JP2010235979A - ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 - Google Patents
ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 Download PDFInfo
- Publication number
- JP2010235979A JP2010235979A JP2009082867A JP2009082867A JP2010235979A JP 2010235979 A JP2010235979 A JP 2010235979A JP 2009082867 A JP2009082867 A JP 2009082867A JP 2009082867 A JP2009082867 A JP 2009082867A JP 2010235979 A JP2010235979 A JP 2010235979A
- Authority
- JP
- Japan
- Prior art keywords
- gas barrier
- layer
- sin
- barrier film
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000004888 barrier function Effects 0.000 title claims abstract description 165
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 239000002985 plastic film Substances 0.000 claims abstract description 37
- 229920006255 plastic film Polymers 0.000 claims abstract description 37
- 239000010410 layer Substances 0.000 claims description 161
- 239000007789 gas Substances 0.000 claims description 126
- 238000004050 hot filament vapor deposition Methods 0.000 claims description 27
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 16
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- -1 silane compound Chemical class 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000004973 liquid crystal related substance Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 238000001228 spectrum Methods 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 description 100
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 17
- 239000011112 polyethylene naphthalate Substances 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000010521 absorption reaction Methods 0.000 description 12
- 239000000758 substrate Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 238000000862 absorption spectrum Methods 0.000 description 8
- 238000007789 sealing Methods 0.000 description 8
- 230000006866 deterioration Effects 0.000 description 7
- 229910010272 inorganic material Inorganic materials 0.000 description 7
- 239000011147 inorganic material Substances 0.000 description 7
- 239000010409 thin film Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- 230000001747 exhibiting effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005401 electroluminescence Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920006393 polyether sulfone Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000005394 sealing glass Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000005525 hole transport Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/36—Carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/42—Silicides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
- H01L31/0392—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/844—Encapsulations
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1341—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Crystallography & Structural Chemistry (AREA)
- Optics & Photonics (AREA)
- Ceramic Engineering (AREA)
- Chemical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
- Electroluminescent Light Sources (AREA)
- Photovoltaic Devices (AREA)
- Wrappers (AREA)
Abstract
【解決手段】プラスティックフィルムの各主面に接するガスバリヤ層は触媒CVDによるSiCNFH層で0.01<I(SiH)/I(SiN)<0.05、0.00<I(CH)/I(SiN)<0.07、0.04<I(NH)/I(SiN)<0.08、および0.05<I(CF)/I(SiN)<0.3の条件、またはSiOCNH層で0.1<I(SiH)/I(NH)<0.9、0.0<I(CH)/I(NH)<0.3、8<I(SiN)/I(NH)<20、および2<I(SiO2)/I(NH)<8の条件、またはSiCNH層で0.01<I(SiH)/I(SiN)<0.05、0.00<I(CH)/I(SiN)<0.07、および0.04<I(NH)/I(SiN)<0.08の条件を満たすガスバリアフィルム。
【選択図】図1
Description
本発明者はまず、本発明に密接に関連する参考例1として、下地のプラスティックフィルムの一方主面上のみに有機・無機ハイブリッド層であるSiCNFH層の単層が形成されたガスバリアフィルムのバリア特性を調べた。
本発明の実施例1によるガスバリアフィルムは、図1に示されているように、下地としてのプラスティックフィルム1の両主面上に単層のガスバリア層2を有している。具体的には、本実施例1において、PENフィルムの両面のいずれ側にも単層のSiCNFHバリヤ層が、参考例1の場合に類似のCat−CVDで形成された。しかし、本実施例1では、Cat−CVDの原料ガス流量比の1MS/H2/N2/NH3/C4F8が5/200/200/200/20(sccm)を基本として種々に変更されるとともに、フィラメント温度をも種々に変化させることによって複数のガスバリアフィルムが作製された。
本発明の実施例2によるガスバリアフィルムにおいても、実施例1の場合に類似して、PENフィルムの両面に単層のガスバリア層が形成された。ただし、本実施例2においては、単層のガスバリア層としてSiOCNH層がCat−CVDで形成された。
本発明の実施例3によるガスバリアフィルムにおいても、実施例1の場合に類似して、PENフィルムの両面に単層のガスバリア層が形成された。ただし、本実施例3においては、単層のガスバリア層としてSiCNH層がCat−CVDで形成された。
上述の実施例では、プラスティックフィルムの両面に同じ種類のガスバリア層を形成した場合が例示として説明された。しかし、プラスティックフィルムの両面に堆積されるガスバリア層が同じ種類であることは必要ではない。すなわち、プラスティックフィルムの一主面上にSiCNFH層、SiOCNH層、およびSiCNH層から選択されたバリア層が堆積され、その一主面上で選択された種類と異なるSiCNFH層、SiOCNH層、およびSiCNH層のいずれかが他方主面上に堆積されてもよい。
上述の背景技術において説明されたように、ガスバリアフィルムは食料品、医薬品、タッチパネル、有機EL(エレクトロ・ルミネッセンス)素子、無機EL素子、太陽電池、電子ペーパなどの種々物品のための保護層として好ましく利用され得る。
Claims (10)
- プラスティックフィルムの両主面の各々に接するガスバリア層を有し、
前記ガスバリア層はCat−CVDで堆積されたSiCNFH層、SiOCNH層、およびSiCNH層のいずれかであり、
前記SiCNFH層は、
0.01<I(SiH)/I(SiN)<0.05、
0.00<I(CH)/I(SiN)<0.07、
0.04<I(NH)/I(SiN)<0.08、および
0.05<I(CF)/I(SiN)<0.3
の条件を満たし、
前記SiOCNH層は、
0.1<I(SiH)/I(NH)<0.9、
0.0<I(CH)/I(NH)<0.3、
8<I(SiN)/I(NH)<20、および
2<I(SiO2)/I(NH)<8
の条件を満たし、そして
前記SiCNH層は、
0.01<I(SiH)/I(SiN)<0.05、
0.00<I(CH)/I(SiN)<0.07、および
0.04<I(NH)/I(SiN)<0.08
の条件を満たし、
ここで、Iはそれに付記された括弧内に示された原子結合に関するフーリエ変換赤外分光スペクトルのピーク強度を表すことを特徴とするガスバリアフィルム。 - 前記SiCNFH層は、
0.01<I(SiH)/I(SiN)<0.03、
0.00<I(CH)/I(SiN)<0.02、
0.05<I(NH)/I(SiN)<0.08、および
0.05<I(CF)/I(SiN)<0.25
の条件を満たし、
前記SiOCNH層は、
0.1<I(SiH)/I(NH)<0.5、
0.0<I(CH)/I(NH)<0.2、
10<I(SiN)/I(NH)<20、および
2<I(SiO2)/I(NH)<5
の条件を満たし、そして
前記SiCNH層は、
0.01<I(SiH)/I(SiN)<0.03、
0.00<I(CH)/I(SiN)<0.02、および
0.05<I(NH)/I(SiN)<0.08
の条件を満たす、
ことを特徴とする請求項1に記載のガスバリアフィルム。 - 前記プラスティックフィルムに接するガスバリア層上において前記SiCNFH層、前記SiOCNH層、および前記SiCNH層のいずれかの付加的なガスバリア層が積層されており、前記プラスティックフィルムに接するガスバリア層と前記付加的ガスバリア層とは互いに異なる種類の層であることを特徴とする請求項1または2に記載のガスバリアフィルム。
- 前記プラスティックフィルムは、120℃以上のガラス転移温度または200℃以上の融点、または200℃以上の液晶転移温度を有する耐熱性のプラスティックフィルムであることを特徴とする請求項1から3のいずれかに記載のガスバリアフィルム。
- 前記プラスティックフィルムは、表面平坦化処理されていることを特徴とする請求項1から4のいずれかに記載のガスバリアフィルム。
- 前記ガスバリアフィルムの少なくとも一方の面上に導電層を付加的に含むことを特徴とする請求項1から5のいずれかに記載のガスバリアフィルム。
- 請求項1から6のいずれかのガスバリアフィルムを保護層として含むことを特徴とする電子デバイス。
- 前記電子デバイスは、タッチパネル、有機ELデバイス、無機ELデバイス、太陽電池、および電子ペーパのいずれかであることを特徴とする請求項7に記載の電子デバイス。
- 請求項1から6のいずれかのガスバリアフィルムで形成されていることを特徴とするガスバリア袋。
- 請求項1から6のいずれかのガスバリアフィルムを製造する方法であって、
有機シラン化合物、有機アミノシリコン化合物、アンモニア、フルオロカーボン、酸素、および水素から選択された原材料を用いてCat−CVDによって前記ガスバリア層が形成されることを特徴とするガスバリアフィルムの製造方法。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009082867A JP5470969B2 (ja) | 2009-03-30 | 2009-03-30 | ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 |
CN201080014250.0A CN102365387B (zh) | 2009-03-30 | 2010-03-23 | 气体屏蔽膜、包含它的电子器件、气体屏蔽袋、以及气体屏蔽膜的制造方法 |
KR1020117025526A KR20120003913A (ko) | 2009-03-30 | 2010-03-23 | 가스 배리어 필름, 이를 포함하는 전자 디바이스, 가스 배리어 백, 및 가스 배리어 필름의 제조 방법 |
US13/259,109 US8871350B2 (en) | 2009-03-30 | 2010-03-23 | Gas barrier film, electronic device including the same, gas barrier bag, and method for producing gas barrier film |
PCT/JP2010/054930 WO2010113693A1 (ja) | 2009-03-30 | 2010-03-23 | ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 |
EP10758467.4A EP2415901A4 (en) | 2009-03-30 | 2010-03-23 | GAS BARRIER FILM, ELECTRONIC DEVICE COMPRISING THE SAME, GAS BARRIER BAG AND METHOD FOR MANUFACTURING THE GAS BARRIER FILM |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009082867A JP5470969B2 (ja) | 2009-03-30 | 2009-03-30 | ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2010235979A true JP2010235979A (ja) | 2010-10-21 |
JP2010235979A5 JP2010235979A5 (ja) | 2012-03-22 |
JP5470969B2 JP5470969B2 (ja) | 2014-04-16 |
Family
ID=42827988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009082867A Expired - Fee Related JP5470969B2 (ja) | 2009-03-30 | 2009-03-30 | ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8871350B2 (ja) |
EP (1) | EP2415901A4 (ja) |
JP (1) | JP5470969B2 (ja) |
KR (1) | KR20120003913A (ja) |
CN (1) | CN102365387B (ja) |
WO (1) | WO2010113693A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011005793A (ja) * | 2009-06-29 | 2011-01-13 | Dainippon Printing Co Ltd | タッチパネル用耐湿熱性透明導電積層体及び耐湿熱透明積層プラスチックタッチパネル |
JP2013218796A (ja) * | 2012-04-04 | 2013-10-24 | Sumitomo Chemical Co Ltd | 電子デバイス |
JP2015229777A (ja) * | 2014-06-03 | 2015-12-21 | 中山 弘 | バリア膜、バリア膜積層体、デバイス、バリア性保護シート、バリア袋およびバリア膜の製造方法 |
JP2016094507A (ja) * | 2014-11-12 | 2016-05-26 | 中山 弘 | 表面改質高分子フィルムの製造方法、高親水性フィルムの製造方法および高撥水性フィルムの製造方法 |
US9410245B2 (en) | 2010-12-28 | 2016-08-09 | Kirin Beer Kabushiki Kaisha | Gas-barrier plastic molded product and manufacturing process therefor |
JP2017073554A (ja) * | 2016-10-28 | 2017-04-13 | 住友化学株式会社 | 電子デバイスの製造方法 |
JP2019077452A (ja) * | 2017-10-20 | 2019-05-23 | 中山 弘 | 包装用袋体及びその包装用フィルムの製造装置 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012020771A1 (ja) * | 2010-08-13 | 2012-02-16 | 旭硝子株式会社 | 積層体および積層体の製造方法 |
TWI530399B (zh) * | 2011-12-27 | 2016-04-21 | Nitto Denko Corp | Transparent gas barrier film, transparent gas barrier film manufacturing method, organic EL element, solar cell and thin film battery (1) |
KR102282214B1 (ko) | 2014-08-01 | 2021-07-26 | 삼성전자주식회사 | 가스 배리어성 점착 시트의 점착층용 조성물, 상기 조성물로부터 제조되는 가스 배리어성 점착 시트, 상기 가스 배리어성 점착 시트가 구비된 광학시트 |
US20160056414A1 (en) * | 2014-08-21 | 2016-02-25 | Universal Display Corporation | Thin film permeation barrier system for substrates and devices and method of making the same |
KR102387751B1 (ko) | 2015-03-11 | 2022-04-15 | 삼성전자주식회사 | 배리어 필름 및 이를 포함하는 양자점-폴리머 복합체 물품 |
US10492221B1 (en) | 2015-06-25 | 2019-11-26 | Marvell International Ltd. | Methods and apparatus for protecting transmissions in a wireless communication network |
US10201009B1 (en) | 2015-08-13 | 2019-02-05 | Marvell International Ltd. | Methods and apparatus for protecting transmissions in a wireless communication network |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004221275A (ja) * | 2003-01-14 | 2004-08-05 | Nec Electronics Corp | 有機絶縁膜及びその製造方法及び有機絶縁膜を用いた半導体装置及びその製造方法。 |
JP2006233064A (ja) * | 2005-02-25 | 2006-09-07 | Material Design Factory:Kk | 光波長変換膜とそれを含む照明装置 |
JP2007088495A (ja) * | 2006-10-30 | 2007-04-05 | Nec Electronics Corp | 有機絶縁膜及びその製造方法及び有機絶縁膜を用いた半導体装置及びその製造方法 |
JP2008155585A (ja) * | 2006-12-26 | 2008-07-10 | Material Design Factory:Kk | ガスバリヤフィルムとその製造方法 |
JP2009502554A (ja) * | 2005-07-20 | 2009-01-29 | スリーエム イノベイティブ プロパティズ カンパニー | 湿気防湿バリアコーティング |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6268695B1 (en) | 1998-12-16 | 2001-07-31 | Battelle Memorial Institute | Environmental barrier material for organic light emitting device and method of making |
WO2000036665A1 (en) | 1998-12-16 | 2000-06-22 | Battelle Memorial Institute | Environmental barrier material for organic light emitting device and method of making |
JP4455039B2 (ja) | 2003-12-16 | 2010-04-21 | 株式会社マテリアルデザインファクトリ− | Si系有機・無機ハイブリッド膜の形成方法 |
US20080009141A1 (en) | 2006-07-05 | 2008-01-10 | International Business Machines Corporation | Methods to form SiCOH or SiCNH dielectrics and structures including the same |
JP4389962B2 (ja) * | 2007-04-26 | 2009-12-24 | ソニー株式会社 | 半導体装置、電子機器、および半導体装置の製造方法 |
-
2009
- 2009-03-30 JP JP2009082867A patent/JP5470969B2/ja not_active Expired - Fee Related
-
2010
- 2010-03-23 EP EP10758467.4A patent/EP2415901A4/en not_active Withdrawn
- 2010-03-23 WO PCT/JP2010/054930 patent/WO2010113693A1/ja active Application Filing
- 2010-03-23 US US13/259,109 patent/US8871350B2/en not_active Expired - Fee Related
- 2010-03-23 CN CN201080014250.0A patent/CN102365387B/zh not_active Expired - Fee Related
- 2010-03-23 KR KR1020117025526A patent/KR20120003913A/ko active Search and Examination
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004221275A (ja) * | 2003-01-14 | 2004-08-05 | Nec Electronics Corp | 有機絶縁膜及びその製造方法及び有機絶縁膜を用いた半導体装置及びその製造方法。 |
JP2006233064A (ja) * | 2005-02-25 | 2006-09-07 | Material Design Factory:Kk | 光波長変換膜とそれを含む照明装置 |
JP2009502554A (ja) * | 2005-07-20 | 2009-01-29 | スリーエム イノベイティブ プロパティズ カンパニー | 湿気防湿バリアコーティング |
JP2007088495A (ja) * | 2006-10-30 | 2007-04-05 | Nec Electronics Corp | 有機絶縁膜及びその製造方法及び有機絶縁膜を用いた半導体装置及びその製造方法 |
JP2008155585A (ja) * | 2006-12-26 | 2008-07-10 | Material Design Factory:Kk | ガスバリヤフィルムとその製造方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011005793A (ja) * | 2009-06-29 | 2011-01-13 | Dainippon Printing Co Ltd | タッチパネル用耐湿熱性透明導電積層体及び耐湿熱透明積層プラスチックタッチパネル |
US9410245B2 (en) | 2010-12-28 | 2016-08-09 | Kirin Beer Kabushiki Kaisha | Gas-barrier plastic molded product and manufacturing process therefor |
JP2013218796A (ja) * | 2012-04-04 | 2013-10-24 | Sumitomo Chemical Co Ltd | 電子デバイス |
JP2015229777A (ja) * | 2014-06-03 | 2015-12-21 | 中山 弘 | バリア膜、バリア膜積層体、デバイス、バリア性保護シート、バリア袋およびバリア膜の製造方法 |
JP2016094507A (ja) * | 2014-11-12 | 2016-05-26 | 中山 弘 | 表面改質高分子フィルムの製造方法、高親水性フィルムの製造方法および高撥水性フィルムの製造方法 |
JP2017073554A (ja) * | 2016-10-28 | 2017-04-13 | 住友化学株式会社 | 電子デバイスの製造方法 |
JP2019077452A (ja) * | 2017-10-20 | 2019-05-23 | 中山 弘 | 包装用袋体及びその包装用フィルムの製造装置 |
Also Published As
Publication number | Publication date |
---|---|
EP2415901A4 (en) | 2013-07-03 |
JP5470969B2 (ja) | 2014-04-16 |
WO2010113693A1 (ja) | 2010-10-07 |
EP2415901A1 (en) | 2012-02-08 |
US20120009368A1 (en) | 2012-01-12 |
CN102365387B (zh) | 2014-05-07 |
KR20120003913A (ko) | 2012-01-11 |
CN102365387A (zh) | 2012-02-29 |
US8871350B2 (en) | 2014-10-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5470969B2 (ja) | ガスバリアフィルム、それを含む電子デバイス、ガスバリア袋、およびガスバリアフィルムの製造方法 | |
US7074501B2 (en) | Coatings with low permeation of gases and vapors | |
JP6056854B2 (ja) | ガスバリア性フィルム、ガスバリア性フィルムの製造方法及び電子デバイス | |
Nam et al. | A composite layer of atomic-layer-deposited Al2O3 and graphene for flexible moisture barrier | |
JP5251071B2 (ja) | バリアフィルムおよびその製造方法 | |
JP2009133000A (ja) | シリコン窒化物膜及びそれを用いたガスバリア膜、薄膜素子 | |
WO2013146964A1 (ja) | 積層フィルム、有機エレクトロルミネッセンス装置、光電変換装置および液晶ディスプレイ | |
JPWO2012077553A1 (ja) | ガスバリア性フィルム、ガスバリア性フィルムの製造方法及び電子デバイス | |
KR102374497B1 (ko) | 적층 필름 및 플렉시블 전자 디바이스 | |
WO2010065966A2 (en) | High rate deposition of thin films with improved barrier layer properties | |
CN102470637A (zh) | 层合体及其制造方法 | |
US20130337259A1 (en) | Gas permeation barrier material | |
JP2009274251A (ja) | 透明バリアフィルムおよびその製造方法 | |
JP2003340971A (ja) | ガスバリア性プラスチックフィルム | |
JP5515861B2 (ja) | ガスバリア性積層フィルム | |
KR20140067079A (ko) | 가스들에 대해 향상된 불투과성을 제공하는 다층 구조 | |
JP5849086B2 (ja) | 多層膜を加工する方法 | |
WO2013188613A1 (en) | Gas permeation barrier material | |
WO2015098670A1 (ja) | 積層フィルム、有機エレクトロルミネッセンス装置、光電変換装置および液晶ディスプレイ | |
JP5078344B2 (ja) | ガスバリヤフィルムとその製造方法 | |
TWI408249B (zh) | 利用電漿增強化學氣相沉積技術在可撓式塑膠基板上連續沉積有機/無機多層水氣阻障層之方法及其製品 | |
WO2015046092A1 (ja) | 積層フィルム、有機エレクトロルミネッセンス装置、光電変換装置および液晶ディスプレイ | |
RU2636075C2 (ru) | Новаторское многослойное барьерное покрытие, способ его изготовления и композиция | |
US11560619B2 (en) | Laminate and method of producing the same, and gas barrier film and method of producing the same | |
JP2009220482A (ja) | 透明バリアフィルムおよびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20110930 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20110930 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120208 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120208 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130917 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131114 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140107 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140120 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |