JP2008528250A - 一酸化炭素の選択メタン化用の触媒活性組成物及び、該組成物を製造する方法 - Google Patents
一酸化炭素の選択メタン化用の触媒活性組成物及び、該組成物を製造する方法 Download PDFInfo
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- JP2008528250A JP2008528250A JP2007551673A JP2007551673A JP2008528250A JP 2008528250 A JP2008528250 A JP 2008528250A JP 2007551673 A JP2007551673 A JP 2007551673A JP 2007551673 A JP2007551673 A JP 2007551673A JP 2008528250 A JP2008528250 A JP 2008528250A
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- catalytically active
- catalyst
- methanation
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- carbon monoxide
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- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 17
- 239000001257 hydrogen Substances 0.000 claims abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 12
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 9
- 239000000446 fuel Substances 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 7
- 239000010948 rhodium Substances 0.000 claims abstract description 7
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 5
- 239000010941 cobalt Substances 0.000 claims abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 239000012876 carrier material Substances 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims 2
- DOMHJQJKOPZSOM-UHFFFAOYSA-N formyloxycarbonyl formate Chemical compound O=COC(=O)OC=O DOMHJQJKOPZSOM-UHFFFAOYSA-N 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 55
- 238000006243 chemical reaction Methods 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
- 239000007789 gas Substances 0.000 description 17
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 241000282326 Felis catus Species 0.000 description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 229910001347 Stellite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000013386 optimize process Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002296 pyrolytic carbon Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- VITRLXDSBBVNCZ-UHFFFAOYSA-K trichloroiron;hydrate Chemical compound O.Cl[Fe](Cl)Cl VITRLXDSBBVNCZ-UHFFFAOYSA-K 0.000 description 1
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical Kinetics & Catalysis (AREA)
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- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005003311A DE102005003311A1 (de) | 2005-01-24 | 2005-01-24 | Katalytisch aktive Zusammensetzung zur selektiven Methanisierung von Kohlenmonoxid und Verfahren zu deren Herstellung |
| PCT/EP2006/050312 WO2006077236A1 (de) | 2005-01-24 | 2006-01-19 | Katalytisch aktive zusammensetzung zur selektiven methanisierung von kohlenmonoxid und verfahren zu deren herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008528250A true JP2008528250A (ja) | 2008-07-31 |
| JP2008528250A5 JP2008528250A5 (enExample) | 2008-10-30 |
Family
ID=36284299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007551673A Pending JP2008528250A (ja) | 2005-01-24 | 2006-01-19 | 一酸化炭素の選択メタン化用の触媒活性組成物及び、該組成物を製造する方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7560496B2 (enExample) |
| EP (1) | EP1843844A1 (enExample) |
| JP (1) | JP2008528250A (enExample) |
| CA (1) | CA2595466A1 (enExample) |
| DE (1) | DE102005003311A1 (enExample) |
| WO (1) | WO2006077236A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010520807A (ja) * | 2007-03-13 | 2010-06-17 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | 一酸化炭素のメタン化のための触媒としての金属ドープ酸化ニッケル |
| JP2011212580A (ja) * | 2010-03-31 | 2011-10-27 | Osaka Gas Co Ltd | 触媒の活性化の程度を判定する方法 |
| WO2013077165A1 (ja) * | 2011-11-25 | 2013-05-30 | 国立大学法人群馬大学 | 金属担持用担体、金属担持触媒、メタネーション反応装置及びこれらに関する方法 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2319542C1 (ru) * | 2006-11-15 | 2008-03-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Катализатор, способ его приготовления и способы очистки водородсодержащего газа от монооксида углерода |
| EP2336083A1 (en) * | 2009-12-17 | 2011-06-22 | Topsøe Fuel Cell A/S | Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas |
| DE102011085165A1 (de) | 2011-10-25 | 2013-04-25 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat |
| DE102011121930A1 (de) * | 2011-12-22 | 2013-06-27 | Solarfuel Gmbh | Methanisierungsreaktor |
| EP3072589A1 (de) | 2015-03-26 | 2016-09-28 | Basf Se | Katalysator und Verfahren zur selektiven Methanisierung von Kohlenmonoxid |
| MX2018004214A (es) * | 2015-10-05 | 2018-05-17 | Basf Se | Metodo para la produccion de catalizadores portadores de rutenio/hierro/carbono. |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5248122B2 (enExample) * | 1975-07-30 | 1977-12-07 | ||
| JPH0393602A (ja) * | 1989-09-07 | 1991-04-18 | Asahi Chem Ind Co Ltd | 一酸化炭素の選択的除去方法 |
| JP2003245555A (ja) * | 2001-12-07 | 2003-09-02 | Basf Ag | 炭素に担持されたルテニウム/鉄触媒の製造 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3424808A (en) * | 1967-10-03 | 1969-01-28 | Foster Grant Co Inc | Dehydrogenation and methanation catalyst and process |
| US3615164A (en) | 1968-01-10 | 1971-10-26 | Bernard S Baker | Process for selective removal by methanation of carbon monoxide from a mixture of gases containing carbon dioxide |
| US3847963A (en) * | 1973-02-01 | 1974-11-12 | Ventron Corp | Methanation processes |
| DE3130805A1 (de) * | 1981-08-04 | 1983-02-24 | Basf Ag, 6700 Ludwigshafen | Neue ruthenium/kohle-hydrierkatalysatoren, deren herstellung und verwendung zur selektiven hydrierung von ungesaettigten carbonylverbindungen |
| GB9609918D0 (en) | 1996-05-11 | 1996-07-17 | Johnson Matthey Plc | Hydrogen purification |
| GB9620287D0 (en) | 1996-09-28 | 1996-11-13 | Johnson Matthey Plc | Carbon monoxide removal |
| CA2362470A1 (en) | 1999-03-05 | 2000-09-14 | Osaka Gas Co., Ltd. | System for removing carbon monoxide and method for removing carbon monoxide |
| JP4460126B2 (ja) | 2000-08-31 | 2010-05-12 | 出光興産株式会社 | 水素含有ガス中の一酸化炭素の除去方法 |
| EP1246286A1 (de) | 2001-03-31 | 2002-10-02 | OMG AG & Co. KG | Kombinierte Kraft- Wärmeanlage mit Gaserzeugungssystem und Brennstoffzellen sowie Verfahren zu ihrem Betrieb |
| JP2004097859A (ja) | 2002-09-04 | 2004-04-02 | Tokyo Inst Of Technol | 一酸化炭素を除去するための触媒及び方法 |
| US7118717B2 (en) * | 2002-09-06 | 2006-10-10 | Engelhard Corporation | Simplified article for carbon monoxide removal |
-
2005
- 2005-01-24 DE DE102005003311A patent/DE102005003311A1/de not_active Withdrawn
-
2006
- 2006-01-19 EP EP06707761A patent/EP1843844A1/de not_active Withdrawn
- 2006-01-19 JP JP2007551673A patent/JP2008528250A/ja active Pending
- 2006-01-19 WO PCT/EP2006/050312 patent/WO2006077236A1/de not_active Ceased
- 2006-01-19 CA CA002595466A patent/CA2595466A1/en not_active Abandoned
- 2006-01-19 US US11/814,581 patent/US7560496B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5248122B2 (enExample) * | 1975-07-30 | 1977-12-07 | ||
| JPH0393602A (ja) * | 1989-09-07 | 1991-04-18 | Asahi Chem Ind Co Ltd | 一酸化炭素の選択的除去方法 |
| JP2003245555A (ja) * | 2001-12-07 | 2003-09-02 | Basf Ag | 炭素に担持されたルテニウム/鉄触媒の製造 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010520807A (ja) * | 2007-03-13 | 2010-06-17 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | 一酸化炭素のメタン化のための触媒としての金属ドープ酸化ニッケル |
| JP2011212580A (ja) * | 2010-03-31 | 2011-10-27 | Osaka Gas Co Ltd | 触媒の活性化の程度を判定する方法 |
| WO2013077165A1 (ja) * | 2011-11-25 | 2013-05-30 | 国立大学法人群馬大学 | 金属担持用担体、金属担持触媒、メタネーション反応装置及びこれらに関する方法 |
| JP2013111496A (ja) * | 2011-11-25 | 2013-06-10 | Gunma Univ | 金属担持用担体、金属担持触媒、メタネーション反応装置及びこれらに関する方法 |
| KR20140102192A (ko) * | 2011-11-25 | 2014-08-21 | 고쿠리츠다이가쿠호진 군마다이가쿠 | 금속 담지용 담체, 금속-담지 촉매, 메탄화 반응 장치 및 이들에 관한 방법 |
| US10005701B2 (en) | 2011-11-25 | 2018-06-26 | National University Corporation Gunma University | Support for supporting metals, metal-supported catalyst, methanation reaction apparatus, and method relating to these |
| KR102040342B1 (ko) * | 2011-11-25 | 2019-11-04 | 고쿠리츠다이가쿠호진 군마다이가쿠 | 금속 담지용 담체, 금속-담지 촉매, 메탄화 반응 장치 및 이들에 관한 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1843844A1 (de) | 2007-10-17 |
| US7560496B2 (en) | 2009-07-14 |
| CA2595466A1 (en) | 2006-07-27 |
| WO2006077236A1 (de) | 2006-07-27 |
| US20080139676A1 (en) | 2008-06-12 |
| DE102005003311A1 (de) | 2006-07-27 |
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