JP2009536911A5 - - Google Patents
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- JP2009536911A5 JP2009536911A5 JP2008558433A JP2008558433A JP2009536911A5 JP 2009536911 A5 JP2009536911 A5 JP 2009536911A5 JP 2008558433 A JP2008558433 A JP 2008558433A JP 2008558433 A JP2008558433 A JP 2008558433A JP 2009536911 A5 JP2009536911 A5 JP 2009536911A5
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- JP
- Japan
- Prior art keywords
- cnt
- dopant
- multilayer structure
- cnts
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002041 carbon nanotube Substances 0.000 claims 31
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 24
- 239000002019 doping agent Substances 0.000 claims 8
- FYSNRJHAOHDILO-UHFFFAOYSA-N Thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims 6
- 239000000758 substrate Substances 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 2
- 238000001237 Raman spectrum Methods 0.000 claims 1
- -1 ZnSe Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000010894 electron beam technology Methods 0.000 claims 1
- 230000001747 exhibiting Effects 0.000 claims 1
- 230000002349 favourable Effects 0.000 claims 1
- 239000002071 nanotube Substances 0.000 claims 1
- 230000001590 oxidative Effects 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- CBENFWSGALASAD-UHFFFAOYSA-N ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims 1
- 238000009832 plasma treatment Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229910052594 sapphire Inorganic materials 0.000 claims 1
- 239000010980 sapphire Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 229910052950 sphalerite Inorganic materials 0.000 claims 1
- 229910052984 zinc sulfide Inorganic materials 0.000 claims 1
Claims (26)
- 固体カーボンナノチューブ(CNT)組成物であって、
カーボンナノチューブと、
少なくとも0.5重量%のS及び少なくとも0.5重量%のClと
を含み、ラマンスペクトルにおいて1593〜1605cm-1のピーク最大値を有する接線モード(TM)を示す、CNT組成物。 - 300S/cmを超えるバルク導電率を有する、請求項1に記載のCNT組成物。
- 300S/cm〜50,000S/cmの範囲のバルク導電率を有する、請求項1又は2に記載のCNT組成物。
- 2000〜5000S/cmの範囲のバルク導電率を有する、請求項1〜3のいずれかに記載のCNT組成物。
- 前記組成物がネットワークフィルムである、請求項1〜4のいずれかに記載のCNT組成物。
- 0.40を超えるCNTの体積分率を有する、請求項1〜5のいずれかに記載のCNT組成物。
- 500nm未満のフィルム厚を有する、請求項1〜6のいずれかに記載のCNT組成物。
- 8を超えるG/Dを有する、請求項1〜7のいずれかに記載のCNT組成物。
- 8〜40の範囲のG/Dを有する、請求項1〜8のいずれかに記載のCNT組成物。
- 14〜18の範囲のG/Dを有する、請求項1〜9のいずれかに記載のCNT組成物。
- CNTの処理方法であって、
CNTを準備し、そして
該CNTとドープ剤とを接触させること
を含み、そして、次の少なくとも一つ:
該CNTにUV処理を施すこと;又は
ドープ剤を添加する前に約14〜約22の範囲のG/D比を示すように該CNTに複数の欠陥を導入すること;又は
該ドープ剤を添加する前に若しくは添加すると同時に該CNTに酸化プラズマ処理を施すこと;又は
該ドープ剤を添加する前に若しくは添加すると同時に該CNTに電子線を照射すること;又は
ドーピング触媒を使用して該ドーピング工程を触媒すること
をさらに特徴とする、CNTの処理方法。 - 前記CNTをUVオゾン処理することを含む、請求項11に記載の方法。
- 異なるドーパントで連続的に処理して、異なるバンドギャップを有するナノチューブにおいて好ましいデプレッションレベルを達成することを含む、請求項11又は12に記載の方法。
- 前記CNTが500nm未満の厚さを有するフィルムの形態にある、請求項11〜13のいずれかに記載の方法。
- 前記CNTを液状ドープ剤で処理することを含む、請求項11〜14のいずれかに記載の方法。
- 前記CNTを少なくとも60%のドープ剤を含有する溶液で処理することを含む、請求項11〜14のいずれかに記載の方法。
- 前記CNTと液体塩化チオニルとを接触させることを含む、請求項15に記載の方法。
- 前記CNTを酸素の存在下でUV光により処理する、請求項11に記載の方法。
- G/D比が8〜30の範囲になるようにCNTに欠陥を導入する、請求項11〜18のいずれかに記載の方法。
- 基材と、ストレージ層と、該ストレージ層に直接接触するドープCNT層とを備える多層構造体。
- 前記基材がNIR又はIRにおいて透明である、請求項20に記載の多層構造体。
- 前記基材がZnS、ZnSe、サファイア、Ge、Si又はそれらの組み合わせを含む、請求項20に記載の多層構造体。
- 前記ドープCNT層が塩化チオニルを含む、請求項20〜22のいずれかに記載の多層構造体。
- 前記ストレージ層が塩化チオニルを含む、請求項20〜23のいずれかに記載の多層構造体。
- 前記ストレージ層が0.01重量%未満のドーパントを含む、請求項20〜24のいずれかに記載の多層構造体。
- 前記ストレージ層が重合体を含む、請求項20〜25のいずれかに記載の多層構造体。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78060706P | 2006-03-09 | 2006-03-09 | |
US87182406P | 2006-12-24 | 2006-12-24 | |
PCT/US2007/006138 WO2008054473A2 (en) | 2006-03-09 | 2007-03-09 | Doped carbon nanotube composition and methods of forming the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009536911A JP2009536911A (ja) | 2009-10-22 |
JP2009536911A5 true JP2009536911A5 (ja) | 2010-04-30 |
Family
ID=39301647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008558433A Pending JP2009536911A (ja) | 2006-03-09 | 2007-03-09 | 改質カーボンナノチューブ及びカーボンナノチューブの形成方法 |
Country Status (5)
Country | Link |
---|---|
US (4) | US9365728B2 (ja) |
EP (2) | EP1996512B1 (ja) |
JP (1) | JP2009536911A (ja) |
KR (1) | KR20080098664A (ja) |
WO (1) | WO2008054473A2 (ja) |
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CA2658578A1 (en) | 2006-07-18 | 2008-09-04 | The University Of Southern California | Organic optoelectronic device electrodes with nanotubes |
KR20100093473A (ko) | 2006-12-27 | 2010-08-25 | 데이비드 브루스 게이건 | 투명한 전도성 나노 복합재 |
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CN101360387B (zh) * | 2007-08-03 | 2012-06-13 | 富葵精密组件(深圳)有限公司 | 柔性电路板基膜、柔性电路板基板及柔性电路板 |
JP2013518439A (ja) * | 2010-01-25 | 2013-05-20 | ボード オブ トラスティーズ オブ ザ レランド スタンフォード ジュニア ユニバーシティ | フラーレンドープナノ構造体及びその作製方法 |
-
2007
- 2007-03-09 US US12/282,173 patent/US9365728B2/en active Active
- 2007-03-09 EP EP07867014.8A patent/EP1996512B1/en active Active
- 2007-03-09 KR KR1020087022670A patent/KR20080098664A/ko not_active Application Discontinuation
- 2007-03-09 EP EP11004569.7A patent/EP2374754B1/en active Active
- 2007-03-09 WO PCT/US2007/006138 patent/WO2008054473A2/en active Application Filing
- 2007-03-09 JP JP2008558433A patent/JP2009536911A/ja active Pending
-
2016
- 2016-05-23 US US15/162,557 patent/US10059848B2/en active Active
- 2016-09-15 US US15/265,860 patent/US10913864B2/en active Active
-
2021
- 2021-01-27 US US17/159,827 patent/US20210147696A1/en not_active Abandoned
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