JP2009531519A - Ｐｂｔ単位を含有する、減少した有機炭素排出量を有する熱可塑性樹脂 - Google Patents
Ｐｂｔ単位を含有する、減少した有機炭素排出量を有する熱可塑性樹脂 Download PDFInfo
- Publication number
- JP2009531519A JP2009531519A JP2009502858A JP2009502858A JP2009531519A JP 2009531519 A JP2009531519 A JP 2009531519A JP 2009502858 A JP2009502858 A JP 2009502858A JP 2009502858 A JP2009502858 A JP 2009502858A JP 2009531519 A JP2009531519 A JP 2009531519A
- Authority
- JP
- Japan
- Prior art keywords
- pbt
- resin
- compound
- titanium catalyst
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract description 10
- 229910052799 carbon Inorganic materials 0.000 title abstract description 10
- 229920005992 thermoplastic resin Polymers 0.000 title description 4
- 229920005989 resin Polymers 0.000 claims abstract description 73
- 239000011347 resin Substances 0.000 claims abstract description 73
- 150000001875 compounds Chemical class 0.000 claims abstract description 60
- 239000010936 titanium Substances 0.000 claims abstract description 58
- 239000003054 catalyst Substances 0.000 claims abstract description 50
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 50
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 38
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 16
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 73
- -1 polybutylene terephthalate Polymers 0.000 claims description 54
- 238000010943 off-gassing Methods 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 229920001971 elastomer Polymers 0.000 claims description 9
- 239000000806 elastomer Substances 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 8
- 125000004104 aryloxy group Chemical group 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- MLCHBQKMVKNBOV-UHFFFAOYSA-M dioxido(phenyl)phosphanium Chemical compound [O-]P(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-M 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- MORLYCDUFHDZKO-UHFFFAOYSA-N 3-[hydroxy(phenyl)phosphoryl]propanoic acid Chemical compound OC(=O)CCP(O)(=O)C1=CC=CC=C1 MORLYCDUFHDZKO-UHFFFAOYSA-N 0.000 claims description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
- KTLIMPGQZDZPSB-UHFFFAOYSA-N diethylphosphinic acid Chemical compound CCP(O)(=O)CC KTLIMPGQZDZPSB-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 2
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 2
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 claims 2
- 229910001380 potassium hypophosphite Inorganic materials 0.000 claims 1
- CRGPNLUFHHUKCM-UHFFFAOYSA-M potassium phosphinate Chemical compound [K+].[O-]P=O CRGPNLUFHHUKCM-UHFFFAOYSA-M 0.000 claims 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 50
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 25
- 150000003839 salts Chemical class 0.000 description 11
- 238000000465 moulding Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 8
- 239000011734 sodium Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 229920010930 Hytrel® 5556 Polymers 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 108091001629 crustin Proteins 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- GGQHNQQPLWRNHD-UHFFFAOYSA-N 1,3,7,9-tetratert-butyl-11-hydroxy-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP(O)(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C GGQHNQQPLWRNHD-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid group Chemical group C(CCCCC(=O)O)(=O)O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical group OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000004949 mass spectrometry Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 125000004437 phosphorous atom Chemical group 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- GRWPYGBKJYICOO-UHFFFAOYSA-N 2-methylpropan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-] GRWPYGBKJYICOO-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 238000004847 absorption spectroscopy Methods 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Chemical group 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- XSAOTYCWGCRGCP-UHFFFAOYSA-K aluminum;diethylphosphinate Chemical compound [Al+3].CCP([O-])(=O)CC.CCP([O-])(=O)CC.CCP([O-])(=O)CC XSAOTYCWGCRGCP-UHFFFAOYSA-K 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- OOYGSFOGFJDDHP-KMCOLRRFSA-N kanamycin A sulfate Chemical group OS(O)(=O)=O.O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CN)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O[C@@H]2[C@@H]([C@@H](N)[C@H](O)[C@@H](CO)O2)O)[C@H](N)C[C@@H]1N OOYGSFOGFJDDHP-KMCOLRRFSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78542706P | 2006-03-24 | 2006-03-24 | |
| PCT/US2007/006940 WO2007111890A2 (en) | 2006-03-24 | 2007-03-20 | Thermoplastic resins containing pbt units, having reduced organic carbon emissions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009531519A true JP2009531519A (ja) | 2009-09-03 |
| JP2009531519A5 JP2009531519A5 (enExample) | 2010-03-25 |
Family
ID=38440254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009502858A Pending JP2009531519A (ja) | 2006-03-24 | 2007-03-20 | Ｐｂｔ単位を含有する、減少した有機炭素排出量を有する熱可塑性樹脂 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8148489B2 (enExample) |
| EP (1) | EP1999181B2 (enExample) |
| JP (1) | JP2009531519A (enExample) |
| CA (1) | CA2641210A1 (enExample) |
| WO (1) | WO2007111890A2 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010265406A (ja) * | 2009-05-15 | 2010-11-25 | Teijin Ltd | ポリエステル組成物およびそれを用いたフィルムとその製造方法 |
| WO2013012002A1 (ja) * | 2011-07-20 | 2013-01-24 | ウィンテックポリマー株式会社 | 樹脂成形体及び自動車内装部品 |
| WO2013012004A1 (ja) * | 2011-07-20 | 2013-01-24 | ウィンテックポリマー株式会社 | 樹脂成形体及び自動車内装部品 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080006970A1 (en) | 2006-07-10 | 2008-01-10 | General Electric Company | Filtered polyetherimide polymer for use as a high heat fiber material |
| US9416465B2 (en) | 2006-07-14 | 2016-08-16 | Sabic Global Technologies B.V. | Process for making a high heat polymer fiber |
| JP5123013B2 (ja) * | 2008-03-11 | 2013-01-16 | 花王株式会社 | 縮重合系樹脂の製造方法 |
| PT3004242T (pt) | 2013-06-07 | 2017-12-11 | Basf Se | Matérias para modelação de poliéster com baixa emissão toc |
| EP2816081A1 (de) | 2013-06-17 | 2014-12-24 | Basf Se | Polyesterformmassen mit geringer TOC Emission |
| EP3218436B1 (en) | 2014-11-13 | 2022-10-05 | SABIC Global Technologies B.V. | Polyester composition and article prepared therefrom |
| WO2016188890A1 (en) | 2015-05-26 | 2016-12-01 | Sabic Global Technologies B.V. | Poly(butylene terephthalate) composition and associated article |
| EP3341429B1 (en) | 2015-08-28 | 2023-10-11 | SABIC Global Technologies B.V. | Poly(butylene terephthalate) method and associated composition and article |
| US20220250292A1 (en) | 2019-07-29 | 2022-08-11 | Lanxess Deutschland Gmbh | Polybutylene Terephthalate With Low THF Content |
| CN114174428B (zh) | 2019-07-29 | 2023-07-18 | 朗盛德国有限责任公司 | 具有低thf含量的聚对苯二甲酸丁二酯 |
| US20220267590A1 (en) * | 2019-07-29 | 2022-08-25 | Lanxess Deutschland Gmbh | Polybutylene Terephthalate With Low THF Content |
| CN120548342A (zh) * | 2022-10-26 | 2025-08-26 | 杜邦中国集团有限公司上海分公司 | 具有低voc排放的聚合物复合材料 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5141095A (enExample) * | 1974-10-03 | 1976-04-06 | Teijin Ltd | |
| JPS5578018A (en) * | 1978-12-06 | 1980-06-12 | Toray Ind Inc | Preparation of polytetramethylene terephthalate |
| JPH09132699A (ja) * | 1995-11-07 | 1997-05-20 | Kuraray Co Ltd | 熱可塑性重合体組成物 |
| JPH1030054A (ja) * | 1996-07-12 | 1998-02-03 | Mitsubishi Rayon Co Ltd | ポリエステル系樹脂組成物 |
| JPH10310638A (ja) * | 1997-05-09 | 1998-11-24 | Polyplastics Co | 熱可塑性ポリエステルの製造方法 |
| JPH1180336A (ja) * | 1997-09-12 | 1999-03-26 | Teijin Ltd | ブロック共重合ポリエステル及びその製造方法 |
| JP2005187732A (ja) * | 2003-12-26 | 2005-07-14 | Du Pont Toray Co Ltd | ポリエステルエラストマ樹脂組成物 |
| JP2006104291A (ja) * | 2004-10-04 | 2006-04-20 | Toyobo Co Ltd | マスターバッチ用熱可塑性樹脂組成物およびその成形材料の製造方法およびそれらを用いた熱可塑性樹脂組成物およびその製造方法 |
| JP2007182476A (ja) * | 2006-01-05 | 2007-07-19 | Toyobo Co Ltd | ポリエステル樹脂及びそれからなるポリエステル樹脂組成物並びにその用途 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1421972A (en) * | 1973-07-16 | 1976-01-21 | Ici Ltd | Polyester catalysts |
| CH594715A5 (enExample) | 1976-02-26 | 1978-01-31 | Ciba Geigy Ag | |
| JPH06172506A (ja) | 1992-12-03 | 1994-06-21 | Polyplastics Co | 改質ポリブチレンテレフタレート樹脂の製造方法 |
| US5789528A (en) * | 1995-12-08 | 1998-08-04 | Akzo Nobel Nv | Process for the preparation of polyesters and copolyesters |
| US6489433B2 (en) * | 2001-02-23 | 2002-12-03 | E. I. Du Pont De Nemours And Company | Metal-containing composition and process therewith |
| TWI255821B (en) | 2003-01-22 | 2006-06-01 | Asahi Kasei Chemicals Corp | Polytrimethylene terephthalate resin and method for production thereof |
| DE10359814A1 (de) † | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Dialkylphosphinsäure-Salze |
| US20050215425A1 (en) | 2004-03-26 | 2005-09-29 | Clair Jerry D S | Esterification catalyst and process therewith |
-
2007
- 2007-03-15 US US11/724,454 patent/US8148489B2/en not_active Expired - Fee Related
- 2007-03-20 CA CA002641210A patent/CA2641210A1/en not_active Abandoned
- 2007-03-20 JP JP2009502858A patent/JP2009531519A/ja active Pending
- 2007-03-20 EP EP07753559.9A patent/EP1999181B2/en not_active Ceased
- 2007-03-20 WO PCT/US2007/006940 patent/WO2007111890A2/en not_active Ceased
-
2012
- 2012-02-27 US US13/405,393 patent/US20120165443A1/en not_active Abandoned
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5141095A (enExample) * | 1974-10-03 | 1976-04-06 | Teijin Ltd | |
| JPS5578018A (en) * | 1978-12-06 | 1980-06-12 | Toray Ind Inc | Preparation of polytetramethylene terephthalate |
| JPH09132699A (ja) * | 1995-11-07 | 1997-05-20 | Kuraray Co Ltd | 熱可塑性重合体組成物 |
| JPH1030054A (ja) * | 1996-07-12 | 1998-02-03 | Mitsubishi Rayon Co Ltd | ポリエステル系樹脂組成物 |
| JPH10310638A (ja) * | 1997-05-09 | 1998-11-24 | Polyplastics Co | 熱可塑性ポリエステルの製造方法 |
| JPH1180336A (ja) * | 1997-09-12 | 1999-03-26 | Teijin Ltd | ブロック共重合ポリエステル及びその製造方法 |
| JP2005187732A (ja) * | 2003-12-26 | 2005-07-14 | Du Pont Toray Co Ltd | ポリエステルエラストマ樹脂組成物 |
| JP2006104291A (ja) * | 2004-10-04 | 2006-04-20 | Toyobo Co Ltd | マスターバッチ用熱可塑性樹脂組成物およびその成形材料の製造方法およびそれらを用いた熱可塑性樹脂組成物およびその製造方法 |
| JP2007182476A (ja) * | 2006-01-05 | 2007-07-19 | Toyobo Co Ltd | ポリエステル樹脂及びそれからなるポリエステル樹脂組成物並びにその用途 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010265406A (ja) * | 2009-05-15 | 2010-11-25 | Teijin Ltd | ポリエステル組成物およびそれを用いたフィルムとその製造方法 |
| WO2013012002A1 (ja) * | 2011-07-20 | 2013-01-24 | ウィンテックポリマー株式会社 | 樹脂成形体及び自動車内装部品 |
| WO2013012004A1 (ja) * | 2011-07-20 | 2013-01-24 | ウィンテックポリマー株式会社 | 樹脂成形体及び自動車内装部品 |
| JPWO2013012002A1 (ja) * | 2011-07-20 | 2015-02-23 | ウィンテックポリマー株式会社 | 樹脂成形体及び自動車内装部品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1999181B2 (en) | 2018-01-17 |
| EP1999181A2 (en) | 2008-12-10 |
| WO2007111890A2 (en) | 2007-10-04 |
| US20070225475A1 (en) | 2007-09-27 |
| US8148489B2 (en) | 2012-04-03 |
| CA2641210A1 (en) | 2007-10-04 |
| WO2007111890A3 (en) | 2008-05-15 |
| US20120165443A1 (en) | 2012-06-28 |
| EP1999181B1 (en) | 2014-07-16 |
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