結果を表1に併せて示す。
Claims (6)
- 主として結晶性芳香族ポリエステルからなる高融点結晶性重合体セグメント(a1)と、主として脂肪族ポリエーテル単位および/または脂肪族ポリエステル単位からなる低融点重合体セグメント(a2)とを主たる構成成分とするポリエステルブロック共重合体(A)5〜70重量%とポリエステル樹脂(B)30〜95重量%からなる樹脂成分100重量部に対し、下記(I)式を満足する量のエポキシ基含有化合物(C)と、0.1〜10重量部のカルボジイミド基含有化合物(D)とを配合した熱可塑性樹脂組成物からなることを特徴とする樹脂製マンドレル。
Y/3000≦X≦Y/50・・・(I)
(式中のXはエポキシ基含有化合物の配合量(重量部)を示し、Yはエポキシ基含有化合物のエポキシ当量(g/eq)を示す。) - 前記ポリエステル樹脂(B)が、ポリブチレンテレフタレート、ポリブチレンナフタレート及び、それらの混合物からなる群より選ばれる少なくとも1種であることを特徴とする請求項1に記載の樹脂製マンドレル。
- 前記エポキシ基含有化合物(C)が、グリシジルエステル型エポキシ樹脂、グリシジル基含有ビニル系共重合体及び、それらの混合物からなる群より選ばれる少なくとも1種であることを特徴とする請求項1または2に記載の樹脂製マンドレル。
- ASTM D1238に記載された方法に従って測定したメルトインデックスが0.1〜15g/分であることを特徴とする請求項1〜3のいずれか1項に記載の樹脂製マンドレル。
- JIS K7113に記載された方法に従って測定した23℃における引張弾性率が800MPa以上であることを特徴とする請求項1〜4のいずれか1項に記載の樹脂製マンドレル。
- 100℃熱水中における引張破断伸び(JIS K7113)保持率半減時間が200時間以上であることを特徴とする請求項〜5のいずれか1項に記載の樹脂製マンドレル。
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WO2020166444A1 (ja) * | 2019-02-12 | 2020-08-20 | 東洋紡株式会社 | ポリブチレンテレフタレート樹脂組成物 |
JPWO2020166444A1 (ja) * | 2019-02-12 | 2021-12-16 | 東洋紡株式会社 | ポリブチレンテレフタレート樹脂組成物 |
JP7400743B2 (ja) | 2019-02-12 | 2023-12-19 | 東洋紡エムシー株式会社 | ポリブチレンテレフタレート樹脂組成物 |
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