JP2010523703A5 - - Google Patents
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- Publication number
- JP2010523703A5 JP2010523703A5 JP2010503224A JP2010503224A JP2010523703A5 JP 2010523703 A5 JP2010523703 A5 JP 2010523703A5 JP 2010503224 A JP2010503224 A JP 2010503224A JP 2010503224 A JP2010503224 A JP 2010503224A JP 2010523703 A5 JP2010523703 A5 JP 2010523703A5
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- mixture
- dichlorohydrin
- phase
- vapor contact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 claims description 81
- 238000000034 method Methods 0.000 claims description 55
- 239000000203 mixture Substances 0.000 claims description 45
- 239000007788 liquid Substances 0.000 claims description 37
- 150000002148 esters Chemical class 0.000 claims description 34
- 239000007791 liquid phase Substances 0.000 claims description 33
- DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 17
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 17
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 17
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 17
- 239000008346 aqueous phase Substances 0.000 claims description 15
- 238000004821 distillation Methods 0.000 claims description 14
- 239000012074 organic phase Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000009835 boiling Methods 0.000 claims description 11
- 239000012320 chlorinating reagent Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 11
- 239000006227 byproduct Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 9
- 238000010992 reflux Methods 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 6
- 239000012808 vapor phase Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000005194 fractionation Methods 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 238000007038 hydrochlorination reaction Methods 0.000 claims description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 230000007423 decrease Effects 0.000 claims description 2
- 238000006735 epoxidation reaction Methods 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- 238000010977 unit operation Methods 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims 3
- -1 water Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US92302007P | 2007-04-12 | 2007-04-12 | |
| PCT/US2008/059979 WO2008128013A1 (en) | 2007-04-12 | 2008-04-11 | Process and apparatus for azeotropic recovery of dichlorohydrins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010523703A JP2010523703A (ja) | 2010-07-15 |
| JP2010523703A5 true JP2010523703A5 (enExample) | 2011-05-19 |
Family
ID=39643205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010503224A Pending JP2010523703A (ja) | 2007-04-12 | 2008-04-11 | ジクロロヒドリンの共沸回収方法及び装置 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8629305B2 (enExample) |
| EP (1) | EP2137124A1 (enExample) |
| JP (1) | JP2010523703A (enExample) |
| KR (1) | KR20090130123A (enExample) |
| CN (1) | CN101657405A (enExample) |
| TW (2) | TW201518267A (enExample) |
| WO (1) | WO2008128013A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101657404B (zh) | 2007-04-12 | 2013-11-06 | 陶氏环球技术公司 | 用于经由共馏回收二氯代醇的方法和设备 |
| TW201518267A (zh) | 2007-04-12 | 2015-05-16 | Dow Global Technologies Llc | 用於二氯丙醇的共沸回收之方法與設備 |
| EP2268597A1 (en) * | 2008-04-09 | 2011-01-05 | Dow Global Technologies Inc. | Process and apparatus for efficient recovery of dichlorohydrins |
| WO2011000896A1 (en) | 2009-07-03 | 2011-01-06 | Akzo Nobel Chemicals International B.V. | Process for preparing dichlorohydrin |
| CN102918015A (zh) * | 2010-05-26 | 2013-02-06 | 陶氏环球技术有限责任公司 | 多羟基化的脂族烃的氢氯化反应的方法 |
| TWI547470B (zh) * | 2015-12-18 | 2016-09-01 | 長春人造樹脂廠股份有限公司 | 製造二氯丙醇之方法 |
| MY192222A (en) * | 2016-08-11 | 2022-08-09 | Eve Rubber Inst Co Ltd | Process for the purification of the solvent deriving from the production of elastomeric blends |
| CN109107207B (zh) * | 2018-07-18 | 2021-07-23 | 万华化学集团股份有限公司 | 一种带有外循环系统的反应精馏装置及其应用 |
| CN111875477A (zh) * | 2020-08-03 | 2020-11-03 | 岳阳隆兴实业公司 | 一种邻氯醇共沸提纯方法 |
| CN111943805A (zh) * | 2020-09-16 | 2020-11-17 | 安徽工业大学 | 一种(r)-3-氯-1,2-丙二醇的制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE197308C (enExample) | ||||
| JPS60258171A (ja) | 1984-06-04 | 1985-12-20 | Showa Denko Kk | エピクロルヒドリンの製造方法 |
| CZ20032346A3 (cs) | 2003-09-01 | 2005-04-13 | Spolek Pro Chemickou A Hutní Výrobu,A.S. | Způsob přípravy dichlorpropanolů z glycerinu |
| EP1770081A1 (en) * | 2003-11-20 | 2007-04-04 | SOLVAY (Société Anonyme) | Process for producing dichloropropanol from glycerol , the glycerol coming eventualy from the conversion of animal fats in the manufacture of biodiesel |
| US6908038B1 (en) * | 2004-02-27 | 2005-06-21 | Imotion Corp. | Multi-connector memory card with retractable sheath to protect the connectors |
| ATE454370T1 (de) * | 2004-07-21 | 2010-01-15 | Dow Global Technologies Inc | Umwandlung eines mehrfach hydroxylierten aliphatischen kohlenwasserstoffes oder esters daraus in ein chlorhydrin |
| EP1762556A1 (en) * | 2005-05-20 | 2007-03-14 | SOLVAY (Société Anonyme) | Process for producing dichloropropanol from glycerol |
| US20080214848A1 (en) * | 2005-05-20 | 2008-09-04 | Solvay (Societe Anonyme) | Method For Making an Epoxy Starting From a Chlorhydrine |
| CN100509726C (zh) | 2007-01-26 | 2009-07-08 | 江苏工业学院 | 一种从甘油制备二氯丙醇的方法 |
| CN101657404B (zh) * | 2007-04-12 | 2013-11-06 | 陶氏环球技术公司 | 用于经由共馏回收二氯代醇的方法和设备 |
| TW201518267A (zh) | 2007-04-12 | 2015-05-16 | Dow Global Technologies Llc | 用於二氯丙醇的共沸回收之方法與設備 |
| US8664453B2 (en) * | 2007-04-12 | 2014-03-04 | Dow Global Technologies Inc. | Multi-stage process and apparatus for recovering dichlorohydrins |
-
2008
- 2008-04-11 TW TW104101060A patent/TW201518267A/zh unknown
- 2008-04-11 JP JP2010503224A patent/JP2010523703A/ja active Pending
- 2008-04-11 TW TW097113155A patent/TWI490193B/zh not_active IP Right Cessation
- 2008-04-11 CN CN200880011774A patent/CN101657405A/zh active Pending
- 2008-04-11 US US12/595,493 patent/US8629305B2/en not_active Expired - Fee Related
- 2008-04-11 KR KR1020097023535A patent/KR20090130123A/ko not_active Ceased
- 2008-04-11 WO PCT/US2008/059979 patent/WO2008128013A1/en not_active Ceased
- 2008-04-11 EP EP08745564A patent/EP2137124A1/en not_active Withdrawn
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