JP2009242297A - 毛髪保護用組成物 - Google Patents
毛髪保護用組成物 Download PDFInfo
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- JP2009242297A JP2009242297A JP2008090711A JP2008090711A JP2009242297A JP 2009242297 A JP2009242297 A JP 2009242297A JP 2008090711 A JP2008090711 A JP 2008090711A JP 2008090711 A JP2008090711 A JP 2008090711A JP 2009242297 A JP2009242297 A JP 2009242297A
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- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000002253 acid Substances 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- -1 alkenyl glyceryl ether Chemical compound 0.000 claims abstract description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 39
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 24
- 235000018330 Macadamia integrifolia Nutrition 0.000 claims description 20
- 240000000912 Macadamia tetraphylla Species 0.000 claims description 20
- 235000003800 Macadamia tetraphylla Nutrition 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 17
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- 210000004761 scalp Anatomy 0.000 description 10
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
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- 230000000052 comparative effect Effects 0.000 description 4
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- DILRJUIACXKSQE-UHFFFAOYSA-N n',n'-dimethylethane-1,2-diamine Chemical compound CN(C)CCN DILRJUIACXKSQE-UHFFFAOYSA-N 0.000 description 2
- KKBOOQDFOWZSDC-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCN(CC)CC KKBOOQDFOWZSDC-UHFFFAOYSA-N 0.000 description 2
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- IFQSXNOEEPCSLW-UHFFFAOYSA-N (1-carboxy-2-sulfanylethyl)azanium;chloride Chemical compound Cl.SCC(N)C(O)=O IFQSXNOEEPCSLW-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- OOWQBDFWEXAXPB-IBGZPJMESA-N 1-O-hexadecyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCCOC[C@@H](O)CO OOWQBDFWEXAXPB-IBGZPJMESA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JAUFWPNLLLUYNV-UHFFFAOYSA-N 3-(16-methylheptadecoxy)propane-1,2-diol Chemical compound CC(C)CCCCCCCCCCCCCCCOCC(O)CO JAUFWPNLLLUYNV-UHFFFAOYSA-N 0.000 description 1
- YWBINCRSORAAMX-UHFFFAOYSA-N 3-docosoxypropane-1,2-diol Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCC(O)CO YWBINCRSORAAMX-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- ZZTCCAPMZLDHFM-UHFFFAOYSA-N ammonium thioglycolate Chemical compound [NH4+].[O-]C(=O)CS ZZTCCAPMZLDHFM-UHFFFAOYSA-N 0.000 description 1
- 229940075861 ammonium thioglycolate Drugs 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- OOWQBDFWEXAXPB-UHFFFAOYSA-N chimyl alcohol Natural products CCCCCCCCCCCCCCCCOCC(O)CO OOWQBDFWEXAXPB-UHFFFAOYSA-N 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- UDGSVBYJWHOHNN-UHFFFAOYSA-N n',n'-diethylethane-1,2-diamine Chemical compound CCN(CC)CCN UDGSVBYJWHOHNN-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 235000002316 solid fats Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
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- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
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- 229920003169 water-soluble polymer Polymers 0.000 description 1
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Abstract
【解決手段】本発明の毛髪保護用組成物は、(A)第3級アミドアミン化合物と酸を反応させて得られたアミドアミン系第3級カチオン界面活性剤、(B)モノC10-22アルキル、若しくはモノC10-22アルケニルグリセリルエーテルを含有することを特徴とする。
【選択図】なし
Description
本発明に係る毛髪保護用組成物は、第3級アミドアミン化合物と酸を反応させて得られたアミドアミン系第3級カチオン界面活性剤を使用することを特徴とする。アミドアミン系第3級カチオン界面活性剤は、頭皮に対して温和に作用するため、かゆみや炎症の原因となることがない。
で表される。
本発明に係る毛髪保護用組成物においては、上記第3級アミドアミン化合物と酸を反応させて得られたアミドアミン系第3級カチオン界面活性剤(A)とともに、モノC10-22アルキル、若しくはモノC10-22アルケニルグリセリルエーテル(B)を含有する。
表1〜3に記載の各成分を混合することにより、毛髪保護用組成物を得た。
(乳化安定性の評価方法)
試料(実施例または比較例で得られた毛髪保護用組成物)300gを、25℃、60%RH条件下で3時間静置し、相分離の有無を目視で観察し、下記基準に従って評価した。
(評価基準)
○:相分離がない
×:相分離している
一束の黒色バージンヘア(長さ:20cm、質量:40g)を二等分し、一方の毛束を基準毛束とし、他方の毛束に下記化学的処理1、及び2を施して損傷を受けさせたものを評価毛束とした。
35重量%過酸化水素水を精製水で10重量%となるように希釈したものと、28重量%アンモニア水を精製水で10重量%となるように希釈したものとを当量混合して、ブリーチ剤を調製した。
得られたブリーチ剤100mL中に、前記評価毛束を浸漬し、35℃に調温した恒温震とう器中で20分間震とうし、水洗した。
DL−システイン塩酸塩5.5重量%と50%チオグリコール酸アンモニウム液2.0重量%、80%モノエタノールアミン液4.8重量%を含有し、28%アンモニウム水でpH9.3に調整して精製水で全量を100%としたものをパーマネントウェーブ用第1剤とし、臭素酸ナトリウム6.5重量%、クエン酸0.1%、リン酸0.05%、リン酸一水素ナトリウム0.5%を含有し、精製水で全量を100%としたものをパーマネントウェーブ用第2剤とした。
ブリーチ処理後の毛束を、パーマネントウェーブ用第1剤100mL中に浸漬し、35℃の恒温震とう器中で30分間震とうし、精製水で水洗した後、自然乾燥し、さらに、パーマネントウェーブ用第2剤100mL中に浸漬し、35℃の恒温震とう器中で30分間震とうし、精製水で水洗した後、自然乾燥した。
評価点基準
基準毛束と比較して感触が向上:2点
基準毛束と比較して同等の感触:1点
基準毛束と比較して感触が劣る:0点
上記評価点の合計点数から、下記評価基準に従って、評価した。
評価基準
20点以上:◎
10点以上、20点未満:○
5点以上、10点未満:△
5点未満:×
Claims (4)
- (A)第3級アミドアミン化合物と酸を反応させて得られたアミドアミン系第3級カチオン界面活性剤、(B)モノC10-22アルキル、若しくはモノC10-22アルケニルグリセリルエーテルを含有することを特徴とする毛髪保護用組成物。
- さらに、(C)マカデミアナッツ油及び/又はマカデミアナッツ脂肪酸エチルを含有する請求項1に記載の毛髪保護用組成物。
- 酸がクエン酸及び/又はグリコール酸である請求項1又は2に記載の毛髪保護用組成物。
- 55〜80℃に加温した状態で、(A)第3級アミドアミン化合物と酸とを反応させて得られたアミドアミン系第3級カチオン界面活性剤を含む組成物に(B)モノC10-22アルキル、若しくはモノC10-22アルケニルグリセリルエーテルを加えて乳化する工程を経て得られる請求項1〜3の何れかの項に記載の毛髪保護用組成物。
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JP2008090711A JP4945830B2 (ja) | 2008-03-31 | 2008-03-31 | 毛髪保護用組成物 |
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JP2009242297A true JP2009242297A (ja) | 2009-10-22 |
JP4945830B2 JP4945830B2 (ja) | 2012-06-06 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011121899A (ja) * | 2009-12-10 | 2011-06-23 | Milbon Co Ltd | 毛髪処理剤 |
JP2014101308A (ja) * | 2012-11-20 | 2014-06-05 | Milbon Co Ltd | 毛髪用処理剤 |
WO2017127344A1 (en) * | 2016-01-20 | 2017-07-27 | The Procter & Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
US9993404B2 (en) | 2015-01-15 | 2018-06-12 | The Procter & Gamble Company | Translucent hair conditioning composition |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57120510A (en) * | 1981-01-19 | 1982-07-27 | Kao Corp | Hair cosmetic |
JPS62255408A (ja) * | 1986-04-25 | 1987-11-07 | Kao Corp | 毛髪化粧料 |
JPH03181412A (ja) * | 1989-12-11 | 1991-08-07 | Kao Corp | 角質繊維処理剤組成物 |
JPH05271035A (ja) * | 1992-03-26 | 1993-10-19 | Shiseido Co Ltd | 毛髪処理剤組成物 |
JPH06345617A (ja) * | 1993-06-07 | 1994-12-20 | Nippon Saafuakutanto Kogyo Kk | 化粧料および外用剤 |
JPH1179947A (ja) * | 1997-09-04 | 1999-03-23 | Toho Chem Ind Co Ltd | 毛髪用組成物 |
JP2003113045A (ja) * | 2001-09-28 | 2003-04-18 | Toho Chem Ind Co Ltd | 毛髪用組成物 |
JP2007186474A (ja) * | 2006-01-16 | 2007-07-26 | Kao Corp | 毛髪化粧料 |
-
2008
- 2008-03-31 JP JP2008090711A patent/JP4945830B2/ja active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57120510A (en) * | 1981-01-19 | 1982-07-27 | Kao Corp | Hair cosmetic |
JPS62255408A (ja) * | 1986-04-25 | 1987-11-07 | Kao Corp | 毛髪化粧料 |
JPH03181412A (ja) * | 1989-12-11 | 1991-08-07 | Kao Corp | 角質繊維処理剤組成物 |
JPH05271035A (ja) * | 1992-03-26 | 1993-10-19 | Shiseido Co Ltd | 毛髪処理剤組成物 |
JPH06345617A (ja) * | 1993-06-07 | 1994-12-20 | Nippon Saafuakutanto Kogyo Kk | 化粧料および外用剤 |
JPH1179947A (ja) * | 1997-09-04 | 1999-03-23 | Toho Chem Ind Co Ltd | 毛髪用組成物 |
JP2003113045A (ja) * | 2001-09-28 | 2003-04-18 | Toho Chem Ind Co Ltd | 毛髪用組成物 |
JP2007186474A (ja) * | 2006-01-16 | 2007-07-26 | Kao Corp | 毛髪化粧料 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011121899A (ja) * | 2009-12-10 | 2011-06-23 | Milbon Co Ltd | 毛髪処理剤 |
JP2014101308A (ja) * | 2012-11-20 | 2014-06-05 | Milbon Co Ltd | 毛髪用処理剤 |
WO2017127344A1 (en) * | 2016-01-20 | 2017-07-27 | The Procter & Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
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