JP2010529284A - ポリ（ヒドロキシアルカン酸）及びそれを使った物品 - Google Patents
ポリ（ヒドロキシアルカン酸）及びそれを使った物品 Download PDFInfo
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- JP2010529284A JP2010529284A JP2010512290A JP2010512290A JP2010529284A JP 2010529284 A JP2010529284 A JP 2010529284A JP 2010512290 A JP2010512290 A JP 2010512290A JP 2010512290 A JP2010512290 A JP 2010512290A JP 2010529284 A JP2010529284 A JP 2010529284A
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- JP
- Japan
- Prior art keywords
- acid
- composition
- poly
- hydroxyalkanoic
- nucleating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002253 acid Substances 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 79
- 238000000034 method Methods 0.000 claims abstract description 31
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims abstract description 3
- 239000002667 nucleating agent Substances 0.000 claims description 33
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- 238000002425 crystallisation Methods 0.000 claims description 31
- 230000008025 crystallization Effects 0.000 claims description 31
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 27
- 229920001577 copolymer Polymers 0.000 claims description 23
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 21
- -1 alkyl amide Chemical class 0.000 claims description 18
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 15
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 14
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- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 10
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- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
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- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
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- FMHKPLXYWVCLME-UHFFFAOYSA-N 4-hydroxy-valeric acid Chemical compound CC(O)CCC(O)=O FMHKPLXYWVCLME-UHFFFAOYSA-N 0.000 claims description 3
- PHOJOSOUIAQEDH-UHFFFAOYSA-N 5-hydroxypentanoic acid Chemical compound OCCCCC(O)=O PHOJOSOUIAQEDH-UHFFFAOYSA-N 0.000 claims description 3
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- AFENDNXGAFYKQO-VKHMYHEASA-N (S)-2-hydroxybutyric acid Chemical compound CC[C@H](O)C(O)=O AFENDNXGAFYKQO-VKHMYHEASA-N 0.000 claims description 2
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- 239000005639 Lauric acid Substances 0.000 claims description 2
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 claims description 2
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 claims 2
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- KZDCPJDWDXMJRA-UHFFFAOYSA-N 2-hydroxybutanoic acid;pentanoic acid Chemical compound CCCCC(O)=O.CCC(O)C(O)=O KZDCPJDWDXMJRA-UHFFFAOYSA-N 0.000 claims 1
- JRHWHSJDIILJAT-UHFFFAOYSA-N 2-hydroxypentanoic acid Chemical compound CCCC(O)C(O)=O JRHWHSJDIILJAT-UHFFFAOYSA-N 0.000 claims 1
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- 125000000217 alkyl group Chemical group 0.000 description 5
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- 238000000113 differential scanning calorimetry Methods 0.000 description 5
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- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 5
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- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 4
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 3
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- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0884—Epoxide-containing esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
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| US93405007P | 2007-06-11 | 2007-06-11 | |
| PCT/US2008/066379 WO2008154527A1 (en) | 2007-06-11 | 2008-06-10 | Poly(hydroxyalkanoic acid) and articles therewith |
Publications (2)
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| JP2010529284A true JP2010529284A (ja) | 2010-08-26 |
| JP2010529284A5 JP2010529284A5 (enExample) | 2011-07-28 |
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| JP2010512290A Pending JP2010529284A (ja) | 2007-06-11 | 2008-06-10 | ポリ（ヒドロキシアルカン酸）及びそれを使った物品 |
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|---|---|
| US (1) | US8586649B2 (enExample) |
| JP (1) | JP2010529284A (enExample) |
| WO (1) | WO2008154527A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014040568A (ja) * | 2012-07-27 | 2014-03-06 | Unitika Ltd | ポリ乳酸系樹脂組成物及び成形体 |
| WO2017026486A1 (ja) * | 2015-08-10 | 2017-02-16 | 日産化学工業株式会社 | アミノトリアジン誘導体及び脂肪酸を含むポリエステル樹脂組成物 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7642301B2 (en) | 2007-09-07 | 2010-01-05 | E.I. Du Pont De Nemours And Company | Poly (hydroxyalkanoic acid) compositions with improved toughness, dimensional stability and stretchability |
| US8653192B2 (en) * | 2009-07-17 | 2014-02-18 | Arkema France | Method for manufacturing a polyester composition having improved impact properties |
| US20110024954A1 (en) * | 2009-07-28 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Modified poly(hydroxyalkanoic acid) composition |
| US20110028622A1 (en) | 2009-07-28 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Poly(hydroxyalkanoic acid) blown film |
| US8349955B2 (en) | 2009-09-24 | 2013-01-08 | E I Du Pont De Nemours And Company | Poly(hydroxyalkanoic acid) plasticized with poly(trimethylene ether) glycol |
| EP3281983B1 (de) * | 2016-08-12 | 2022-06-15 | Evonik Operations GmbH | Zähe polyamidformmasse |
| CN114989583A (zh) * | 2022-05-20 | 2022-09-02 | 北京蓝晶微生物科技有限公司 | 聚羟基烷酸酯的酸类成核剂及聚羟基烷酸酯成型体 |
| CN115232456B (zh) * | 2022-09-22 | 2023-01-17 | 北京蓝晶微生物科技有限公司 | 含羟基酸类成核剂的聚羟基烷酸酯组合物、聚羟基烷酸酯成型体及其制备方法 |
| CN117209980B (zh) * | 2023-05-29 | 2024-04-30 | 北京蓝晶微生物科技有限公司 | 一种聚羟基脂肪酸酯组合物、聚羟基脂肪酸酯成型体及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02166154A (ja) * | 1988-12-20 | 1990-06-26 | Nippon Petrochem Co Ltd | 熱可塑性ポリエステル組成物 |
| JPH07188537A (ja) * | 1993-12-27 | 1995-07-25 | Tokuyama Corp | 樹脂組成物 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014040568A (ja) * | 2012-07-27 | 2014-03-06 | Unitika Ltd | ポリ乳酸系樹脂組成物及び成形体 |
| WO2017026486A1 (ja) * | 2015-08-10 | 2017-02-16 | 日産化学工業株式会社 | アミノトリアジン誘導体及び脂肪酸を含むポリエステル樹脂組成物 |
| JPWO2017026486A1 (ja) * | 2015-08-10 | 2018-05-31 | 日産化学工業株式会社 | アミノトリアジン誘導体及び脂肪酸を含むポリエステル樹脂組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008154527A1 (en) | 2008-12-18 |
| US20080306185A1 (en) | 2008-12-11 |
| US8586649B2 (en) | 2013-11-19 |
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