JP2010513651A5 - - Google Patents
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- Publication number
- JP2010513651A5 JP2010513651A5 JP2009542271A JP2009542271A JP2010513651A5 JP 2010513651 A5 JP2010513651 A5 JP 2010513651A5 JP 2009542271 A JP2009542271 A JP 2009542271A JP 2009542271 A JP2009542271 A JP 2009542271A JP 2010513651 A5 JP2010513651 A5 JP 2010513651A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- composition according
- magnesium
- dichloride
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003054 catalyst Substances 0.000 claims 16
- -1 aluminum compound Chemical class 0.000 claims 5
- 239000000126 substance Substances 0.000 claims 5
- 150000001336 alkenes Chemical class 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 125000005843 halogen group Chemical group 0.000 claims 4
- 239000002245 particle Substances 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 239000012190 activator Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 150000002681 magnesium compounds Chemical class 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 239000011148 porous material Substances 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 2
- 150000002430 hydrocarbons Chemical group 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims 2
- 239000004800 polyvinyl chloride Substances 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- PTIYVPNUBVBVES-UHFFFAOYSA-K Cl[V](Cl)(Cl)C1C=CC=C1 Chemical compound Cl[V](Cl)(Cl)C1C=CC=C1 PTIYVPNUBVBVES-UHFFFAOYSA-K 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910021549 Vanadium(II) chloride Inorganic materials 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- XBSRAMGGHVSEBQ-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)[Zr+2]C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(CCC)[Zr+2]C1C=CC=C1 XBSRAMGGHVSEBQ-UHFFFAOYSA-L 0.000 claims 1
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 125000006165 cyclic alkyl group Chemical group 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- IKDHFLDEDJBKMR-UHFFFAOYSA-K cyclopenta-1,3-diene;hafnium(4+);trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Hf+4].C1C=CC=[C-]1 IKDHFLDEDJBKMR-UHFFFAOYSA-K 0.000 claims 1
- YMNCCEXICREQQV-UHFFFAOYSA-L cyclopenta-1,3-diene;titanium(4+);dichloride Chemical compound [Cl-].[Cl-].[Ti+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 YMNCCEXICREQQV-UHFFFAOYSA-L 0.000 claims 1
- QOXHZZQZTIGPEV-UHFFFAOYSA-K cyclopenta-1,3-diene;titanium(4+);trichloride Chemical compound Cl[Ti+](Cl)Cl.C=1C=C[CH-]C=1 QOXHZZQZTIGPEV-UHFFFAOYSA-K 0.000 claims 1
- 229910052735 hafnium Chemical group 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 claims 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 claims 1
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 claims 1
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 claims 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 claims 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 claims 1
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 claims 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 239000011949 solid catalyst Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- ITAKKORXEUJTBC-UHFFFAOYSA-L vanadium(ii) chloride Chemical compound Cl[V]Cl ITAKKORXEUJTBC-UHFFFAOYSA-L 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 claims 1
- QMBQEXOLIRBNPN-UHFFFAOYSA-L zirconocene dichloride Chemical compound [Cl-].[Cl-].[Zr+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 QMBQEXOLIRBNPN-UHFFFAOYSA-L 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/641,160 US7662894B2 (en) | 2006-12-19 | 2006-12-19 | Polymer supported metallocene catalyst composition for polymerizing olefins |
| PCT/IB2007/004396 WO2008075202A2 (en) | 2006-12-19 | 2007-12-19 | Polymer supported metallocene catalyst composition for polymerizing olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010513651A JP2010513651A (ja) | 2010-04-30 |
| JP2010513651A5 true JP2010513651A5 (OSRAM) | 2010-12-24 |
Family
ID=39528254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009542271A Withdrawn JP2010513651A (ja) | 2006-12-19 | 2007-12-19 | オレフィンを重合するためのポリマー担持型メタロセン触媒組成物 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7662894B2 (OSRAM) |
| EP (1) | EP2129696A2 (OSRAM) |
| JP (1) | JP2010513651A (OSRAM) |
| WO (1) | WO2008075202A2 (OSRAM) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011072851A1 (en) * | 2009-12-18 | 2011-06-23 | Basell Polyolefine Gmbh | Process for the preparation of supported catalysts |
| JP6457716B2 (ja) * | 2011-01-14 | 2019-01-23 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 修飾メタロセン触媒の作成法、生成された触媒およびそれらの使用 |
| KR101339550B1 (ko) * | 2011-11-24 | 2013-12-10 | 삼성토탈 주식회사 | 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법 |
| US8957168B1 (en) * | 2013-08-09 | 2015-02-17 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations with an alcohol compound |
| US9244785B2 (en) | 2013-11-13 | 2016-01-26 | Sandisk Enterprise Ip Llc | Simulated power failure and data hardening |
| KR102403962B1 (ko) * | 2014-02-11 | 2022-06-02 | 유니베이션 테크놀로지즈, 엘엘씨 | 폴리올레핀 생성물의 제조 방법 |
| GB2533770B (en) * | 2014-12-22 | 2021-02-10 | Norner Verdandi As | Polyethylene for pipes |
| KR101800866B1 (ko) * | 2016-04-26 | 2017-12-21 | 대림산업 주식회사 | 용융강도가 높은 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체 |
| US10723819B2 (en) | 2017-02-20 | 2020-07-28 | Exxonmobil Chemical Patents, Inc. | Supported catalyst systems and processes for use thereof |
| KR102271789B1 (ko) | 2017-02-20 | 2021-06-30 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 지지된 촉매 시스템 및 그의 사용 방법 |
| US10844150B2 (en) | 2017-08-04 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes |
| CN111108130B (zh) | 2017-08-04 | 2022-06-28 | 埃克森美孚化学专利公司 | 具有含-CH2-SiMe3部分的非桥连二茂铪的混合催化剂 |
| US10703838B2 (en) | 2017-10-31 | 2020-07-07 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems with four metallocenes on a single support |
| CN115850552B (zh) | 2017-12-01 | 2024-08-06 | 埃克森美孚化学专利公司 | 催化剂体系和使用其的聚合方法 |
| US10926250B2 (en) | 2017-12-01 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
| ES2978120T3 (es) | 2017-12-18 | 2024-09-05 | Dow Global Technologies Llc | Sistema de catalizador de circonoceno-titanoceno |
| US20210079129A1 (en) * | 2017-12-18 | 2021-03-18 | Dow Global Technologies Llc | Hafnocene-titanocene catalyst system |
| US10851187B2 (en) | 2018-01-31 | 2020-12-01 | Exxonmobil Chemical Patents Inc. | Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same |
| US10865258B2 (en) | 2018-01-31 | 2020-12-15 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same |
| ES3041743T3 (en) | 2018-03-26 | 2025-11-14 | Dow Global Technologies Llc | Spray-dried zirconocene catalyst system |
| CN109012744B (zh) * | 2018-09-20 | 2021-06-11 | 四川文理学院 | 一种可见光催化降解氮氧化物的方法 |
| KR102576669B1 (ko) * | 2018-12-26 | 2023-09-11 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 올레핀계 중합체의 제조방법 |
| KR102512380B1 (ko) * | 2019-02-20 | 2023-03-22 | 주식회사 엘지화학 | 촉매 조성물 및 이를 이용한 폴리올레핀의 제조 방법 |
Family Cites Families (30)
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| US4382124B1 (en) * | 1958-07-18 | 1994-10-04 | Rohm & Haas | Process for preparing macroreticular resins, copolymers and products of said process |
| US4021599A (en) * | 1975-08-04 | 1977-05-03 | Gulf Research & Development Company | Olefin polymerization process and catalyst |
| US4414369A (en) * | 1977-08-17 | 1983-11-08 | Nippon Oil Company, Limited | Continuous process for the preparation of polyolefins having widely distributed molecular weights |
| US4530841A (en) * | 1980-08-08 | 1985-07-23 | Merck & Co., Inc. | 6- And 6,6-disubstituted-3-substituted amino-1-azabicyclo-[3.2.0]hept-2-en-7-one-2-carboxylic acid |
| JPS6045645B2 (ja) * | 1980-10-09 | 1985-10-11 | 三井化学株式会社 | オレフイン類の気相重合方法 |
| US4522982A (en) * | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| FR2577558B1 (fr) * | 1985-02-19 | 1987-03-06 | Bp Chimie Sa | Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse |
| US5124418A (en) * | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US5118648A (en) * | 1988-10-05 | 1992-06-02 | Mobil Oil Corporation | Particulate polymer-supported olefin polymerization catalyst |
| US5032562A (en) * | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
| US5070055A (en) * | 1990-06-29 | 1991-12-03 | Union Carbide Chemicals And Plastics Technology Corporation | Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution |
| EP0724604B2 (en) * | 1993-10-21 | 2005-12-14 | Exxonmobil Oil Corporation | Polyolefin blends of bimodal molecular weight distribution |
| US5614456A (en) * | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| IT1270070B (it) * | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
| US5882750A (en) * | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
| US6413901B1 (en) * | 1998-10-16 | 2002-07-02 | Saudi Basic Industries Corporation | Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same |
| US6403520B1 (en) * | 1999-09-17 | 2002-06-11 | Saudi Basic Industries Corporation | Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst |
| US6288182B1 (en) * | 1999-10-12 | 2001-09-11 | Saudi Basic Industries Corporation | Supported metallocene catalyst system for olefin polymerization |
| NO20013880L (no) * | 2000-08-22 | 2002-02-25 | Rohm & Haas | Matriks og fremgangsmåte for fremstilling av polyolefiner |
| GB0023662D0 (en) | 2000-09-27 | 2000-11-08 | Borealis Tech Oy | Supported catalyst |
| GC0000293A (en) * | 2000-10-10 | 2006-11-01 | Saudi Basic Ind Corp | Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems |
| CN1131246C (zh) * | 2000-12-14 | 2003-12-17 | 中国石油化工股份有限公司 | 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用 |
| DE60104809T2 (de) * | 2001-02-07 | 2005-01-05 | Saudi Basic Industries Corp. | Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung |
| EP1231223B1 (en) * | 2001-02-07 | 2004-04-28 | Saudi Basic Industries Corporation | Process for the polymerization of olefins |
| US6861487B2 (en) * | 2003-04-15 | 2005-03-01 | Saudi Basic Industries Corporation | Catalyst precursor for the polymerization of olefins and polymerization process using the same |
-
2006
- 2006-12-19 US US11/641,160 patent/US7662894B2/en not_active Expired - Fee Related
-
2007
- 2007-12-19 WO PCT/IB2007/004396 patent/WO2008075202A2/en not_active Ceased
- 2007-12-19 JP JP2009542271A patent/JP2010513651A/ja not_active Withdrawn
- 2007-12-19 EP EP07872054A patent/EP2129696A2/en not_active Withdrawn
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