JP2009516092A5 - - Google Patents
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- Publication number
- JP2009516092A5 JP2009516092A5 JP2008541273A JP2008541273A JP2009516092A5 JP 2009516092 A5 JP2009516092 A5 JP 2009516092A5 JP 2008541273 A JP2008541273 A JP 2008541273A JP 2008541273 A JP2008541273 A JP 2008541273A JP 2009516092 A5 JP2009516092 A5 JP 2009516092A5
- Authority
- JP
- Japan
- Prior art keywords
- glycol
- spandex
- group
- ether
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 85
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 40
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 35
- 229920002334 Spandex Polymers 0.000 claims 27
- 239000004759 spandex Substances 0.000 claims 27
- -1 pyrazolene Chemical compound 0.000 claims 18
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 16
- 239000000203 mixture Substances 0.000 claims 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 15
- 239000007795 chemical reaction product Substances 0.000 claims 15
- 230000003287 optical effect Effects 0.000 claims 13
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 10
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 10
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims 10
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 10
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims 8
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 claims 8
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims 8
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims 8
- 239000012965 benzophenone Substances 0.000 claims 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims 8
- 239000012964 benzotriazole Substances 0.000 claims 8
- 235000010290 biphenyl Nutrition 0.000 claims 8
- 239000004305 biphenyl Substances 0.000 claims 8
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims 8
- 238000000034 method Methods 0.000 claims 8
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 claims 8
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims 8
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims 8
- 235000021286 stilbenes Nutrition 0.000 claims 8
- 239000004744 fabric Substances 0.000 claims 6
- 239000000047 product Substances 0.000 claims 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 5
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims 5
- 239000004970 Chain extender Substances 0.000 claims 5
- 239000005977 Ethylene Substances 0.000 claims 5
- 239000004698 Polyethylene Substances 0.000 claims 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 5
- 239000001361 adipic acid Substances 0.000 claims 5
- 235000011037 adipic acid Nutrition 0.000 claims 5
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 5
- 125000005442 diisocyanate group Chemical group 0.000 claims 5
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims 5
- 125000002971 oxazolyl group Chemical group 0.000 claims 5
- 229920000728 polyester Polymers 0.000 claims 5
- 229920000570 polyether Polymers 0.000 claims 5
- 229920000573 polyethylene Polymers 0.000 claims 5
- 238000009987 spinning Methods 0.000 claims 5
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 claims 3
- 230000014759 maintenance of location Effects 0.000 claims 3
- 150000001412 amines Chemical class 0.000 claims 2
- 239000002981 blocking agent Substances 0.000 claims 2
- 239000006081 fluorescent whitening agent Substances 0.000 claims 2
- 239000003517 fume Substances 0.000 claims 2
- 239000004611 light stabiliser Substances 0.000 claims 2
- 238000009991 scouring Methods 0.000 claims 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 claims 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 claims 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims 1
- 238000010998 test method Methods 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US73697605P | 2005-11-14 | 2005-11-14 | |
| US60/736,976 | 2005-11-14 | ||
| PCT/US2006/044150 WO2007059109A2 (en) | 2005-11-14 | 2006-11-14 | Spandex having enhanced whiteness, and fabrics and garments comprising the same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011279647A Division JP5459641B2 (ja) | 2005-11-14 | 2011-12-21 | 向上した白色度を有するスパンデックスを含む組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009516092A JP2009516092A (ja) | 2009-04-16 |
| JP2009516092A5 true JP2009516092A5 (https=) | 2009-12-17 |
| JP5150839B2 JP5150839B2 (ja) | 2013-02-27 |
Family
ID=37946225
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008541273A Expired - Fee Related JP5150839B2 (ja) | 2005-11-14 | 2006-11-14 | 向上した白色度を有するスパンデックスならびにそれを含む布および衣料品 |
| JP2011279647A Expired - Fee Related JP5459641B2 (ja) | 2005-11-14 | 2011-12-21 | 向上した白色度を有するスパンデックスを含む組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011279647A Expired - Fee Related JP5459641B2 (ja) | 2005-11-14 | 2011-12-21 | 向上した白色度を有するスパンデックスを含む組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20070174972A1 (https=) |
| EP (2) | EP2050844B1 (https=) |
| JP (2) | JP5150839B2 (https=) |
| KR (1) | KR101367082B1 (https=) |
| CN (1) | CN101310050B (https=) |
| AT (2) | ATE478179T1 (https=) |
| BR (1) | BRPI0620512A2 (https=) |
| DE (2) | DE602006008653D1 (https=) |
| ES (2) | ES2350153T3 (https=) |
| WO (1) | WO2007059109A2 (https=) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080090945A1 (en) * | 2006-09-19 | 2008-04-17 | Invista North America S.A R.L. | Polyamide composition with improved heat stability and whiteness |
| TWI400376B (zh) * | 2010-06-25 | 2013-07-01 | Inprotex Co Ltd | Sun light can cloth |
| CN101906696B (zh) * | 2010-07-16 | 2012-09-19 | 吴国林 | 防晒光能布 |
| CN101906676B (zh) * | 2010-08-17 | 2012-06-13 | 东华大学 | 一种抗紫外老化聚对苯撑苯并二噁唑纤维及其制备方法 |
| CN104695225B (zh) * | 2013-12-04 | 2017-12-19 | 东丽纤维研究所(中国)有限公司 | 一种抗紫外纺织品 |
| CN104131361A (zh) * | 2014-08-13 | 2014-11-05 | 浙江华峰氨纶股份有限公司 | 一种荧光氨纶的制备方法 |
| JP2020056116A (ja) * | 2017-02-13 | 2020-04-09 | 旭化成株式会社 | ポリウレタン弾性繊維 |
| TWI633223B (zh) * | 2017-05-11 | 2018-08-21 | 建躍實業股份有限公司 | Sunscreen light energy cloth (2) |
| TWI633224B (zh) * | 2017-05-11 | 2018-08-21 | 建躍實業股份有限公司 | Sunscreen light energy cloth (3) |
| TWI706066B (zh) * | 2017-06-19 | 2020-10-01 | 陳承正 | 熱昇華布料之隱形螢光白染劑轉印方法 |
| KR101957439B1 (ko) * | 2018-02-20 | 2019-03-12 | 김태건 | 2,5-비스-(5’부틸-벤즈옥사졸릴)티오펜을 포함하는 다기능 섬유 소재, 및 이를 함유하는 다기능 섬유 및 마스터배치 |
| KR101960080B1 (ko) * | 2018-03-19 | 2019-03-19 | 주식회사 지클로 | 냉감 기능을 갖는 자외선 차단 섬유 및 원단 |
| CN108659189A (zh) * | 2018-03-22 | 2018-10-16 | 黔南民族师范学院 | 一种金属离子及pH响应荧光扩链剂及其制备方法和应用 |
| KR101974180B1 (ko) * | 2018-06-22 | 2019-04-30 | 주식회사 지클로 | 나일론 섬유를 포함하는 냉감 방적사 및 원단 |
| KR200496039Y1 (ko) * | 2020-06-16 | 2022-10-19 | (주)튤립코리아 | 물놀이 마스크 |
| US12104297B1 (en) | 2021-02-03 | 2024-10-01 | Global Trademarks, Inc. | Chemical resistant fabric |
| JP2024076480A (ja) * | 2022-11-25 | 2024-06-06 | 東レ・オペロンテックス株式会社 | ポリウレタン弾性繊維 |
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| NL266243A (https=) * | 1960-06-22 | 1900-01-01 | ||
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| US4962142A (en) * | 1987-12-29 | 1990-10-09 | Milliken Research Corporation | Reactive, non-yellowing triazine compounds useful as UV screening agents for polymers |
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| US5000899A (en) * | 1988-05-26 | 1991-03-19 | E. I. Du Pont De Nemours And Company | Spandex fiber with copolymer soft segment |
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| US5059647A (en) * | 1989-09-29 | 1991-10-22 | E. I. Du Pont De Nemours And Company | Oligomeric semicarbazide additives for spandex |
| US5189084A (en) * | 1989-12-21 | 1993-02-23 | Ciba-Geigy Corporation | Process for incorporating o-hydroxyphenyl-s-triazines in organic polymers |
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| DE69125095T2 (de) * | 1990-10-29 | 1997-08-21 | Cytec Tech Corp | Hydroxyaryltriazine und Tetraalkylpiperidine enthaltende synergistische UV-Absorbermischung |
| JPH04352810A (ja) * | 1991-05-29 | 1992-12-07 | Kanegafuchi Chem Ind Co Ltd | 白度に優れ光に対して安定な合成繊維 |
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| DE4330725A1 (de) * | 1993-09-10 | 1995-03-16 | Bayer Ag | Verfahren zur Herstellung von Elastanfasern durch Einspinnen einer Kombination von PDMS und ethoxyliertem PDMS |
| JP3717186B2 (ja) * | 1995-06-23 | 2005-11-16 | 旭化成せんい株式会社 | ポリウレタン弾性繊維及びその製造方法 |
| US5626960A (en) * | 1995-09-07 | 1997-05-06 | E. I. Du Pont De Nemours And Company | Spandex containing a huntite and hydromagnesite additive |
| AU7513996A (en) * | 1995-10-12 | 1997-04-30 | E.I. Du Pont De Nemours And Company | Process and apparatus for knitting fabric with non-elastic yarn and bare elastomeric yarn and sweater knit fabric construction |
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| JP2004190198A (ja) * | 2002-12-13 | 2004-07-08 | Nisshinbo Ind Inc | ポリウレタン弾性繊維 |
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| US20050239921A1 (en) * | 2004-04-27 | 2005-10-27 | Birmingham John N | Preparation of organic additive-treated, pyrogenic silica-encapsulated titanium dioxide particles |
-
2006
- 2006-11-13 US US11/559,165 patent/US20070174972A1/en not_active Abandoned
- 2006-11-14 WO PCT/US2006/044150 patent/WO2007059109A2/en not_active Ceased
- 2006-11-14 KR KR1020087011332A patent/KR101367082B1/ko not_active Expired - Fee Related
- 2006-11-14 DE DE602006008653T patent/DE602006008653D1/de active Active
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