JP2010534762A5 - - Google Patents
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- Publication number
- JP2010534762A5 JP2010534762A5 JP2010520050A JP2010520050A JP2010534762A5 JP 2010534762 A5 JP2010534762 A5 JP 2010534762A5 JP 2010520050 A JP2010520050 A JP 2010520050A JP 2010520050 A JP2010520050 A JP 2010520050A JP 2010534762 A5 JP2010534762 A5 JP 2010534762A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- olefin
- producing
- meso
- borate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- -1 alkylaluminum compound Chemical class 0.000 claims 15
- 238000000034 method Methods 0.000 claims 12
- 229920013639 polyalphaolefin Polymers 0.000 claims 12
- 239000007788 liquid Substances 0.000 claims 11
- 239000012190 activator Substances 0.000 claims 8
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 8
- 239000000178 monomer Substances 0.000 claims 6
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims 5
- NMLGKEDSNASIHM-UHFFFAOYSA-N (2,3,4,5,6,7,8-heptafluoronaphthalen-1-yl)oxyboronic acid Chemical compound FC1=C(F)C(F)=C2C(OB(O)O)=C(F)C(F)=C(F)C2=C1F NMLGKEDSNASIHM-UHFFFAOYSA-N 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 4
- 125000000129 anionic group Chemical group 0.000 claims 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 239000003446 ligand Substances 0.000 claims 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 3
- 229910052726 zirconium Inorganic materials 0.000 claims 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- 230000008018 melting Effects 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 125000005207 tetraalkylammonium group Chemical group 0.000 claims 2
- 150000003623 transition metal compounds Chemical class 0.000 claims 2
- 125000005208 trialkylammonium group Chemical group 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000002841 Lewis acid Substances 0.000 claims 1
- 229910004354 OF 20 W Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 150000004703 alkoxides Chemical class 0.000 claims 1
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 239000000539 dimer Substances 0.000 claims 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052735 hafnium Chemical group 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 claims 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 150000007517 lewis acids Chemical class 0.000 claims 1
- 239000012968 metallocene catalyst Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- SRSUADNYIFOSLP-UHFFFAOYSA-N tris(2,3,4,5,6,7,8-heptafluoronaphthalen-1-yl)borane Chemical compound FC1=C(F)C(F)=C2C(B(C=3C4=C(F)C(F)=C(F)C(F)=C4C(F)=C(F)C=3F)C=3C4=C(F)C(F)=C(C(=C4C(F)=C(F)C=3F)F)F)=C(F)C(F)=C(F)C2=C1F SRSUADNYIFOSLP-UHFFFAOYSA-N 0.000 claims 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/832,287 US8513478B2 (en) | 2007-08-01 | 2007-08-01 | Process to produce polyalphaolefins |
| US11/832,287 | 2007-08-01 | ||
| PCT/US2008/069832 WO2009017953A2 (en) | 2007-08-01 | 2008-07-11 | Process to produce polyalphaolefins |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013181933A Division JP5934684B2 (ja) | 2007-08-01 | 2013-09-03 | ポリアルファオレフィンの製造プロセス |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010534762A JP2010534762A (ja) | 2010-11-11 |
| JP2010534762A5 true JP2010534762A5 (OSRAM) | 2012-03-01 |
| JP5401458B2 JP5401458B2 (ja) | 2014-01-29 |
Family
ID=38871767
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010520050A Expired - Fee Related JP5401458B2 (ja) | 2007-08-01 | 2008-07-11 | ポリアルファオレフィンの製造プロセス |
| JP2013181933A Expired - Fee Related JP5934684B2 (ja) | 2007-08-01 | 2013-09-03 | ポリアルファオレフィンの製造プロセス |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013181933A Expired - Fee Related JP5934684B2 (ja) | 2007-08-01 | 2013-09-03 | ポリアルファオレフィンの製造プロセス |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8513478B2 (OSRAM) |
| EP (1) | EP2173779A2 (OSRAM) |
| JP (2) | JP5401458B2 (OSRAM) |
| CN (2) | CN101809042B (OSRAM) |
| CA (1) | CA2693060C (OSRAM) |
| WO (1) | WO2009017953A2 (OSRAM) |
Families Citing this family (97)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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- 2008-07-11 CN CN200880101551.XA patent/CN101809042B/zh active Active
- 2008-07-11 CN CN201410611933.4A patent/CN104327200B/zh active Active
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2013
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